US3728102A - Anti-piping composition for the production of metal ingots and castings - Google Patents

Anti-piping composition for the production of metal ingots and castings Download PDF

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Publication number
US3728102A
US3728102A US00119943A US3728102DA US3728102A US 3728102 A US3728102 A US 3728102A US 00119943 A US00119943 A US 00119943A US 3728102D A US3728102D A US 3728102DA US 3728102 A US3728102 A US 3728102A
Authority
US
United States
Prior art keywords
composition
piping
flour
aluminium
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00119943A
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English (en)
Inventor
W Buckingham
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foseco International Ltd
Original Assignee
Foseco International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foseco International Ltd filed Critical Foseco International Ltd
Application granted granted Critical
Publication of US3728102A publication Critical patent/US3728102A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • B22D27/06Heating the top discard of ingots

Definitions

  • the exothermic compositions used as anti-piping compounds are generally of an aluminothermic composition i.e. containing finely divided aluminium and oxidising agent therefore. It is possible to use aluminium in relatively pure elemental form, as powders, turnings, sawings or the like but since it is desirable to keep the cost of the antipiping compound as low as possible it is convenient to use the commercial material known as ball mill dust. This is the ground product from slags obtained in the metallurgy of aluminium and usually contains alumina, flux residues and the like and aproportion of aluminium metal. The proportion of aluminium may vary Widely depending on the source of the ball mill dust but is generally 10 to 30% by weight.
  • a fluoride e.g. an alkali metal or alkaline earth metal fluoride, or aluminium fluoride
  • a mixed fluoride salt e.g. cryolite
  • a fluoro complex salt such as a titano, boro or silico fluoride
  • an anti-piping composition in powder or granular form which comprises aluminium and oxidising agent therefor together with an organic additive which at the temperature of the molten metal generates flame.
  • organic materials comprising high proportions of carbon hydrogen and oxygen are very suitable for the purpose and many cellulosic materials are of value, for example, paper pulp, wood pulp and shredded paper. Materials such as wood flour and the like are particularly suitable.
  • the material should preferably have a low bulk densitypreferably 0.2-0.4 gm./cc.-and a low moisture content.
  • wood flour and sawdust preferably from hard wood and of particle size passing a 10 B88 mesh but without a substantial quantity passing a E88 mesh
  • ground cobs or cob flour grain hulls and nut shells
  • polystyrene and similar plastics chips cereal flours
  • organic gums such as sulphite lye and gum arabic being usable but not preferred.
  • a particularly preferred materials is 20+ 100 E58 mesh cob flour.
  • a proportion of a humectant such as glycol or glycerol in a proportion of 1-20%, preferably 5-15% by weight of the composition to aid in reducing dust from the material.
  • a humectant such as glycol or glycerol
  • the anti-piping compositions according to this invention may contain a flame retardant which serves to spread the action of the anti-piping compound over a period of time rather than allowing it to proceed violently for only a short period of time.
  • a flame retardant which serves to spread the action of the anti-piping compound over a period of time rather than allowing it to proceed violently for only a short period of time.
  • Suitable materials for this purpose are silica flour and sodium chloride.
  • a granular anti-piping composition for application to the surface of molten metal during casting thereof, the composition consisting essentially of aluminum and an oxidizing agent therefor and wherein the composition generates fumes upon its ignition after application to the surface of the molten metal, the improvement comprising including in the composition 1 -20% by weight of an organic additive, said organic additive being capable of generating a flame at the temperature of the molten metal and being present in an amount sufficient to consume the fumes produced by the composition.
  • An anti-piping composition according to claim 1 which includes a humectant in an amount of 1-20 by weight of the composition.
  • An anti-piping composition according to claim 1 which contains a proportion of a flame retardant.
  • a method of casting molten metal comprising pouring said metal into a mold and applying to the surface of said molten metal during solidification in the mold a granular exothermic anti-piping composition containing aluminum and an oxidizing agent therefor, whereby application of the composition to the molten metal generates fumes, the improvement comprising applying to the surface of said molten metal with said anti-piping composition an organic additive which generates a flame at the temperature of said molten metal the additive being applied in an amount sufiicient to substantially consume the generated fumes.
  • An anti-piping composition according to claim 1 wherein the organic additive is a member selected from the group consisting of paper pulp, shredded paper, wood flour, sawdust and cob flour.
  • the organic additive is a member selected from the group consisting of paper pulp, shredded paper, wood flour, sawdust and cob flour.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Mold Materials And Core Materials (AREA)
  • Paper (AREA)
  • Fireproofing Substances (AREA)
US00119943A 1967-12-13 1971-03-01 Anti-piping composition for the production of metal ingots and castings Expired - Lifetime US3728102A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5670467 1967-12-13

Publications (1)

Publication Number Publication Date
US3728102A true US3728102A (en) 1973-04-17

Family

ID=10477325

Family Applications (1)

Application Number Title Priority Date Filing Date
US00119943A Expired - Lifetime US3728102A (en) 1967-12-13 1971-03-01 Anti-piping composition for the production of metal ingots and castings

Country Status (4)

Country Link
US (1) US3728102A (enrdf_load_stackoverflow)
JP (1) JPS5220931B1 (enrdf_load_stackoverflow)
DE (1) DE1814637A1 (enrdf_load_stackoverflow)
FR (1) FR1595059A (enrdf_load_stackoverflow)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3878142A (en) * 1971-12-03 1975-04-15 Tidd Chemisch Tech Produkte G Compositions for lining casting moulds and related articles and method of making such articles
US4031046A (en) * 1974-04-02 1977-06-21 Firma Tido Chemisch-Technische Produkte Gmbh Exothermic lining for metallurgical purposes and method of making the same
US4039326A (en) * 1975-04-17 1977-08-02 Acciaierie Di Piombino S.P.A. Antiscorific powder for the casting of steels into ingot molds

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1280768A (en) * 1970-03-23 1972-07-05 Foseco Int Anti-piping compounds
IT1063606B (it) * 1976-01-15 1985-02-11 Fonderit S R L Composizione per uso metallurgico,particolarmente polvere di copertura del metallo fuso nella testa di lingottiere
JPS5548807U (enrdf_load_stackoverflow) * 1978-09-25 1980-03-31

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3878142A (en) * 1971-12-03 1975-04-15 Tidd Chemisch Tech Produkte G Compositions for lining casting moulds and related articles and method of making such articles
US4031046A (en) * 1974-04-02 1977-06-21 Firma Tido Chemisch-Technische Produkte Gmbh Exothermic lining for metallurgical purposes and method of making the same
US4039326A (en) * 1975-04-17 1977-08-02 Acciaierie Di Piombino S.P.A. Antiscorific powder for the casting of steels into ingot molds

Also Published As

Publication number Publication date
DE1814637A1 (de) 1969-07-10
FR1595059A (enrdf_load_stackoverflow) 1970-06-08
JPS5220931B1 (enrdf_load_stackoverflow) 1977-06-07

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