US3598679A - Method of making a pressure-transferrable tape - Google Patents

Method of making a pressure-transferrable tape Download PDF

Info

Publication number
US3598679A
US3598679A US3598679DA US3598679A US 3598679 A US3598679 A US 3598679A US 3598679D A US3598679D A US 3598679DA US 3598679 A US3598679 A US 3598679A
Authority
US
United States
Prior art keywords
casting
castings
pressure
tape
transferrable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Inventor
Kitty S Ettre
George R Castles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vitta Corp
Original Assignee
Vitta Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vitta Corp filed Critical Vitta Corp
Priority to US71016768A priority Critical
Application granted granted Critical
Publication of US3598679A publication Critical patent/US3598679A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • B44C1/1733Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/914Transfer or decalcomania
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/17Surface bonding means and/or assemblymeans with work feeding or handling means
    • Y10T156/1702For plural parts or plural areas of single part
    • Y10T156/1705Lamina transferred to base from adhered flexible web or sheet type carrier
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1462Polymer derived from material having at least one acrylic or alkacrylic group or the nitrile or amide derivative thereof [e.g., acrylamide, acrylate ester, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645Next to addition polymer from unsaturated monomers
    • Y10T428/31649Ester, halide or nitrile of addition polymer

Abstract

A FLEXIBLE TRANSFERRABLE FILMLIKE CASTING. INDIVIDUAL THIN FILMS ARE CAST ONTO THE FLEXIBLE SUPPORTING SUBSTRATE BY DOCTOR-BLADING A HEAVILY LOADED SLURRY OF A SOLID INORGANIC POWDER MIXED WITH A PLASTICIZED BINDER. THE EXPOSED SURFACE OF THE RESULTING SLURRY CASTING IS DRIED, WHILE THE SURFACE CONTACTING THE SUBSTRATE REMAINS TACKY AND CAN BE USED AS AN ADHESIVE. ONE CASTING MAY BE STRIPPED FROM ITS SUBSTRATE AND THE TACKY SURFACE APPLIED TO THE EXPOSED DRY SURFACE AND ANOTHER CASTING. THE SUPERIMPOSED CASTINGS ARE THEN BONDED TOGETHER SOLELY BY PRESSURE.

