US3761252A - Aluminum base alloy - Google Patents
Aluminum base alloy Download PDFInfo
- Publication number
- US3761252A US3761252A US00297209A US3761252DA US3761252A US 3761252 A US3761252 A US 3761252A US 00297209 A US00297209 A US 00297209A US 3761252D A US3761252D A US 3761252DA US 3761252 A US3761252 A US 3761252A
- Authority
- US
- United States
- Prior art keywords
- alloy
- silicon
- aluminum base
- cast
- hardness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title abstract description 55
- 239000000956 alloy Substances 0.000 title abstract description 55
- 229910052782 aluminium Inorganic materials 0.000 title abstract description 40
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract description 40
- 229910052710 silicon Inorganic materials 0.000 abstract description 22
- 239000010703 silicon Substances 0.000 abstract description 22
- 229910052790 beryllium Inorganic materials 0.000 abstract description 19
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 abstract description 19
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 18
- 239000010949 copper Substances 0.000 abstract description 18
- 229910052802 copper Inorganic materials 0.000 abstract description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 17
- 239000012535 impurity Substances 0.000 abstract description 17
- 239000010936 titanium Substances 0.000 abstract description 17
- 229910052719 titanium Inorganic materials 0.000 abstract description 17
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 16
- 229910052749 magnesium Inorganic materials 0.000 abstract description 16
- 239000011777 magnesium Substances 0.000 abstract description 16
- 239000011701 zinc Substances 0.000 abstract description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 15
- 229910052725 zinc Inorganic materials 0.000 abstract description 15
- 230000010076 replication Effects 0.000 abstract description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000005266 casting Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000010791 quenching Methods 0.000 description 5
- 230000002411 adverse Effects 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 241000282887 Suidae Species 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000952 Be alloy Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- NRUQNUIWEUZVLI-UHFFFAOYSA-O diethanolammonium nitrate Chemical compound [O-][N+]([O-])=O.OCC[NH2+]CCO NRUQNUIWEUZVLI-UHFFFAOYSA-O 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
Definitions
- High silicon aluminum base alloys are well known.
- a typical example of an aluminum base alloy is that which is shown and described in Pat. No. 2,830,173 and in Ser. No. 185,440 filed Sept. 30, 1971, now Pat. No. 3,716,355 dated Feb. 13, 1973.
- Very often, the introduction of materials which reduce the grain size do so at the sacrifice of other properties.
- materials which are added for one purpose may adversely affect another desired property.
- Maintenance of relatively high as-cast hardness is important, particularly in the production of molds characterized by fine detail such as, for example, a wood grain pattern. Replicability of the pattern detail depends upon not only the hardness but also the ability of the alloys to reproduce fine detail.
- These alloys are particularly useful in producing a cast-to-shape mold for foam molding of plastics to make simulated wood grain furniture parts and development of desirable properties upon submission to a thermal history hereinafter more particularly described.
- the hardness of these alloys both at room temperature and after exposure to temperatures below 1,000 F. provides material which has excellent durability in actual molding operations performed at temperatures of the order of 300 F. to 500 F.
- These alloys are light in weight and therefore provide more volume per unit cost and greater ease of transport and handling in molding operations. These alloys do not depend upon the use of any nickel component as in the case of Ser. No.
- the ingredients of the alloy are sufiiciently inexpensive to make the cost attractive to plastic mold fabricators and plastic molders.
- the achievement of hardness levels of the order of R 95 without heat treatment is attractive as it eliminates a cost producing operation and does not involve risk of distortion or oxidation of a finished part.
- the present invention is in an aluminum base alloy characterized by high as-cast or initial hardness. These alloys are composed of from 8-13% silicon, 1.5 to 5.0% copper, 5.0 to 8.0% zinc, 0.5 to 1.5% magnesium, 0.01 to 0.20% beryllium, 0.01 to 0.30% titanium, trace amounts of impurities, and balance aluminum.
