US3737386A - Solvent based detergent - Google Patents
Solvent based detergent Download PDFInfo
- Publication number
- US3737386A US3737386A US00060924A US3737386DA US3737386A US 3737386 A US3737386 A US 3737386A US 00060924 A US00060924 A US 00060924A US 3737386D A US3737386D A US 3737386DA US 3737386 A US3737386 A US 3737386A
- Authority
- US
- United States
- Prior art keywords
- weight
- methylene chloride
- composition
- isopropanol
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title abstract description 29
- 239000002904 solvent Substances 0.000 title description 10
- 238000004140 cleaning Methods 0.000 abstract description 7
- 239000003960 organic solvent Substances 0.000 abstract description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 57
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 38
- 239000000203 mixture Substances 0.000 description 37
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 36
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 24
- -1 greases Substances 0.000 description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000002966 varnish Substances 0.000 description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 8
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical class [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000003925 fat Substances 0.000 description 8
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- 239000004141 Sodium laurylsulphate Substances 0.000 description 7
- 239000000314 lubricant Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 239000011269 tar Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 5
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 4
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 4
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical class CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 4
- 235000011149 sulphuric acid Nutrition 0.000 description 4
- 239000001117 sulphuric acid Substances 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229950005499 carbon tetrachloride Drugs 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229960001701 chloroform Drugs 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002169 ethanolamines Chemical class 0.000 description 2
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical class CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 2
- 229940090181 propyl acetate Drugs 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical class CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000385654 Gymnothorax tile Species 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N Methyl butyrate Chemical class CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical class CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 description 1
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical class CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 1
- BTMVHUNTONAYDX-UHFFFAOYSA-N butyl propionate Chemical class CCCCOC(=O)CC BTMVHUNTONAYDX-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N ethyl butyrate Chemical class CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical class CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- AYOOGWWGECJQPI-NSHDSACASA-N n-[(1s)-1-(5-fluoropyrimidin-2-yl)ethyl]-3-(3-propan-2-yloxy-1h-pyrazol-5-yl)imidazo[4,5-b]pyridin-5-amine Chemical group N1C(OC(C)C)=CC(N2C3=NC(N[C@@H](C)C=4N=CC(F)=CN=4)=CC=C3N=C2)=N1 AYOOGWWGECJQPI-NSHDSACASA-N 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- HUAZGNHGCJGYNP-UHFFFAOYSA-N propyl butyrate Chemical class CCCOC(=O)CCC HUAZGNHGCJGYNP-UHFFFAOYSA-N 0.000 description 1
- MCSINKKTEDDPNK-UHFFFAOYSA-N propyl propionate Chemical class CCCOC(=O)CC MCSINKKTEDDPNK-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
Definitions
- detergents of the known prior art have proved to be insufficient, particularly for cleaning construction units e.g. tiles in service-stations, tunnels, railway stations and similar buildings, soiled concrete areas and other cemented surfaces.
- the dirt on walls and floors of such buildings consists of tars, greases, oils, rosins, resins, asphaltenes, set paints and varnishes as well as of mechanical impurities.
- a detergent composition comprising in combination several solvents which can be applied even at high levels of impurity, i.e. which exhibit good solving properties and which make it possible to wash away the lubricants composed of dirt (tars, greases, oils, rosins, resins, etc.).
- the new detergents are liquid mixtures which can be mixed with water and consist of:
- esters methyl acetate, propyl acetates and butyl acetates, as well as the corresponding propionates and butyrates including ethyl esters; as ketones: diethyl, methyl propyl and isomeric ethyl butyl ketones;
- (D) as anionic surface active agents sulphates and ether sulphates of fatty alcohols, acyl sulphonates, aryl alkyl sulphonates and alkyl aryl sulphonates, ethylene oxide adducts, e.g. sodium lauryl sulphates, lauryl alcohol sulfuric acid ester and triethanolamine salts of ether sulphates of fat alcohols.
- Test l.-Test composition without a surface active substance The test composition had the following ingredients:
- Test 2 composition without chlorinated hydrocarbon The mixture had the following ingredients:
- EXAMPLE 1 The tiles to be cleaned were soiled with the above mentioned lubricant forming dirt composition and submitted to an ageing process of one year. -By means of a cleaning cloth soaked with the above mentioned detergent an area of tiles of 1 m? was cleaned and rinsed with water in '30 sec. time. This detergency power 30 seconds could be considered as very good.
