US3667258A - Apparatus for producing striped colorations on dyeable substrates in continuous form - Google Patents

Apparatus for producing striped colorations on dyeable substrates in continuous form Download PDF

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Publication number
US3667258A
US3667258A US97433A US3667258DA US3667258A US 3667258 A US3667258 A US 3667258A US 97433 A US97433 A US 97433A US 3667258D A US3667258D A US 3667258DA US 3667258 A US3667258 A US 3667258A
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United States
Prior art keywords
substrate
dyestuff
streams
colorations
striped
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Expired - Lifetime
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US97433A
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English (en)
Inventor
Clifford Newton
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Imperial Chemical Industries Ltd
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Imperial Chemical Industries Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00Treatment of selected parts of textile materials, e.g. partial dyeing
    • D06B11/0056Treatment of selected parts of textile materials, e.g. partial dyeing of fabrics
    • D06B11/0063Treatment of selected parts of textile materials, e.g. partial dyeing of fabrics by pouring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C5/00Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
    • B05C5/007Slide-hopper coaters, i.e. apparatus in which the liquid or other fluent material flows freely on an inclined surface before contacting the work

Definitions

  • This invention relates to a novel process whereby substrates in continuous or sheet form, such as textiles and like fibrous materials, may be colored in reproducible striped patterns without recourse to conventional printing machines and techniques.
  • a process for the production of striped colorations on dyeable substrates in continuous or sheet form by applying a plurality of streams of dyestuff solutions or suspensions to the substrate at selected fixed points across the width thereof while the substrate is moved in a longitudinal manner relatively to the points of application, and thereafter passing the substrate between nip rollers or like pressure-applying means, each dyestuff stream being continuously applied to the substrate at each of the said points in an amount which can be completely absorbed by that part of the substrate which passes beneath and immediately to each side of 'the point of application of that stream, so that on passage through the nip the dyestuffs are squeezed into the substrate to form non-overlapping longitudinal stripes of the desired respective widths.
  • the distances between the points of application of the dyestuff streams and the rates of application of the individual streams are thus selected so that for each stream there is available a band of substrate of sufficient width to allow the dyestuff solution or suspension freely to spread laterally under the influence of the applied pressure to the extent which the absorptive power of the substrate determines, without overlapping of adjacent streams taking place.
  • the widths of the stripes may be altered either by varying the rate of supply of a dyestuff stream to its point of application to the substrate or by varying the speed of movement of the substrate, or both.
  • a variation in the speed of movement of the substrate will, of course, produce a proportional change in the widths of all the colored stripes, while a variation in the rate of supply of one or more dyestuff streams relative to that of the other streams will produce a differential broadening or narrowing of certain of the stripes only.
  • the widths of the strips can also be influenced by the pressure applied to the substrate by the nip rollers, but in practice this is a factor which is less susceptible to accurately controlled variation and it is found more satisfactory to operate with a constant pressure setting and to adjust the pattern in the way described.
  • the process of the invention can be applied to a wide variety of substrates provided that these are in continuous or sheet form.
  • fibrous materials which include yarns and rovings, webs such as paper and non-woven fabrics, and woven or knitted fabrics, as well as to films and other sheet material.
  • Such substrates may be composed of natural, artificial or synthetic polymeric materials or blends thereof.
  • Natural polymeric materials include cellulosic materials such as cotton and linen; artificial polymeric materials include regenerated cellulosic materials such as viscose rayon, and cellulose esters such as cellulose secondary acetate and triacetate; synthetic polymeric material includes polyamides such as nylon, polyesters such as polyethylene terephthalate, and polymers or copolymers or acrylonitrile.
  • the process of the invention is particularly of interest for the coloration of natural or regenerated cellulosic materials and their blends with synthetic polymeric materials such as polyesters.
