US3526546A - Process for degreasing sheet-like rolled aluminum products - Google Patents
Process for degreasing sheet-like rolled aluminum products Download PDFInfo
- Publication number
- US3526546A US3526546A US692268A US3526546DA US3526546A US 3526546 A US3526546 A US 3526546A US 692268 A US692268 A US 692268A US 3526546D A US3526546D A US 3526546DA US 3526546 A US3526546 A US 3526546A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- air
- grease
- percent
- rolled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052782 aluminium Inorganic materials 0.000 title description 32
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title description 32
- 238000000034 method Methods 0.000 title description 22
- 238000005238 degreasing Methods 0.000 title description 9
- 230000008569 process Effects 0.000 title description 9
- 239000004519 grease Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000007664 blowing Methods 0.000 description 9
- 238000007639 printing Methods 0.000 description 9
- 230000007547 defect Effects 0.000 description 6
- 230000001680 brushing effect Effects 0.000 description 5
- 239000011888 foil Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 3
- 238000001459 lithography Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- -1 e.g. Chemical class 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/03—Chemical or electrical pretreatment
Definitions
- the present invention relates to the degreasing of sheetlike rolled aluminum products, in particular aluminum strips or webs of aluminum foil, and also sheets or cuts of rolled aluminum.
- sheetlike rolled aluminum products in particular aluminum strips or webs of aluminum foil, and also sheets or cuts of rolled aluminum.
- the invention will be described in the following particularly with reference to aluminum strips, but the statements made herein apply also to thinner or thicker aluminum webs and to cuts of all thicknesses.
- Equivalent to rolled aluminum products, in the sense of the present invention are rolled products of other nonferrous metals, such as e.g., rolled products of aluminum alloys.
- the simplest method is by annealing, so that any adhering grease is evaporated or burned. During this heat treatment, the aluminum becomes soft, so that this method can not be used in those cases where the aluminum is to be used in a hard rolled condition.
- the traces of grease are removed by means of solvents, e.g. aliphatic chlorinated hydrocarbons, by passing the aluminum strips or sheets through apparatus provided for this purpose.
- solvents e.g. aliphatic chlorinated hydrocarbons
- Still another method is a treatment with chemical means, e.g., aqueous alkaline substances, which causes the residual rolling grease to be partially dissolved in the form of soaps, any unsaponifiable components being removed at the same time.
- Oxidative methods are also known, wherein aluminum objects are treated, e.g., with chromosulfuric acid or salt melts.
- the aluminum surface is freed from greasy impurities by mechanical treatment, e.g., brushing or grinding.
- This method is employed, e.g.,for delustering aluminum strips and foils. It cleans the aluminum surface very thoroughly and it is, therefore, also used for cleaning aluminum strips or foils which are to be used in lithography for the preparation of printing plates.
- the requirements with regard to the purity of the surfaces are very high even for low-grade printing plates; for printing plates of very good quality they are extremely high.
- the aluminum must be in a hard, rolled condition.
- the present invention provides a process for degreasing sheetlike rolled aluminum products which results in a more satisfactory degreasing than the methods hitherto used.
- the process of the present invention includes the known cleaning of aluminum surfaces by mechanical means and removal of the detached particles by blowing with air, but it is performed in a novel manner. It has been found that a noticeably better degreasing is achieved by adding water vapor to the air supplied during the mechanical degreasing process, e.g., by brushing or grinding, or by blowing with water vapor instead of air.
- the effectiveness of the new method becomes apparent when using the aluminum strips degreased by the new process. For instance, if printing plates are prepared therefrom, a successful treatment becomes apparent in a reduction or, optimally, the complete absence of defects in the printing plate, i.e., defects which otherwise would accept printing ink and thus print and which would have to be removed by correction if the printing plate is to yield flawless prints.
- the degree of purity of the cleaned .aluminum strip also can be judged more easily and quickly by first wiping the surface of a sample with a molar phosphoric acid solution and then inking it up with a protective ink, as is customary in lithography for newly prepared offset printing plates in order to provide them with a coating which protects the printing image on the offset plate against wear during storage and handling.
- a protective ink as is customary in lithography for newly prepared offset printing plates in order to provide them with a coating which protects the printing image on the offset plate against wear during storage and handling.
