US3723105A - Process for preparing selenium tellurium alloys - Google Patents

Process for preparing selenium tellurium alloys Download PDF

Info

Publication number
US3723105A
US3723105A US00180000A US3723105DA US3723105A US 3723105 A US3723105 A US 3723105A US 00180000 A US00180000 A US 00180000A US 3723105D A US3723105D A US 3723105DA US 3723105 A US3723105 A US 3723105A
Authority
US
United States
Prior art keywords
tellurium
selenium
alloy
alloys
potential
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00180000A
Inventor
N Kitajima
T Masaki
H Kondo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canon Inc filed Critical Canon Inc
Application granted granted Critical
Publication of US3723105A publication Critical patent/US3723105A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02—Charge-receiving layers
    • G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/08—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic
    • G03G5/082—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic and not being incorporated in a bonding material, e.g. vacuum deposited
    • G03G5/08207—Selenium-based
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C28/00—Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00

Definitions

  • a selenium-tellurium alloy suitable for electrophotographic photosensitive member is prepared by heating a mixture of selenium and tellurium containing 125% by weight of tellurium to a temperative not lower than 350 C. to melt the mixture, cooling gradually the molten selenium and tellurium to around the melting point of the selenium-tellurium alloy at a rate not higher than 100 C./hr. and then quenching to room temperature within 10 minutes.
  • This invention relates to a process for preparing selenium-tellurium alloys having excellent electrophotographic photosensitive characteristics and high durability.
  • the figure is a graph for explaining the definition of the sensitivity used in this invention.
  • the mixture of selenium and tellurium used in this invention contains 1-25% by weight of tellurium, preferred with 520% by weight, and balance of selenium.
  • tellurium When the contents of tellurium is less than 1% by weight, dark resistance increases to reduce the sensitivity while dark resistance becomes too low to use as an electrophotographic photosensitive member when the contents of tellurium is higher than 25% by weight.
  • the cooling procedure in this invention comprises two steps i.e. gradual cooling and quenching.
  • the gradual cooling step is carried out by cooling the melt of the selenium and tellurium at a temperature not lower than 350 C. to around the melting point of the seleniumtellurium alloys at a cooling rate of not higher than C./hr.
  • the quenching step is carried out by quenching the selenium and tellurium composition at around the melting point to room temperature within 10 minutes. It is preferable to quench the alloys in an instant.
  • the gradual cooling step produces a relatively long binding chain of selenium-tellurium in a hexagonal structure and the quenching step freeze the thermally and chemically stable binding chain group in the alloy.
  • thermal formation of ring-like or monoclinic structure of selenium-tellurium chain showing undesirable photosensible characteristics is inhibited and thereby deterioration of photosensitive characteristics of the selenium-tellurum alloy is prevented.
  • the selenium-tellurium alloys obtained according to the present invention may be formed as a photosensitive layer on a support by a conventional vapor depositing method to produce a photosensitive member for electrophotographic processes.
  • the photosensitive member may be that of three layer structure, that is, an insulating layer may overlie the selenium-tellurium alloy photosenstive layer.
  • EXAMPLE 1 (1) In a Pyrex glass vessel having a softening point of about 600 C. were placed selenium particles (purity, 99.99%) having radius of about 1.5 mm. and powdered tellurium (120-180 mesh) in a mixing ratio of 85 to by weight to fill /2 volume of the vessel. The vessel was brought to a pressure of about 5 10 torr and the upper end of the vessel was sealed, and then the sealed vessel was placed in a stainless steel container. Aluminum oxide wool was packed in the stainless steel container so as to prevent the Pyrex glass vessel from contacting with the stainless steel container. The stainless container was, then, covered with a lid, placed in an electric furnace, and heated.
  • the stainless steel container was vibrated for about 2 hours so as to agitate the melt in the Pyrex glass vessel. The heating was stopped, cooled gradually at a rate of about 100 C./hr. to about 260 C. and then thrown into water to quench the melt.
  • the seleniumtellurium alloy thus produced is hereinafter called A.
  • Each of the above-mentioned three kinds of selenium tellurium alloy was vapor-deposited on a conductive base plate at a pressure of about 2 10 torr with a distance of cm. between the base plate and the melting boat containing the selenium-tellurium alloy at the same base plate temperature for the same vapor-depositing time to produce an electrophotographic photosensitive plate.
  • a conductive base plate There may be used various metals and conductive glasses, but a nickel-plated brass of about 1 mm. thick was employed here.
  • Photosensitive members obtained by a process as mentioned above were subjected to an electrophotographic process comprising uniform charging and exposure and an electrophotometer was used for measuring characteristics of the photosensitive member.
  • the sensitivity is defined as an exposure amount when a dark decay potential a and a light decay potential b satisfy the relation:
  • Example 2 The procedure of Example 1 above was followed except that the ratio of selenium to tellurium by weight was 95:5 or :20 in place of :15 to obtain alloys A B and C or alloys A B and C The resulting alloy was used as a photoconductive layer to form a photosensitive plate. The characteristics of the photosensitive plate was measured by an electrophotometer. The result is shown in Table 2 and Table 3.
  • EXAMPLE 4 In a way similar to Example 3, a photosensitive member was given a surface potential of 2.2 kv. by a primary charging, subjected to projection of a light and dark pattern at an exposure amount of 6 lux. sec. simultaneously with applying a secondary corona charging of +7 kv. and then subjected to a blanket irradiation to produce an electrostatic latent image (cf. Japanese patent publication No. 24748/1968).
  • the photosensitive member using selenium-tellurium alloy A shows an electrostatic contrast far higher than that using selenium-tellurium alloy B or C.
  • a photosensitive member obtained by vapor-depositing the selenium-tellurium alloy produced by the present invention is particularly suitable for electrophotographic processes since the residual potential is almost zero and a high electrostatic contrast can be obtained and thereby a clear and fogless image is produced.
  • a process for preparing a selenium-tellurium alloy which comprises heating a mixture of selenium and tellurium containing 125% by weight of tellurium to a temperature not lower than 350 C. to melt the mixture, cooling gradually the molten selenium and tellurium to around the melting point of the selenium-tellurium alloy at a rate not higher than 100 C./hr. and then quenching to room temperature within 10 minutes.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Photoreceptors In Electrophotography (AREA)

