US3763915A - Evaporative treatment of liquids by submerged combustion - Google Patents

Evaporative treatment of liquids by submerged combustion Download PDF

Info

Publication number
US3763915A
US3763915A US00164814A US3763915DA US3763915A US 3763915 A US3763915 A US 3763915A US 00164814 A US00164814 A US 00164814A US 3763915D A US3763915D A US 3763915DA US 3763915 A US3763915 A US 3763915A
Authority
US
United States
Prior art keywords
chamber
roof
bath
tank
liquor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00164814A
Other languages
English (en)
Inventor
I Perry
B Watson
J Lagerche
T Goding
G Moffett
G Denman
N Irvine
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Copper Refineries Pty Ltd
Original Assignee
Copper Refineries Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Copper Refineries Pty Ltd filed Critical Copper Refineries Pty Ltd
Application granted granted Critical
Publication of US3763915A publication Critical patent/US3763915A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/14Evaporating with heated gases or vapours or liquids in contact with the liquid
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00Concentrating evaporators
    • Y10S159/13Scale

Definitions

  • SHEET 2UP 2 EEEQZS EVAPORATIVE TREATMENT OF LIQUIDS BY SUBMERGED COMBUSTION This invention relates to the evaporative treatment of liquids to concentrate them and remove matters dissolved therein. Such treatment may be carried out merely to concentrate, purify or re-condition the liquid, or merely to recover the dissolved matter, or with both of those ends combinedly in view.
  • the invention is applicable generally to the treatment of liquids for the purposes indicated. However, it is presently expected that the invention will be particularly advantageous in the treatment of electrolyte as used in the electrolytic refining of copper; to recondition the electrolyte for re-use and to recover from it matters of commercial importance which accumulate in it as a result of its sustained use in the copper refining process. Because of this expectation the invention will be further described herein primarily in terms of that particular use but is not to be regarded as restricted thereto.
  • the most commonly used electrolyte is a solution of sulphuric acid and copper sulphate and the copper anodes usually contain nickel as an impurity at levels less than 1 percent.
  • Ni content is, of course, freed during the electrolytic migration, but if it is not removed from the electrolyte it will accumulate and increasingly contaminate the deposited cathode copper by occlusion of electrolyte during deposition. It is thus necessary for the Ni concentration in the electrolyte to be kept sufficiently low to ensure no more than an acceptable proportion (for example, 2 ppm) of Ni in the cathode copper.
  • the purification of an electrolyte comprises two stages.
  • the first stage accomplishes the removal of copper and arsenic, electrolytically or otherwise, and thus prepares the feed liquor for the second stage, viz. the concentration process to which this invention applies.
  • This stage two feed liquor consists of a solution of sulphuric acid, nickel sulphate, iron sulphate, calcium sulphate and small proportions of other materials.
  • purification plant may be on a relatively small scale compared with the prior art. In an experimental practicing of this plant it was found that a satisfactory alien matter concentration was not exceeded, with the continuous withdrawal of 3 gals/min. from a total refinery pump output of 1,620 gals/min.
  • the purification circuit is, in effect, a subcircuit in parallel with the refining circuit; the purification circuit has a liquid intake pipe which branches from the output pipe of the refinery pump and a discharge pipe by which finally purified electrolyte is fed back into the intake pipe leading back to the refining circuit pump.
  • any second stage purifica tion in essence consists in heating the electrolyte so to concentrate the liquid by driving off excess water and to bring the salts dissolved in the electrolyte to a state of saturated solution so that upon subsequent cooling a satisfactory removal of the dissolved salts is effected.
  • the crystals are precipitated partly in the evaporator and partly by subsequent cooling and thus may be removed and the concentrated liquid, freed of at least its most damaging impurities, can then be returned to the refining circuit for re-use.