- compositions with considerably changing concentrations of the ingredients were examined, i.e. compositions with a considerably higher or lower amount of methylene chloride, methyl ethyl ketone, ethyl acetate, surface active substances and alcohols according to Examples .1 to 5.
- TEST COMPARISON REPORT (a) varnish of a polyacrylic resin (b) a mixed styrene butadiene polymer (c) a dispersion of polyvinyl acetate (d) lignite tar (e) motor oil recovered from waste oils and fat and submitted to an ageing process, comprising the following steps: for 12 hours the tiles were dryed by infrared light and aerated and then for 12 hours submitted to a relative humidity of 65% at 20 C. The prepared tiles were then treated with each 250 g. of the detergent in the composition of the invention and of the fluid detergent known from the German published patent application 1,200,460. In the examples which follow, after 5 minutes time we tried to remove the impurities with water. Out of the known detergents were applied those of Examples 1 (with perchloroethylene), 2 and 6 of the German published patent 1,200,460.
- Example 1 of the German patent contains parts by weight of carbon tetrachloride or percholorethylene and 20 parts by weight of a 80% technical alkyl benzene sulfonic acid, neutralized with 15 parts by weight of crude pyridine.
- Example 2 of the German patent contains 2320 parts by weight of perchloroethylene, parts by Weight of a sulfated polyglycol ether of fat alcohol and 660 parts by weight of the above mentioned alkylbenzene sulfonic acid neutralized with 330 parts by weight of crude pyridine and parts by weight of morpholine.
- Example -6 of the German patent contains 2600 parts by weight of decylphenolepolyglycolether and 390 parts by Weight of a 80% dibutylnaphthalenesulfonic acid, which was neutralized with 100 parts by Weight of pyridine.
- compositions were capable of solving only oils (e) and tars (d); only these tars and fats could be removed in the form of aqueous emulsions; varnishes i.e. resins (a), (b) and (c) remained, however, unchanged and could not be removed.
- varnishes i.e. resins (a), (b) and (c) remained, however, unchanged and could not be removed.
- the known detergents which were used for comparison are effective at solving oil and fat but have no or only minor solving efficiency to solve varnish, paint and resin.
- the detergents of the present invention removed varnish, paint and resin easily.
- the detergents of the present invention are universal cleansing agents.
- a solvent based detergent composition that is miscible with water consisting essentially of (A) 10 to 25% by weight of liquid lower aliphatic chlorinated hydrocarbons,
- (B) is methyl ethyl ketone or ethyl acetate
- (C) is isopropanol, propanol or butanol and (D) is an anionic surface active agent.
- a detergent composition of claim 1 wherein said chlorinated hydrocarbons are selected from the group consisting of monochloromethane, trichloromethane, tetrachloromethane, dichloroethane, trichloroethaue and tetrachloroethane.
- esters (B) are selected from the group consisting of methyl acetate, propyl acetates, butyl acetates, methyl propionates, ethyl propionates, propyl propionates, butyl propionates, methyl butyrates, ethyl butyrates, propyl butyrates and butyl butyrates.
- a detergent composition of claim 1 wherein (A) is methylene chloride, (B) is methyl propyl ketone, (C) is propanol and (D) is ammonium salt of sulphuric acid ester of lauryl alcohol.
- a detergent composition of claim 1 wherein (A) is methylene chloride, (B) is diethyl ketone and ethyl acetate, (C) is butanol and (D) is monoethanolamine salt of the sulphonated coconut fatty alcohols ether.
- a detergent composition of claim 1 wherein (A) is methylene chloride, (B) is methyl ethyl ketone and propyl acetate, (C) is ethanol and (D) is triethanolamine salt of the lauryl alcohol sulphuric acid ester.