Abstract

A SELENIUM-TELLURIUM ALLOY SUITABLE FOR ELECTROPHOTOGRAPHIC PHOTOSENITIVE MEMBER IS PREPARED BY HEATING A MIXTURE OF SELENIUM AND TELLURIUM CONTAINING 1-25% BY WEIGHT OF TELLURIUM TO A TEMPERATIVE NOT LOWER THAN 350*C. TO MELT THE MIXTURE, COOLING GRADUALLY THE MOLTEN SELENIUM AND TELLURIUM TO AROUND THE MELTING POINT OF THE SELENIUM-TELLURIUM ALLOY AT A RATE NOT HIGHER THAN 100*C./HR. AND THEN QUENCHING TO ROOM TEMPERATURE WITHIN 10 MINUTES.

Description

March 1973 NOBUO KITAJIMA- ETAL 3,723,105
PROCESS FOR PREPARING SELENIUM-TELLURIUM ALLOYS Filed Sept. 13, 1971 SURFACE POTENTlAL (V) United States Patent U.S. Cl. 75--134 H 1 Claim ABSTRACT OF THE DISCLOSURE A selenium-tellurium alloy suitable for electrophotographic photosensitive member is prepared by heating a mixture of selenium and tellurium containing 125% by weight of tellurium to a temperative not lower than 350 C. to melt the mixture, cooling gradually the molten selenium and tellurium to around the melting point of the selenium-tellurium alloy at a rate not higher than 100 C./hr. and then quenching to room temperature within 10 minutes.
BACKGROUND OF THE INVENTION Field of the invention This invention relates to a process for preparing selenium-tellurium alloys having excellent electrophotographic photosensitive characteristics and high durability.
Description of the prior art It is well known that selenium-tellurium alloys are used for an electrophotographic photosensitive member. The photosensitivity has been improved by various methods such as methods disclosed in U.S. Pat. No. 2,745,327 and U.S. Pat. No. 2,803,541 in which contents of selenium and tellurium are changed, methods disclosed in J. C. Schottmiller, D. L. Bauman and C. Wood: Journal of Applied Physics, vol. 39, No. 3, pp. 1663-9 (1968) in which an element other than selenium and tellurium is added to the alloy, and methods disclosed in Taul. H. Keck: Journal of Optical Society of America, vol. 42, No. 4, pp. 221- (1952) and Taul. H. Keck: Journal of Optical Society of America, vol. 41, No. 1, pp. 53-55 (1951) in which the depositing conditions such as a temperature of deposit base and depositing time are appropriately controlled upon preparing the photosensitive member.
The above mentioned prior arts fails to produce selenium-tellurium alloys having satisfactory electrophotographic properties. Particularly, it has been very diflicult to obtain selenium-tellurium alloys free from residual potential which causes fog.
SUMMARY OF THE INVENTION for preparing selenium-tellurium alloys having a good electrophotographic characteristics.
It is another object of this invention to provide a process for preparing selenium-tellurium alloys of good photosensitivity and high durability for electrophotography.
ice
It is a further object of this invention to provide a process for preparing selenium-tellurium alloys forming no residual potential and capable of producing electrostatic latent images of high contrast when used in electrophotographic processes.
It is still another object of this invention to provide a process for producing selenium-tellurium alloys having photosensitive characteristics suitable for electrophotographic processes by controlling temperature conditions in the preparation.
BRIEF DESCRIPTION OF THE DRAWING The figure is a graph for explaining the definition of the sensitivity used in this invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS The mixture of selenium and tellurium used in this invention contains 1-25% by weight of tellurium, preferred with 520% by weight, and balance of selenium. When the contents of tellurium is less than 1% by weight, dark resistance increases to reduce the sensitivity while dark resistance becomes too low to use as an electrophotographic photosensitive member when the contents of tellurium is higher than 25% by weight.
The cooling procedure in this invention comprises two steps i.e. gradual cooling and quenching. The gradual cooling step is carried out by cooling the melt of the selenium and tellurium at a temperature not lower than 350 C. to around the melting point of the seleniumtellurium alloys at a cooling rate of not higher than C./hr. The quenching step is carried out by quenching the selenium and tellurium composition at around the melting point to room temperature within 10 minutes. It is preferable to quench the alloys in an instant.
