US3607809A - Blast furnace taphole plugs - Google Patents
Blast furnace taphole plugs Download PDFInfo
- Publication number
- US3607809A US3607809A US657499A US3607809DA US3607809A US 3607809 A US3607809 A US 3607809A US 657499 A US657499 A US 657499A US 3607809D A US3607809D A US 3607809DA US 3607809 A US3607809 A US 3607809A
- Authority
- US
- United States
- Prior art keywords
- mass
- taphole
- blast furnace
- plugs
- plugging
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920003180 amino resin Polymers 0.000 claims description 4
- 229920001568 phenolic resin Polymers 0.000 claims description 4
- 239000000463 material Substances 0.000 abstract description 16
- 239000011230 binding agent Substances 0.000 abstract description 9
- 239000000203 mixture Substances 0.000 abstract description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011822 basic refractory Substances 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- 238000005266 casting Methods 0.000 description 14
- 239000011269 tar Substances 0.000 description 10
- 238000004939 coking Methods 0.000 description 7
- 239000004576 sand Substances 0.000 description 7
- 239000004927 clay Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910000805 Pig iron Inorganic materials 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 230000035943 smell Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 206010047700 Vomiting Diseases 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- -1 aldehyde amine Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/12—Opening or sealing the tap holes
- C21B7/125—Refractory plugging mass
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
Definitions
- This invention relates to anhydrous plugs for stopping the tapholes of blast furnaces.
- This plug comprises, as a basic refractory material, a mixture consisting of low alumina pure silica and one or more refractory or gritty clays,
- a binder a resin or a plastic material containing a setting retarder such that the plug be heat stable at about 200 C.
- This invention relates to the manufacture of anhydrous masses or plugs for stopping the tapholes of blast furnaces.
- anhydrous stopping plugs consist as a rule of a mass or paste made of 20 percent of coking plant tar, percent of powdered coke or coal and 70 percent of an aggregate of refractory materials, these powders being ground to a suitable mesh size, well known to manufacturers; the resulting masses became extremely hard after firing so that the tapholes were no more worn away by the outflowing cast iron. Thus, it was no longer necessary to slow down the blast furnace operation at each casting, whereby a substantial gain was achieved in the daily production.
- the coking operation necessary for hardening the plug material makes it necessary to insert a stopper gun for a period of about 1 hour into the taphole; the space thus occupied in front of the blast furnace and in the main clay-lined trough or runner is particularly detrimental to the blast furnace operators or casters who are confronted with the difficult task of cleaning and repairing this trough or runner between successive castings.
- the time available for allowing the paste located inside the blast furnace to be fired completely is too short and when the plug is removed clots of unfired tar appear which produce flames thrown at relatively great distances, and likely to injure the men working on the front area of the blast furnace.
- the plug mass hardens at a very fast rate in the taphole and therefore the plugger can be withdrawn from the taphole 10 to 15 minutes after the plugging. Under these conditions, the works for reconditioning the casting trough or channel can be carried out more easily. In certain cases the gain of time permits a reduction of the number of men comprising the casting crew.
- the cleaning of this gun is much easier for the men entrusted with this task.
- the smell released from this paste is particularly light and cannot cause discomfort to the crew.
- the use of a binder in the plug mass improves the plasticity of the mass mixed with tars. Therefore, the improved mass according to this invention can be thrusted into the taphole by using taphole-plugging units of lower power rating, thereby enabling smaller concerns or plants to avoid the cost of powerful and therefore very costly plugging machines.
- the improved quick-hardening mass according to this invention is adaptable to the crucible of the blast furnace and constitutes a perfect lining for the internal wall of the crucible. Due to its quick-setting and high-hardness properties, it eliminates cast-iron infiltrations sometimes found after 40- inch to 45-inch drilling, which make drilling operations particularly difficult and costly due to the frequent breakage of drills.
- the first feature characterizing this invention consists in using, as a basic refractory material, a mixture consisting of pure silica (quartz sand) having a very low alumina content (not in excess of 3 to 4 percent) and of one or a plurality of refractory or gritty clays.