- This invention also relates to a cast aluminum base alloy of the above composition cast at a temperature of from 1000 F. to 1300 F.
- aluminum base alloys herein, we refer to those aluminum alloys which contain at least 70% aluminum.
- aluminum as herein employed refers to the metal as commercially produced, which does contain some impurities, or to the elemental material. Where in the appended claims the balance of an alloy is said to be aluminum, it is intended that this expression shall permit the inclusion in the alloy composition of other elements which do not adversely affect the properties herein set forth as well as the usual impurities associated with aluminum.
- trace as used herein contemplates 0.005% to 0.5% by weight.
- a specific example of an alloy in accordance herewith has the following composition and is compounded as a melt in air at a temperature of from 1200 F. to 1450 F. maximum temperature in an induction furnace:
- the foregoing metals are air melted in the induction furnace at a temperature which does not exceed 1450 F.
- This alloy when cast at 1250 F. into a graphite mold and naturally aged has hardness of R (Rockwell E) 95.
- the Brinell number at 500 kg. is 113; the ultimate strength in k.s.i. 35,000; the yield at 0.2% offset in k.s.i. 32,000; the percent elongation 1.0%; the percent IACS conductivity is 21.
- this alloy shows a Rockwell E hardness of 105, a Brinell 500 kg. of 130, an ultimate strength in k.s.i.
- the raw alloys of the present invention may be produced by known means.
- the components in their elemental form may be melt-blended in air at temperatures of from 1200 to 1500 F. in an induction furnace or in a gas-fired furnace with mechanical agitation.
- a commercial aluminum melt and to add to it a master batch of silicon and aluminum containing 50% silicon until a percentage of silicon in the combined melt yields the desired amount of silicon, e.g. an ultimate concentration of 10% by weight of silicon.
- Beryllium can be added as Al-5Be or Cu-4Be master alloys or as copper beryllium scrap. Titanium can be added as Cu-6Ti master alloy. The other elements are frequently added as elemental materials.
- the raw alloy may be cast into pigs at a temperature in the range of from 1200 to 1500 F.
- the pigs undergo a thermal history such as that described above in order to develop within the alloy the desired properties brought about by the combination of various elements present in these improved alloys.
- This thermal history includes casting the material into the master mold at a temperature generally between 1100 and 1300 F. and preferably in the range of from 1225 to 1275 F.
- the cast product may then be solution treated in accordance with known practice for a period of 8 to 24 hours, for example 16 hours, at a temperature in the range of from 900 F. to 1000 F., for example 935 F., and thereafter liquid quenched, for example in water, from the solution treating temperature.
- the liquid quenching agent may be water, ice water, boiling water, or oil.
- the cast product may then be aged for a period of from 8 to 24 hours, e.g. 16 hours, at a relatively mild temperature in the range of from 300 F. to 600 F., for example 340 F.
- the casting temperature not exceed about 1400 F. Best results are secured if the -final casting temperature is within the range of from 1200 F. to 1400 F.
- An aluminum base alloy consisting of 8-13% silicon, 1.5 to 5.0% copper, 5 to 8% zinc, 0.5 to 1.5% magnesium, 0.01 to 0.20% beryllium, 0.01 to 0.30% titanium, impurities, and balance aluminum.
- An aluminum base alloy consisting of 10.38% silicon, 2.56% copper, 7.26% zinc, 0.63% magnesium, 0.12% beryllium, 0.08% titanium, impurities, and balance aluminum.
- An aluminum base alloy consisting of 10.18% silicon, 2.20% copper, 6.50% zinc, 0.61% magnesium, 0.12% beryllium, 0.16% titanium, impurities, and balance aluminum.
- An aluminum base alloy consisting of 10.14% silicon, 2.22% copper, 6.80% zinc, 0.59% magnesium, 0.13% beryllium, 0.16% titanium, impurities, and balance aluminum.
