US3717303A - Method of vacuum-packing insecticidal materials - Google Patents
Method of vacuum-packing insecticidal materials Download PDFInfo
- Publication number
- US3717303A US3717303A US3717303DA US3717303A US 3717303 A US3717303 A US 3717303A US 3717303D A US3717303D A US 3717303DA US 3717303 A US3717303 A US 3717303A
- Authority
- US
- United States
- Prior art keywords
- bag
- pressure
- sheet
- diffuser
- chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/26—Articles or materials wholly enclosed in laminated sheets or wrapper blanks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
- B65B31/02—Filling, closing, or filling and closing, containers or wrappers in chambers maintained under vacuum or superatmospheric pressure or containing a special atmosphere, e.g. of inert gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
- B65B31/02—Filling, closing, or filling and closing, containers or wrappers in chambers maintained under vacuum or superatmospheric pressure or containing a special atmosphere, e.g. of inert gas
- B65B31/024—Filling, closing, or filling and closing, containers or wrappers in chambers maintained under vacuum or superatmospheric pressure or containing a special atmosphere, e.g. of inert gas specially adapted for wrappers or bags
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/52—Details
- B65D75/54—Cards, coupons, or other inserts or accessories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
- B65D81/20—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas
- B65D81/2069—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas in a special atmosphere
- B65D81/2084—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas in a special atmosphere in a flexible container
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
Definitions
- ABSTRACT 4 Claims 2 Drawing Figures METHOD OF VACUUM-PACKING INSECTICIDAL MATERIALS SUMMARY OF THE INVENTION pregnate sheets of absorbent material. When these sheets are exposed to the open air they release vapors which are capable of killing insects. The evaporation of the active insecticidal compound is slowed by the presence of the liquid having a high viscosity.
- the diffusers In order to prevent the insecticidal product from gradually evaporating during storage the diffusers, with their impregnated sheets, have heretofore been enclosed in small air-tight bags such, for example, as bags made of plastic material, and heat sealed.
- the quantity of air contained in the sealed bag is by no means negligible, because of the thickness of the diffusing box, and the presence of a relatively large volume of oxygen inside the sealed package results in a slow deteriation of the active insecticidal product.
- the air contained in the bag is slightly humid, hydrolysis of the active product may result, followed by an oxidation which yields acid compounds, such as formic acid.
- the presence of formic acid which has tear-inducing and irritating properties, becomes immediately apparent when the bag is open.
- the efficacity of diffusers containing a sheet impregnated with insecticide is greatly reduced as a consequence of this deteriation of the active product.
- the heat sealing step which is used to close the bag may not be perfectly carried out. This disadvantage is not detectable at the time of manufacture and the incompletely sealed bag will admit air.
- the active product such as dimethyldichloro-vinylphosphate, is then oxidized, not only by the oxygen originally contained inside the bag, but also by oxygen which thereafter penetrates into the bag, and the decrease in the efiicacity of the insecticidal sheet which results therefrom is very substantial.
- the present invention is accordingly directed to a method of packaging an insecticidal product, and in particular a sheet impregnated with an insecticide which is to slowly evaporate within a perforated box which acts as a diffuser.
- This process is essentially characterized by the fact that the perforated box holding the impregnated sheet is positioned inside a bag made of a flexible gas-tight material.
- This bag is placed in a chamber in which a partial vacuum is induced.
- An inert gas is then introduced into this chamber to increase the pressure to a value which is still less than atmospheric pressure.
- the bag containing the diffuser is then sealed and the chamber returned to atmospheric pressure.
- the bag containing the diffuser with its impregnated sheet is made of a sheet made of plastic material.
- This sheet of plastic material may be formed of several superposed layers of different plastic materials, the innermost of which is heat-scalable.
- the sheet from which the bag is made may be from 0.05 mm to 0.5 mm thick.
- the bag is heat sealed.
- the pressure inside the chamber is reduced to from 1 to 10 cm of mercury.
- the inert gas introduced into the chamber is nitrogen.
- the pressure at which the inert gas is introduced is between 30 and cm of mercury.
- the inert gas is introduced in such a way as to sweep the chamber and thereby still further reduce the residual quantity of oxygen.
- the inert gas it is preferable to limit the introduction of the inert gas to a pressure below atmospheric pressure.
- the pressure difference results in forcing the walls of the bag against the walls of the diffuser. If there is a leak in the bag, an inflow of air results, so that in a very short time the walls of the bag are no longer pressed against the walls of the diffuser. This makes it very easy to detect from the external appearance of the package those bags in which the seal is defective.
