US3607470A - Thixotropic gelled liquid rocket fuel containing hydrazine and aluminum hydride coated with a semicarbazide copolymer - Google Patents

Thixotropic gelled liquid rocket fuel containing hydrazine and aluminum hydride coated with a semicarbazide copolymer Download PDF

Info

Publication number
US3607470A
US3607470A US698660A US3607470DA US3607470A US 3607470 A US3607470 A US 3607470A US 698660 A US698660 A US 698660A US 3607470D A US3607470D A US 3607470DA US 3607470 A US3607470 A US 3607470A
Authority
US
United States
Prior art keywords
aluminum hydride
hydrazine
semicarbazide
alkyl
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US698660A
Inventor
James M Lucas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aerojet Rocketdyne Inc
Original Assignee
Aerojet General Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aerojet General Corp filed Critical Aerojet General Corp
Application granted granted Critical
Publication of US3607470A publication Critical patent/US3607470A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
    • C06B45/18—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component
    • C06B45/30—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component
    • C06B45/32—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component the coating containing an organic compound
    • C06B45/34—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component the coating containing an organic compound the compound being an organic explosive or an organic thermic component
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
    • C06B23/001—Fillers, gelling and thickening agents (e.g. fibres), absorbents for nitroglycerine
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
    • C06B45/18—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component
    • C06B45/30—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component
    • C06B45/32—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component the coating containing an organic compound
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
    • C06B47/02—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant
    • C06B47/08—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant a component containing hydrazine or a hydrazine derivative

Definitions

  • the present invention comprises a novel thixotropic, mechanically stable, gelled liquid fuel composition
  • hydrazine fuel containing uniformly distributed therein aluminum hydride coated with a poly [(alkyl or aryl)-(alkyl or aryl) semicarbazide] copolymer.
  • the gelled fuels of the present invention provide a storable propellant system.
  • the aluminum hydride does not tend to settle in the bottom nor does it tend to generate gas from the hydrazine fuel.
  • the novel gelled fuel of the present invention is prepared by adding an inert solvent containing alkyl or aryl dihydrazine to aluminum hydride to form a slurry.
  • An aryl or alkyl diisocyanate dissolved in an inert solvent is added to the agitated slurry.
  • the mixture is separated by filtration.
  • the solid product is washed with fresh solvent and dried.
  • the coated aluminum hydride is then mixed with a hydrazine fuel and a uniform stable thixotropic suspension is formed.
  • the addition of the dihydrazine and the diisocyanate is normally carried out at ambient temperatures.
  • R and R represent alkyl or aryl groups. Usually, these groups contain from 1 to about 12 carbon atoms.
  • the polymers are prepared by reacting the dihydrazine and diisocyanate in a one-to-one mole ratio.
  • the weight ratio of coated aluminum hydride to hydrazine fuel approximates one-to-one.
  • the minimum weight ratio of the polymer coating to the aluminum hydride is normally about 1 to 20.
  • the proportions and ratios referred to are not critical to this invention. The optimum values vary with the particular type of aluminum hydride and polymeric coating used. For any given system, those skilled in the art will be able to optimize the ratios and proportions by performing a few simple tests to establish good gelling and low gas evolution. As a general proposition, the polymeric coating and aluminum hydride are present in effective gelling and gas evolution-controlling amounts.
  • Typical dihydrazines and diisocyanates used in this invention include ethylene dihydrazine, phenylene dihydrazine, hexamethylene diisocyanate, and phenylene diisocyanate.
  • EXAMPLE I Ethylene dihydrazine (2 millimoles) was mixed with 50 ml. of diethylether and this dispersion was added to 10 grams of aluminum hydride in a flask equipped with a stirrer, con denser, addition funnel, and inert gas inlet. The additions and reactions were conducted under an atmosphere of nitrogen. Hexamethylene diisocyanate (2 millimoles) was dissolved in 25 ml. of diethyl either and this solution was added drop-wise to the stirred slurry of aluminum hydride, ethylene hexamethylene and diethyl ether. The mixture was stirred for 3 hours at room temperature after the additions were completed. The mixture was filtered; the solid residue was washed twice with 10 ml. of diethyl ether and then dried at room temperature to a constant weight.
  • Example II The dried product of Example 1 was added to an anhydrous hydrazine to form a mixture of 50.2 weight percent hydrazine and 49.8 weight percent coated aluminum hydride. After stirring for one-half hour, a smooth uniform, thixotropic suspension was performed. The density of this suspension was 1.18 grams per ml. and the viscosity at a shear rate of l7,300 sec. 1 was 24.0 cp. This moisture was chemically and mechanically stable for 93 days at which time the experiment was terminated.
  • the unique polymer coated aluminum hydride of the present invention represents a major breakthrough in the field of liquid rocket propellants.
  • This system provides a fuel which is feasible for handling in the available liquid rocket engines while minimizing the hazards previously associated with these materials.
  • the problem of gas evolution and lack of a mechanically stable gel have been overcome.
  • a novel thixotropic gelled liquid rocket fuel composition comprising hydrazine fuel containing uniformly distributed therein aluminum hydride coated with an effective gelproducing and gas formation-inhibiting amount of a poly [(alkyl or aryl)-(alkyl or aryl) semicarbazide] copolymer having the repeating units:
  • R and R are alkyl or aryl.
  • a novel thixotropic gelled liquid rocket fuel composition comprising hydrazine fuel containing uniformly distributed therein aluminum hydride coated with an effective gelproducing and gas formation-inhibiting amount of poly(lethylene-4-hexamethylene semicarbazide).
  • R and R are alkyl or aryl, said copolymer forming a coating on the aluminum hydride, and combining the coated aluminum hydride with hydrazine fuel.
  • copolymer comprises poly (l-ethylene-4-hexarnethylenesemicarbazide).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