Description

Aug. 10, 1971 K, s ETTRE EI'AL 3,598,679
METHOD OF MAKING A PRESSURE-TRANSFERRABLE TAPE Filed March 4, 1968 2 Sheet s-Sheet 1 INWFWTORS )fiiiy .5: iiire eorye 1?. 6457165 BY Aug. 10, 1971 K. s. ETTRE ETAL 3,598,679
METHOD OF MAKING A PRESSURE-TRANSFERRABLE TAPE Filed March 4, 1968 2 Sheets-Sheet 23 V04 [/ME PL/JS 7' lC/Z E 0 BINDER United States Patent 3,598,679 METHOD OF MAKING A PRESSURE- TRANSFERRABLE TAPE Kitty S. Ettre, Norwalk, and George R. Castles, Stamford, Conn., assignors to Vitta Corporation Filed Mar. 4, 1968, Ser. No. 710,167
Int. Cl. C09j 7/00 US Cl. 156-306 9 Claims ABSTRACT OF THE DISCLOSURE A flexible transferrable fllmlike casting. Individual thin The invention relates to flexible films or castings of the type which may be transferred from a temporary substrate to another surface and then fired to set the casting and bond it to a permanent substrate. More particularly, it relates to such castings which have a tacky surface contacting the temporary substrate, which tacky surface is used to adhere the casting to the new supporting surface.
It is known to produce transferrable fireable castings by doctor-blading a slurry of inorganic powder in a binder onto a temporary substrate and drying it, to form a transferrable casting. Such known transferrable castings are then typically coated with adhesive to assist the transfer of the casting from the temporary substrate to the final substrate. The addition of such an adhesive is undesirable for many types of transferrable casting. Known adhesives may react with some constituent of the casting, and usually leave some sort of residue during the firing operation, which residue may interfere with uniformity of the casting or with the bonding of the casting to the final substrate. Additional problems arise if it is desired to produce a transferrable casting having a thickness greater than approximately ten mils, since the drying time increases considerably faster than the increase in casting thickness.
With castings greater than ten mils in thickness, air drying at ambient temperatures can take as long as an hour or more. If heated in ovens or by other sources of externally applied heat, the heat must be carefully controlled to avoid cracking of the casting or other defects. Other problems are known to be associated With the use of heat for drying the castings.
Such thick castings according to the prior art, can only be successfully formed on a rigid, non-shrinkable supporting substrate such as stainless steel. If an organic temporary substrate (such as polyethylene film) is used for preparation of thick castings, the organic solvent used to prepare the slurry will have time to penetrate slight- "ice ly into the surface of the organic substrate, which effect becomes more pronounced as the wet thickness is increased. Such penetration of the solvent into the organic substrate tends to distort the casting and substrate. This renders necessary the use of a rigid, non-shrinkable material such as stainless steel, if a thick casting is to be made in one casting step.
If such a rigid material is used for the substrate, the casting is separated from the temporary substrate after drying. The removed casting has only a limited storage life, however. If the casting is stored on a rigid temporary substrate, the film can be stored for a very much longer period, but cannot be conveniently rolled for shipping and storage. Shipping costs. and the required inventory of rigid temporary substrate are serious disadvantages of storing the castings on rigid temporary substrate.
These and further problems of the prior art are avoided according to one aspect of the present invention by provision of self-adhesive tapes which do not require a separate adhesive. By selection of proper combinations of inorganic fireable powder, binders, plasticizers and solvents, the face of the casting which contacts the temporary substrate remains tacky after the exposed surface of the casting is dry. The casting can therefore be used as a pressure-sensitive adhesive casting after removal of the temporary substrate, without the use of a separate adhesive.
According to another aspect of the invention, the temporary substrate can be a flexible organic film, permitting ease of storage and shipping. According to another aspect of the invention, individual castings are laminated together using the tacky side as the adhesive, to produce castings of any desired thickness. The lamination process is effected solely by the use of pressure, i.e., without the use of mechanical vibration, externally applied heat, additional adhesive, solvents, or the like.
Accordingly, a primary object of the invention is to provide a tape including a pressure transferrable casting.
A further object is to provide a tape of the above character wherein the transferrable casting is supported on a flexible temporary substrate.
A further object is to provide a tape of the above character wherein the casting does not require a separate adhesive.
A further object is to provide a tape of the above character wherein the casting is tacky 0n the side contacted by the temporary substrate, and is substantially non-tacky or dry on the opposite surface.
A further object is to provide a tape of the above character wherein the casting has excellent storage life.
A further object is to provide a tape of the above character wherein the casting is formed of superimposed laminated layers bonded together by pressure.
A further object is to provide a method for making tapes of the above character.
A further object is to provide apparatus for making tapes of the above character.