  • the dyestuffs used in the coloration process will normally be those usually associated with dyeing processes for the sub strate being colored, e.g. disperse dyes in the cases of polyamides, polyesters and cellulose acetates and vat or reactive dyes in the case of cellulosic materials.
  • the process may be employed so that a single dyestufi' is applied from solution or suspension to the substrate at all the points of application; or so that different colored dyestuffs are applied at difierent points.
  • Variegated striped patterns may also be obtained when the composition of the solution or suspension which is applied to the substrate at a given application point is made to vary with respect to the dyestuff present, and hence to the color which isimparted to the substrate.
  • the dyestuff solutions or suspensions may advantageously contain thickeners, whereby their absorption by the substrate following application thereto may be retarded until the streams are spread out in controlled fashion by passage through the nip.
  • the process of the invention may be performed with the aid of a modified padding machine, the modification consisting in the provision of suitable means for applying the streams of dyestuff solutions or suspensions to the substrate.
  • suitable means may consist, for example, of jets or conduits whereby the solution or suspensions are conveyed directly to the surface of the substrate from storage vessels, optionally with the incorporation of valve means to control the rate of flow of each stream.
  • a preferred application means consists of an inclined plane the lower edge of which is maintained in contact with the substrate across its entire width and in trailing relationship thereto, the upper surface of the plane being provided with a number of spaced troughs or channels, terminating at its lower edge, into which dyestuff solutions or suspensions may be continuously discharged so that they flow on to the substratefrom the aforesaid lower edge.
  • the number of troughs or channels will correspond in general to the number of individual dyestufi streams.
  • the troughs or channels are of U- or V-shaped section, in order to contain the streams of solution of suspension in the narrowest width possible until they are taken up by the substrate.
  • the lower edge of the upper surface of the inclined plane should be maintained in as close contact as possible with the substrate, in order to produce smooth striped colorations of the sharpest definition.
  • the solutions or suspensions may be so discharged from an equal number of jets communicating with suitable storage vessels optionally by way of flow-controlling valve means.
  • jets may advantageously be mounted upon one or more lateral supports which are capable of reciprocating motion in a direction transverse to the alignment of the array of troughs or channels (that is to say, transverse to the direction of motion of the substrate), so that two or more different dyestuff streams may be arranged to flow alternatively down any given trough or channel and so give rise to variegated colored stripe effects. It is however, important to arrange that the change-over of supply from one dyestufi solution or suspension to another into a given channel should be instantaneous, so that there is no interruption in the flow of the stream which is applied to the substrate.
  • reproducible color stripes can be produced in which the width and spacing of the stripes are comparable in constancy with those obtained by conventional printing techniques.
  • the present process has the advantage over such techniques that a markedly increased depth of penetration of the dyestuff into the substrate is achieved, and on a wide variety of substrates duplex type patterns are produced (that is to say, both the face and the back of the substrate are dyed to eual extents).
  • the present process is also advantageous in that it calls for only simple equipment which can readily be adjusted so as to produce a wide variety of different striped patterns, thereby avoiding the need for an individually engraved roller to be fashioned for each different pattern required.
  • the process of the invention is of particular interest for the coloration of textile fabrics consisting of cellulosic material or of blends thereof with non-cellulosic material such as synthetic polyester material, using vat dyes or reactive dyes.
  • the vat dyes may be applied as a suspension or a solution of either the leuco or the stabilized leuco form.
  • the vat dyes can be fixed on the textile material by first drying the pigmented fabric and then passing it through a cold alkaline reducing solution. followed by a heating or steaming step and the usualoxidation treatments.
  • the dyestufi can be fixed by submission to the usual oxidation treatments.
  • Reactive dyestufis may be fixed by a number of methods applicable to these dyestuffs.
  • the dyestufi may be applied from a neutral solution on to a fabric already impregnated with alkali and dried; alternatively the dye may be applied from neutral solution and fixed by subsequent immersion of the textile material in an alkaline saline bath, optionally aided by a short steaming or heatingstep in the cases of dyestuffs of lower activity.