- a detergent composition of claim 1 wherein (A) is methylene chloride, (B) is methyl ethyl ketone and ethyl acetate, (C) is isopropanol and (D) is sodium lauryl sulphate.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691940018 DE1940018A1 (de) | 1969-08-06 | 1969-08-06 | Reinigungsmittel auf Loesungsmittelbasis |
| US6092470A | 1970-08-04 | 1970-08-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3737386A true US3737386A (en) | 1973-06-05 |
Family
ID=25757764
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00060924A Expired - Lifetime US3737386A (en) | 1969-08-06 | 1970-08-04 | Solvent based detergent |
| US00350393A Expired - Lifetime US3856695A (en) | 1969-08-06 | 1973-04-12 | Solvent based detergent |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00350393A Expired - Lifetime US3856695A (en) | 1969-08-06 | 1973-04-12 | Solvent based detergent |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US3737386A (enrdf_load_stackoverflow) |
| BE (1) | BE754318A (enrdf_load_stackoverflow) |
| CH (1) | CH531561A (enrdf_load_stackoverflow) |
| DE (1) | DE1940018A1 (enrdf_load_stackoverflow) |
| DK (1) | DK128856A (enrdf_load_stackoverflow) |
| FR (1) | FR2057946A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1319068A (enrdf_load_stackoverflow) |
| NL (1) | NL7011628A (enrdf_load_stackoverflow) |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3988256A (en) * | 1974-04-03 | 1976-10-26 | Allied Chemical Corporation | Photoresist stripper rinse |
| US4085059A (en) * | 1974-05-02 | 1978-04-18 | Bunker Ramo Corporation | Foam type coating remover |
| US4220549A (en) * | 1978-05-04 | 1980-09-02 | Ronnie J. Moore | Method for removing reflective decal |
| US4271214A (en) * | 1978-09-07 | 1981-06-02 | Nippon Paint Co., Ltd. | Method for recovering acrylic resin from excess of sprayed powder coating composition by using aromatic solvents |
| US4309300A (en) * | 1979-05-04 | 1982-01-05 | Mcdonnell Douglas Corporation | Cleaning solvent and method of cleaning a metal surface |
| US4333845A (en) * | 1978-08-11 | 1982-06-08 | Grow Group, Inc. | Coating composition thinner for decreasing pollution resulting from the application of a coating composition |
| US4336024A (en) * | 1980-02-22 | 1982-06-22 | Airwick Industries, Inc. | Process for cleaning clothes at home |
| US4421665A (en) * | 1980-08-25 | 1983-12-20 | Lloyd Eugene A | Contact lens cleaning composition containing lipid solvent and method of using |
| FR2551766A1 (fr) * | 1983-09-13 | 1985-03-15 | Elf Aquitaine | Composition aqueuse pour la dispersion de substances hydrophobes applicable notamment au nettoyage d'objets souilles par une peinture ou similaire |
| US4518518A (en) * | 1983-03-30 | 1985-05-21 | Amchem Products, Inc. | Cold paint stripping composition |
| US4664721A (en) * | 1981-12-07 | 1987-05-12 | Intercontinental Chemical Corporation | Printing screen cleaning and reclaiming compositions |
| US4810411A (en) * | 1986-04-16 | 1989-03-07 | E. I. Du Pont De Nemours And Company | Solvent-based fabric protector |
| FR2624518A1 (fr) * | 1987-12-09 | 1989-06-16 | Grandry Gerard | Liquide adjuvant pour la pulverisation, le lavage, le degraissage, le detachage ou la dilution de peinture |
| US4965010A (en) * | 1988-10-27 | 1990-10-23 | Swett Ralph R | Paint stripping composition containing ketones, methanol, and aromatic hydrocarbon |
| US5045224A (en) * | 1988-01-12 | 1991-09-03 | Toyota Jidosha Kabushiki Kaisha | Color-change washing solution, suitable for spray coating devices |
