US3692684A - Detergent - Google Patents
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- Publication number
- US3692684A US3692684A US20425A US3692684DA US3692684A US 3692684 A US3692684 A US 3692684A US 20425 A US20425 A US 20425A US 3692684D A US3692684D A US 3692684DA US 3692684 A US3692684 A US 3692684A
- Authority
- US
- United States
- Prior art keywords
- acid
- detergent
- acids
- fatty
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000003599 detergent Substances 0.000 title abstract description 24
- 229910019142 PO4 Inorganic materials 0.000 abstract description 10
- 159000000011 group IA salts Chemical class 0.000 abstract description 7
- 150000003839 salts Chemical class 0.000 abstract description 6
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 4
- 238000012851 eutrophication Methods 0.000 abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 3
- 150000008064 anhydrides Chemical class 0.000 abstract description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 229930195729 fatty acid Natural products 0.000 description 16
- -1 aromatic carboxylic acids Chemical class 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000002253 acid Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 150000002191 fatty alcohols Chemical class 0.000 description 9
- 235000021317 phosphate Nutrition 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
- 229920000151 polyglycol Polymers 0.000 description 6
- 239000010695 polyglycol Substances 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 150000001408 amides Chemical class 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 238000005282 brightening Methods 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 5
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- 229930195725 Mannitol Natural products 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000000594 mannitol Substances 0.000 description 4
- 235000010355 mannitol Nutrition 0.000 description 4
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- GCAIEATUVJFSMC-UHFFFAOYSA-N benzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1C(O)=O GCAIEATUVJFSMC-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- QPHPUQJVKQXISS-UHFFFAOYSA-N 4-oxo-4-sulfanylbutanoic acid Chemical compound OC(=O)CCC(S)=O QPHPUQJVKQXISS-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 150000001734 carboxylic acid salts Chemical class 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- SDHMGKANHNMOSS-UHFFFAOYSA-N 1-aminoethanesulfonic acid Chemical class CC(N)S(O)(=O)=O SDHMGKANHNMOSS-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 201000002451 Overnutrition Diseases 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229960000250 adipic acid Drugs 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000005791 algae growth Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 150000002395 hexacarboxylic acids Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000020823 overnutrition Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
Definitions
- the present invention relates to a washing dish-washing and cleaning detergent in the shape of powders, granules or pastes or liquids, the phosphates previously used in such a detergent being completely or partly replaced by chemicals which are more suitable from the eutrophic point of view.
- the purpose of the phosphates in detergent compositions is to soften the water and to keep thehardening agents in the water in solution. Further, the phosphates have a certain dispersion effect on the dirt particles and improves the effects of the tensides in certain respects.
- carboxylic acids which are not dangerous from toxicologic point of view may be used.
- One condition is of course that they could be accepted from water care'point of view. They must also give a satisfactory washing result.
- COOH-groups give the best results in surface Washing and at the same time many of these acids are toxicologically and allergologically undangerous and do not endanger water care. Several of these carboxylic acids occur in nature and form so to say a natural component of the plants and animals.
- anionic, double-ionic or nonionic tensides which may be present in the detergents according to the inventhem water soluble, this group being of anionic or nonionie character.
- anionic active detergent soaps sulphonates and glp hates are of importance.
- phosphate tion phosphate tion
- NTA increases the algae growth why this solution of the eutrophication problem still is unsolved. Further, one does not know anything about the reactions between trace elements in natural watercourses and NTA.
- the present invention relates to detergent compositions which contain alkaline salts of aliphatic and aromatic car boxylic acids and/or their anhydrides having as a maximum eight carbon atoms in the hydrophobic part or having one or several carboxylic groups or the free acids in a mixture with the alkaline salts of inorganic acids, e.g. carbonates and silicates.
- alkaline salts of aliphatic and aromatic car boxylic acids and/or their anhydrides having as a maximum eight carbon atoms in the hydrophobic part or having one or several carboxylic groups or the free acids in a mixture with the alkaline salts of inorganic acids, e.g. carbonates and silicates.
- inorganic acids e.g. carbonates and silicates.
- Said acids are used because they contain only tensides cou be used.
- the sulphonates may comprise alkylaryl sulphonates, alkyl sulphonates, alkene sulphonates and oxyalkane sulphonates. Also sulphonated esters may be used.