The mechanism of formation of the selenium-tellurium alloy of excellent electrophotographic characteristics is not yet fully understood, but it is believed as follows.
The gradual cooling step produces a relatively long binding chain of selenium-tellurium in a hexagonal structure and the quenching step freeze the thermally and chemically stable binding chain group in the alloy. As the result, thermal formation of ring-like or monoclinic structure of selenium-tellurium chain showing undesirable photosensible characteristics is inhibited and thereby deterioration of photosensitive characteristics of the selenium-tellurum alloy is prevented.
There is a prior art for producing selenium-tellurium alloys which comprises mixing powdered selenium and powdered tellurium of high purity, melting under vacuum and quenching the melt by throwing into water. In this prior art, it is believed that the hexagonal structure is not sufliciently formed and the relatively unstable binding chain group is frozen to produce a selenium-tellurium alloy having undesirable photosensitive characteristics.
There is another prior art for producing selenium-tellurium alloys which comprises mixing powdered selenium and powdered tellurium of high purity, melting under vacuum and cooling gradually to room temperature by allowing to stand. In this case, it is believed that the gradual cooling at the temperature range below the melting point of the selenium-tellurium mixture results in formation of binding chain of selenium and tellurium in a form of ring-like or monoclinic structure which deteriorates photosensitive characteristics.
The selenium-tellurium alloys obtained according to the present invention may be formed as a photosensitive layer on a support by a conventional vapor depositing method to produce a photosensitive member for electrophotographic processes. The photosensitive member may be that of three layer structure, that is, an insulating layer may overlie the selenium-tellurium alloy photosenstive layer.
The following examples are given for purposes of illustration and not by way of limitation.
EXAMPLE 1 (1) In a Pyrex glass vessel having a softening point of about 600 C. were placed selenium particles (purity, 99.99%) having radius of about 1.5 mm. and powdered tellurium (120-180 mesh) in a mixing ratio of 85 to by weight to fill /2 volume of the vessel. The vessel was brought to a pressure of about 5 10 torr and the upper end of the vessel was sealed, and then the sealed vessel was placed in a stainless steel container. Aluminum oxide wool was packed in the stainless steel container so as to prevent the Pyrex glass vessel from contacting with the stainless steel container. The stainless container was, then, covered with a lid, placed in an electric furnace, and heated. When the temperature of the furnace was about 550 C., the stainless steel container was vibrated for about 2 hours so as to agitate the melt in the Pyrex glass vessel. The heating was stopped, cooled gradually at a rate of about 100 C./hr. to about 260 C. and then thrown into water to quench the melt. The seleniumtellurium alloy thus produced is hereinafter called A.
(2) A stainless steel container containing a melt obtained by heating at about 550 C. for about 2 hours with stirring in a way similar to item (1) above was directly thrown into water for quenching. The resulting seleniumtellurium alloy is hereinafter called B.
(3) A melt obtained by heating at about 550 C. for about 2 hours in a way similar to item 1) above was cooled to room temperature by allowing to stand. The resuiting selenium-tellurium alloy is hereinafter called C.
The preparation procedures in items (2) and (3) are prior arts which are given here for comparing with the present invention.
Each of the above-mentioned three kinds of selenium tellurium alloy was vapor-deposited on a conductive base plate at a pressure of about 2 10 torr with a distance of cm. between the base plate and the melting boat containing the selenium-tellurium alloy at the same base plate temperature for the same vapor-depositing time to produce an electrophotographic photosensitive plate. There may be used various metals and conductive glasses, but a nickel-plated brass of about 1 mm. thick was employed here.