| US5102573A (en) * | 1987-04-10 | 1992-04-07 | Colgate Palmolive Co. | Detergent composition |
| US5676764A (en) * | 1993-02-12 | 1997-10-14 | Mcdonnell Douglas Corporation | Low vapor pressure solvent |
| US5690747A (en) * | 1988-05-20 | 1997-11-25 | The Boeing Company | Method for removing photoresist with solvent and ultrasonic agitation |
| EP0698118A4 (en) * | 1994-03-11 | 1999-06-16 | Biogenex Lab | DEPARAFFINIZATION COMPOSITIONS AND METHOD FOR USE THEREOF |
| US6200945B1 (en) | 1999-05-20 | 2001-03-13 | Mcdonnell Douglas Corporation | Environmentally safe solvent composition |
| CN106118212A (zh) * | 2016-08-18 | 2016-11-16 | 中国航天科技集团公司第九研究院第七七研究所 | 航天印刷电路板的三防涂层去除方法及去除剂和去除剂制备 |
| CN110129813A (zh) * | 2019-05-08 | 2019-08-16 | 东莞市杰川电子材料科技有限公司 | 用于清洗稀土的清洗剂及其制备方法 |
| WO2024247638A1 (ja) * | 2023-05-29 | 2024-12-05 | 第一工業製薬株式会社 | 樹脂用除去剤及び樹脂の除去方法 |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1058727B (it) * | 1976-04-01 | 1982-05-10 | Rialdi G | Composizione per il trattamento della superficie di vetri |
| US4260509A (en) * | 1980-01-04 | 1981-04-07 | The United States Of America As Represented By The Secretary Of The Navy | Solvent having high flash point |
| US4302365A (en) * | 1980-02-11 | 1981-11-24 | American Grease Stick Company | Engine degreaser composition |
| FR2486535A1 (fr) * | 1980-07-09 | 1982-01-15 | Gottschalk Meinhardt | Produit pour le decollage de revetements de sol fibreux, et procede d'utilisation |
| FR2538809B1 (fr) * | 1982-12-29 | 1985-07-12 | Lumer Sa Ste Indle Produits Ch | Produit pour le decollage des revetements de sols et murs, par application sur la face non collee |
| US4592856A (en) * | 1983-11-14 | 1986-06-03 | Shin-Etsu Chemical Co., Ltd. | Liquid detergent composition |
| US4543206A (en) * | 1984-05-03 | 1985-09-24 | Adams Cornell L | Nail lacquer and enamel remover |
| US4741784A (en) * | 1984-11-26 | 1988-05-03 | Kote-Off, Inc. | Composition and method for removing conformal coatings |
| NZ224148A (en) * | 1987-04-10 | 1991-02-26 | Colgate Palmolive Co | Pre-spotting composition for food residue removal |
| DE3911078A1 (de) * | 1989-01-13 | 1990-10-11 | Kali Chemie Ag | Reinigungszusammensetzungen |
| US5424010A (en) * | 1993-01-06 | 1995-06-13 | Duliba; Edward P. | Light duty liquid detergent composition containing 3-methyl-3-methoxy-butanol |
| JP3390245B2 (ja) * | 1993-06-01 | 2003-03-24 | 富士通株式会社 | 洗浄液及び洗浄方法 |
| DE19501661C2 (de) * | 1995-01-20 | 1996-11-21 | Herberts Gmbh | Verfahren zur Reinigung von Geräten und Gerätereiniger zur Durchführung des Verfahrens |
| US5827809A (en) * | 1996-10-15 | 1998-10-27 | Vulcan Materials Company | Low-residue macroemulsion cleaner with perchloroethylene |
| CA2445375A1 (en) * | 2001-04-24 | 2002-10-31 | Gage Products Company | Water-based purge composition |
| EP3170884A1 (en) * | 2015-11-20 | 2017-05-24 | The Procter and Gamble Company | Alcohols in liquid cleaning compositions to remove stains from surfaces |
| EP3399012A1 (en) | 2017-05-05 | 2018-11-07 | The Procter & Gamble Company | Liquid detergent compositions with improved rheology |
| EP3399013B1 (en) | 2017-05-05 | 2022-08-03 | The Procter & Gamble Company | Laundry detergent compositions with improved grease removal |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2371647A (en) * | 1943-12-28 | 1945-03-20 | Westvaco Chlorine Products Cor | Degreasing process |
| US2630409A (en) * | 1949-10-06 | 1953-03-03 | Du Pont | Paint and varnish remover |