- the sulphates may comprise e.g. alkylene sulphate, fatty alcohol ether sulphate, sulphated amides of fatty acids, sulphated monoglycerides, sulphating products of ethoxylated and/or propoxylated fatty alcohols, alkyl phenols, fatty acid amines, etc.
- Sulphonates of fatty acid esters of oxethane sulphonic acid and dioxypropane sulphonic acid, fatty alcoholic esters of lower aliphatic and aromatic thiomonoand dicarboxylic acids as well as condensation products of fatty acids with aminoethane sulphonic acids may be used.
- Synthetic capillary active carboxylates and condensation products of fatty acids with aminocarboxylic acids or with protein hydrolysates as well as phosphate esters of fatty alcohols and fatty acids may be used.
- nonionic tensides one may use e.g. alkylic phenol, fatty alcohol, alkyl amino, fatty acid, fatty acid alkylol amide fatty amide polyglycolethers, phosphate esters of ethoxylated fatty alcohols, block polymerisates of ethylene oxide and propylene oxide etc.
- amphoteric tensides may be used such as imidazoline derivatives of fatty acids, carboxybetaines, compounds with the phosphoric acid groups in the acid test or with sulphonic or sulphuric acid groups.
- Foam stabilizers or foam inhibitors as well as corrosion inhibitors may be included and so may dirt carrying sub- It has turned out in practice that acids with several enzymes, dyes and water. Also different types of bleaching agents containing oxygen or chlorine and activators and stabilizers belonging thereto.
- a multivalent higher alcohol in an amount up to 25%, preferably 0.58% as calculated on the quantity of said salts.
- the multivalent alcohols are selected from the group consisting of sorbitol, mannitol, pentaerythritol, trimethylol propane, trirnethanol ethane, hexanetriol and butane triol.
- EXAMPLE 3 Detergent for ordinary washing, sprayed I Parts Na-dodecyl benzene sulphonate .Q 10 Fatty alcohol polyglycol ether 5 Xylene sulphonate 7 SEHITJ'I'WBW 2 Phosphate ester of ethoxylated fatty alcohol 2 Na-perborate 15 Na-citrate 30 Mannitol 5 Na-silicate 10 EDTA or NTA 3 Na-salt of benzene tetracarboxylic acid 2 CMC, opt. brightening agent, Mg-silicate 9 EXAMPLE 4 Small-washing detergent, gran.
- EXAMPLE 7 Dish-washing machine detergent Parts Polypropylene-ethylene oxide-addition product 3 Sodium alkylic polyglycol etherphosphate 3 Na-acetate 25 Na-sulphate 25 Na-citrate 30 Perfumes, dyes, bactericides, water l4
- EXAMPLE 8 Washing and cleansing paste Parts Fatty acid imidazoline derivate, 50% 10 Succinic acid-Z-ethyl hexylic monoester 3 Undecylene acid monoethanol amide 3
- Fatty acid condensation product with methyl taurine l6 Glycol derivate 7 Na-citrate 11 1,4-butane dicarboxylic acid 2 CMC 3 Water 45 What I claim is: 1.
- a detergent composition consisting essentially of: a water-soluble surface active agent have 8 to 30 6 carbon atoms in the hydrophobic group thereof, 3.
- surface active agent is an anionic wetting agent.