A further object is to provide preferred casting compositions for making tapes of the above character.
Other objects of the invention will in part be obvious and will in part appear hereinafter.
The invention accordingly comprises the several steps and the relation of one or more of such steps with respect to each of the others, the apparatus embodying features of construction, combinations and arrangement of parts which are adapted to effect such steps, and the article which possesses the characteristics, properties and relation of elements, all as exemplified in the detailed disclosure hereinafter set forth, and the scope of the invention will be indicated in the claims.
For a more complete understanding of the nature and objects of the invention, reference should be had to the following detailed description taken in connection with the accompanying drawings, in which:
FIG. 1 is a schematic side elevation view of exemplary apparatus forming a tape according to one aspect of the invention.
FIG. 2 is a perspective view of the tape produced by the FIG. 1 apparatus, showing a flexible, self-adhesive casting carried on the flexible temporary substrate;
FIG. 3 is a schematic side elevation view of apparatus for laminating a casting from a first tape onto a casting on a second tape;
FIG. 4 is a perspective view of the laminated tape produced by the FIG. 3 apparatus; and
FIG. 5 is a graph showing the effect of inorganic particle size on the required amount of plasticized binder.
Suitable tapes according to the invention may be produced by the exemplary apparatus illustrated in FIG. 1, wherein a flexible, temporary substrate in the form of continuous polyethylene film 20 is withdrawn from feed roll 22. Film 20 passes under guide roll 24 and beneath slurry supply tank 26. Slurry 28 is fed from tank 26 onto the upper surface of film 20, to form a casting layer 30 thereon. Doctor blade 32 is vertically adjustable to control the thickness of casting 30. The laminated tape consisting of filni'20 and slurry casting 30 is fed through dryer 34 and collected on take-up roll 36. In dryer 34, the film is subjected to a flow of air, preferably at or near room temperature, to drive off the volatile solvent and render the exposed surface of casting 30 dry to the touch.
The resulting tape 38 is shown in FIG. 2, wherein a portion of casting 30 has been peeled back. As will be further discussed below, upper surface 42 of casting 30 is substantially dry, while lower surface 40 is still sufficiently tacky to render the casting pressure-transferrable. Pressure-transferrable, as used in the specification and claims, means that when surface 40 (of a casting 30 which is at least approximately 1 mil thick) is pressed for 1 second against a surface such as fire-polished glass with a pressure of about to about 10,000 pounds per square inch (p.s.i.), casting 30 will adhere so strongly that it cannot be readily stripped off again without tearing. If surface 40 will thus adhere at a pressure substantially less than about 10 p.s.i., the casting will be too soft and rubbery for the uses according to the present invention. The dry surface 42 should require at least 100 times the pressure, and preferably at least 1,000 times the pressure, to similarly adhere to the polished glass surface. Thus, if the tacky side will adhere at 10 p.s.i., the dry side should not similarly adhere at less than 1,000 p.s.i. and preferably should not adhere at less than 10,000 p.s.i. Accordingly, castings according to the invention have a tackiness differential on opposite sides of at least 100 times, and preferably at least 1,000 times.
Castings 30 having these properties are produced according to one aspect of the invention by the proper slurry compositions and drying conditions. Slurry 28 includes a major portion of the desired inorganic fireable powder, intimately mixed with a plasticized binder which is dissolved in sufficient temporary volatile solvent to permit flow of slurry 28 onto film 20.
The inorganic powder can include any of the known 4 fireable glasses, ceramic, or metals, or mixtures of these materials. Selection of suitable inorganic powders or loading materials is well within the scope of one skilled in the art, and will depend upon the desired end use for the casting. One suitable specific example of inorganic loading materials is a bore-silicate glass material having the following approximate chemical composition: SiO 80%, B 0 14%, Na;;() 4%, and A1 0 2%. A suitable lead oxide solder glass contains PbO 71.40%, ZnO 16.24%, B 0 10.11%, A1 0 0.28%, Na O 0.05%, and CaO 1%. A suitable ceramic material includes: A1 0 92%, CaO 3%, SiO 3%, and H Mg (SiO 2%. Another exemplary material is BaTiO An exemplary metallic loading material is a mixture of 80% molybdenum and 20% manganese. All references in the specification and claims to percentages refer to percentages by weight, where not otherwise specified.
The function of the binder according to the prior art is to provide a matrix for binding together the inorganic powder until it is fired. According to the present invention, the plasticized binder also renders the casting pressure-transferrable. The binder may be selected from a wide variety of known organic film-forming materials, depending on the desired properties of the casting. Suitable exemplary binder materials include polyvinyl butyral, cellulose acetate, polyvinyl alcohol, and the polymethacrylates, such as poly (n-butyl methacrylate). The polymethacrylates are particularly desirable because during the firing of the casting onto the final substrate the polymethacrylates decompose into gaseous products, leaving virtually no organic residue in the final fired casting.