| US3535392A (en) * | 1958-02-03 | 1970-10-20 | Ppg Industries Inc | Stabilized methylchloroform |
| US3179609A (en) * | 1958-09-25 | 1965-04-20 | Union Carbide Corp | Finish removal formulation |
| US3338756A (en) * | 1963-10-28 | 1967-08-29 | Hooker Chemical Corp | Method for removing coatings |
| US3423323A (en) * | 1964-11-16 | 1969-01-21 | Exxon Research Engineering Co | Process for cleaning olefin separation equipment |
| US3475343A (en) * | 1965-03-23 | 1969-10-28 | Chisso Corp | Process for producing solvent for paint and lacquer |
-
0
- DK DK128856D patent/DK128856A/da unknown
- BE BE754318D patent/BE754318A/xx unknown
-
1969
- 1969-08-06 DE DE19691940018 patent/DE1940018A1/de active Pending
-
1970
- 1970-07-16 CH CH1080570A patent/CH531561A/de not_active IP Right Cessation
- 1970-07-30 FR FR7028961A patent/FR2057946A5/fr not_active Expired
- 1970-08-04 US US00060924A patent/US3737386A/en not_active Expired - Lifetime
- 1970-08-04 GB GB3765070A patent/GB1319068A/en not_active Expired
- 1970-08-06 NL NL7011628A patent/NL7011628A/xx unknown
-
1973
- 1973-04-12 US US00350393A patent/US3856695A/en not_active Expired - Lifetime
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3988256A (en) * | 1974-04-03 | 1976-10-26 | Allied Chemical Corporation | Photoresist stripper rinse |
| US4085059A (en) * | 1974-05-02 | 1978-04-18 | Bunker Ramo Corporation | Foam type coating remover |
| US4220549A (en) * | 1978-05-04 | 1980-09-02 | Ronnie J. Moore | Method for removing reflective decal |
| US4333845A (en) * | 1978-08-11 | 1982-06-08 | Grow Group, Inc. | Coating composition thinner for decreasing pollution resulting from the application of a coating composition |
| US4271214A (en) * | 1978-09-07 | 1981-06-02 | Nippon Paint Co., Ltd. | Method for recovering acrylic resin from excess of sprayed powder coating composition by using aromatic solvents |
| US4309300A (en) * | 1979-05-04 | 1982-01-05 | Mcdonnell Douglas Corporation | Cleaning solvent and method of cleaning a metal surface |
| US4336024A (en) * | 1980-02-22 | 1982-06-22 | Airwick Industries, Inc. | Process for cleaning clothes at home |
| US4421665A (en) * | 1980-08-25 | 1983-12-20 | Lloyd Eugene A | Contact lens cleaning composition containing lipid solvent and method of using |
| US4664721A (en) * | 1981-12-07 | 1987-05-12 | Intercontinental Chemical Corporation | Printing screen cleaning and reclaiming compositions |
| US4518518A (en) * | 1983-03-30 | 1985-05-21 | Amchem Products, Inc. | Cold paint stripping composition |
| FR2551766A1 (fr) * | 1983-09-13 | 1985-03-15 | Elf Aquitaine | Composition aqueuse pour la dispersion de substances hydrophobes applicable notamment au nettoyage d'objets souilles par une peinture ou similaire |
| EP0139560A1 (fr) * | 1983-09-13 | 1985-05-02 | Societe Nationale Elf Aquitaine | Composition aqueuse pour la dispersion de substances hydrophobes, applicable notamment au nettoyage d'objets souillés par une peinture ou similaire |
| US4810411A (en) * | 1986-04-16 | 1989-03-07 | E. I. Du Pont De Nemours And Company | Solvent-based fabric protector |
| US5102573A (en) * | 1987-04-10 | 1992-04-07 | Colgate Palmolive Co. | Detergent composition |
| EP0320394A3 (fr) * | 1987-12-09 | 1990-05-23 | Gérard Grandry | Liquide adjuvant pour la pulvérisation et le lavage des pulvérisateurs |
| FR2624518A1 (fr) * | 1987-12-09 | 1989-06-16 | Grandry Gerard | Liquide adjuvant pour la pulverisation, le lavage, le degraissage, le detachage ou la dilution de peinture |