  • One commonly used second stage purification incorporates the use of an ordinary tubular heat exchanger applying heat by means of steam or heated gases. This is satisfactory up to a point, but it rapidly becomes inefficient through accumulation of solid encrustations, in that keeping one of the heat exchange surfaces (that having liquid under treatment in contact with it) clean is a major task which virtually prohibits continuous operation.
  • a further advantage due to the present invention is that it permits second stage purification to be carried out continuously during the process of electrolytic refining and the first stage purification of the electrolyte involved in the refining process.
  • the invention consists in a method of evaporatively concentrating a liquid and removing dissolved matter therefrom, comprising the steps of: burning fuel in an open-bottomed, otherwise closed, chamber whereof the bottom rim is below the surface of a bath of said liquid so that the products of combustion are discharged directly into the liquid, cooling the interior surfaces of said chamber by application of cooling media to the chamber exterior, flushing said interior surfaces sufficiently to clear therefrom solid particles tending to accumulate thereon, and removing solid matter precipitated in said bath.
  • FIG. 1 shows a plan view of a combustion chamber
  • FIG. 2 shows, in front elevation and partly in section, a view along the line 2--2 of FIG. 1 and,
  • FIG. 3 shows, in side elevation, a tank containing a bath of liquor in which three of said combustion chambers are partially submerged.
  • a combustion chamber 1 surrounded by a jacket 2 termimates in a skirt 3 in which a plurality of slots such as 4 is formed.
  • a mounting flange 6, fixed to the outer wall of said water jacket 2, permits the chamber 1 to be mounted with respect to a tank hereinafter described.
  • Above the roof7 of the chamber is mounted anair manifold 8 from which a refractory spacer 9 separates the burner tile 10 which communicates with an oil burner 11.
  • Beneath the roof 7, a steam spray ring 12 is mounted with a plurality of steam nozzles 13 depending therefrom.
  • Said chamber is adapted to be partially immersed in said bath so that liquor therein rises to the level 14.
  • the medium used to flush the interior surfaces such as 15 of the chamber 1 may be water directly sprayed on to those surfaces, but is preferably steam emitted from the nozzles 13 which by condensation on the cooled inner surfaces of the chamber provides a filmlike stream of water which runs down the walls and acts as a solvent or parting layer which prevents solids from building up as encrustations on that surface.
  • flush water in any form, to the bath of liquid under treatment increases the amount of water to be driven off so that the required level of concentration of the liquid is maintained. Therefore, it is preferable for the flush medium to be applied sparingly, for example, by short intermittent blasts of steam directed towards the walls of the chamber.
  • a presently preferred apparatus for carrying out the invention comprises the chamber 1 having a cylindrical wall as shown, with its open bottom terminating the skirt 3 being adapted to dip into a bath of the liquid to be subjected to second stage purification.
  • the oil burner 11 employs any suitable liquid fuel such as diesel distillate injected via suitable nozzles thereinto together with the air necessary for its combustion. Because the fuel is liquid, it may be burnt under controlled conditions so that the products of combustion will be virtually oxygen and ash free.
  • the jacket 2 is supplied with a coolant such as water circulated continuously therein by means of a suitable pump which derives the water from a cooling tower or the like.
  • the circulation rate of the cooling water is preferably such as will maintain the chamber walls at a temperature such that the effluent temperature of the cooling water does not exceed C.
  • the effluent heat of the cooling water may be advantageously employed by using it in a heat exchanger as pre-heating counter current to the liquor leaving the first stage of purification on its way to the second stage.
  • the roof of the combustion chamber may be water cooled in much the same manner as just described with reference to the chamber walls, but, for preference, roof cooling is effected by use of the manifold 8 as a pre-heating feed duct for the air necessary for fuel combustion in the burner chamber.
  • Discharge of steam within the chamber may be carried out in several different ways, but for preference, the tubular steam spray ring 12 is mounted in the chamber 1 immediately below the roof 7 thereof.