This patent describes a thixotropic, storage and mechanically stable, gelled liquid rocket fuel comprising hydrazine fuel containing therein a suspension of a polysemicarbazide coated aluminum hydride, and the method for the preparation of the same.

Description

United States Patent James M. Lucas El Dorado Hills, Calif. 698,660
Jan. 12, 1968 Sept. 21, 1 971 Aerojet-General Corporation El Monte, Calif.
Inventor Appl. No. Filed Patented Assignee THIXOTROPIC GELLED LIQUID ROCKET FUEL CONTAINING HYDRAZINE AND ALUMINUM I-IYDRIDE COATED WITH A SEMICARBAZIDE COPOLYMER [56] References Cited UNITED STATES PATENTS 2,970,899 2/1961 Ryker 149/36 X 3,077,072 2/1963 Rice 149/36 3,092,959 6/1963 Scurlock et a1. 149/36 X 3,164,505 1/1965 l-lsieh et a1 149/36 3,177,652 4/1965 Lewis 149/36 X 3,359,144 12/1967 Atkins et a1 149/36 Primary Examiner-Carl D. Quarforth Assistant Examiner-S. J. Lechert Anorneys Edward O. Ansell, D. Gordon Angus and T. Reid Anderson ABSTRACT: This patent describes a thixotropic, storage and mechanically stable, gelled liquid rocket fuel comprising hydrazine fuel containing therein a suspension of a polysemicarbazide coated aluminum hydride, and the method for the preparation of the same.
TI-IIXOTROPIC GELLED LIQUID ROCKET FUEL CONTAINING IIYDRAZINE AND ALUMINUM I'IYDRIDE COATED WITH A SEMICARBAZIDE COPOLYMER BACKGROUND OF THE INVENTION When a fuel composed of hydrazine and aluminum hydride is used in conjunction with nitrogen tetroxide, the theoretical impulse is substantially greater (about 39 percent) than is the system in which the aluminum hydride is omitted. This performance increase is particularly attractive for propellants to be used in tactical weapons. The advantages of aluminum hydride over other high energy fuels such as beryllium hydride are the absence of toxic exhaust products and lower cost. However, heretofore, major difficulties have been encountered with hydrazine fuels containing aluminum hydride due to the evolution of gas during storage. The evolution of gas is apparently caused by the catalytic decomposition of hydrazine on the surface of the aluminum hydride. To overcome the gas evolution problem, it has been proposed to coat the aluminum hydride with various polymeric coating materials. In another aspect of the problem, it has been long recognized that in order to avoid sloshing and minimize the hazards of spills and the like, a liquid rocket propellant should be in the form of a mechanically stable thixotropic gel. The gellation of hydrazine containing aluminum hydride has been accomplished using a number of different commercially available gelling agents. However, most of these gelling agents are not satisfactory because they are easily shear thinned and have a long recovery time.
The present invention is based upon the surprising discovery that a poly [(alkyl or aryl)-(alkyl or aryl) semicarbazide] copolymer coating on aluminum hydride eliminates the gas evolution problem and causes gelling of the hydrazine fuel to eliminate the need for additional gelling agents. The present invention provides the only known aluminum hydridehydrazine fuel system in which the coating used to eliminate gas evolution also produces a thixotropic gel.
SUMMARY OF THE INVENTION Briefly, the present invention comprises a novel thixotropic, mechanically stable, gelled liquid fuel composition comprising hydrazine fuel containing uniformly distributed therein aluminum hydride coated with a poly [(alkyl or aryl)-(alkyl or aryl) semicarbazide] copolymer. It has been found that the gelled fuels of the present invention provide a storable propellant system. In other words, the aluminum hydride does not tend to settle in the bottom nor does it tend to generate gas from the hydrazine fuel.
It is an object of this invention to prepare a novel gelled liquid rocket fuel.
More particularly, it is an object of this invention to provide a fuel containing aluminum hydride in which a single agent causes gelling and reduces gas evolution.