| US5045224A (en) * | 1988-01-12 | 1991-09-03 | Toyota Jidosha Kabushiki Kaisha | Color-change washing solution, suitable for spray coating devices |
| US5690747A (en) * | 1988-05-20 | 1997-11-25 | The Boeing Company | Method for removing photoresist with solvent and ultrasonic agitation |
| US4965010A (en) * | 1988-10-27 | 1990-10-23 | Swett Ralph R | Paint stripping composition containing ketones, methanol, and aromatic hydrocarbon |
| US5676764A (en) * | 1993-02-12 | 1997-10-14 | Mcdonnell Douglas Corporation | Low vapor pressure solvent |
| EP0698118A4 (en) * | 1994-03-11 | 1999-06-16 | Biogenex Lab | DEPARAFFINIZATION COMPOSITIONS AND METHOD FOR USE THEREOF |
| US6200945B1 (en) | 1999-05-20 | 2001-03-13 | Mcdonnell Douglas Corporation | Environmentally safe solvent composition |
| EP1179041B2 (en) † | 1999-05-20 | 2008-02-20 | The Boeing Company | Environmentally safe solvent composition |
| CN106118212A (zh) * | 2016-08-18 | 2016-11-16 | 中国航天科技集团公司第九研究院第七七研究所 | 航天印刷电路板的三防涂层去除方法及去除剂和去除剂制备 |
| CN106118212B (zh) * | 2016-08-18 | 2019-08-20 | 中国航天科技集团公司第九研究院第七七一研究所 | 航天印刷电路板的三防涂层去除方法及去除剂和去除剂制备 |
| CN110129813A (zh) * | 2019-05-08 | 2019-08-16 | 东莞市杰川电子材料科技有限公司 | 用于清洗稀土的清洗剂及其制备方法 |
| CN110129813B (zh) * | 2019-05-08 | 2023-09-12 | 东莞市杰川电子材料科技有限公司 | 用于清洗稀土的清洗剂及其制备方法 |
| WO2024247638A1 (ja) * | 2023-05-29 | 2024-12-05 | 第一工業製薬株式会社 | 樹脂用除去剤及び樹脂の除去方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CH531561A (de) | 1972-12-15 |
| US3856695A (en) | 1974-12-24 |
| DE1940018A1 (de) | 1971-02-18 |
| NL7011628A (enrdf_load_stackoverflow) | 1971-02-09 |
| GB1319068A (en) | 1973-05-31 |
| DK128856A (enrdf_load_stackoverflow) | |
| FR2057946A5 (enrdf_load_stackoverflow) | 1971-05-21 |
| BE754318A (fr) | 1971-01-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3737386A (en) | Solvent based detergent | |
| AU2011289224B2 (en) | Carboxy ester ketal removal compositions, methods of manufacture, and uses thereof | |
| US6096699A (en) | Environmentally friendly solvent | |
| CA2382600C (en) | Environmentally friendly solvent | |
| US5503681A (en) | Method of cleaning an object | |
| US3832235A (en) | Vapor solvent paint removing method | |
| US2396776A (en) | Cleaning composition | |
| JP2523111B2 (ja) | 解乳化清浄製剤 | |
| AU646246B2 (en) | Method and apparatus for cleaning | |
| DE19504192A1 (de) | Verdickende wäßrige Reinigungsmittel für harte Oberflächen | |
| WO2017064551A1 (en) | Cleaning formulations with improved performances | |
| US5744437A (en) | Single phase liquid composition for cleaning and paint stripping and use thereof | |
| US2897104A (en) | Silicone resin remover and method | |
| US5472631A (en) | Method of removing oil-based paint from painting articles | |
| PL71975B1 (en) | Process for removing intaglio ink from a wiping cylinder[US3389656A] | |
| US2697674A (en) | Method for cleaning paint brushes | |
| US3717590A (en) | Liquid water-soluble detergent compositions | |
| US2951043A (en) | Cleaner for paint applicators | |
| CN114214126A (zh) | 水基清洗组合物及其制备方法和应用 | |
| DE2505252A1 (de) | Verfahren zum reinigen und entfetten von gegenstaenden | |
| US2383114A (en) | Detergent composition | |
| DE4102709C1 (en) | Degreasing metal surfaces using aq. prepn. - contg. biologically degradable adducts of lower alkylene oxide(s), fatty alcohol(s) and cationic surfactants | |
| JP3375104B2 (ja) | 物品の洗浄方法 | |
| DE3004835C2 (de) | Selbsttätig wirkende Reinigungsflüssigkeit | |
| US1785417A (en) | Paint and varnish remover |