US3652277A - Processing for photographic silver halide light-sensitive element - Google Patents
Processing for photographic silver halide light-sensitive element Download PDFInfo
- Publication number
- US3652277A US3652277A US844129A US3652277DA US3652277A US 3652277 A US3652277 A US 3652277A US 844129 A US844129 A US 844129A US 3652277D A US3652277D A US 3652277DA US 3652277 A US3652277 A US 3652277A
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- US
- United States
- Prior art keywords
- group
- silver halide
- developer
- sensitive element
- photographic silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- -1 silver halide Chemical class 0.000 title claims abstract description 47
- 238000012545 processing Methods 0.000 title claims abstract description 41
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 36
- 239000004332 silver Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 57
- 150000001875 compounds Chemical group 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims description 15
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 10
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 9
- 229940015043 glyoxal Drugs 0.000 claims description 5
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 5
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 claims description 5
- 229950005308 oxymethurea Drugs 0.000 claims description 5
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 3
- 150000004986 phenylenediamines Chemical class 0.000 claims description 2
- 239000004848 polyfunctional curative Substances 0.000 claims description 2
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 claims 1
- 238000011161 development Methods 0.000 abstract description 32
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract description 12
- 239000002253 acid Substances 0.000 abstract description 6
- 150000003839 salts Chemical class 0.000 abstract description 5
- 125000000623 heterocyclic group Chemical group 0.000 abstract description 4
- 125000000547 substituted alkyl group Chemical group 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 27
- 238000005406 washing Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 8
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 6
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 5
- 150000001299 aldehydes Chemical class 0.000 description 5
- 230000035945 sensitivity Effects 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical compound CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 2
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229940125904 compound 1 Drugs 0.000 description 2
- 229940125773 compound 10 Drugs 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- GHYOCDFICYLMRF-UTIIJYGPSA-N (2S,3R)-N-[(2S)-3-(cyclopenten-1-yl)-1-[(2R)-2-methyloxiran-2-yl]-1-oxopropan-2-yl]-3-hydroxy-3-(4-methoxyphenyl)-2-[[(2S)-2-[(2-morpholin-4-ylacetyl)amino]propanoyl]amino]propanamide Chemical compound C1(=CCCC1)C[C@@H](C(=O)[C@@]1(OC1)C)NC([C@H]([C@@H](C1=CC=C(C=C1)OC)O)NC([C@H](C)NC(CN1CCOCC1)=O)=O)=O GHYOCDFICYLMRF-UTIIJYGPSA-N 0.000 description 1
- JEOQACOXAOEPLX-WCCKRBBISA-N (2s)-2-amino-5-(diaminomethylideneamino)pentanoic acid;1,3-thiazolidine-4-carboxylic acid Chemical compound OC(=O)C1CSCN1.OC(=O)[C@@H](N)CCCN=C(N)N JEOQACOXAOEPLX-WCCKRBBISA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 125000003412 L-alanyl group Chemical group [H]N([H])[C@@](C([H])([H])[H])(C(=O)[*])[H] 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- FZGDWZOVHIUGQS-UHFFFAOYSA-M [OH-].[Na+].C(C)(=O)NC1=CC=CC=C1 Chemical compound [OH-].[Na+].C(C)(=O)NC1=CC=CC=C1 FZGDWZOVHIUGQS-UHFFFAOYSA-M 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- DNSISZSEWVHGLH-UHFFFAOYSA-N butanamide Chemical compound CCCC(N)=O DNSISZSEWVHGLH-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229940125797 compound 12 Drugs 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- YFMGHVQBAINRBB-UHFFFAOYSA-L disodium hydrogen carbonate chloride hydrate Chemical compound C([O-])(O)=O.[Na+].Cl.[OH-].[Na+] YFMGHVQBAINRBB-UHFFFAOYSA-L 0.000 description 1
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- BBYVLVFSYYVGCD-UHFFFAOYSA-M potassium bromide hydrochloride Chemical compound Cl.[K+].[Br-] BBYVLVFSYYVGCD-UHFFFAOYSA-M 0.000 description 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
- 229940116357 potassium thiocyanate Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/167—X-ray
Definitions
- the present invention relates to a method for processing photographic silver halide light-sensitive elements and more particularly to a method for processing photographic silver halide light-sensitive elements using an aldehyde-containing gelatin hardening agent and an antifoggant.