  • the outside diameter of this ring is preferably such as to be almost equal to the internal diameter of the chamber.
  • Steam is fed to the ring from any conventional source of supply and the ring is furnished with a plurality of nozzles 13 by which the steam is directed onto the walls and roof of the chamber, the nozzles being sufficiently closely spaced as will ensure that the condensate curtain formed on the inner wall of the chamber is circumferentially continuous before it reaches the bottom rim of the container which dips into the liquor to be treated.
  • the preferred steam supply is saturated steam at a nozzle pressure of about lbs/ins.
  • the preferred bath has a liquid capacity equal to 450 gallons, and a feed liquor input of about 3 gals. per min.
  • the internal dimensions of the chamber 1 are preferably about 20 inches in height and 26 inches in diameter are under these conditions a suitable rate of steam infeed is intermittently discharged into the chamber in the form of short bursts each of about 1 min. duration alternating with inactive intervals of 2 hours duration.
  • the skirt 3 of the chamber is preferably multitudinously slotted or of sawtooth shape so that the combustion gases will enter the bath as a large number of small streams, thus to reduce what might otherwise be excessive bath turbulence, and for preference the submerged skirt is surrounded by an open bottom annular duct or inverted channel 5 having a circumferential outer wall which is similarly slotted or sawtoothed to provide a still greater multiciplicity of outlets through which combustion gases are discharged into the bath liquor.
  • the operation is preferably conducted continuously at a constant concentration in the bath so that the rate of addition of feed liquor just balances the rate of evaporation of water plus the runoff of concentrated liquor. In practice this is preferably achieved by continuous addition of feed liquor and intermittent discharge of concentrated liquor so that the level in the bath alternates between upper and lower limits. In the preferred method of operation, the concentration of sulphuric acid is maintained above that which will corrosively attack the steel components.
  • a tank 16 contains a bath 17 of liquor which rises to the level 14.
  • This tank receives at a level near its roof via the inlet 18 the liquor to be purified, and at its lower or floor level has a concentrated liquor take-off pipe 19.
  • Means may be provided for ensuring that the level of concentrated liquor in the bath is maintained substantially constant and that the level is maintained above that at which the combustion gases are discharged into it.
  • the tank 16 includes a roof plate 21 to which a plurality of (in this case, three) chambers such as 1 are attached by means of the mounting flange 6. Each said chamber is fitted through an opening in the roof 2! which is equipped with a flue or the like for taking off the exhaust gases after they have bubbled their way through the bath 17.
  • Apparatus for evaporatively concentrating a liquid to recover matters dissolved therein comprising:
  • a tank to contain the liquid to be concentrated b. an open-bottom chamber, consisting of a side wall and a roof, mounted on said tank so that its open bottom is submerged below the surface of the liquid in said tank,
  • a fuel burner mounted on said roof and arranged to direct the products of combustion produced into 7 said chamber through an aperture in said roof
  • said bath is in the form of a tank which receives liquor to be purified near the level of the roof of said tank and which possesses a concentrated liquor take-off pipe at or near the floor level of said tank, and means which maintain the level of concentration liquor substantially constant whereby said last-mentioned level is maintained above said chamber open bottom at which said combustion gases are discharged, said tank including a roof plate which separates a plurality of said chambers, and said roof having an opening therein constituting an intake end of a flue adapted to take off exhaust gases after the latter have bubbled their way through the bath liquor.
  • said means for injecting fuel and air defines a refractory duct, said duct being furnished with nozzles for injection thereinto of fuel and air.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Paper (AREA)
  • Electrolytic Production Of Metals (AREA)
US00164814A 1970-07-22 1971-07-21 Evaporative treatment of liquids by submerged combustion Expired - Lifetime US3763915A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AU192370 1970-07-22