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- Life Sciences & Earth Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE13492/69A SE352652B (ja) | 1969-10-01 | 1969-10-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3692684A true US3692684A (en) | 1972-09-19 |
Family
ID=20297485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US20425A Expired - Lifetime US3692684A (en) | 1969-10-01 | 1970-03-17 | Detergent |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3692684A (ja) |
| JP (1) | JPS507610B1 (ja) |
| BE (1) | BE750676A (ja) |
| CH (1) | CH540973A (ja) |
| DE (1) | DE2026739C3 (ja) |
| FR (1) | FR2065800A5 (ja) |
| GB (1) | GB1309814A (ja) |
| LU (1) | LU60901A1 (ja) |
| NL (1) | NL7007168A (ja) |
| SE (1) | SE352652B (ja) |
| SU (1) | SU479299A3 (ja) |
| ZA (1) | ZA706253B (ja) |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3844982A (en) * | 1969-11-24 | 1974-10-29 | Procter & Gamble | Built detergent composition |
| US3852220A (en) * | 1972-01-12 | 1974-12-03 | Marathon Oil Co | Isocyanurate-based polyelectrolyte detergent composition |
| US3859224A (en) * | 1971-09-24 | 1975-01-07 | Hoechst Ag | Detergent composition containing, as a builder, the sodium salt of glycerol tricitrate |
| US3872020A (en) * | 1971-09-14 | 1975-03-18 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent compositions |
| US3896040A (en) * | 1971-01-04 | 1975-07-22 | Andre Danesh | Detergent composition |
| US3915879A (en) * | 1973-04-10 | 1975-10-28 | Lever Brothers Ltd | Detergent compositions |
| US3920569A (en) * | 1972-02-14 | 1975-11-18 | Lever Brothers Ltd | Detergent composition having substituted phthalic acid salt builder |
| US3951877A (en) * | 1972-07-17 | 1976-04-20 | Lion Fat & Oil Co., Ltd. | Heavy-duty granular detergent composition with sodium citrate builder |
| US3953352A (en) * | 1973-06-04 | 1976-04-27 | Kao Soap Co., Ltd. | Acidic cleaning composition |
| US3962149A (en) * | 1973-10-12 | 1976-06-08 | Colgate-Palmolive Company | Non-phosphate spray dried detergents containing dicarboxylic acid salts |
| US3971728A (en) * | 1972-03-07 | 1976-07-27 | Ethyl Corporation | Sequestering agent |
| US4009114A (en) * | 1974-09-23 | 1977-02-22 | Colgate-Palmolive Company | Non-phosphate detergent composition |
| US4013579A (en) * | 1973-06-06 | 1977-03-22 | Kao Soap Co., Ltd. | Acidic cleaning composition |
| US4040972A (en) * | 1975-03-12 | 1977-08-09 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Ion-exchanging aluminum silicate with hydrophilic surfaces |
| US4088593A (en) * | 1975-03-12 | 1978-05-09 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Ion-exchanging aluminum silicate with hydrophilic surfaces |
| US4102799A (en) * | 1974-08-29 | 1978-07-25 | Colgate-Palmolive Company | Automatic dishwasher detergent with improved effects on overglaze |
| US4123375A (en) * | 1975-11-22 | 1978-10-31 | Henkel Kommanditgesellschaft Auf Aktien | Dishwasher detergent with clear rinsing effect and method of machine washing dishes |
| US4210550A (en) * | 1978-07-14 | 1980-07-01 | Akzo N.V. | Detergent composition containing an alkali carbonate |
| US4239641A (en) * | 1978-08-03 | 1980-12-16 | Basf Aktiengesellschaft | Use of polyhydric alcohols, carboxylic acids, hydroxy-carboxylic acids and/or their esters with polyhydric alcohols as viscosity regulators |
| US4239552A (en) * | 1978-08-03 | 1980-12-16 | Basf Aktiengesellschaft | Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents |
| US4252663A (en) * | 1971-01-15 | 1981-02-24 | Ab Helios, Kemisk-Tekniska Fabriker | Detergent compositions |
| US4395365A (en) * | 1980-09-08 | 1983-07-26 | Nissan Motor Co., Ltd. | Metal cleaning composition containing a fatty acid succrose ester and other detergent components |
| US4594175A (en) * | 1984-08-29 | 1986-06-10 | Economics Laboratory, Inc. | Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen |
| US4612137A (en) * | 1984-09-03 | 1986-09-16 | Kao Corporation | Anti-yellowing detergent composition containing citrate and isocitrate |
| US4613448A (en) * | 1973-09-24 | 1986-09-23 | The Colgate-Palmolive Co. | Detergent compositions |
| US4902439A (en) * | 1987-04-15 | 1990-02-20 | Ciba-Geigy Corporation | Detergent composition for washing off dyeings obtained with fibre-reactive dyes, process for the preparation thereof and use thereof |
| US4935158A (en) * | 1986-10-30 | 1990-06-19 | Aszman Harry W | Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture |
| US4983315A (en) * | 1989-08-10 | 1991-01-08 | The Procter & Gamble Company | N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions |
| US5427707A (en) * | 1985-06-14 | 1995-06-27 | Colgate Palmolive Co. | Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA72142B (en) * | 1971-01-25 | 1973-09-26 | Colgate Palmolive Co | Heavy duty liquid detergent |
| CA966751A (en) * | 1971-03-18 | 1975-04-29 | Charles R. Ries | Phosphorus-free detergent composition |
| BE787682A (fr) * | 1971-08-17 | 1973-02-19 | Unilever Nv | Compositions detergentes |
| US4013577A (en) * | 1972-04-14 | 1977-03-22 | Colgate-Palmolive Company | Heavy duty dry biodegradable detergent composition |
| GB1432137A (en) * | 1972-06-13 | 1976-04-14 | Chem Y | Detergent compositions |
| DE2230453A1 (de) * | 1972-06-22 | 1974-01-17 | Benckiser Gmbh Joh A | Grundstoffansatz fuer wasch- und reinigungsmittel |
| IT1002614B (it) * | 1973-01-15 | 1976-05-20 | Colgate Palmolive Co | Detersivo anionico privo di fosfati |
| NL7407851A (ja) * | 1973-06-15 | 1974-12-17 | ||
| US3971815A (en) * | 1974-11-13 | 1976-07-27 | The Procter & Gamble Company | Acid mix process |
| GB2000177B (en) * | 1977-06-27 | 1982-01-20 | Akzo Nv | Detergent compositions |
| IT1124027B (it) * | 1979-03-23 | 1986-05-07 | Mira Lanza Spa | Composizione detersiva a basso o nullo tenore di fosforo |
| GB8522621D0 (en) * | 1985-09-12 | 1985-10-16 | Unilever Plc | Detergent powder |
| GB2330588B (en) * | 1997-10-24 | 1999-08-18 | Cheng Wen Lin | Multipurpose cleaning agent |
| DE19851662A1 (de) * | 1998-11-10 | 2000-05-18 | Menno Chemie Vertriebsges M B | Mittel zur Beseitigung der Klebefähigkeit von Helmintheneiern |
| RU2530883C2 (ru) * | 2012-08-29 | 2014-10-20 | Общество с ограниченной ответственностью Пермская производственная фирма "Фантом" | Моющая композиция для очистки поверхностей различных твердых тел |
-
1969
- 1969-10-01 SE SE13492/69A patent/SE352652B/xx unknown
-
1970
- 1970-03-17 US US20425A patent/US3692684A/en not_active Expired - Lifetime
- 1970-05-06 CH CH680070A patent/CH540973A/de not_active IP Right Cessation
- 1970-05-07 GB GB2196070A patent/GB1309814A/en not_active Expired
- 1970-05-12 LU LU60901D patent/LU60901A1/xx unknown
- 1970-05-14 JP JP45040551A patent/JPS507610B1/ja active Pending
- 1970-05-16 NL NL7007168A patent/NL7007168A/xx unknown
- 1970-05-19 FR FR7017212A patent/FR2065800A5/fr not_active Expired
- 1970-05-20 BE BE750676D patent/BE750676A/xx unknown
- 1970-06-01 DE DE2026739A patent/DE2026739C3/de not_active Expired
- 1970-09-08 SU SU1474363A patent/SU479299A3/ru active
- 1970-09-14 ZA ZA706253A patent/ZA706253B/xx unknown
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3844982A (en) * | 1969-11-24 | 1974-10-29 | Procter & Gamble | Built detergent composition |
| US3896040A (en) * | 1971-01-04 | 1975-07-22 | Andre Danesh | Detergent composition |
| US4252663A (en) * | 1971-01-15 | 1981-02-24 | Ab Helios, Kemisk-Tekniska Fabriker | Detergent compositions |
| US3872020A (en) * | 1971-09-14 | 1975-03-18 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent compositions |
| US3859224A (en) * | 1971-09-24 | 1975-01-07 | Hoechst Ag | Detergent composition containing, as a builder, the sodium salt of glycerol tricitrate |