These and other objects and advantages of .this invention will be apparent from the detailed description which follows.
DESCRIPTION OF PREFERRED EMBODIMENTS In general, the novel gelled fuel of the present invention is prepared by adding an inert solvent containing alkyl or aryl dihydrazine to aluminum hydride to form a slurry. An aryl or alkyl diisocyanate dissolved in an inert solvent is added to the agitated slurry. After completion of the reaction, the mixture is separated by filtration. The solid product is washed with fresh solvent and dried. The coated aluminum hydride is then mixed with a hydrazine fuel and a uniform stable thixotropic suspension is formed. The addition of the dihydrazine and the diisocyanate is normally carried out at ambient temperatures.
The chemical reaction involved in the formation of the poly [(alkyl or aryl)-(alkyl or aryl) semicarbazide] copolymer is as follows:
and
wherein R and R represent alkyl or aryl groups. Usually, these groups contain from 1 to about 12 carbon atoms.
Preferably, although not necessarily, the polymers are prepared by reacting the dihydrazine and diisocyanate in a one-to-one mole ratio. For optimum results, the weight ratio of coated aluminum hydride to hydrazine fuel approximates one-to-one. The minimum weight ratio of the polymer coating to the aluminum hydride is normally about 1 to 20. In general, the proportions and ratios referred to are not critical to this invention. The optimum values vary with the particular type of aluminum hydride and polymeric coating used. For any given system, those skilled in the art will be able to optimize the ratios and proportions by performing a few simple tests to establish good gelling and low gas evolution. As a general proposition, the polymeric coating and aluminum hydride are present in effective gelling and gas evolution-controlling amounts.
Typical dihydrazines and diisocyanates used in this invention include ethylene dihydrazine, phenylene dihydrazine, hexamethylene diisocyanate, and phenylene diisocyanate.
The following examples are presented solely to illustrate the invention and should not be regarded as limiting in any way. In the examples, the parts and percentages are by weight unless otherwise indicated.
EXAMPLE I Ethylene dihydrazine (2 millimoles) was mixed with 50 ml. of diethylether and this dispersion was added to 10 grams of aluminum hydride in a flask equipped with a stirrer, con denser, addition funnel, and inert gas inlet. The additions and reactions were conducted under an atmosphere of nitrogen. Hexamethylene diisocyanate (2 millimoles) was dissolved in 25 ml. of diethyl either and this solution was added drop-wise to the stirred slurry of aluminum hydride, ethylene hexamethylene and diethyl ether. The mixture was stirred for 3 hours at room temperature after the additions were completed. The mixture was filtered; the solid residue was washed twice with 10 ml. of diethyl ether and then dried at room temperature to a constant weight.
EXAMPLE II The dried product of Example 1 was added to an anhydrous hydrazine to form a mixture of 50.2 weight percent hydrazine and 49.8 weight percent coated aluminum hydride. After stirring for one-half hour, a smooth uniform, thixotropic suspension was performed. The density of this suspension was 1.18 grams per ml. and the viscosity at a shear rate of l7,300 sec. 1 was 24.0 cp. This moisture was chemically and mechanically stable for 93 days at which time the experiment was terminated.
TABLE I.THE EFFECT OF POLYMERIC COATINGS HYDRIDE IN HYDRAZINE ON THE PRESSURE Example Polymeric coating, No. wt. percent total mix AlHa microns Particle'slze AlH: loading, percent Pressure rise rate, mm.
Hg/day after (weeks) 1 2 3 4 Remarks 10.9% polymer of Example l No 8 2.2% polymer of Example 1...- 9 l. 9.4% polymer of Example 1 49 9. 47 Gel thixotropic, stable for 95 days. 43 Stable gel, yield Too last to measure 56 4 Too fast to measure 32 20 stress=2,700 dynes/crnfl, Brookfield viscosity at 6 r.p.m.=1l.2 op.