- the pressure during the packaging operation is, in general, sufficient to prevent condensation of the active insecticidal product on the internal surfaces of the walls of the bag, because the saturating vapor tension of the insecticidal product used is generally substantially less than the pressure within the bag.
- the bag is sealed fluid-tight, and contains a very small quantity of oxygen.
- the pressure of the gas inside the bag is less than atmospheric pressure.
- the pressure inside the bag is between 30 and 60 cm of mercury.
- the residual quantity of oxygen is that which remains in the bag after the pressure therewithin has purely by way of illustration and example, with reference to the accompanying drawing, in which:
- FIG. 1 is a sectional view taken through a diffuser enclosed in a bag in accordance with the invention.
- FIG. 2 is a sectional view taken along the line II--ll of FIG. 1.
- EXAMPLE 1 An insecticidal sheet 2 consisting of a substantially rectangular sheet of cotton and asbestos felt is posi-v tioned inside a diffuser 1 such as the one described in French Pat. application Ser. No. 6902574, filed Feb. 5, 1969. This sheet weighs 9 g and has a surface area of 150 cm. It is impregnated with 35 g of a mixture consisting of:
- This diffuser is placed inside a bag 3 formed from a sheet consisting of three superposed layers laminated to each other.
- the first layer 4 comprises a thin film 5 of aluminum foil, a film 6 of cellophane and a film 7 of a plastic material sold under the trademark SARAN.
- the second layer 8 consists of a film 9 of SARAN, and a film 10'of plastic material sold under the trademark MYLAR," and the third is a layer 11 of polyethylene.
- the total thickness of the sheet is about 0.1 mm.
- the polyethylene forms the inner surface of the bag.
- the foregoing bag 3, holding its diffuser 1, is positioned while open, inside a chamber at atmospheric pressure. A partial vacuum of 4 cm of mercury is produced. Nitrogen is then introduced into this chamber to raise the pressure to 46 cm of mercury. Inside the chamber the bag is then heat sealed by a heating bar, which welds together the polyethylene layers 11- which form the inner surfaces of the bag.
- EXAMPLE 2 v The said diffuser and the same bag are used as in Example 1.
- the sheet inside the diffuser is made of the same material having the same area and is impregnated with 35 g of the following mixture:
- the bag containing the diffuser with its impregnated sheet is subjected to the same packaging process as described in Example 1 and the bag is heat sealed.
- the product has the same advantages as the one described in Example 1.
- the efficacity of the insecticidal product does not decrease after long storage.
- EXAMPLE 3 The said difiuser and bag are used as in Example I.
- the sheet inside the diffuser is made of the same material as in Example 1 and is of the same size. It is impregnated with 35 g of the following mixture:
- the bag containing the diffuser with its impregnated sheet is treated in the same way as in Example 1, and the bag is heat sealed.
- a gas-impervious flexible bag housing a perforated box having a sheet impregnated with an insecticidal material therein, said bag having an inert gas therein of between 30 and 60 cm of mercury, said bag being heatsealed to contain said inert gas therein, the difference in the pressure within the bag and the ambient pressures surrounding the same causing said bag to engage with the walls of the perforated box and to remain in contact with the walls of said perforated box until such time as the pressure within said bag is at least equal to the surrounding atmosphere, whereupon said bag will no longer contact said walls.
- Bag as claimed in claim 1 which consists of a sheet of plastic material comprising several superposed layers of different plastic materials.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6932983A FR2058812A5 (de) | 1969-09-26 | 1969-09-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3717303A true US3717303A (en) | 1973-02-20 |
Family
ID=9040693
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US3717303D Expired - Lifetime US3717303A (en) | 1969-09-26 | 1970-09-11 | Method of vacuum-packing insecticidal materials |
Country Status (7)
Country | Link |
---|---|
US (1) | US3717303A (de) |
BE (1) | BE755396A (de) |
CA (1) | CA933891A (de) |
CH (1) | CH526265A (de) |
DE (1) | DE2047168C3 (de) |
