US3753695A - Bearing materials - Google Patents

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US3753695A
US3753695A US00114660A US3753695DA US3753695A US 3753695 A US3753695 A US 3753695A US 00114660 A US00114660 A US 00114660A US 3753695D A US3753695D A US 3753695DA US 3753695 A US3753695 A US 3753695A
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percent
bismuth
aluminium
weight
bearing
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US00114660A
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K Lloyd
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Federal Mogul Engineering Ltd
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Glacier Metal Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/003Alloys based on aluminium containing at least 2.6% of one or more of the elements: tin, lead, antimony, bismuth, cadmium, and titanium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/12Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • F16C33/121Use of special materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/923Physical dimension
    • Y10S428/924Composite
    • Y10S428/925Relative dimension specified
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12458All metal or with adjacent metals having composition, density, or hardness gradient
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12736Al-base component
    • Y10T428/1275Next to Group VIII or IB metal-base component
    • Y10T428/12757Fe

Definitions

  • the invention is a bearing material of which a major Cl 38, constituent is aluminum characterised by between 1 75/139, 75/144, 75/148 percent and 16 percent (preferably between 3 percent [51] Int. Cl. C22c 21/02 and 7 percent or between 7 percent and 10 percent or [58] Field of Search 75/138, 139, 143, between 10 percent'and 16 percent of bismuth by 1 75/148, 144; 148/32, 32.5; 29/ 196.2 weight, and optionally including 0 3 percent copper, 1 i 0 3 percent nickel, O 3 percent manganese, 0 1 l [56] References Cited percent silicon.
  • a bearing alloy comprises aluminium and more than 1 percent of bismuth by weight. Preferably there is from 7-l0 percent bismuth; or for some purposes there may be up to 16 percent by weight bismuth.
  • the aluminium may or not constitute the balance, but will usually constitute at least 50 percent by weight of the material.
  • Aluminium/bismuth is an alternative and is believed to have surface properties equal to or better than the three alloys for alloys with the same percentage of the low melting point constituent.
  • This desirable property of aluminium/bismuth is believed to be due to the Rhomboidal structure of bismuth.
  • the corrosion resistance of bismuth in engine oils is believed to be betterthan, for example, a similar alloy of aluminium-lead.
  • Tin is conventionally added to aluminium-lead alloys to increase the corrosion resistance to engine oils and in the comparison we are referring to aluminium-lead without a tin additive.
  • Bismuth is also unusual in that it expands when solidifying, and it is believed that this phenomenonmay assist in reducing the tension forces existing along the boundary between the soft material and the surrounding stronger matrix thereby increasing the fatigue strength of the material.
  • the porosity of the alloy is reduced if the bismuth expands to fill the interstices in the surrounding aluminium.
  • the bismuth provides the surface properties required of a bearing alloy and so the defined composition could be only at or near the bearing surface. However, the whole alloy could also be of uniform composition.
  • the bismuth has good surface properties in that it can accommodate dirt being embodied in it without its bearing properties being seriously lost and accordingly it is not necessary to provide a lead/tin or other plated over-lay on the bearing surface as has been found to be necessary in the past for many bearing materials which are primarily of aluminium. The extra expense of including the hismuth is, therefore, compensated for by avoiding the need for such an overlay.
  • the invention includes a bearing comprising at least a bearing-surface-layer of an alloy as defined, and also a layer of the alloy bonded to a steel or other backing.
  • aluminium/- lead alloys are less than that of an aluminium/bismuth alloy having the same proportion of bismuth.
  • the bismuth in an aluminium alloy when rolled down to a thickness suitable for bonding to a steel backing tends to form long stringers which readily form into globules when the alloy is annealed. This contrasts with aluminium/lead alloys which do not form globules readily on annealing.
  • This property of aluminium/bismuth in conjunction with the expansion on solidification reduces the forces occurring along the aluminium boundary as compared with tin or lead and provides a potentially greater fatigue strength.
  • a bearing alloy consists of:
  • Bismuth 3 percent by weight Copper 1 percent by weight Aluminium 96 percent by weight The component metals in correct proportions are introduced into a tun dish and raised to a temperature sufficient to melt them all, after which a billet of the alloy is cast and subsequently rolled into a slab with a thickness of about 0.050 inches. The slab is then bonded to a steel backing to make a bearing strip.
  • Bismuth l6 percent by weight Copper l percent by weight Nickel l percent by weight Manganese l percent by weight Silicon ll percent by weight Aluminium percent by weight is melted in a tun dish and poured as a slab into a shallow mould. The alloy is allowed to cool slowly so that most of the bismuth tends to drop through the aluminium which is much lighter, so that at the bottom surface the percentage of bismuth is high, whereas at the top surface there may be very little bismuth. This forms a satisfactory bearing with the high bismuth surface acting as the bearing surface and the low bismuth surface bonded to the steel backing.
  • Bismuth l percent by weight Copper 2 percent by weight Silicon 1 percent by weight Aluminium 87 percent by weight The appropriate proportions of the metals were mixed in powder form and the composite powder was sintered on a backing and bonded to the backing by rolling.
  • the accompanying drawing shows some test results obtained with aluminium based alloys with bismuth and tin as the second phase. It will be seen that even an alloy with a tin content of about 18.3 percent by weight its cycle to seizure is not significantly better than an alloy with a bismuth content of 13.6 percent. The drawing also shows that an alloy containing 6.2 percent by weight of bismuth gives 200 cycles of seizure while an alloy containing 6.2 percent of tin gives only 140 cycles to seizure.
  • a bearing material consisting essentially of bismuth about 16 wt.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Sliding-Contact Bearings (AREA)