- R represents a lower alkyl group or a substituted alkyl group
- Ar represents a phenyl group or a substituted I phenyl group
- n is strength of the emulsion layers of the'light-sensitive elements in the high temperature developer or other processing solution must be prevented from being degraded. Therefore, it is necessary to increase the mechanical strength of the emulsion layer before development or during development and maintain the mechanical strength thereof throughout the development.
- a photographic silver halide light-sensitive element is, before development, subjected to a prehardening processing in a prehardening solution containing an aldehyde type hardening agent.
- the aldehyde compound remaining unreacted in the emulsion layer is removed by water washing or is made harmless by processing it in a solution before development.
- Such a method has the advantages that the processing time is shortened by the high temperature development and the efficiency of the processing is improved but has the disadvantage that the nurnber of the processing steps is greater than those in the usual method.
- the disadvantage is caused by the use of an aldehyde compound as the hardening agent, for example; when an aldehyde, particularly a dialdehyde, is added to a developer, the formation of fog of a black and white photographic film or a photographic color film processed in the developer is remarkably increased.
- the formation of the fog caused by the addition of such an aldehyde can be prevented by using a strong antifoggant such as benztriazole or mercatobenztetrazole.
- a strong antifoggant such as benztriazole or mercatobenztetrazole.
- the use of such an antifoggant strongly supresses the progress of development at the same time, the sensitivity of the emulsion is greatly decreased.
- FIGS. 1 and 2 show the amount of fog occuring in various films after being processed in various developer solutions.
- an object of the present invention is to provide a process for processing a light-exposed photographic silver halide light-sensitive element without forming fog.
- Another object of this invention is to provide a process fo preventing the formation of fog caused by processing'a photographic silver halide light-sensitive element in a processing solution containing an aldehyde-type hardening agent.
- a further object of this invention is to provide a process for developing a photographic silver halide light-sensitive element without reducing the developing speed and the sensitivity of emulsion.
- the present inventors have investigated the methods of achieving the above-mentioned objects and, as a result thereof, have found that the aforesaid objects can be achieved by utilizing the present invention. More specifically, the above objects of this invention can be achieved by incorporating, in a or 1, said n being 0 when the compound is an internal salt.
- the lower alkyl group R the following may be used: a methyl group, an ethyl group, a propyl group and a butyl group and as the substituted alkyl group, a carboxymethyl group, a B-carboxyethyl group, a 'y-carboxypropyl group, a fl-hydroxyethyl group, a B-acetoxyethyl group, a B-sulfoethyl group, a 'y-sulfobutyl group, a 8- sulfobutyl group, a methoxyethyl group and the like.
- substituted phenyl group Ar the following are examples: phenyl groups substituted by a lower alkyl group; a hydroxyl group, an alkoxyl group, a nitro group, a halogen atom, a carboxyl group, NHCOR (wherein R represents a lower alkyl group), or
- R and R" each represents a lower alkyl group, an aralkyl group or an aryl group, R and R" being the same or different.
- acid residual group X there may be illustrated the following: halogen ions, such as a chlorine ion or a bromine ion, a methyl sulfate ion, a p-toluene sulfonate ion, and the like.
- the development processing steps in the specification of this invention mean a prehardening process and a development process.
- the light-exposed photographic silver halide element be processed in a developer containing the compound represented by the above-mentioned general formula and an aldehyde-type hardening agent but thelightexposed photographic element may be processed in a prehardening solution containing an aldehyde-type hardening agent and the aforesaid compound or may be processed in a prehardening agent and thereafter in a developer containing the aforesaid compound.
- the amount of the compound represented by the aforesaid general formula giving an effective antifogging effect in the case of incorporating the compound in a developer containing the aldehyde-type hardening agent is usually 20-400 mg. particularly -300 mg. per 1 liter of developer.
- the proportion is higher than 400 mg., the development is excessively suppressed with the result that the sensitivity is reduced.
- the amount is lower than 20 mg., the antifogging effect is very small.
- an alkaline aqueous solution containing a developing agent such as N-methyl-p-aminophenol, dihydroxybenzene, 1- phenyl-3-pyrazolidine, phenylenediamine or derivatives thereof.
- the aldehyde-test hardening agent used in this invention is a compound having at least one aldehyde group, such as formaldehyde, dimethylol urea, 'glyoxal, glutalaldehyde or the like, a sulfite thereof or a bisulfite thereof.