- An aluminum base alloy consisting of 9.82% silicon, 3.90% copper, 8.16% zinc, 0.50% magnesium, 0.14% beryllium, 0.11% titanium, impurities, and balance aluminum.
- An aluminum base alloy consisting of 10.29% silicon, 2.88% copper, 6.75% zinc, 0.64% magnesium, 0.18% beryllium, 0.16% titanium, impurities, and balance aluminum.
- a cast aluminum base alloy consisting of from 8- 13% silicon, 1.5 to 5.0% copper, 5 to 8% zinc, 0.5 to 1.5% magnesium, 0.01 to 0.20% beryllium, 0.01 to 0.30% titanium, impurities, and balance aluminum, and having the hardness Obtained by casting the alloy at a temperature between 1100 F. and 1300 F., solution treating for a period of from 8 to 24 hours at a temperature of from 900 to 1000 F water or oil quenching from the solution treatment temperature, and aging for a period of from 8 to 24 hours at a temperature in the range of from 300 F. to 600 F.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Motor Or Generator Current Collectors (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29720972A | 1972-10-13 | 1972-10-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3761252A true US3761252A (en) | 1973-09-25 |
Family
ID=23145323
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00297209A Expired - Lifetime US3761252A (en) | 1972-10-13 | 1972-10-13 | Aluminum base alloy |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3761252A (OSRAM) |
| JP (1) | JPS4973316A (OSRAM) |
| DE (1) | DE2335894A1 (OSRAM) |
| FR (1) | FR2202949A1 (OSRAM) |
| GB (1) | GB1385145A (OSRAM) |
| IT (1) | IT1004546B (OSRAM) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4364159A (en) * | 1980-07-14 | 1982-12-21 | Trw Inc. | Method for manufacturing a forged piston with reinforced ring groove |
| US6719859B2 (en) | 2002-02-15 | 2004-04-13 | Northwest Aluminum Company | High strength aluminum base alloy |
| CN105624487A (zh) * | 2015-04-07 | 2016-06-01 | Sj技术股份有限公司 | 压铸用铝合金及利用其的铝合金铸件的制备方法 |
| CN109280820A (zh) * | 2018-10-26 | 2019-01-29 | 中国航发北京航空材料研究院 | 一种用于增材制造的高强度铝合金及其粉末的制备方法 |
-
1972
- 1972-10-13 US US00297209A patent/US3761252A/en not_active Expired - Lifetime
-
1973
- 1973-06-22 GB GB2986073A patent/GB1385145A/en not_active Expired
- 1973-07-14 DE DE19732335894 patent/DE2335894A1/de active Pending
- 1973-07-20 FR FR7326760A patent/FR2202949A1/fr not_active Withdrawn
- 1973-08-06 IT IT69367/73A patent/IT1004546B/it active
- 1973-08-13 JP JP48090089A patent/JPS4973316A/ja active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4364159A (en) * | 1980-07-14 | 1982-12-21 | Trw Inc. | Method for manufacturing a forged piston with reinforced ring groove |
| US6719859B2 (en) | 2002-02-15 | 2004-04-13 | Northwest Aluminum Company | High strength aluminum base alloy |
| CN105624487A (zh) * | 2015-04-07 | 2016-06-01 | Sj技术股份有限公司 | 压铸用铝合金及利用其的铝合金铸件的制备方法 |
| CN109280820A (zh) * | 2018-10-26 | 2019-01-29 | 中国航发北京航空材料研究院 | 一种用于增材制造的高强度铝合金及其粉末的制备方法 |
| CN109280820B (zh) * | 2018-10-26 | 2021-03-26 | 中国航发北京航空材料研究院 | 一种用于增材制造的高强度铝合金及其粉末的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1385145A (en) | 1975-02-26 |
| DE2335894A1 (de) | 1974-04-18 |
| IT1004546B (it) | 1976-07-20 |
| JPS4973316A (OSRAM) | 1974-07-16 |
| FR2202949A1 (OSRAM) | 1974-05-10 |
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