The plasticizer must be chosen to be compatible with the selected binder, so as not to separate into a separate phase, and must be present in the proper amount. If too much plasticizer is present, both surfaces of the casting will be tacky and the casting will not readily strip from the temporary substrate. On the other hand, if the amount of plasticizer is too low, surface 40 will not develop sufficient tackiness to make casting 30 pressure-transferrable. Suitable plasticizers for polymethacrylates include dibutyl phthalate, diisodecyl phthalate, diisobutyl adipate, diethyl oxalate, sucrose acetate isobutyrate, and fatty acid type plasticizers. Glycerine is a suitable exemplary plasticizer for polyvinyl alcohol.
Temporary substrate 20 must be chemically inert to slurry 28, and must have appropriate surface characteristics for temporarily lightly bonding to surface 40 so that casting 30 can be readily stripped therefrom when desired. Suitable substrate materials include untreated polyethylene, certain papers, Tedlar (polyvinyl fluoride) and Mylar (a glycol-terephthalic acid polyester).
The volatile solvent should preferably wet the surface of temporary substrate 20, and should dissolve the binder and plasticizer without chemically reacting with the slurry components. Exemplary solvents include acetone, amyl acetate, benzene, ethanol, and a mixture of ethanol and water. Preferably the solvent is sutliciently volatile to readily evaporate at room temperature, so that drying can be accomplished without the need for heaters in dryer 34.
The proportions of the various slurry components are determined by several considerations. Ordinarily the inorganic powder constitutes at least about by weight of the slurry (exclusive of the solvent), and preferably constitutes a considerably higher portion. To obtain the desired tackiness and pressure-transferable properties as above defined, the ratio of pla'sticized binder to inorganic powder must be selected within certain ranges, which will vary somewhat depending on the particle size of the inorganic powder and the properties of the binder and plasticizer selected.
TABLE I showing that the volume of a given plasticized binder should be increased as particle size decreases.
The inert solvent is added in an amount sufficient to Tape type Ceramic tape Glass tape Metal tape Average particle diameter, microns Density, g./cm.
Grams Grams Grams Inorganic substance(s) A1203... 300 Mo 240 Mistron 1 n 60 Poly(n-butyl methacrylate) 24 18 Dibutyl phthalate 6 4.
Total organic 30 22. 5
Inorganic substance(s) A1203" 300 Mo 240 Mistron. Mn 60 Poly (n-butyl methacrylate) Dibutyl phthalate 5 3. 75
Total organic 54. 9 18. 75
Inorganic substance(s) A1203" 288 Solder glass. 300 Mo 240 Mistron. Mn 60 Poly(n-butyl methacrylate) 16 13 Dlbutyl phthalate 6. 6 4 3. 25
Total organic 36. 6 20 16. 26
l Hydrous magnesium silicate.
See the following table:
Pressure required, p s i g 10 10 10 Type of roller Rubber Rubber Steel Durometer hardness 40 8 Table II shows the effect of varying inorganic particle size on the amount of a given plasticized binder required to produce a particular transfer pressure. This effect is independent of the type of inorganic material used. -It should be understood that the optimum ratios of plasticized binder to inorganic .powder will vary with different binders and lasticizers.
TABLE II Lead oxide solder glass transfer tapes (density: 6.3 gmJcmfi) In Table I, wherein the inorganic powders had substantially the same particle size, the samples providing a transfer pressure of 10 p.s.i. had approximately 59% inorganic powder and 41% plasticized binder, the samples having a transfer pressure of 1,000 p.s.i. had approxi mately 63% inorganic powder and 37% plasticized binder, while the samples having a transfer pressure of 10,000 p.s.i. had approximately 72% inorganic powder and 28% plasticized binder, expressed in terms of volume.
In Table II, the sample having an average particle diameter of 24 microns contained 37% plasticized hinder, the sample having an average particle diameter of 47 microns contained 30% plasticized binder, while the sample having an average particle diameter of 10-15 microns contained 24% plasticized binder.
The results of Tables I and II are plotted in FIG. 5,
render the given composition readily flowable. Using the specific compositions disclosed in Tables I and II above, for example, approximately 15 cc. of acetone per cc. of inorganic powder and plasticized binder is an appropriate amount.
The individual tapes 38, as above described, include only a single casting 30, having a thickness of preferably less than 10 mils. A laminated casting of any desired thickness may be produced according to a further aspect of the invention, by laminating the castings, using the tacky sides 40 to effect bonding. Suitable apparatus for performing this process is illustrated in FIG. 3 wherein a first tape 46 is withdrawn from a supply roll 48, fed between pressure rolls 50 and 52, and collected on take up roll 54. A second similar tape is supplied on roll 56. Roll 56 is rotated in the counterclockwise direction as illustrated in FIG. 3. The temporary substrate 58 of the second tape is stripped away from its casting 60. Casting 60 is fed (see FIG. 4) with its tacky side 62 contacting the upper dry side 64 of casting 66 of tape 46.
Castings 60 and 66 are pressure bonded (i.e., bonded together in the absence of added adhesives, solvents, mechanical vibration, heat, etc.) on passing between rolls 50 and 52, so that the tape wound on roll 54 contains a laminated casting. Temporary substrate 58 preferably is passed between roll 52 and casting 60, to strip substrate 58 from casting 60' without further apparatus. Substrate 58 then ma pass over a guide roll 68 (FIG. 3) to a suitable container 70.