Publications (1)

Publication Number Publication Date
US3763915A true US3763915A (en) 1973-10-09

Family

ID=3692420

Family Applications (1)

Application Number Title Priority Date Filing Date
US00164814A Expired - Lifetime US3763915A (en) 1970-07-22 1971-07-21 Evaporative treatment of liquids by submerged combustion

Country Status (8)

Country Link
US (1) US3763915A (ja)
JP (1) JPS5140547B1 (ja)
BE (1) BE770334A (ja)
CA (1) CA943453A (ja)
DE (1) DE2136686A1 (ja)
FR (1) FR2103215A5 (ja)
GB (1) GB1337313A (ja)
SE (1) SE387861B (ja)

Cited By (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6736129B1 (en) 2001-03-12 2004-05-18 David G. Smith Submerged combustion snow melting apparatus
US7214290B2 (en) 2002-09-04 2007-05-08 Shaw Liquid Solutions Llc. Treatment of spent caustic refinery effluents
US20080110417A1 (en) * 2006-11-13 2008-05-15 Smith David G Submerged combustion disposal of produced water
US8707740B2 (en) 2011-10-07 2014-04-29 Johns Manville Submerged combustion glass manufacturing systems and methods
US8875544B2 (en) 2011-10-07 2014-11-04 Johns Manville Burner apparatus, submerged combustion melters including the burner, and methods of use
US8973405B2 (en) 2010-06-17 2015-03-10 Johns Manville Apparatus, systems and methods for reducing foaming downstream of a submerged combustion melter producing molten glass
US8973400B2 (en) 2010-06-17 2015-03-10 Johns Manville Methods of using a submerged combustion melter to produce glass products
US8991215B2 (en) 2010-06-17 2015-03-31 Johns Manville Methods and systems for controlling bubble size and bubble decay rate in foamed glass produced by a submerged combustion melter
US8997525B2 (en) 2010-06-17 2015-04-07 Johns Manville Systems and methods for making foamed glass using submerged combustion
US9021838B2 (en) 2010-06-17 2015-05-05 Johns Manville Systems and methods for glass manufacturing
US9096452B2 (en) 2010-06-17 2015-08-04 Johns Manville Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter
ES2551802A1 (es) * 2014-05-23 2015-11-23 Valoriza Servicios Medioambientales, S.A. Sistema y procedimiento para adsorción por evaporación directa de lixiviados efluentes de un vertedero de residuos sólidos urbanos
US9492831B2 (en) 2010-06-17 2016-11-15 Johns Manville Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter
US9533905B2 (en) 2012-10-03 2017-01-03 Johns Manville Submerged combustion melters having an extended treatment zone and methods of producing molten glass
US9676644B2 (en) 2012-11-29 2017-06-13 Johns Manville Methods and systems for making well-fined glass using submerged combustion
USRE46462E1 (en) 2011-10-07 2017-07-04 Johns Manville Apparatus, systems and methods for conditioning molten glass
US9731990B2 (en) 2013-05-30 2017-08-15 Johns Manville Submerged combustion glass melting systems and methods of use
US9751792B2 (en) 2015-08-12 2017-09-05 Johns Manville Post-manufacturing processes for submerged combustion burner
US9777922B2 (en) 2013-05-22 2017-10-03 Johns Mansville Submerged combustion burners and melters, and methods of use
US9776903B2 (en) 2010-06-17 2017-10-03 Johns Manville Apparatus, systems and methods for processing molten glass
US9815726B2 (en) 2015-09-03 2017-11-14 Johns Manville Apparatus, systems, and methods for pre-heating feedstock to a melter using melter exhaust
US9926219B2 (en) 2012-07-03 2018-03-27 Johns Manville Process of using a submerged combustion melter to produce hollow glass fiber or solid glass fiber having entrained bubbles, and burners and systems to make such fibers
US9982884B2 (en) 2015-09-15 2018-05-29 Johns Manville Methods of melting feedstock using a submerged combustion melter
USRE46896E1 (en) 2010-09-23 2018-06-19 Johns Manville Methods and apparatus for recycling glass products using submerged combustion
US10041666B2 (en) 2015-08-27 2018-08-07 Johns Manville Burner panels including dry-tip burners, submerged combustion melters, and methods
US10081563B2 (en) 2015-09-23 2018-09-25 Johns Manville Systems and methods for mechanically binding loose scrap
US10131563B2 (en) 2013-05-22 2018-11-20 Johns Manville Submerged combustion burners
US10138151B2 (en) 2013-05-22 2018-11-27 Johns Manville Submerged combustion burners and melters, and methods of use
US10144666B2 (en) 2015-10-20 2018-12-04 Johns Manville Processing organics and inorganics in a submerged combustion melter
US10183884B2 (en) 2013-05-30 2019-01-22 Johns Manville Submerged combustion burners, submerged combustion glass melters including the burners, and methods of use
US10196294B2 (en) 2016-09-07 2019-02-05 Johns Manville Submerged combustion melters, wall structures or panels of same, and methods of using same
US10233105B2 (en) 2016-10-14 2019-03-19 Johns Manville Submerged combustion melters and methods of feeding particulate material into such melters
US10246362B2 (en) 2016-06-22 2019-04-02 Johns Manville Effective discharge of exhaust from submerged combustion melters and methods
US10301208B2 (en) 2016-08-25 2019-05-28 Johns Manville Continuous flow submerged combustion melter cooling wall panels, submerged combustion melters, and methods of using same
US10322960B2 (en) 2010-06-17 2019-06-18 Johns Manville Controlling foam in apparatus downstream of a melter by adjustment of alkali oxide content in the melter
US10337732B2 (en) 2016-08-25 2019-07-02 Johns Manville Consumable tip burners, submerged combustion melters including same, and methods
US10654740B2 (en) 2013-05-22 2020-05-19 Johns Manville Submerged combustion burners, melters, and methods of use
US10670261B2 (en) 2015-08-27 2020-06-02 Johns Manville Burner panels, submerged combustion melters, and methods
US10837705B2 (en) 2015-09-16 2020-11-17 Johns Manville Change-out system for submerged combustion melting burner
US10858278B2 (en) 2013-07-18 2020-12-08 Johns Manville Combustion burner
US11142476B2 (en) 2013-05-22 2021-10-12 Johns Manville Burner for submerged combustion melting
US11613488B2 (en) 2012-10-03 2023-03-28 Johns Manville Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52131244U (ja) * 1976-03-31 1977-10-05