Abstract

The invention is a bearing material of which a major constituent is aluminum characterised by between 1 percent and 16 percent (preferably between 3 percent and 7 percent or between 7 percent and 10 percent or between 10 percent and 16 percent of bismuth by weight, and optionally including 0 - 3 percent copper, 0 - 3 percent nickel, 0 - 3 percent manganese, 0 - 11 percent silicon.

Description

United States Patent, 1 1 [111 3,753,695
Lloyd Aug. 21, 1973 [54] BEARING MATERIALS 2,752,240 6/1956 Schluchter 75/148 2,026,546 1/1936 Kem fet al.. 75/138 [751 Invent! Kenneth Loud, Eula 3,410,331 11/1968 Mille et al. 75/138 [73] Assignee: The Glacier Metal Company Limited, Alperton, England Primary Examiner-Richard 0. Dean Flled: 111 1971 Attorney-Pierce, Schefiler & Parker 211 Appl. No.: 114,660
[30] Foreign Application Priority Data [57] ABSTRACT Feb. 13, 1970 Great Britain 7,058/70 The invention is a bearing material of which a major Cl 38, constituent is aluminum characterised by between 1 75/139, 75/144, 75/148 percent and 16 percent (preferably between 3 percent [51] Int. Cl. C22c 21/02 and 7 percent or between 7 percent and 10 percent or [58] Field of Search 75/138, 139, 143, between 10 percent'and 16 percent of bismuth by 1 75/148, 144; 148/32, 32.5; 29/ 196.2 weight, and optionally including 0 3 percent copper, 1 i 0 3 percent nickel, O 3 percent manganese, 0 1 l [56] References Cited percent silicon.
UNITED STATES PATENTS 3,562,884 2/1971 Webbere 75/138 5 Claims, 1 Drawing Figure o TEST CONDITIONS= 450 RPM. N f l6lb.APPLlED LOAD 0 Al l /0 Cu l/o N1+Sn No LUBRCATON El Al- 1% Cu+Sn 11 t 01 j 400 u u 4, O 2 4 6 8 1o 12 14 1e 1s 20 WT. OF SECOND PHASE TIN OR BISMUTiH) PATENTEBMIGZI I873 ON Q m. a N O- w w v N BEARING MATERIALS This invention relates to an aluminium base alloy for use as a bearing material, for example in thin shell bearings where the alloy requires to be bonded, by rolling for example, to a steel backing either directly or with an intermediate layer of metal foil, or after the backing has been plated with, say, nickel or cobalt.
According to the present invention, a bearing alloy comprises aluminium and more than 1 percent of bismuth by weight. Preferably there is from 7-l0 percent bismuth; or for some purposes there may be up to 16 percent by weight bismuth. The aluminium may or not constitute the balance, but will usually constitute at least 50 percent by weight of the material.
it has been discovered that such a bearing has a surprising ability to survive without pick-up or siezure during momentary contact with the journal when for any reason the oil film thickness becomes locally less than the surface roughness. This property is known as compatibility. While softness of the material is a factor in obtaining this property, other factors are relevant, and the property is, in general, little understood. There are three known aluminium-based alloys having a soft low melting point phase which are used for their properties of having high compatibility. These are aluminium/tin, aluminium/lead and aluminium/cadmium.
, Aluminium/bismuth is an alternative and is believed to have surface properties equal to or better than the three alloys for alloys with the same percentage of the low melting point constituent.
This desirable property of aluminium/bismuth is believed to be due to the Rhomboidal structure of bismuth. The corrosion resistance of bismuth in engine oils is believed to be betterthan, for example, a similar alloy of aluminium-lead. Tin is conventionally added to aluminium-lead alloys to increase the corrosion resistance to engine oils and in the comparison we are referring to aluminium-lead without a tin additive. Bismuth is also unusual in that it expands when solidifying, and it is believed that this phenomenonmay assist in reducing the tension forces existing along the boundary between the soft material and the surrounding stronger matrix thereby increasing the fatigue strength of the material. Clearly the porosity of the alloy is reduced if the bismuth expands to fill the interstices in the surrounding aluminium.
According to a feature of the invention an aluminium base alloy, suitablefor use as a bearing alloy and capable of being bonded to a steel backing contains by weight from 1 percent or3-7 percent bismuth including lead impurities, the balance being aluminium except for normal impurities and from to 3 percent of each of one or more of the elements copper, nickel and manganese to improve the strength of the aluminium matrix. in addition up to 5 percent or 1 1 percent silicon may be added with, say, 1 percent copper or nickel or both. it may be desirable to include a small percentage of a metal or other substance which improves resistance to corrosion.
The bismuth provides the surface properties required of a bearing alloy and so the defined composition could be only at or near the bearing surface. However, the whole alloy could also be of uniform composition.