  • the dyestuff may be applied in an alkaline solution and fixation effected by heating, steaming or'allowingto stand in a moist condition for a suitable period of time, dependent on the alkalinity of the solution and the nature of the reactive dye.
  • fixation effected by heating, steaming or'allowingto stand in a moist condition for a suitable period of time, dependent on the alkalinity of the solution and the nature of the reactive dye.
  • These solutions can contain the usual additives, e.g. thickeners, wetting agents and smallamounts of neutral electrolytes.
  • FIG. 1 is a side view of the apparatus and FIG. 2 is a front view seen from point A in FlG. l.
  • the fabric 1 is drawn continuously from a taking-ofi roller 2, from where it passes below the lower edge of an inclined dyestuff delivery plane 3, then through the nip rollers 4 and 5 of a padding mangle and in finally wound up on a taking-up roller 6, an impermeable film 7 being fed in from a roll 8 so as to separate adjacent layers of the fabric 1 on the roller 6 and thus prevent marking off whilst the fabric is still moist.
  • the inclined plane 3, which lies at an angle of 45 to the fabric 1, is provided with upstanding ribs which divide its surface into four channels 10 terminating at its lower edge, and above each channel is located a dye delivery device consisting of a jet 1] connected by a feed duct. 12 through a control valve 13 to a storage vessel 14 for dyestufi solution.
  • Each valve 13 is of the simple on/off type and the rate of flow .of the solution is set by suitable choice of the size of the jet 11 at 25cc/min.
  • the vessels 14 of the two middle d e delivery devices are charged with solution iii described a ve and the vessels of the two are allowed to run down their respective channels 10 on to the moving fabric 1 and as the latter passes between the nip rollers 4 and 5 the bands of solution so applied are squeezed into the fabric to produce stripes of color of uniform width approximately 18mm.
  • the striped poplin collected on the roller 6 is allowed to stand at 2025 C for 2 hours, then washed off in the usual way in a bath containing 1 g/l of a detergent and 1 g/l of hexamethylene tetramine.
  • the resultant fabric displays two central stripes of flame color and outer stripes of blue and gold, each pair of stripes being separated by bands of white with clearly defined boundaries between the dyed and undyed areas.
  • the surface of the inclined plane 3 which lies between each pair of ribs 9 is slightly recessed towards the center, so that the channels 10 are of a shallow U shape in cross section. In this way the movement of the dyestuff streams down the channels is more effectively controlled.
  • FIG. 3 of the accompanying drawings there is shown a view corresponding to that of FIG. 2 of a modified form of inclined dyestuff delivery plane with its associated delivery devices.
  • the ribs 9 attached to the surface of the plane 3 are in the form of triangular baffles, so that the surface of the plane is divided up into a plurality of equally spaced inverted triangular troughs 10, the apexes of which are cut away so as to'provide outlets for the dyestuff solutions at the lower edge of the plane.
  • the apexes of the baffles 9 are however fully pointed, so as to provide a sharp demarcation between one trough and the next.
  • the feed ducts 12 are made of flexible material to accommodate this motiom
  • the vessels 14 of the dye delivery devices are in this case charged with dyestufi solutions of color which readily blend with each other, and by reciprocating the support 15 in the manner described color streams of regularly varying composition can be made to flow down each of the troughs 10, so giving rise to variegated stripe effects on the fabric 1.
  • the equal spacing of the jets l l and the apexes of the baffles 9 ensures that there is no interruption in the flow of dyestuff solution down any of the troughs as the source of supply is continually alternated.
  • Apparatus suitable for the production of striped colorations on dyeable substrates in continuous form which comprises the combination of a padding machine and means for applying a plurality of streams of liquid dyestuff compositions to the substrate before passage through the padding machine, an inclined plane the lower edge of which is maintained in contact with the substrate across the entire width thereof and in trailing relationship thereto, the upper surface of the plane being provided with a number of spaced channels terminating at the said lower edge, and a number, equal to the number of channels, of jets from which'the liquid dyestufi compositions are continuously discharged into the said channels.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Coloring (AREA)
US97433A 1969-11-13 1970-11-06 Apparatus for producing striped colorations on dyeable substrates in continuous form Expired - Lifetime US3667258A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB55608/69A GB1279814A (en) 1969-11-13 1969-11-13 Coloration process