- the alumina content of the mixture is selected to keep the silica/alumina ratio as remote as possible from values likely to promote the development of an eutectic structure.
- Silica was the preferential choice because this material expands and tends to offset the shrinking of clay. As the mass hardens it adheres strongly to the walls of the taphole without producing cracks therein. On the other hand, as the absorption power of silica is very low, a lower amount of binder is required to produce a quick-setting plastic paste.
- this material is commonly referred to as a natural or synthetic resin (or) plastic material, and is thermosetting
- This organic material acts as a fluidizer and homogenizer during the manufacture of the plug mass. It also acts subsidiarily as a quickhardener during the plugging operation proper when, by heat conductibility, the heat gradually spreads through the plug mass, and furthermore this organic material promotes the setting of the plug mass within about to minutes.
- plug masses thus prepared had all the requisite properties of first quality taphole plugs at the first application, but as these masses are reconditioned the tapholes lost more and more their original tightness and eventually the plugs became unsuitable for properly sealing the taphole.
- the other feature characterizing this invention consists in utilizing as a binder-hardening substance a resin and a settingretarding agent such that the product be heat stable at about 200 C.
- the resin may be selected from the group comprising phenoplasts and aminoplasts.
- the anhydrous mass may further include materials selected from the group consisting of polyvinyl chloride, benzyl alcohol, and tricresyl phosphate.
- the binder pH value should range from 6 to 7.4.
- the paste can be used with the maximum safety and under practical operating conditions, thus affording considerable savings of material, labor and time.
- the basic materials such as the quartz sand and the heat stable adjuvant afford a competitive cost, and furthermore the amount of mass to be introduced into the taphole is reduced by one-half in relation to conventional masses.
- Refractory material 68% (34% sand, 18% clay) Coke over tar l 1% Liquid tar l7% Resol-type phenol resin 3.5%
- anhydrous mass for plugging blast-furnace tapholes comprising refractory clay and silica sand with tar as a hinder
- the improvement which comprises including in said mass approximately 2 percent to 5 percent of a thermosetting resin selected from the group consisting of phenoplasts and aminoplasts and heat stable at 200 C. and a material selected from the group consisting of polyvinyl chloride, benzyl al cohol, and tricresyl phosphate, said sand containing not more than 4 percent of alumina.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Ceramic Products (AREA)
- Mold Materials And Core Materials (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR112264A FR1535664A (fr) | 1967-06-28 | 1967-06-28 | Masses de bouchage pour hauts-fourneaux |
Publications (1)
Publication Number | Publication Date |
---|---|
US3607809A true US3607809A (en) | 1971-09-21 |
Family
ID=8634009
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US657499A Expired - Lifetime US3607809A (en) | 1967-06-28 | 1967-08-01 | Blast furnace taphole plugs |
Country Status (7)
Country | Link |
---|---|
US (1) | US3607809A (en, 2012) |
BE (1) | BE702208A (en, 2012) |
DE (1) | DE1583172C2 (en, 2012) |
FR (1) | FR1535664A (en, 2012) |
GB (1) | GB1189200A (en, 2012) |
LU (1) | LU56000A1 (en, 2012) |
NL (1) | NL6809217A (en, 2012) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3717602A (en) * | 1970-11-13 | 1973-02-20 | Didier Werke Ag | Stamping mass for metallurgical furnaces |