Additional thin castings can be laminated onto tape 46 to produce a final laminated casting of any desired thickness, and the lamination can be carried out either in successive steps or simultaneously. Since castings less than about 10 mils thick can be made rapidly with excellent control of casting thickness, a laminated thick casting can be made having closely controlled thickness in a fraction of the time required to dry a casting of equal thickness formed directly from the slurry. It should be noted that the several laminations may include different inorganic powders if desired.
It may be seen from the above disclosure and accompanying drawings that the present invention provides a pressure-transferrable casting exposed on a flexible temporary substrate. The resulting tape can be stored for periods of months before losing the pressure-transferrable property, and can be conveniently rolled for storage and shipping. The casting does not require the addition of a separate adhesive for its transfer property, and is thus advantageous in many uses.
In the embodiments wherein the final casting is formed from superimposed thinner castings, great precision is possible in the control of the final casting thickness. In addition, thick castings can be produced by the lamination process in a much shorter period of time than would be required if the casting were formed from slurry in a single step. In addition, the laminated construction permits production of castings wherein different layers can be of different compositions. The presently preferred methods of producing tapes of the above character are simple and efficient, as is the specifically disclosed apparatus.
It will thus be seen that the objects set forth above, among those made apparent from the preceding description, are efficiently attained and, since certain changes may be made in carrying out the above process, in the described product, and in the constructions set forth without departing from the scope of the invention, it is intended that all matter contained in the above description or shown in the accompanying drawing shall be interpreted as illustrative and not in a limiting sense.
It is also to be understood that the following claims are intended to cover all of the generic and specific features of the invention herein described, and statements of the scope of the invention which, as a matter of language, might be said to fall therebetween.
Having described our invention, what we claim as new and desire to secure by Letters Patent is:
1. A method of making a thick self-adhesive unfired casting which is carried on and pressure-transferrable from a temporary substrate comprising, in combination, the steps of:
(A) producing each of at least a pair of castings by (l) preparing a slurry comprising an organic binder composition loaded with inorganic pow der,
(a) said organic binder composition comprising a volatile solvent, a binder and a plasticizer,
(2) providing a ratio of binder to plasticizer in relation to the particle size of said powder so that upon evaporation of said solvent the exposed surface of the resultant casting is substantially dry while the surface contacting the substrate remains tacky,
(3) spreading said slurry to a predetermined thickness on a temporary substrate, and then (4) evaporating said solvent,
(B) maintaining a first one of said pair of castings adhered to its temporary substrate,
(C) stripping the temporary substrate from the second one of said pair of castings to expose the tacky surface thereof, and
(D) laminating said castings by (l) placing said tacky surface of said second casting in contact with the dry exposed surface of said first casting and (2) applying bonding pressure to said contacting pair of castings.
2. A method as defined in claim 1 wherein said pair of castings are each provided with different compositions.
3. A method as defined in claim 1 wherein said binder in at least one of said castings is selected from the group consisting of polyvinyl butyral, cellulose acetate, polyvinyl alcohol, and polymethacrylates.
4. A method as defined in claim 1 wherein, in at least one of said castings, said binder is a polymethacrylate and said plasticizer is selected from the group consisting of dibutyl phthalate, diisodecyl phthalate, diisobutyl adipate, diethyl oxalate, sucrose acetate isobutyrate and fatty acid type plasticizers.
5. A method as defined in claim 1 wherein said binder in at least one of said castings is poly(n-butyl methacrylate).
6. A method as defined in claim 1 wherein, in at least one of said castings, said binder is polyvinyl alcohol and said plasticizer is glycerine.
7. A method as defined in claim 1 wherein, in at least one of said castings, said binder is poly(n-butyl methacrylate) and said plasticizer is dibutyl phthalate.
8. A method as defined in claim 7 wherein the ratio of said binder to said plasticizer is between about 3.5/1 and 5/1.
9. A method as defined in claim 7 wherein the ratio of said binder to said plasticizer is between about 4/1 and 4.5/1.
References Cited UNITED STATES PATENTS 2,956,310 10/1960 Roop ct a1. 52309UX 2,957,793 10/1960 Dickey 156-306X 3,008,862 11/1961 Haine et a1. 156-309X 3,362,862 1/1968 King 156-309X REUBEN EPSTEIN, Primary Examiner US. Cl. X.R.
l56309, 540; ll1l67; 264216
US3598679D 1968-03-04 1968-03-04 Method of making a pressure-transferrable tape Expired - Lifetime US3598679A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US71016768A true 1968-03-04 1968-03-04