it seems that providing there is bismuth at the bearing surface it is not necessary to have bismuth throughout the thickness of the bearing material. The bismuth has good surface properties in that it can accommodate dirt being embodied in it without its bearing properties being seriously lost and accordingly it is not necessary to provide a lead/tin or other plated over-lay on the bearing surface as has been found to be necessary in the past for many bearing materials which are primarily of aluminium. The extra expense of including the hismuth is, therefore, compensated for by avoiding the need for such an overlay.
The invention includes a bearing comprising at least a bearing-surface-layer of an alloy as defined, and also a layer of the alloy bonded to a steel or other backing.
It is believed that the fatigue strength of aluminium/- lead alloys is less than that of an aluminium/bismuth alloy having the same proportion of bismuth. The bismuth in an aluminium alloy when rolled down to a thickness suitable for bonding to a steel backing tends to form long stringers which readily form into globules when the alloy is annealed. This contrasts with aluminium/lead alloys which do not form globules readily on annealing. This property of aluminium/bismuth in conjunction with the expansion on solidification, reduces the forces occurring along the aluminium boundary as compared with tin or lead and provides a potentially greater fatigue strength. Tests have been carried out on aluminium/bismuth bearing materials which suggest that the percentage of bismuth in aluminium to provide adequate surface properties can be less than those of tin or lead and this also tends to increase the fatigue strength because less of the softer inclusion is required in the surrounding matrix of aluminium.
Certain examples of alloys embodying the invention will now be described.
EXAMPLE I A bearing alloy consists of:
Bismuth 3 percent by weight Copper 1 percent by weight Aluminium 96 percent by weight The component metals in correct proportions are introduced into a tun dish and raised to a temperature sufficient to melt them all, after which a billet of the alloy is cast and subsequently rolled into a slab with a thickness of about 0.050 inches. The slab is then bonded to a steel backing to make a bearing strip.
EXAMPLE ii A bearing strip is made by the same method described in Example I but the proportions are:
Bismuth 7 percent by weight Nickel 2 percent by weight Silicon 4 percent by weight Aluminium 87 percent by weight EXAMPLE [II A bearing alloy with the following composition:
Bismuth l6 percent by weight Copper l percent by weight Nickel l percent by weight Manganese l percent by weight Silicon ll percent by weight Aluminium percent by weight is melted in a tun dish and poured as a slab into a shallow mould. The alloy is allowed to cool slowly so that most of the bismuth tends to drop through the aluminium which is much lighter, so that at the bottom surface the percentage of bismuth is high, whereas at the top surface there may be very little bismuth. This forms a satisfactory bearing with the high bismuth surface acting as the bearing surface and the low bismuth surface bonded to the steel backing.
EXAMPLE iv A bearing material was made with metals in the following proportions:
Bismuth l percent by weight Copper 2 percent by weight Silicon 1 percent by weight Aluminium 87 percent by weight The appropriate proportions of the metals were mixed in powder form and the composite powder was sintered on a backing and bonded to the backing by rolling.
The accompanying drawing shows some test results obtained with aluminium based alloys with bismuth and tin as the second phase. It will be seen that even an alloy with a tin content of about 18.3 percent by weight its cycle to seizure is not significantly better than an alloy with a bismuth content of 13.6 percent. The drawing also shows that an alloy containing 6.2 percent by weight of bismuth gives 200 cycles of seizure while an alloy containing 6.2 percent of tin gives only 140 cycles to seizure.
It is also possible to include bismuth in a shaft which is co-operating with a bearing.
There could be 1 percent, 3 percent, 6 percent, 8 percent, 12 percent or l6 percent say, of bismuth by weight, whether the shaft is steel or aluminium or any other metal.
What I claim as my invention and desire to secure by Letters Patent is:
l. A bearing material consisting essentially of bismuth about 16 wt.
silicon about ll wt.
copper about 1 wt.
nickel about 1 wt.
manganese about 1 wt. and
aluminum about 70 wt.
2. A bearing material as claimed in claim 1, in the form of a slab whose thickness is small compared with its length and breadth.
3. A bearing material as claimed in claim 2, in which the proportion of bismuth at one of the larger surfaces of the slab is greater than the proportion of bismuth at the other of the larger surfaces.
4. A bearing material as claimed in claim 3, in which there is about 16% by weight of bismuth at the one of the larger surfaces.
5. A hearing material as claimed in claim 3, in which there is substantially no bismuth at the said other of the larger surfaces.
a s s a a