US4008194A (en) * | 1974-11-27 | 1977-02-15 | Kurosaki Refractories Co., Ltd. | Compositions for plugs of refractory material |
US4022739A (en) * | 1973-06-06 | 1977-05-10 | Terrac Company Limited | Composition for plugging blast-furnace tap-hole |
US4082718A (en) * | 1975-05-30 | 1978-04-04 | Nippon Steel Corporation | Tap hole mix |
US4327185A (en) * | 1980-12-05 | 1982-04-27 | Eltra Corporation | Refractory compositions with binder |
US4501836A (en) * | 1982-05-18 | 1985-02-26 | Sumitomo Durez Company, Ltd. | Liquid refractory binder |
US5447292A (en) * | 1992-09-30 | 1995-09-05 | Terres Refractaires Du Boulonnais | Method for the injection of a plugging mass in a tapping hole of a metallurgical reactor, such as a blast furnace |
US20100261599A1 (en) * | 2009-04-10 | 2010-10-14 | Edw. C. Levy Co. | Taphole Fill Material and Method for Manufacturing the Same |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU67749A1 (en, 2012) * | 1973-06-06 | 1973-08-16 | ||
DE2723792C3 (de) * | 1977-05-26 | 1980-12-11 | Ruetgerswerke Ag, 6000 Frankfurt | Feuerfeste Masse |
JPS6050751B2 (ja) * | 1978-07-24 | 1985-11-09 | 日石三菱株式会社 | 閉塞材組成物 |
EP0338174A1 (en) * | 1988-04-18 | 1989-10-25 | Dresser Industries, Inc. | Resin-bonded taphole mix |
US6469125B1 (en) | 2001-08-27 | 2002-10-22 | Arizona Chemical Company | Tall oil pitch-modified phenolic resin and methods related thereto |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2709659A (en) * | 1951-06-30 | 1955-05-31 | Union Carbide & Carbon Corp | Tap hole mix |
-
1967
- 1967-06-28 FR FR112264A patent/FR1535664A/fr not_active Expired
- 1967-08-01 US US657499A patent/US3607809A/en not_active Expired - Lifetime
- 1967-08-02 GB GB35531/67A patent/GB1189200A/en not_active Expired
- 1967-08-02 BE BE702208D patent/BE702208A/xx not_active IP Right Cessation
- 1967-12-22 DE DE1583172A patent/DE1583172C2/de not_active Expired
-
1968
- 1968-04-30 LU LU56000D patent/LU56000A1/xx unknown
- 1968-06-28 NL NL6809217A patent/NL6809217A/xx unknown
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3717602A (en) * | 1970-11-13 | 1973-02-20 | Didier Werke Ag | Stamping mass for metallurgical furnaces |
US4022739A (en) * | 1973-06-06 | 1977-05-10 | Terrac Company Limited | Composition for plugging blast-furnace tap-hole |
US4008194A (en) * | 1974-11-27 | 1977-02-15 | Kurosaki Refractories Co., Ltd. | Compositions for plugs of refractory material |
US4082718A (en) * | 1975-05-30 | 1978-04-04 | Nippon Steel Corporation | Tap hole mix |
US4327185A (en) * | 1980-12-05 | 1982-04-27 | Eltra Corporation | Refractory compositions with binder |
US4501836A (en) * | 1982-05-18 | 1985-02-26 | Sumitomo Durez Company, Ltd. | Liquid refractory binder |
US5447292A (en) * | 1992-09-30 | 1995-09-05 | Terres Refractaires Du Boulonnais | Method for the injection of a plugging mass in a tapping hole of a metallurgical reactor, such as a blast furnace |
US20100261599A1 (en) * | 2009-04-10 | 2010-10-14 | Edw. C. Levy Co. | Taphole Fill Material and Method for Manufacturing the Same |
US8062577B2 (en) | 2009-04-10 | 2011-11-22 | Edw. C. Levy Co. | Alumina taphole fill material and method for manufacturing |
US8216954B2 (en) | 2009-04-10 | 2012-07-10 | Edw. C. Levy Co. | Taphole fill material and method for manufacturing the same |
Also Published As
Publication number | Publication date |
---|---|
DE1583172B1 (de) | 1970-10-15 |
FR1535664A (fr) | 1968-08-09 |
GB1189200A (en) | 1970-04-22 |
DE1583172C2 (de) | 1973-12-20 |
BE702208A (en, 2012) | 1968-01-15 |
LU56000A1 (en, 2012) | 1968-08-30 |
NL6809217A (en, 2012) | 1968-12-30 |
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