- the process of this invention may be applied to the developing process for all photographic silver halide light-sensitive elements but may be particularly applied to a high temperature and high speed processing for black and white or color photographic elements.
- FIGS. 1 and 2 of the accompanying drawings which shows that the sample processed in developer B or developer C showed less fog than the sample processed in developer A (control). Also, the gamma and the effective sensitivity in the former (B or C) were higher than in the latter EXAMPLE 2
- Commercially available high speed black and white negative photographic light-sensitive films were exposed by using a standard sensitometer and each of them was developed for 8 minutes at 20 C.
- EXAMPLE 3 The photographic films as in Example 2 were exposed by using a sensitometer. One sample was then processed for 2 minutes in prehardening solution A (an aqueous solution having a pH of 10.3 and containing 10 ml. of 25 percent glutalaldehyde per 1 liter of the solution) and another sample was processed for 2 minutes in prehardening solution B (an aqueous solution having a pH of 10.3 and containing 10 ml. of 25 percent glutalaldehyde and 100 ml. of Compound 10 per 1 liter of the solution). Thereafter, the samples were processed for 8 minutes at C. in developer D as in example 2. The results showed that the formation of fog in the sample processed in prehardening solution B was much less than that of the sample processed in prehardening solution A as in Examples l and 2.
- the prehardening step and the water washing step before the first development in the so-called coupler-indeveloper type color developing system can be omitted, as well as reducing the period of time required for finishing the first development by conducting the development at a high temperature without being accompanied with the aforesaid drawbacks, which make the process of this invention very profitable.
- An example of the improved steps for this development is shown below:
- First development 40 hardening development
- Water washing 40 First developer
- Cyan color developer Anhydrous sodium sulfite 5.0 g. d-amino-J-methyl-N,N-diethylaniline 0.6 g. hydrochloride Sodium carbonate (mono-hydrate) 15.0 g. Potassium bromide 0.25 g. Potassium iodide (0.1% aq. soln.) 2 ml. l,5-Dihydroxy-2,6-dibromonaphthalcne 1.2 g. Sodium hydroxide 2.0 g.
- Magenta color developer Anhydrous sodium sulfite 5.0 g. 4 amino-3-methyl-N,N-diethylaniline 2.0 g. hydrochloride Potassium bromide I 0.2 g. l-phenyl-3-(m-nitrobenzylamino)- 1.4 g. S-pyrazolone Sodium hydroxide 2.5 g. n-butylamide 5 ml. Water to make 1 liter Bleaching solution Ferricyanide 100 g. Potassium bromide g. Borax 2 g. Boric acid 1 g. Water to make l liter Fixing solution Sodium thiosulfate 150 g. Anhydrous sodium sulfile 10 g.
- R represents a member selected from the group consisting of a lower alkyl group and a substituted lower alkyl group of from one to four carbon atoms
- Ar represents a member selected from the group consisting of a phenyl group and a substituted phenyl group
- X represents an acid residual group
- n is 0 or 1, said It being 0 when the compound forms an internal salt.
- aldehyde-type hardening agent is a member selected from the group consisting of formaldehyde, dimethylol urea, glyoxal and glutalaldehyde.
- said hardening agent is a member selected from the group consisting of the sulfite and bisulfite adduct of formaldehyde, dimethylol urea, glyoxal and glutalaldehyde.
- said developing agent is a member selected from the group consisting of N-methyl-pamino phenol, dihydroxy benzene, l-phenyl-3-pyrazolidone, phenylene diamine and derivatives thereof.
- the substituted lower alkyl group is a member selected from the group consisting of a carboxymethyl group, a fl-carboxyethyl group, a 'ycarboxypropyl group, a B-hydroxyethyl group, a fi-acetoxyethyl group, a fi-sulfoethyl group, 8-sulfobutyl group, a 'y-sulfobutyl group and a methoxyethyl group.
- a method of developing a photographic silver halide light-sensitive element which comprises prehardening and developing an exposed photographic silver halide light-sensitive element, wherein the element is pro-hardened in a solution containing an aldehyde-type hardening agent and subsequently processing in a conventional developer containing a compound represented by the formula:
- R 1' wherein Z represents an atom necessary to complete a heterocyclic ring, R represents a member selected from the group consisting of a lower alkyl group and a substituted lower alkyl group of from one to four carbon atoms, Ar represents a member selected from the group consisting of a phenyl group and a substituted phenyl group, X represents an acid residual group, and n is 0 or i, said n being 0 when the compound forms an internal salt.