Publications (1)

Publication Number Publication Date
US3667258A true US3667258A (en) 1972-06-06

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US97433A Expired - Lifetime US3667258A (en) 1969-11-13 1970-11-06 Apparatus for producing striped colorations on dyeable substrates in continuous form

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US (1) US3667258A (xx)
BE (1) BE758949A (xx)
DE (1) DE2055952A1 (xx)
ES (1) ES385517A1 (xx)
FR (1) FR2069303A5 (xx)
GB (1) GB1279814A (xx)
NL (1) NL7016422A (xx)
ZA (1) ZA707536B (xx)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3795082A (en) * 1972-05-04 1974-03-05 Beloit Corp Paper roll coding device
US3828405A (en) * 1972-10-12 1974-08-13 Vinney G De Method for imparting coloration to a textile yarn
US4369640A (en) * 1980-08-20 1983-01-25 Wadsworth-Greenwood Corporation Apparatus for obtaining uniform solid colors or variegated patterns in fabrics
US4377080A (en) * 1980-08-20 1983-03-22 Greenwood Corp. Of America Apparatus for obtaining variegated patterns
US4381726A (en) * 1981-11-17 1983-05-03 A/S Phonix Tagpap Og Vejmaterialer Apparatus for applying stripe material to a solid surface
US5222266A (en) * 1990-09-11 1993-06-29 Btr Operations Nz Limited Process and apparatus for the space dyeing of hanks of fibre or yarn
US5737813A (en) * 1988-04-14 1998-04-14 International Paper Company Method and apparatus for striped patterning of dyed fabric by hydrojet treatment
US5866173A (en) * 1996-11-18 1999-02-02 The Procter & Gamble Company Apparatus for producing absorbent products
US5887459A (en) * 1995-07-14 1999-03-30 Fleissner Gmbh & Co., Mashinenfabrik Device for applying a liquid film, uniformly thin over the working width, to a web of goods
US5913905A (en) * 1996-12-12 1999-06-22 Fleissner Gmbh & Co. Maschinenfabrik Device for applying a liquid film to a continuously advanced web of goods
WO2003059528A1 (en) * 2002-01-16 2003-07-24 Metso Paper, Inc. Method and apparatus for feeding a treating agent onto a moving surface
CN101143356B (zh) * 2007-11-01 2010-05-19 上海誉辉化工有限公司 泡沫施加装置

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2850833C3 (de) * 1978-11-24 1981-10-15 Messerschmitt-Bölkow-Blohm GmbH, 8000 München Verfahren zur Herstellung von orientierten Kurzfaservliesen
DE3127469A1 (de) * 1981-07-11 1983-01-27 Mathias 4815 Schloss Holte Mitter Vorrichtung zum auftragen von fluessigen, verschaeumten oder pastoesen medien auf eine warenbahn
EP0123367A1 (en) * 1983-03-09 1984-10-31 West Point-Pepperell, Inc. Apparatus for applying repeatable patterns of dye-carrying foam onto a moving web
KR920000782Y1 (ko) * 1990-03-05 1992-01-31 동양섬유산업 주식회사 다댁상기포염색가공기의 제트 애프리케이터(Jet Applicator)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2916012A (en) * 1957-02-19 1959-12-08 Raytheon Co Line ruling devices and method
GB901062A (en) * 1960-04-20 1962-07-11 Metal Insulated Fabrics Ltd Improvements in apparatus for dyeing or colouring textile fabrics
US3052211A (en) * 1955-07-26 1962-09-04 Riegel Textile Corp Apparatus for striping fabric material
US3155540A (en) * 1959-06-15 1964-11-03 Landers Corp Apparatus for the extrusion coating of fabric or like materials
US3256581A (en) * 1966-06-21 Apparatus for creating designs in pile fabrics