Claims (4)

  1. 2. A bearing material as claimed in claim 1, in the form of a slab whose thickness is small compared with its length and breadth.
  2. 3. A bearing material as claimed in claim 2, in which the proportion of bismuth at one of the larger surfaces of the slab is greater than the proportion of bismuth at the other of the larger surfaces.
  3. 4. A bearing material as claimed in claim 3, in which there is about 16% by weight of bismuth at the one of the larger surfaces.
  4. 5. A bearing material as claimed in claim 3, in which there is substantially no bismuth at the said other of the larger surfaces.
US00114660A 1970-02-13 1971-02-11 Bearing materials Expired - Lifetime US3753695A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4590133A (en) * 1985-02-01 1986-05-20 D.A.B. Industries Bearing material
US4747889A (en) * 1985-05-22 1988-05-31 Sumitomo Electric Industries, Ltd. Interconnecting wire for semiconductor devices
US4957822A (en) * 1986-11-26 1990-09-18 Glyco-Metall-Werke Daelen & Loos Gmbh Laminated material for friction bearing elements, comprising an antifriction layer of an aluminum based bearing material
US5286445A (en) * 1990-11-30 1994-02-15 Taiho Kogyo Co., Ltd. Aluminium bearing alloy containing bismuth
US5300368A (en) * 1990-02-03 1994-04-05 Glyco-Metall-Werke Glyco B.V. & Co. Kg Highly wear-resistant overlay with improved slip and a method of its production
US6315947B1 (en) 2000-05-23 2001-11-13 Reynolds Metals Company Free-machining aluminum alloy and method of use
US6409966B1 (en) 1998-05-19 2002-06-25 Reynolds Metals Company Free machining aluminum alloy containing bismuth or bismuth-tin for free machining and a method of use
US6510726B1 (en) 1998-12-23 2003-01-28 Federal-Mogul World Wide, Inc. Bismuth tracer bearings
US20030143096A1 (en) * 2002-01-29 2003-07-31 Teruo Shimizu Sintered alloy article, its production method and a motorized fuel pump comprising a bearing comprised of sintered alloy article
US6746154B2 (en) 2001-10-08 2004-06-08 Federal-Mogul World Wide, Inc. Lead-free bearing
US20160010185A1 (en) * 2014-07-08 2016-01-14 Samara State Aerospace University High-temperature stable electro-conductive aluminum-base alloy