Publications (1)

Publication Number Publication Date
US3598679A true US3598679A (en) 1971-08-10

Family

ID=24852894

Family Applications (1)

Application Number Title Priority Date Filing Date
US3598679D Expired - Lifetime US3598679A (en) 1968-03-04 1968-03-04 Method of making a pressure-transferrable tape

Country Status (2)

Country Link
US (1) US3598679A (en)
JP (1) JPS5146761B1 (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4240867A (en) * 1978-05-03 1980-12-23 Diegel Herbert F Apparatus for dispensing adhesive-backed foil
US4252596A (en) * 1978-11-22 1981-02-24 Sachs-Systemtechnik Gmbh Method and arrangement for the production of thick layers of contact adhesive
US4574021A (en) * 1983-03-03 1986-03-04 Kimberly-Clark Corporation Soft moisture resistant tissue product
WO1989008026A1 (en) * 1988-03-02 1989-09-08 E.I. Du Pont De Nemours And Company Method of manufacturing thermal printer head
US5008151A (en) * 1987-09-11 1991-04-16 Nitto Denko Corporation Glass powder adhesive sheet
US5089071A (en) * 1989-11-03 1992-02-18 Nitto Electrical Industrial Process for producing a multilayered ceramic structure using an adhesive film
US5849131A (en) * 1995-01-12 1998-12-15 Owens Corning Fiberglas Technology, Inc. Method for applying adhesive to an insulation assembly
US5868891A (en) * 1996-10-31 1999-02-09 Owens Corning Fiberglas Technology, Inc. Peel and stick insulation having a common carrier sheet
US5916393A (en) * 1997-06-24 1999-06-29 Owens Corning Fiberglas Technology, Inc. Method for applying adhesive on a porous substrate
US6527890B1 (en) 1998-10-09 2003-03-04 Motorola, Inc. Multilayered ceramic micro-gas chromatograph and method for making the same
US6592696B1 (en) 1998-10-09 2003-07-15 Motorola, Inc. Method for fabricating a multilayered structure and the structures formed by the method