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3256581A (en) * 1966-06-21 Apparatus for creating designs in pile fabrics
US3052211A (en) * 1955-07-26 1962-09-04 Riegel Textile Corp Apparatus for striping fabric material
US2916012A (en) * 1957-02-19 1959-12-08 Raytheon Co Line ruling devices and method
US3155540A (en) * 1959-06-15 1964-11-03 Landers Corp Apparatus for the extrusion coating of fabric or like materials
GB901062A (en) * 1960-04-20 1962-07-11 Metal Insulated Fabrics Ltd Improvements in apparatus for dyeing or colouring textile fabrics

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3795082A (en) * 1972-05-04 1974-03-05 Beloit Corp Paper roll coding device
US3828405A (en) * 1972-10-12 1974-08-13 Vinney G De Method for imparting coloration to a textile yarn
US4369640A (en) * 1980-08-20 1983-01-25 Wadsworth-Greenwood Corporation Apparatus for obtaining uniform solid colors or variegated patterns in fabrics
US4377080A (en) * 1980-08-20 1983-03-22 Greenwood Corp. Of America Apparatus for obtaining variegated patterns
US4381726A (en) * 1981-11-17 1983-05-03 A/S Phonix Tagpap Og Vejmaterialer Apparatus for applying stripe material to a solid surface
US5737813A (en) * 1988-04-14 1998-04-14 International Paper Company Method and apparatus for striped patterning of dyed fabric by hydrojet treatment
US5222266A (en) * 1990-09-11 1993-06-29 Btr Operations Nz Limited Process and apparatus for the space dyeing of hanks of fibre or yarn
AU639358B2 (en) * 1990-09-11 1993-07-22 Btr Operations Nz Limited Dyeing process
US5887459A (en) * 1995-07-14 1999-03-30 Fleissner Gmbh & Co., Mashinenfabrik Device for applying a liquid film, uniformly thin over the working width, to a web of goods
US6048489A (en) * 1996-11-18 2000-04-11 The Procter & Gamble Company Absorbent products, and apparatus and method for producing the same
US5866173A (en) * 1996-11-18 1999-02-02 The Procter & Gamble Company Apparatus for producing absorbent products
US5996154A (en) * 1996-12-12 1999-12-07 Fleissner Gmbh & Co. Maschinenfabrik Device for applying a liquid film to a continuously advanced web of goods, method for producing a color pattern on a web of goods, and pattern produced by this method
US5913905A (en) * 1996-12-12 1999-06-22 Fleissner Gmbh & Co. Maschinenfabrik Device for applying a liquid film to a continuously advanced web of goods
WO1998037268A1 (en) * 1997-02-24 1998-08-27 Bba Nonwovens Simpsonville, Inc. Method and apparatus for striped patterning of dyed fabric by hydrojet treatment
WO2003059528A1 (en) * 2002-01-16 2003-07-24 Metso Paper, Inc. Method and apparatus for feeding a treating agent onto a moving surface
US20050066889A1 (en) * 2002-01-16 2005-03-31 Rauno Rantanen Method and apparatus for feeding a treating agent onto a moving surface
US7303634B2 (en) 2002-01-16 2007-12-04 Metso Paper, Inc. Method and apparatus for feeding a treating agent onto a moving surface
CN101143356B (zh) * 2007-11-01 2010-05-19 上海誉辉化工有限公司 泡沫施加装置

Also Published As

Publication number Publication date
ZA707536B (en) 1971-07-28
GB1279814A (en) 1972-06-28
FR2069303A5 (xx) 1971-09-03
DE2055952A1 (de) 1971-05-27
ES385517A1 (es) 1973-03-16
BE758949A (fr) 1971-05-13
NL7016422A (xx) 1971-05-17

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