- a method of developing a photographic silver halide light-sensitive element said element containing in the silver halide emulsion layer or in a photographic layer adjacent to said silver halide emulsion layer a compound represented by the formula:
- R represents a member selected from the group consisting of a lower alkyl group and a substituted lower'alkyl group of from one to four carbon atoms
- Ar represents a member selected from the group consisting of a phenyl group and a substituted phenyl group
- X represents an acid residual group
- n is 0 or 1, said It being 0 when the compound forms an internal salt, which comprises processing said exposed photographic silver halide light-sensitive element with a processing solution containing an aldehyde-type hardening agent.
- a method of developing a photographic silver halide light-sensitive element which comprises pre-hardening an exposed photographic silver halide light sensitive element in a pre-hardening solution containing an aldehyde-type hardening agent and a compound represented by the formula:
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5206968 | 1968-07-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3652277A true US3652277A (en) | 1972-03-28 |
Family
ID=12904511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US844129A Expired - Lifetime US3652277A (en) | 1968-07-23 | 1969-07-23 | Processing for photographic silver halide light-sensitive element |
Country Status (4)
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4322494A (en) * | 1980-01-23 | 1982-03-30 | Fuji Photo Film Co., Ltd. | Photographic light-sensitive material |
| US4416981A (en) * | 1982-04-29 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Benzothiazoline derivatives as silver halide antifoggants |
| US5082765A (en) * | 1986-04-04 | 1992-01-21 | Konica Corporation | Method of processing light-sensitive silver halide photographic material |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1550356A (en) * | 1975-05-01 | 1979-08-15 | Agfa Gevaert | Hardening developers for silver halide photography |
| JPS5251940A (en) * | 1975-10-24 | 1977-04-26 | Fuji Photo Film Co Ltd | Processing of silver halide photographic light sensitive material |
| US20240030757A1 (en) | 2020-12-17 | 2024-01-25 | Nidec Psa Emotors | Coil intended to be inserted in the notches of a stator of a rotating electrical machine |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2320654A (en) * | 1940-08-08 | 1943-06-01 | Riester Oskar | Sensitization of photographic emulsions |
| US2494032A (en) * | 1946-06-03 | 1950-01-10 | Eastman Kodak Co | Styryl dyes |
| US2901351A (en) * | 1954-12-10 | 1959-08-25 | Gavaert Photo Producten N V | Direct positive photographic material |
| US3071465A (en) * | 1961-03-14 | 1963-01-01 | Gen Aniline & Film Corp | Fog reduction in silver halide emulsions by 2h-tetrazolium halides |
-
1969
- 1969-07-21 DE DE19691937049 patent/DE1937049A1/de active Pending
- 1969-07-21 GB GB36621/69A patent/GB1260710A/en not_active Expired
- 1969-07-23 US US844129A patent/US3652277A/en not_active Expired - Lifetime
- 1969-07-23 FR FR6925098A patent/FR2013543A1/fr not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2320654A (en) * | 1940-08-08 | 1943-06-01 | Riester Oskar | Sensitization of photographic emulsions |
| US2494032A (en) * | 1946-06-03 | 1950-01-10 | Eastman Kodak Co | Styryl dyes |
| US2901351A (en) * | 1954-12-10 | 1959-08-25 | Gavaert Photo Producten N V | Direct positive photographic material |
| US3071465A (en) * | 1961-03-14 | 1963-01-01 | Gen Aniline & Film Corp | Fog reduction in silver halide emulsions by 2h-tetrazolium halides |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4322494A (en) * | 1980-01-23 | 1982-03-30 | Fuji Photo Film Co., Ltd. | Photographic light-sensitive material |
| US4416981A (en) * | 1982-04-29 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Benzothiazoline derivatives as silver halide antifoggants |
| US5082765A (en) * | 1986-04-04 | 1992-01-21 | Konica Corporation | Method of processing light-sensitive silver halide photographic material |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1260710A (en) | 1972-01-19 |
| DE1937049A1 (de) | 1970-02-19 |
| FR2013543A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1970-04-03 |
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