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB410652A (en) * 1932-08-12 1934-05-24 Chem Ind Basel Process for evaporating, concentrating and distilling
US2373519A (en) * 1940-06-07 1945-04-10 Semet Solvay Eng Corp Wash box
US2590905A (en) * 1947-10-15 1952-04-01 Canada Paper Company Apparatus for concentrating residual pulp liquor by direct contact with flue gases
US2640761A (en) * 1949-11-25 1953-06-02 West End Chemical Company Evaporating apparatus
US2867972A (en) * 1951-12-05 1959-01-13 Anaconda Co Submerged flame evaporator
US2980179A (en) * 1954-06-25 1961-04-18 Babcock & Wilcox Co Cyclone evaporator for residual liquor
US3057700A (en) * 1959-10-12 1962-10-09 Chemical Construction Corp Phosphoric acid process
US3088812A (en) * 1959-02-12 1963-05-07 Thermal Res & Engineering Corp Submerged exhaust combustion unit
US3193350A (en) * 1960-03-05 1965-07-06 Knapsack Ag Method of producing higher polyphosphoric acids
US3212559A (en) * 1962-11-29 1965-10-19 Freeport Sulphur Co Method of concentrating liquidcontaining mixtures

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB410652A (en) * 1932-08-12 1934-05-24 Chem Ind Basel Process for evaporating, concentrating and distilling
US2373519A (en) * 1940-06-07 1945-04-10 Semet Solvay Eng Corp Wash box
US2590905A (en) * 1947-10-15 1952-04-01 Canada Paper Company Apparatus for concentrating residual pulp liquor by direct contact with flue gases
US2640761A (en) * 1949-11-25 1953-06-02 West End Chemical Company Evaporating apparatus
US2867972A (en) * 1951-12-05 1959-01-13 Anaconda Co Submerged flame evaporator
US2980179A (en) * 1954-06-25 1961-04-18 Babcock & Wilcox Co Cyclone evaporator for residual liquor
US3088812A (en) * 1959-02-12 1963-05-07 Thermal Res & Engineering Corp Submerged exhaust combustion unit
US3057700A (en) * 1959-10-12 1962-10-09 Chemical Construction Corp Phosphoric acid process
US3193350A (en) * 1960-03-05 1965-07-06 Knapsack Ag Method of producing higher polyphosphoric acids
US3212559A (en) * 1962-11-29 1965-10-19 Freeport Sulphur Co Method of concentrating liquidcontaining mixtures

