US3642613A - Black oil conversion process startup procedure - Google Patents
Black oil conversion process startup procedure Download PDFInfo
- Publication number
- US3642613A US3642613A US47905A US3642613DA US3642613A US 3642613 A US3642613 A US 3642613A US 47905 A US47905 A US 47905A US 3642613D A US3642613D A US 3642613DA US 3642613 A US3642613 A US 3642613A
- Authority
- US
- United States
- Prior art keywords
- temperature
- catalyst
- black oil
- hydrogen
- hydrocarbon mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 58
- 238000006243 chemical reaction Methods 0.000 title abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 24
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 24
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 24
- 239000003921 oil Substances 0.000 abstract description 42
- 239000003054 catalyst Substances 0.000 abstract description 35
- 239000001257 hydrogen Substances 0.000 abstract description 24
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 23
- 230000003197 catalytic effect Effects 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 description 10
- 239000002131 composite material Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- 238000009835 boiling Methods 0.000 description 6
- 238000006477 desulfuration reaction Methods 0.000 description 5
- 230000023556 desulfurization Effects 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000007792 gaseous phase Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000010420 art technique Methods 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/24—Starting-up hydrotreatment operations
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Definitions
- black oil conversion conditions include a pressure from 1,000 to about 5,000 p.s.i.g. a hydrogen concentration from 5,000 s.c.f./bbl. and a liquid hourly space velocity (defined as volumes of fresh feed liquid charge per hour, measured at 60 F., per volume of catalyst disposed within the reaction zone) in the range of about 0.2 to about 3.0.
- the temperature is increased to a level in the range of 400 to about 500 F. for the sulfiding operation.
- the hydrogen sulfide concentration in the hydrogen-rich gaseous phase is monitored to determine the time when an equilibrium content is attained.
- the black oil charge stock is introduced, the flow of sulfiding oil is ceased and the temperature increased to the operational level in the range of 700 to about 900 F.
- the flow of the sulfiding oil is continued while the temperature is increased to 500 to about 600 F., at which time the black oil is introduced, and the temperature further increased as aforesaid.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4790570A | 1970-06-19 | 1970-06-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3642613A true US3642613A (en) | 1972-02-15 |
Family
ID=21951670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US47905A Expired - Lifetime US3642613A (en) | 1970-06-19 | 1970-06-19 | Black oil conversion process startup procedure |
Country Status (15)
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953321A (en) * | 1974-12-27 | 1976-04-27 | Texaco Inc. | Method of hydrodesulfurizing heavy petroleum fraction in the initial stage of the on-stream period |
| US3992284A (en) * | 1975-09-17 | 1976-11-16 | Uop Inc. | Black oil conversion process startup and shutdown methods |
| US4348270A (en) * | 1979-11-13 | 1982-09-07 | Exxon Research And Engineering Co. | Catalysts and hydrocarbon treating processes utilizing the same |
| US4357229A (en) * | 1979-11-01 | 1982-11-02 | Exxon Research And Engineering Co. | Catalysts and hydrocarbon treating processes utilizing the same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4053390A (en) * | 1975-12-17 | 1977-10-11 | Cities Service Research And Development Company | Start-up procedure for a residual oil processing unit |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2953519A (en) * | 1957-12-16 | 1960-09-20 | Gulf Research Development Co | Start up procedure for catalytic hydrogen treatment of hydrocarbons |
| US3423307A (en) * | 1965-11-12 | 1969-01-21 | Gulf Research Development Co | Start-up of a hydrodesulfurization reaction |