Photosensitive members obtained by a process as mentioned above were subjected to an electrophotographic process comprising uniform charging and exposure and an electrophotometer was used for measuring characteristics of the photosensitive member.
When a xerographic plate was positively charged (Carlson process) TABLE 1 Base Thickness plate Depositof photo- Sensi- Residual temperaing time, sensitive tivity, potential, ture, C. min. layer, t lux. sec. v.
The sensitivity is defined as an exposure amount when a dark decay potential a and a light decay potential b satisfy the relation:
zero so that any fog is not observed and a clear image of high contrast is obtained.
EXAMPLE 2 The procedure of Example 1 above was followed except that the ratio of selenium to tellurium by weight was 95:5 or :20 in place of :15 to obtain alloys A B and C or alloys A B and C The resulting alloy was used as a photoconductive layer to form a photosensitive plate. The characteristics of the photosensitive plate was measured by an electrophotometer. The result is shown in Table 2 and Table 3.
TABLE 2 [Weight ratio of selenium to tellurium, :5]
Base Thickness plate Depositof photo- Sensi- Residual temperaing time, sensitive tivity, potential, ture, 0 min. layer, a lux. sec. v,
TABLE 3 [Weight ratio of selenium to tellurium, 80:20]
Base Thickness plate Depositof photo- Sensi- Residual temperaing time, sensitive tivity, potential, ture, C. min. layer, lux. sec v EXAMPLE 3 Selenium-tellurium alloy A, B or C produced in Example 1 was vapor-deposited under vacuum on a nickelplated conductive base plate at a base plate temperature of 65 C. and further a polyester film of 25p. thick was adhered with an epoxy resin to the selenium-tellurium alloy deposit layer to product a photosensitive member of three-layer structure. The resulting photosensitive plate was given a uniform surface potential of 2.2 kv. by a primary corona charging and then was subjected to an AC. corona charging of 7.5 kv. simultaneously with projecting a light image at an exposure amount of 6 lux. sec. Further, a blanket radiation was applied to the surface of the photosensitive member (cf. Japanese patent publication No. 23910/ 1967). The dark decoy potential and the light decay potential were measured and the result is shown in Table 4 below.
TABLE 4 Dark surface Light surface Electrostatic potential, v. potential, v. contrast, v.
As is clear from Table 4, a photosensitive member using the alloy A shows an electrostatic contrast far higher than that of the alloy B or alloy C.
EXAMPLE 4 In a way similar to Example 3, a photosensitive member was given a surface potential of 2.2 kv. by a primary charging, subjected to projection of a light and dark pattern at an exposure amount of 6 lux. sec. simultaneously with applying a secondary corona charging of +7 kv. and then subjected to a blanket irradiation to produce an electrostatic latent image (cf. Japanese patent publication No. 24748/1968).
The dark surface potential and the light surface potential were measured. The result is shown in Table 5 below.
As is clear from the above table, the photosensitive member using selenium-tellurium alloy A shows an electrostatic contrast far higher than that using selenium-tellurium alloy B or C.
A photosensitive member obtained by vapor-depositing the selenium-tellurium alloy produced by the present invention is particularly suitable for electrophotographic processes since the residual potential is almost zero and a high electrostatic contrast can be obtained and thereby a clear and fogless image is produced.
What is claimed is:
1. A process for preparing a selenium-tellurium alloy which comprises heating a mixture of selenium and tellurium containing 125% by weight of tellurium to a temperature not lower than 350 C. to melt the mixture, cooling gradually the molten selenium and tellurium to around the melting point of the selenium-tellurium alloy at a rate not higher than 100 C./hr. and then quenching to room temperature within 10 minutes.
References Cited UNITED STATES PATENTS 2,745,327 5/1956 Mengali 961.5 2,803,541 8/1957 Paris 961.5 3,041,166 6/1962 Bardeen 96-1.5 3,655,377 4/1972 Sechak 961.5
CHARLES N. LOVELL, Primary Examiner E. L. WEISE, Assistant Examiner US. Cl. X.R. 961.5; 252-501
US00180000A 1970-09-19 1971-09-13 Process for preparing selenium tellurium alloys Expired - Lifetime US3723105A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP45082399A JPS4930329B1 (en) 1970-09-19 1970-09-19