Cited By (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6736129B1 (en) 2001-03-12 2004-05-18 David G. Smith Submerged combustion snow melting apparatus
US7214290B2 (en) 2002-09-04 2007-05-08 Shaw Liquid Solutions Llc. Treatment of spent caustic refinery effluents
US20080110417A1 (en) * 2006-11-13 2008-05-15 Smith David G Submerged combustion disposal of produced water
US7845314B2 (en) 2006-11-13 2010-12-07 Smith David G Submerged combustion disposal of produced water
US9481593B2 (en) 2010-06-17 2016-11-01 Johns Manville Methods of using a submerged combustion melter to produce glass products
US10322960B2 (en) 2010-06-17 2019-06-18 Johns Manville Controlling foam in apparatus downstream of a melter by adjustment of alkali oxide content in the melter
US8973405B2 (en) 2010-06-17 2015-03-10 Johns Manville Apparatus, systems and methods for reducing foaming downstream of a submerged combustion melter producing molten glass
US8973400B2 (en) 2010-06-17 2015-03-10 Johns Manville Methods of using a submerged combustion melter to produce glass products
US8991215B2 (en) 2010-06-17 2015-03-31 Johns Manville Methods and systems for controlling bubble size and bubble decay rate in foamed glass produced by a submerged combustion melter
US8997525B2 (en) 2010-06-17 2015-04-07 Johns Manville Systems and methods for making foamed glass using submerged combustion
US9021838B2 (en) 2010-06-17 2015-05-05 Johns Manville Systems and methods for glass manufacturing
US9096452B2 (en) 2010-06-17 2015-08-04 Johns Manville Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter
US10472268B2 (en) 2010-06-17 2019-11-12 Johns Manville Systems and methods for glass manufacturing
US9481592B2 (en) 2010-06-17 2016-11-01 Johns Manville Submerged combustion glass manufacturing system and method
US9840430B2 (en) 2010-06-17 2017-12-12 Johns Manville Methods and systems for controlling bubble size and bubble decay rate in foamed glass produced by a submerged combustion melter
US9492831B2 (en) 2010-06-17 2016-11-15 Johns Manville Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter
US9533906B2 (en) 2010-06-17 2017-01-03 Johns Manville Burner apparatus, submerged combustion melters including the burner, and methods of use
US9776903B2 (en) 2010-06-17 2017-10-03 Johns Manville Apparatus, systems and methods for processing molten glass
US9573831B2 (en) 2010-06-17 2017-02-21 Johns Manville Systems and methods for glass manufacturing
US9676652B2 (en) 2010-06-17 2017-06-13 Johns Manville Systems and methods for making foamed glass using submerged combustion
US10081565B2 (en) 2010-06-17 2018-09-25 Johns Manville Systems and methods for making foamed glass using submerged combustion
USRE46896E1 (en) 2010-09-23 2018-06-19 Johns Manville Methods and apparatus for recycling glass products using submerged combustion
US9580344B2 (en) 2011-10-07 2017-02-28 Johns Manville Burner apparatus, submerged combustion melters including the burner, and methods of use
USRE46462E1 (en) 2011-10-07 2017-07-04 Johns Manville Apparatus, systems and methods for conditioning molten glass
US9957184B2 (en) 2011-10-07 2018-05-01 Johns Manville Submerged combustion glass manufacturing system and method
US8707740B2 (en) 2011-10-07 2014-04-29 Johns Manville Submerged combustion glass manufacturing systems and methods
US9776901B2 (en) 2011-10-07 2017-10-03 Johns Manville Submerged combustion glass manufacturing system and method
US8875544B2 (en) 2011-10-07 2014-11-04 Johns Manville Burner apparatus, submerged combustion melters including the burner, and methods of use
US9650277B2 (en) 2012-04-27 2017-05-16 Johns Manville Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter
US9926219B2 (en) 2012-07-03 2018-03-27 Johns Manville Process of using a submerged combustion melter to produce hollow glass fiber or solid glass fiber having entrained bubbles, and burners and systems to make such fibers
US11233484B2 (en) 2012-07-03 2022-01-25 Johns Manville Process of using a submerged combustion melter to produce hollow glass fiber or solid glass fiber having entrained bubbles, and burners and systems to make such fibers
US11613488B2 (en) 2012-10-03 2023-03-28 Johns Manville Methods and systems for destabilizing foam in equipment downstream of a submerged combustion melter
US10392285B2 (en) 2012-10-03 2019-08-27 Johns Manville Submerged combustion melters having an extended treatment zone and methods of producing molten glass