FR (1) | FR2058812A5 (de) |
GB (1) | GB1279339A (de) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3807082A (en) * | 1971-07-16 | 1974-04-30 | Globol Werk | Apparatus for killing insects |
DE2534074A1 (de) * | 1975-07-30 | 1977-02-17 | Wacker Chemitronic | Stapelbare paletten-verpackung fuer halbleiterscheiben |
US4399911A (en) * | 1980-07-23 | 1983-08-23 | Societe Anonyme D'explosifs Et De Produits Chimiques | Cartridge for use in anchor bolting |
US4558781A (en) * | 1980-07-23 | 1985-12-17 | Societe Anonyme D'explosifs Et De Produits Chimiques | Cartridge for use in anchor bolting |
US5170886A (en) * | 1990-05-12 | 1992-12-15 | Firmenich S.A. | Plastic multicompartment package for solid and liquid products |
US20050154055A1 (en) * | 2004-01-14 | 2005-07-14 | Philippe Gouat | Method of stabilizing alkylenebisdithiocarbamates |
US20060130391A1 (en) * | 2004-12-22 | 2006-06-22 | Annette Livingston | Repelling rodents |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2086046A (en) * | 1933-04-19 | 1937-07-06 | Harry R Schlau | Insect destroying means |
US2542206A (en) * | 1948-01-30 | 1951-02-20 | Corp E F Kemp | Art of packaging nuts |
US2679969A (en) * | 1954-01-12 | 1954-06-01 | Transparent Package Company | Package construction |
US3027678A (en) * | 1957-08-23 | 1962-04-03 | Aerovap Holdings Ltd | Pesticides and other volatile compounds |
US3214221A (en) * | 1961-10-23 | 1965-10-26 | Dk Mfg Company | Method of and apparatus for storing and preserving granular material |
US3274004A (en) * | 1963-05-14 | 1966-09-20 | Curwood Inc | Laminated food package |
US3343663A (en) * | 1965-10-24 | 1967-09-26 | Dow Chemical Co | Package and laminate thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2967777A (en) * | 1957-10-31 | 1961-01-10 | Paul E Grindrod | Method of packaging food products to inhibit growth of molds and bacteria |
-
1969
- 1969-09-26 FR FR6932983A patent/FR2058812A5/fr not_active Expired
-
1970
- 1970-08-27 BE BE70@@@@@@@@A patent/BE755396A/xx unknown
- 1970-09-11 US US3717303D patent/US3717303A/en not_active Expired - Lifetime
- 1970-09-17 CH CH1382770A patent/CH526265A/fr not_active IP Right Cessation
- 1970-09-24 DE DE2047168A patent/DE2047168C3/de not_active Expired
- 1970-09-24 GB GB4563770A patent/GB1279339A/en not_active Expired
- 1970-09-25 CA CA094158A patent/CA933891A/en not_active Expired
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2086046A (en) * | 1933-04-19 | 1937-07-06 | Harry R Schlau | Insect destroying means |
US2542206A (en) * | 1948-01-30 | 1951-02-20 | Corp E F Kemp | Art of packaging nuts |
US2679969A (en) * | 1954-01-12 | 1954-06-01 | Transparent Package Company | Package construction |
US3027678A (en) * | 1957-08-23 | 1962-04-03 | Aerovap Holdings Ltd | Pesticides and other volatile compounds |
US3214221A (en) * | 1961-10-23 | 1965-10-26 | Dk Mfg Company | Method of and apparatus for storing and preserving granular material |
US3274004A (en) * | 1963-05-14 | 1966-09-20 | Curwood Inc | Laminated food package |
US3343663A (en) * | 1965-10-24 | 1967-09-26 | Dow Chemical Co | Package and laminate thereof |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3807082A (en) * | 1971-07-16 | 1974-04-30 | Globol Werk | Apparatus for killing insects |
DE2534074A1 (de) * | 1975-07-30 | 1977-02-17 | Wacker Chemitronic | Stapelbare paletten-verpackung fuer halbleiterscheiben |
US4399911A (en) * | 1980-07-23 | 1983-08-23 | Societe Anonyme D'explosifs Et De Produits Chimiques | Cartridge for use in anchor bolting |
US4558781A (en) * | 1980-07-23 | 1985-12-17 | Societe Anonyme D'explosifs Et De Produits Chimiques | Cartridge for use in anchor bolting |
US5170886A (en) * | 1990-05-12 | 1992-12-15 | Firmenich S.A. | Plastic multicompartment package for solid and liquid products |
US20050154055A1 (en) * | 2004-01-14 | 2005-07-14 | Philippe Gouat | Method of stabilizing alkylenebisdithiocarbamates |
US20060130391A1 (en) * | 2004-12-22 | 2006-06-22 | Annette Livingston | Repelling rodents |
US7380370B2 (en) * | 2004-12-22 | 2008-06-03 | Armex, Llc | Repelling rodents |
Also Published As
Publication number | Publication date |
---|---|
CH526265A (fr) | 1972-08-15 |
BE755396A (fr) | 1971-03-01 |
DE2047168C3 (de) | 1974-02-07 |
DE2047168B2 (de) | 1973-07-26 |
GB1279339A (en) | 1972-06-28 |
DE2047168A1 (de) | 1971-04-22 |
CA933891A (en) | 1973-09-18 |
FR2058812A5 (de) | 1971-05-28 |
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