The data in the foregoing tables clearly show the effectiveness of the coated aluminum hydride in hydrazine.
While not bound by any theory, it is believed that the polymerization of ethylene dihydrazine and hexamethylene diisocyanate forms either or both poly (l-ethylene-4-hexamethylene semicarbazide) and poly (2-ethylene-4-hexamethylene semicarbazide). If the latter polymer predominates, excess hexamethylene diisocyanate tends to condense .with the free primary amine to give a branched chain polymer. This branched chain polymer if held to the surface of an aluminum hydride particle by chelate bond, contains the hydrazine solvophylic groups, that may suspend the aluminum hydride particles in hydrazine similar to a dispersion of particles in an oil-water emulsion. The suspension of aluminum hydride coated by the branched chain polymer in hydrazine is suggested as the probably mechanism since a stable gel is not obtained when ethylene dihydrazine is replaced by either hydrazine or 1,4-diamino-Z-methyl-piperazine. Apparently, because a solvophylic polymer like the branched chain polymer will not form in either case. It has also been found that a more stable gel is formed as the mole ratio of hexamethylene diisocyanate to ethylene dihydrazine is increased, one-to-one mole ratio being the minimum ratio with this polymer coating at 5 weight percent on aluminum hydride. The above postulated mechanism is also supported by the observation that hydrazine and the branched chain polymer without any aluminum hydride form a 2phase liquid-solid system which was not uniformly dispersed. Likewise, hydrazine and elemental aluminum coated with the branched chain polymer formed a similar nonuniform dispersion, apparently due to the fact that the branched chain polymer was unable to chelate with aluminum or hydrazine to effect a cross-linked polymer chain structure. Similar results are obtained with polymers from propylene dihydrazine and phenylene diisocyanate.
As will be apparent in the foregoing, the unique polymer coated aluminum hydride of the present invention represents a major breakthrough in the field of liquid rocket propellants. This system provides a fuel which is feasible for handling in the available liquid rocket engines while minimizing the hazards previously associated with these materials. The problem of gas evolution and lack of a mechanically stable gel have been overcome.
Having fully described the invention, it is intended that it be limited only by the lawful scope of the appended claims.
1. A novel thixotropic gelled liquid rocket fuel composition comprising hydrazine fuel containing uniformly distributed therein aluminum hydride coated with an effective gelproducing and gas formation-inhibiting amount of a poly [(alkyl or aryl)-(alkyl or aryl) semicarbazide] copolymer having the repeating units:
and
wherein R and R are alkyl or aryl.
2. A novel thixotropic gelled liquid rocket fuel composition comprising hydrazine fuel containing uniformly distributed therein aluminum hydride coated with an effective gelproducing and gas formation-inhibiting amount of poly(lethylene-4-hexamethylene semicarbazide).
3. The composition of claim 1 wherein the weight ratio of coated aluminum hydride to hydrazine fuel is about one-toone.
4. The method of preparing a novel thixotropic gelled fuel composition which comprises contacting an alkyl or aryl dihydrazine with uncoated aluminum hydride, adding an alkyl or aryl diisocyanate to form a poly [(alkyl or aryl)(alkyl or aryl) semicarbazide] copolymer having the recurring units:
wherein R and R are alkyl or aryl, said copolymer forming a coating on the aluminum hydride, and combining the coated aluminum hydride with hydrazine fuel.
5. The method of claim 4 wherein the weight ratio of coated aluminum hydride to hydrazine fuel is about one-to-one.
6. The method of claim 4 wherein the copolymer comprises poly (l-ethylene-4-hexarnethylenesemicarbazide).