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5638667B2 (en) * 1972-01-20 1981-09-08
US5122207A (en) * 1991-07-22 1992-06-16 General Motors Corporation Hypo-eutectic aluminum-silicon-copper alloy having bismuth additions
US5106436A (en) * 1991-09-30 1992-04-21 General Motors Corporation Wear resistant eutectic aluminum-silicon alloy

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2026546A (en) * 1933-09-18 1936-01-07 Aluminum Co Of America Free cutting alloys
US2752240A (en) * 1952-12-27 1956-06-26 Gen Motors Corp Aluminum base alloy bearing
US3410331A (en) * 1966-03-16 1968-11-12 Gen Motors Corp Method of casting an aluminumbased bearing alloy
US3562884A (en) * 1968-10-29 1971-02-16 Gen Motors Corp Aluminum-based alloy bearing material and method of making

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2026546A (en) * 1933-09-18 1936-01-07 Aluminum Co Of America Free cutting alloys
US2752240A (en) * 1952-12-27 1956-06-26 Gen Motors Corp Aluminum base alloy bearing
US3410331A (en) * 1966-03-16 1968-11-12 Gen Motors Corp Method of casting an aluminumbased bearing alloy
US3562884A (en) * 1968-10-29 1971-02-16 Gen Motors Corp Aluminum-based alloy bearing material and method of making

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4590133A (en) * 1985-02-01 1986-05-20 D.A.B. Industries Bearing material
US4747889A (en) * 1985-05-22 1988-05-31 Sumitomo Electric Industries, Ltd. Interconnecting wire for semiconductor devices
US4957822A (en) * 1986-11-26 1990-09-18 Glyco-Metall-Werke Daelen & Loos Gmbh Laminated material for friction bearing elements, comprising an antifriction layer of an aluminum based bearing material
US5300368A (en) * 1990-02-03 1994-04-05 Glyco-Metall-Werke Glyco B.V. & Co. Kg Highly wear-resistant overlay with improved slip and a method of its production
US5286445A (en) * 1990-11-30 1994-02-15 Taiho Kogyo Co., Ltd. Aluminium bearing alloy containing bismuth
US6409966B1 (en) 1998-05-19 2002-06-25 Reynolds Metals Company Free machining aluminum alloy containing bismuth or bismuth-tin for free machining and a method of use
US6510726B1 (en) 1998-12-23 2003-01-28 Federal-Mogul World Wide, Inc. Bismuth tracer bearings
US6315947B1 (en) 2000-05-23 2001-11-13 Reynolds Metals Company Free-machining aluminum alloy and method of use
US6746154B2 (en) 2001-10-08 2004-06-08 Federal-Mogul World Wide, Inc. Lead-free bearing
US20040111892A1 (en) * 2001-10-08 2004-06-17 Greene Robert L. Lead-free bearing
US6854183B2 (en) 2001-10-08 2005-02-15 Federal-Mogul World Wide, Inc. Lead-free bearing
US20030143096A1 (en) * 2002-01-29 2003-07-31 Teruo Shimizu Sintered alloy article, its production method and a motorized fuel pump comprising a bearing comprised of sintered alloy article
US20160010185A1 (en) * 2014-07-08 2016-01-14 Samara State Aerospace University High-temperature stable electro-conductive aluminum-base alloy

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DE2106391A1 (en) 1971-08-19
GB1340489A (en) 1973-12-12
FR2078514A5 (en) 1971-11-05
CA958565A (en) 1974-12-03

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