| US3441500A (en) * | 1966-08-04 | 1969-04-29 | Sinclair Research Inc | Process for activating a fixed bed of hydrorefining catalyst |
| US3528910A (en) * | 1967-06-26 | 1970-09-15 | Sinclair Research Inc | Hydrotreating process utilizing alkyl disulfide for in situ catalyst activation |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL198189A (enrdf_load_stackoverflow) * | 1954-06-21 | |||
| US3244617A (en) * | 1963-06-11 | 1966-04-05 | Cities Service Res & Dev Co | Start-up of a hydrogenation-hydrocracking reaction |
| US3291722A (en) * | 1963-11-19 | 1966-12-13 | Chevron Res | Hydrocarbon conversion process startup procedure |
| US3287258A (en) * | 1964-04-13 | 1966-11-22 | Chevron Res | Hydrocarbon conversion process start-up procedure |
| US3481862A (en) * | 1967-10-30 | 1969-12-02 | Sun Oil Co | Cs2 sulfiding of catalysts |
-
1970
- 1970-06-19 US US47905A patent/US3642613A/en not_active Expired - Lifetime
-
1971
- 1971-06-16 EG EG259/71A patent/EG10736A/xx active
- 1971-06-17 NL NL7108331A patent/NL7108331A/xx not_active Application Discontinuation
- 1971-06-18 CA CA116,069A patent/CA944710A/en not_active Expired
- 1971-06-18 DK DK302571AA patent/DK139914B/da not_active IP Right Cessation
- 1971-06-18 AR AR236284A patent/AR202883A1/es active
- 1971-06-18 ES ES392405A patent/ES392405A1/es not_active Expired
- 1971-06-18 DE DE19712130398 patent/DE2130398A1/de active Pending
- 1971-06-18 FR FR7122277A patent/FR2095369B1/fr not_active Expired
- 1971-06-18 SU SU1669584A patent/SU421198A3/ru active
- 1971-06-18 ZA ZA713994A patent/ZA713994B/xx unknown
- 1971-06-18 GB GB2866871A patent/GB1343792A/en not_active Expired
- 1971-06-18 SE SE7107970A patent/SE393628B/xx unknown
- 1971-06-19 JP JP46044455A patent/JPS5218201B1/ja active Pending
- 1971-06-21 AT AT537171A patent/AT315993B/de not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2953519A (en) * | 1957-12-16 | 1960-09-20 | Gulf Research Development Co | Start up procedure for catalytic hydrogen treatment of hydrocarbons |
| US3423307A (en) * | 1965-11-12 | 1969-01-21 | Gulf Research Development Co | Start-up of a hydrodesulfurization reaction |
| US3441500A (en) * | 1966-08-04 | 1969-04-29 | Sinclair Research Inc | Process for activating a fixed bed of hydrorefining catalyst |
| US3528910A (en) * | 1967-06-26 | 1970-09-15 | Sinclair Research Inc | Hydrotreating process utilizing alkyl disulfide for in situ catalyst activation |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953321A (en) * | 1974-12-27 | 1976-04-27 | Texaco Inc. | Method of hydrodesulfurizing heavy petroleum fraction in the initial stage of the on-stream period |
| US3992284A (en) * | 1975-09-17 | 1976-11-16 | Uop Inc. | Black oil conversion process startup and shutdown methods |
| US4357229A (en) * | 1979-11-01 | 1982-11-02 | Exxon Research And Engineering Co. | Catalysts and hydrocarbon treating processes utilizing the same |
| US4348270A (en) * | 1979-11-13 | 1982-09-07 | Exxon Research And Engineering Co. | Catalysts and hydrocarbon treating processes utilizing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| DK139914C (enrdf_load_stackoverflow) | 1979-10-15 |
| SU421198A3 (ru) | 1974-03-25 |
| FR2095369B1 (enrdf_load_stackoverflow) | 1974-09-27 |
| DK139914B (da) | 1979-05-14 |
| CA944710A (en) | 1974-04-02 |
| GB1343792A (en) | 1974-01-16 |
| ZA713994B (en) | 1972-09-27 |
| EG10736A (en) | 1976-04-30 |
| FR2095369A1 (enrdf_load_stackoverflow) | 1972-02-11 |
| DE2130398A1 (de) | 1971-12-23 |
| ES392405A1 (es) | 1973-08-16 |
| JPS5218201B1 (enrdf_load_stackoverflow) | 1977-05-20 |
| NL7108331A (enrdf_load_stackoverflow) | 1971-12-21 |
| AR202883A1 (es) | 1975-07-31 |
| AT315993B (de) | 1974-06-25 |
| SE393628B (sv) | 1977-05-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: UOP, DES PLAINES, IL, A NY GENERAL PARTNERSHIP Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:KATALISTIKS INTERNATIONAL, INC., A CORP. OF MD;REEL/FRAME:005006/0782 Effective date: 19880916 |
|
| AS | Assignment |
Owner name: UOP, A GENERAL PARTNERSHIP OF NY, ILLINOIS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:UOP INC.;REEL/FRAME:005077/0005 Effective date: 19880822 |