Publications (1)

Publication Number Publication Date
US3723105A true US3723105A (en) 1973-03-27

Family

ID=13773498

Family Applications (1)

Application Number Title Priority Date Filing Date
US00180000A Expired - Lifetime US3723105A (en) 1970-09-19 1971-09-13 Process for preparing selenium tellurium alloys

Country Status (2)

Country Link
US (1) US3723105A (en)
JP (1) JPS4930329B1 (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3816116A (en) * 1970-12-29 1974-06-11 Canon Kk N-type photosensitive member for electrophotography
US3957693A (en) * 1968-03-19 1976-05-18 Siemens Aktiengesellschaft Process for producing selenium homogeneously doped with tellurium
US3990894A (en) * 1969-10-29 1976-11-09 Katsuragawa Denki Kabushiki Kaisha Method of preparing photosensitive element for use in electrophotography
US4001014A (en) * 1973-09-17 1977-01-04 Matsushita Electric Industrial Co., Ltd. Electrophotographic photosensitive plate having tellurium present in varying concentrations across its thickness
US4049505A (en) * 1974-10-14 1977-09-20 Chatterji Arun K Photoconductors for electrostatic imaging systems
FR2458100A1 (en) * 1979-05-31 1980-12-26 Ricoh Kk PHOTOCONDUCTIVE MATERIAL FOR ELECTROPHOTOGRAPHIC COPYING MACHINE
US4277551A (en) * 1979-08-20 1981-07-07 Minnesota Mining And Manufacturing Company Electrophotographic plate having charge transport overlayer
US4389389A (en) * 1982-08-02 1983-06-21 Xerox Corporation Process for preparation of high purity tellurium
US4411698A (en) * 1982-08-02 1983-10-25 Xerox Corporation Process for reclaimation of high purity selenium, tellurtum, and arsenic from scrap alloys
US4460408A (en) * 1982-08-05 1984-07-17 Xerox Corporation Process for preparation of chalcogenide alloys by coreduction of esters
US4548800A (en) * 1982-08-02 1985-10-22 Xerox Corporation Process for selenium purification
US5084301A (en) * 1990-09-04 1992-01-28 Xerox Corporation Alloying and coating process