Claims (5)

  1. 2. A novel thixotropic gelled liquid rocket fuel composition comprising hydrazine fuel containing uniformly distributed therein aluminum hydride coated with an effective gel-producing and gas formation-inhibiting amount of poly(1-ethylene-4-hexamethylene semicarbazide).
  2. 3. The composition of claim 1 wherein the weight ratio of coated aluminum hydride to hydrazine fuel is about one-to-one.
  3. 4. The method of preparing a novel thixotropic gelled fuel composition which comprises contacting an alkyl or aryl dihydrazine with uncoated aluminum hydride, adding an alkyl or aryl diisocyanate to form a poly ((alkyl or aryl)-(alkyl or aryl) semicarbazide) copolymer having the recurring units:
  4. 5. The method of claim 4 wherein the weight ratio of coated aluminum hydride to hydrazine fuel is about one-to-one.
  5. 6. The method of claim 4 wherein the copolymer comprises poly (l-ethylene-4-hexamethylene semicarbazide).
US698660A 1968-01-12 1968-01-12 Thixotropic gelled liquid rocket fuel containing hydrazine and aluminum hydride coated with a semicarbazide copolymer Expired - Lifetime US3607470A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US69866068A 1968-01-12 1968-01-12

Publications (1)

Publication Number Publication Date
US3607470A true US3607470A (en) 1971-09-21

Family

ID=24806173

Family Applications (1)

Application Number Title Priority Date Filing Date
US698660A Expired - Lifetime US3607470A (en) 1968-01-12 1968-01-12 Thixotropic gelled liquid rocket fuel containing hydrazine and aluminum hydride coated with a semicarbazide copolymer

Country Status (1)

Country Link
US (1) US3607470A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5139589A (en) * 1990-07-26 1992-08-18 Erno Raumfahrttechnik Gmbh Fuel for use independently of atmospheric air and method for producing the fuel
US5487798A (en) * 1990-03-13 1996-01-30 Martin Marietta Corporation High velocity gun propellant
US5565646A (en) * 1992-07-02 1996-10-15 Martin Marietta Corporation High velocity gun propellant

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5487798A (en) * 1990-03-13 1996-01-30 Martin Marietta Corporation High velocity gun propellant
US5663523A (en) * 1990-03-13 1997-09-02 Martin Marietta Corporation Method of propelling a projectile with ammonium azide
US5139589A (en) * 1990-07-26 1992-08-18 Erno Raumfahrttechnik Gmbh Fuel for use independently of atmospheric air and method for producing the fuel
US5565646A (en) * 1992-07-02 1996-10-15 Martin Marietta Corporation High velocity gun propellant

Similar Documents

Publication Publication Date Title
US4187129A (en) Gelled mechanically stable high energy fuel composition containing metal platelets
US3035948A (en) Gelled nitroalkane propellants
US3164503A (en) Aqueous emulsified ammonium nitrate blasting agents containing nitric acid
US3607470A (en) Thixotropic gelled liquid rocket fuel containing hydrazine and aluminum hydride coated with a semicarbazide copolymer
US3819819A (en) Aluminum hydride in hexagonal or rhombohedral crystalline form
US3197348A (en) Thixotropic propellant
US3986906A (en) Ultrahigh burning rate propellants containing an organic perchlorate oxidizer
US3662802A (en) Hydrazine perchlorate lithium perchlorate eutectics
US3676232A (en) Preparation of uniform and storable fuel mixtures
US3850709A (en) Non-solvated particulate aluminum hydride coated with a cyano-containing compound useful in solid propellants
US4108696A (en) Solid propellant having incorporated therein a ferrocene combustion catalyst
US3523840A (en) Polymer solution of eutectic of hydrazine perchlorate and lithium perchlorate
US3354172A (en) Triaminoguanidinium 5-aminotetrazo-late and its preparation
US3762972A (en) Reaction product of phosphine oxide with carboxylic acids
US3342814A (en) Adducts of metal borohydrides and organic polynitrogen compounds
US3128254A (en) Polymeric boron compositions
US3471346A (en) Fatty alcohol sulfate modified water-bearing explosives containing nitrogen-base salt
US3629021A (en) Slurry explosive composition containing nitrogen-base salt and tnt, smokeless powder or composition b
US3512932A (en) Coordination compounds containing trivalent phosphorus compounds and certain metal compounds
US3146248A (en) Endblocked polysilanes
US3066170A (en) Boron hydride derivatives
US4138282A (en) High burning rate propellants with coprecipitated salts of decahydrodecaboric acid
US3634154A (en) Solid propellant composition containing gelled hydrazine
US6197135B1 (en) Enhanced energetic composites
US4202668A (en) Gelled fuel simulant