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4240867A (en) * 1978-05-03 1980-12-23 Diegel Herbert F Apparatus for dispensing adhesive-backed foil
US4252596A (en) * 1978-11-22 1981-02-24 Sachs-Systemtechnik Gmbh Method and arrangement for the production of thick layers of contact adhesive
US4574021A (en) * 1983-03-03 1986-03-04 Kimberly-Clark Corporation Soft moisture resistant tissue product
US5008151A (en) * 1987-09-11 1991-04-16 Nitto Denko Corporation Glass powder adhesive sheet
WO1989008026A1 (en) * 1988-03-02 1989-09-08 E.I. Du Pont De Nemours And Company Method of manufacturing thermal printer head
US5089071A (en) * 1989-11-03 1992-02-18 Nitto Electrical Industrial Process for producing a multilayered ceramic structure using an adhesive film
US5849131A (en) * 1995-01-12 1998-12-15 Owens Corning Fiberglas Technology, Inc. Method for applying adhesive to an insulation assembly
US5868891A (en) * 1996-10-31 1999-02-09 Owens Corning Fiberglas Technology, Inc. Peel and stick insulation having a common carrier sheet
US5916393A (en) * 1997-06-24 1999-06-29 Owens Corning Fiberglas Technology, Inc. Method for applying adhesive on a porous substrate
US6527890B1 (en) 1998-10-09 2003-03-04 Motorola, Inc. Multilayered ceramic micro-gas chromatograph and method for making the same
US6544734B1 (en) 1998-10-09 2003-04-08 Cynthia G. Briscoe Multilayered microfluidic DNA analysis system and method
US6572830B1 (en) 1998-10-09 2003-06-03 Motorola, Inc. Integrated multilayered microfludic devices and methods for making the same
US6592696B1 (en) 1998-10-09 2003-07-15 Motorola, Inc. Method for fabricating a multilayered structure and the structures formed by the method
US6732567B2 (en) 1998-10-09 2004-05-11 Motorola, Inc. Multilayered ceramic micro-gas chromatograph and method for making the same

Also Published As

Publication number Publication date
JPS5146761B1 (en) 1976-12-10

Similar Documents

Publication Publication Date Title
US3096202A (en) Polyvinyl pyrrolidone pressure sensitive adhestive and tape containing same
JP2970963B2 (en) Peelable pressure-sensitive adhesive and adhesive member thereof
US4072771A (en) Copper thick film conductor
US2970076A (en) Vitreous decalcomania and method of decorating ceramic articles
US3112184A (en) Method of making ceramic articles
EP0479223B1 (en) Transfer sheet
JP2937476B2 (en) Pressure-sensitive adhesive laminate
EP2361236B1 (en) Methods and apparatus for casting ceramic sheets
US3896249A (en) Self-adhesive transfers
US3652378A (en) Strengthening alumina substrates by incorporating grain growth inhibitor in surface and promoter in interior
US3623944A (en) Pressure sensitive adhesive coated polymeric film laminates
US3262827A (en) Foam sheet with pressure-sensitive adhesive coating and method of making same
TWI228733B (en) Manufacturing method of electronic component having internal electrode
JPH0697565B2 (en) Dielectric composition
JP4084385B2 (en) Method for manufacturing multilayer unit for multilayer electronic component
JP2648918B2 (en) Coating method
JP3760942B2 (en) Manufacturing method of multilayer ceramic electronic component
US2838421A (en) Adhesives and adhesive tapes
US2628929A (en) Method and apparatus for transferring a magnetic sound track to movie film
EP2961588A2 (en) Tack and bond adhesive system and method for layered object manufacture
DK162128B (en) Installable dielectric preparation, procedure for the creation of a dielectric unbrained tire (aegreen tapeae) thereof and procedure for the creation of a multiple-submitted unlimited submission submitted unlimited single part
WO2002074715A1 (en) Method for joining ceramic green bodies using a transfer tape and conversion of bonded green body into a ceramic body
US2395668A (en) Liner for adherent rubber surfaces and the like
US4289719A (en) Method of making a multi-layer ceramic substrate
GB883123A (en) Vitreous decalcomania