US9533905B2 (en) 2012-10-03 2017-01-03 Johns Manville Submerged combustion melters having an extended treatment zone and methods of producing molten glass
US9676644B2 (en) 2012-11-29 2017-06-13 Johns Manville Methods and systems for making well-fined glass using submerged combustion
US10138151B2 (en) 2013-05-22 2018-11-27 Johns Manville Submerged combustion burners and melters, and methods of use
US11623887B2 (en) 2013-05-22 2023-04-11 Johns Manville Submerged combustion burners, melters, and methods of use
US10131563B2 (en) 2013-05-22 2018-11-20 Johns Manville Submerged combustion burners
US9777922B2 (en) 2013-05-22 2017-10-03 Johns Mansville Submerged combustion burners and melters, and methods of use
US11142476B2 (en) 2013-05-22 2021-10-12 Johns Manville Burner for submerged combustion melting
US10654740B2 (en) 2013-05-22 2020-05-19 Johns Manville Submerged combustion burners, melters, and methods of use
US11186510B2 (en) 2013-05-30 2021-11-30 Johns Manville Submerged combustion burners, submerged combustion glass melters including the burners, and methods of use
US10183884B2 (en) 2013-05-30 2019-01-22 Johns Manville Submerged combustion burners, submerged combustion glass melters including the burners, and methods of use
US10618830B2 (en) 2013-05-30 2020-04-14 Johns Manville Submerged combustion burners, submerged combustion glass melters including the burners, and methods of use
US9731990B2 (en) 2013-05-30 2017-08-15 Johns Manville Submerged combustion glass melting systems and methods of use
US10858278B2 (en) 2013-07-18 2020-12-08 Johns Manville Combustion burner
ES2551802A1 (es) * 2014-05-23 2015-11-23 Valoriza Servicios Medioambientales, S.A. Sistema y procedimiento para adsorción por evaporación directa de lixiviados efluentes de un vertedero de residuos sólidos urbanos
US10442717B2 (en) 2015-08-12 2019-10-15 Johns Manville Post-manufacturing processes for submerged combustion burner
US9751792B2 (en) 2015-08-12 2017-09-05 Johns Manville Post-manufacturing processes for submerged combustion burner
US10955132B2 (en) 2015-08-27 2021-03-23 Johns Manville Burner panels including dry-tip burners, submerged combustion melters, and methods
US10041666B2 (en) 2015-08-27 2018-08-07 Johns Manville Burner panels including dry-tip burners, submerged combustion melters, and methods
US10670261B2 (en) 2015-08-27 2020-06-02 Johns Manville Burner panels, submerged combustion melters, and methods
US9815726B2 (en) 2015-09-03 2017-11-14 Johns Manville Apparatus, systems, and methods for pre-heating feedstock to a melter using melter exhaust
US9982884B2 (en) 2015-09-15 2018-05-29 Johns Manville Methods of melting feedstock using a submerged combustion melter
US10837705B2 (en) 2015-09-16 2020-11-17 Johns Manville Change-out system for submerged combustion melting burner
US10435320B2 (en) 2015-09-23 2019-10-08 Johns Manville Systems and methods for mechanically binding loose scrap
US10081563B2 (en) 2015-09-23 2018-09-25 Johns Manville Systems and methods for mechanically binding loose scrap
US10144666B2 (en) 2015-10-20 2018-12-04 Johns Manville Processing organics and inorganics in a submerged combustion melter
US10793459B2 (en) 2016-06-22 2020-10-06 Johns Manville Effective discharge of exhaust from submerged combustion melters and methods
US10246362B2 (en) 2016-06-22 2019-04-02 Johns Manville Effective discharge of exhaust from submerged combustion melters and methods
US11248787B2 (en) 2016-08-25 2022-02-15 Johns Manville Consumable tip burners, submerged combustion melters including same, and methods
US11396470B2 (en) 2016-08-25 2022-07-26 Johns Manville Continuous flow submerged combustion melter cooling wall panels, submerged combustion melters, and methods of using same
US10301208B2 (en) 2016-08-25 2019-05-28 Johns Manville Continuous flow submerged combustion melter cooling wall panels, submerged combustion melters, and methods of using same
US10337732B2 (en) 2016-08-25 2019-07-02 Johns Manville Consumable tip burners, submerged combustion melters including same, and methods
US10196294B2 (en) 2016-09-07 2019-02-05 Johns Manville Submerged combustion melters, wall structures or panels of same, and methods of using same
US10233105B2 (en) 2016-10-14 2019-03-19 Johns Manville Submerged combustion melters and methods of feeding particulate material into such melters