| US3852220A (en) * | 1972-01-12 | 1974-12-03 | Marathon Oil Co | Isocyanurate-based polyelectrolyte detergent composition |
| US3920569A (en) * | 1972-02-14 | 1975-11-18 | Lever Brothers Ltd | Detergent composition having substituted phthalic acid salt builder |
| US3971728A (en) * | 1972-03-07 | 1976-07-27 | Ethyl Corporation | Sequestering agent |
| US3951877A (en) * | 1972-07-17 | 1976-04-20 | Lion Fat & Oil Co., Ltd. | Heavy-duty granular detergent composition with sodium citrate builder |
| US3915879A (en) * | 1973-04-10 | 1975-10-28 | Lever Brothers Ltd | Detergent compositions |
| US3953352A (en) * | 1973-06-04 | 1976-04-27 | Kao Soap Co., Ltd. | Acidic cleaning composition |
| US4013579A (en) * | 1973-06-06 | 1977-03-22 | Kao Soap Co., Ltd. | Acidic cleaning composition |
| US4613448A (en) * | 1973-09-24 | 1986-09-23 | The Colgate-Palmolive Co. | Detergent compositions |
| US3962149A (en) * | 1973-10-12 | 1976-06-08 | Colgate-Palmolive Company | Non-phosphate spray dried detergents containing dicarboxylic acid salts |
| US4102799A (en) * | 1974-08-29 | 1978-07-25 | Colgate-Palmolive Company | Automatic dishwasher detergent with improved effects on overglaze |
| US4009114A (en) * | 1974-09-23 | 1977-02-22 | Colgate-Palmolive Company | Non-phosphate detergent composition |
| US4088593A (en) * | 1975-03-12 | 1978-05-09 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Ion-exchanging aluminum silicate with hydrophilic surfaces |
| US4040972A (en) * | 1975-03-12 | 1977-08-09 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Ion-exchanging aluminum silicate with hydrophilic surfaces |
| US4123375A (en) * | 1975-11-22 | 1978-10-31 | Henkel Kommanditgesellschaft Auf Aktien | Dishwasher detergent with clear rinsing effect and method of machine washing dishes |
| US4210550A (en) * | 1978-07-14 | 1980-07-01 | Akzo N.V. | Detergent composition containing an alkali carbonate |
| US4239641A (en) * | 1978-08-03 | 1980-12-16 | Basf Aktiengesellschaft | Use of polyhydric alcohols, carboxylic acids, hydroxy-carboxylic acids and/or their esters with polyhydric alcohols as viscosity regulators |
| US4239552A (en) * | 1978-08-03 | 1980-12-16 | Basf Aktiengesellschaft | Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents |
| US4395365A (en) * | 1980-09-08 | 1983-07-26 | Nissan Motor Co., Ltd. | Metal cleaning composition containing a fatty acid succrose ester and other detergent components |
| US4594175A (en) * | 1984-08-29 | 1986-06-10 | Economics Laboratory, Inc. | Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen |
| US4612137A (en) * | 1984-09-03 | 1986-09-16 | Kao Corporation | Anti-yellowing detergent composition containing citrate and isocitrate |
| US5427707A (en) * | 1985-06-14 | 1995-06-27 | Colgate Palmolive Co. | Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer |
| US4935158A (en) * | 1986-10-30 | 1990-06-19 | Aszman Harry W | Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture |
| US4902439A (en) * | 1987-04-15 | 1990-02-20 | Ciba-Geigy Corporation | Detergent composition for washing off dyeings obtained with fibre-reactive dyes, process for the preparation thereof and use thereof |
| US4983315A (en) * | 1989-08-10 | 1991-01-08 | The Procter & Gamble Company | N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| BE750676A (fr) | 1970-11-03 |
| GB1309814A (en) | 1973-03-14 |
| SE352652B (ja) | 1973-01-08 |
| DE2026739A1 (de) | 1971-04-22 |
| CH540973A (de) | 1973-08-31 |
| ZA706253B (en) | 1971-05-27 |
| LU60901A1 (ja) | 1970-07-16 |
| DE2026739B2 (de) | 1978-04-27 |
| DE2026739C3 (de) | 1979-01-18 |
| JPS507610B1 (ja) | 1975-03-27 |
| FR2065800A5 (ja) | 1971-08-06 |
| NL7007168A (ja) | 1971-04-05 |
| SU479299A3 (ru) | 1975-07-30 |
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