- EXAMPLE A cold-rolled aluminum strip was washed with gasoline, so that the greater part of the grease adhering thereto from the rolling process was removed. Thereafter, the strip was cleaned by brushing it in an atmosphere of 50 percent relative humidity with the dust brushed ofi being removed by blowing with air. A sample of the cleaned strip was inked up with protective ink. Numerous spots colored by the protective ink became visible On the sample sheet. They indicated the presence of an equal number of grease spots.
- blowing in was performed with air humidified to a relative humidity of percent.
- a sample taken during this test showed only a small number of defects, but more than a sample taken from a strip treated 'with air of percent relative humidity.
- a process for degreasing a rolled aluminum product which comprises mechanically removing grease from the surface of the aluminum and blowing a stream of air having a relative humidity of at least 60 percent onto the surface.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Photoreceptors In Electrophotography (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Printing Plates And Materials Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK0061011 | 1966-12-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3526546A true US3526546A (en) | 1970-09-01 |
Family
ID=7229874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US692268A Expired - Lifetime US3526546A (en) | 1966-12-23 | 1967-12-21 | Process for degreasing sheet-like rolled aluminum products |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3526546A (de) |
| AT (1) | AT269592B (de) |
| BE (1) | BE708302A (de) |
| DE (1) | DE1621607A1 (de) |
| FR (1) | FR1548999A (de) |
| GB (1) | GB1200500A (de) |
| NL (1) | NL6716957A (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3935041A (en) * | 1971-10-18 | 1976-01-27 | Chemcut Corporation | Method for treatment fluid application and removal |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3801387A (en) * | 1971-10-18 | 1974-04-02 | Chemcut Corp | Etchant remover apparatus and method |
| FR2572334A1 (fr) * | 1984-10-25 | 1986-05-02 | Pierre Richard | Procede pour la fabrication d'une ardoise pour ecrire |
| DE4201592A1 (de) * | 1992-01-22 | 1993-07-29 | Johann Gehrig | Verfahren sowie anlage zum konservieren von maschinenbauteilen mit hohlraeumen |
| DE4208035C1 (en) * | 1992-03-13 | 1993-05-06 | Rasselstein Ag, 5450 Neuwied, De | Oil coating measurement on sample of sheet e.g. mild steel with ellipsometer - by removing coating by evapn. with hot airstream at temp. close to b.pt. of oil and below 210 deg. C. with blowpipe in measuring chambers for simplicity |
| DE19951563A1 (de) * | 1999-10-27 | 2001-05-03 | Volkswagen Ag | Verfahren zur Reinigung einer metallischen Oberfläche |
| DE10001488B4 (de) * | 2000-01-15 | 2004-12-16 | Daimlerchrysler Ag | Verfahren und Vorrichtung zum prozesssicheren Fügen ölverschmutzter Werkstücke, insbesondere Blechteile |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2423343A (en) * | 1945-04-27 | 1947-07-01 | Westvaco Chlorine Products Cor | Process of degreasing aluminum and magnesium surfaces |
| US2431595A (en) * | 1942-08-06 | 1947-11-25 | Aluminum Co Of America | Method for cleaning aluminum |
-
1966
- 1966-12-23 DE DE19661621607 patent/DE1621607A1/de active Pending
-
1967
- 1967-12-13 NL NL6716957A patent/NL6716957A/xx unknown
- 1967-12-20 BE BE708302D patent/BE708302A/xx unknown
- 1967-12-20 AT AT1153367A patent/AT269592B/de active
- 1967-12-21 US US692268A patent/US3526546A/en not_active Expired - Lifetime
- 1967-12-21 GB GB58179/67A patent/GB1200500A/en not_active Expired
- 1967-12-21 FR FR1548999D patent/FR1548999A/fr not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2431595A (en) * | 1942-08-06 | 1947-11-25 | Aluminum Co Of America | Method for cleaning aluminum |
| US2423343A (en) * | 1945-04-27 | 1947-07-01 | Westvaco Chlorine Products Cor | Process of degreasing aluminum and magnesium surfaces |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3935041A (en) * | 1971-10-18 | 1976-01-27 | Chemcut Corporation | Method for treatment fluid application and removal |
Also Published As
| Publication number | Publication date |
|---|---|
| BE708302A (de) | 1968-06-20 |
| GB1200500A (en) | 1970-07-29 |
| FR1548999A (de) | 1968-12-06 |
| DE1621607A1 (de) | 1971-05-06 |
| NL6716957A (de) | 1968-06-24 |
| AT269592B (de) | 1969-03-25 |
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