Also Published As

Publication number Publication date
SE387861B (sv) 1976-09-20
BE770334A (fr) 1971-12-01
GB1337313A (en) 1973-11-14
DE2136686A1 (de) 1972-01-27
JPS5140547B1 (ja) 1976-11-04
FR2103215A5 (ja) 1972-04-07
CA943453A (en) 1974-03-12

Similar Documents

Publication Publication Date Title
US3763915A (en) Evaporative treatment of liquids by submerged combustion
CA2114555C (en) Leachate treatment system
US3870585A (en) Apparatus and method for evaporative concentration of aqueous solutions and slurries
CN107399876A (zh) 一种高氨氮废水的处理方法
CN104925986A (zh) 钢材行业酸洗废液及冲洗废水近零排放处理系统及其工艺
CN1102663C (zh) 箱式退火炉和使用该炉的金属板的退火方法以及退火过的金属板
KR100399381B1 (ko) 황산암모늄을함유하는석유연료의연소재에대한습식처리방법및습식처리법에의해회수되는암모니아성분의이용방법
GB1585855A (en) Method and apparatus for crystallisation of solution containing salts
JPS61502038A (ja) 汚濁液電気化学的浄化装置
CN112742055B (zh) 闪蒸结垢罐、含有其的污水处理装置及工艺
US1382037A (en) Process and apparatus for recovering soluble constituents from furnace-fumes
US3459638A (en) Distillation desalination of sea water using heated metal balls to vaporize water
CN204607739U (zh) 一种钢材行业酸洗废液及冲洗废水近零排放处理系统
CN114604980A (zh) 一种原水加热除硬水处理装置
US1429140A (en) Method of treating sludge acids
US591219A (en) Henri joseph ernest hennebutte
CN2883327Y (zh) 一种稀硫酸浓缩装置
SU1758019A1 (ru) Способ очистки сточных вод от альдегидов
FI68687B (fi) Foerfarande vid lutaotervinning efter sodahuspannan vid sulfatprocesser
SU67574A1 (ru) Аппарат дл ум гчени воды
JP2604847B2 (ja) 塗装設備
KR950009446B1 (ko) 미문(微紋) 및 무문(無紋) 아연도금강판 제조장치 및 제조방법
JPS61216716A (ja) 炭素繊維製造における排ガス処理方法
SU472108A1 (ru) Способ термического разложени медноаммиачных комплексов
CA1039863A (en) Method and apparatus for treating organic sludge