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3070094B1 (en) * 2017-08-11 2019-09-06 Isorg DISPLAY SYSTEM COMPRISING AN IMAGE SENSOR

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3957693A (en) * 1968-03-19 1976-05-18 Siemens Aktiengesellschaft Process for producing selenium homogeneously doped with tellurium
US3990894A (en) * 1969-10-29 1976-11-09 Katsuragawa Denki Kabushiki Kaisha Method of preparing photosensitive element for use in electrophotography
US3816116A (en) * 1970-12-29 1974-06-11 Canon Kk N-type photosensitive member for electrophotography
US4001014A (en) * 1973-09-17 1977-01-04 Matsushita Electric Industrial Co., Ltd. Electrophotographic photosensitive plate having tellurium present in varying concentrations across its thickness
US4049505A (en) * 1974-10-14 1977-09-20 Chatterji Arun K Photoconductors for electrostatic imaging systems
FR2458100A1 (en) * 1979-05-31 1980-12-26 Ricoh Kk PHOTOCONDUCTIVE MATERIAL FOR ELECTROPHOTOGRAPHIC COPYING MACHINE
US4277551A (en) * 1979-08-20 1981-07-07 Minnesota Mining And Manufacturing Company Electrophotographic plate having charge transport overlayer
US4389389A (en) * 1982-08-02 1983-06-21 Xerox Corporation Process for preparation of high purity tellurium
US4411698A (en) * 1982-08-02 1983-10-25 Xerox Corporation Process for reclaimation of high purity selenium, tellurtum, and arsenic from scrap alloys
US4548800A (en) * 1982-08-02 1985-10-22 Xerox Corporation Process for selenium purification
US4460408A (en) * 1982-08-05 1984-07-17 Xerox Corporation Process for preparation of chalcogenide alloys by coreduction of esters
US5084301A (en) * 1990-09-04 1992-01-28 Xerox Corporation Alloying and coating process

Also Published As

Publication number Publication date
JPS4930329B1 (en) 1974-08-12

Similar Documents

Publication Publication Date Title
US3467548A (en) Method of making xerographic plate by vacuum evaporation of selenium alloy
US3723105A (en) Process for preparing selenium tellurium alloys
US2803542A (en) Xerographic plate
US3524745A (en) Photoconductive alloy of arsenic,antimony and selenium
US2822300A (en) Photoconductive material
US3973960A (en) Electrophotographic element having a selenium layer containing arsenic in varying concentrations across the layer thickness
US4842973A (en) Vacuum deposition of selenium alloy
US3903107A (en) Direct alpha to X phase conversion of metal containing phthalocyanine
JPS5913021B2 (en) Composite photoreceptor material
US2863768A (en) Xerographic plate
US4822712A (en) Reduction of selenium alloy fractionation
US3498835A (en) Method for making xerographic plates
US3932180A (en) Direct alpha to X phase conversion of metal-free phthalocyanine
US4601965A (en) Photosensitive material for use in electrophotography
US4008082A (en) Method for producing an electrophotographic recording material
US3501343A (en) Light insensitive xerographic plate and method for making same
US4585621A (en) Vapor-deposited film of selenium or selenium alloy for electrophotography
US3966470A (en) Photo-conductive coating containing Ge, S, and Pb or Sn
US3490903A (en) Alloys of antimony and selenium used in photoconductive elements
US3816116A (en) N-type photosensitive member for electrophotography
US4894307A (en) Processes for preparing and controlling the fractionation of chalcogenide alloys
US3427157A (en) Xerographic process utilizing a photoconductive alloy of thallium in selenium
US5002734A (en) Processes for preparing chalcogenide alloys
US4859411A (en) Control of selenium alloy fractionation
US3666554A (en) Manufacture of electrophotographic plate