US3523797A - Development of light-sensitive silver halide emulsions - Google Patents

Development of light-sensitive silver halide emulsions Download PDF

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Publication number
US3523797A
US3523797A US584655A US3523797DA US3523797A US 3523797 A US3523797 A US 3523797A US 584655 A US584655 A US 584655A US 3523797D A US3523797D A US 3523797DA US 3523797 A US3523797 A US 3523797A
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US
United States
Prior art keywords
silver halide
compounds
water
development
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US584655A
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English (en)
Inventor
Jozef Frans Willems
Francis Jeanne Sels
Robrecht Julius Thiers
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Agfa Gevaert NV
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Agfa Gevaert NV
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Publication of US3523797A publication Critical patent/US3523797A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02Polyamines
    • C08G73/024Polyamines containing oxygen in the form of ether bonds in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62Alcohols or phenols
    • C08G59/64Amino alcohols
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/04Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
    • G03C1/043Polyalkylene oxides; Polyalkylene sulfides; Polyalkylene selenides; Polyalkylene tellurides

Definitions

  • the development accelerators are preferably added in dissolved form in water or in aqueous mixture of water and water-miscible organic solvents that do not impair the photographic properties of the light-sensitive silver halide emulsion.
  • the polyaddition products are not sul'ficiently soluble in water in their base form, they are converted into their salt form by neutralization, e.g., with an acid such as sulphuric acid, hydrochloric acid, p-toluenesulphonic acid, or acetic acid.
  • the optimum amount of development accelerator added to the silver halide emulsion depends on the very compound, on the nature of the colloid binding agent for the silver halide grains, and on the amount and the kind of the silver halide in the emulsion.
  • the development accelerators are added to the light-sensitive material in amounts ranging from mg. to 10 g. per mole of silver halide. In the developing bath they are normally used in amounts ranging from 0.1 g. to 10 g. per liter. If necessary, these compounds can also be added in amounts exceeding these limits.
  • This emulsion is divided into several aliquot portions and to the separate portions is added one of the development accelerators according to the present invention.
  • the emulsion portions are separately applied to a cellulose triacetate support and dried.
  • test strips obtained are then exposed in the same conditions through a grey Wedge and developed for 7 minutes at C. in a fine-grain developer of the following composition:
  • the speed is given in relative exposure values in respect of an emulsion to which no sensitizer Was added.
  • a decrease of the exposure value of means a doubling of the speed.
  • Amount of compound per Sensitometrlc results Number of the kg. of emuladded compound sion Fog Gamma Speed EXAMPLE 2
  • An emulsion as described in Example 1 is used, except that the test strips after having been exposed, are developed for 5 min. at 20 C. in a classical fast acting hydroquinone/p-N-methylaminophenol developer of the following composition:
  • Amount of compound per Sensltometrlc results Number of the kg. of emuladded compound sion Fog Gamma Speed 0. 07 0. 42 189 0. 10 0. 50 174 0. 09 0. 56 0. 13 0. 60 164 0. 13 0. 60 166 0. 20 0. 63 158 0. 10 0. 50 174 0. 09 0. 56 165 0. 19 0. 54 157 0.20 0. 68 149 0. 15 0. 60 163 g 0. 16 0. 61 161 0. 08 0. 62 165 19 300 mg 0. 08 0. 58 168 1 g 0.12 0. 63 162 What we claim is:
  • R is an alkyl group of 1 to 5 carbon atoms, or an aralkyl group
  • a photographic light-sensitive silver halide material comprising a polymeric compound containing alkylene (N alkyl) amino alkylene groups linked through hydroxy-substituted oxyalkylene groups and/or such polymeric compounds wherein the hydrogen atoms of said hydroxyl groups are wholly or partly substituted.
  • a photographic developing bath for exposed lightsensitive silver halide materials containing from 0.1 g. to 10 g. per liter of a polymeric compound obtained in basic form by polyaddition of a N-alkyl-dialkanolamine and/ or a trialkanolamine with a bis-epoxide or by polyaddition of a N-alkyl-containing bis-epoxide with a diol.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Polyethers (AREA)
US584655A 1965-10-11 1966-10-06 Development of light-sensitive silver halide emulsions Expired - Lifetime US3523797A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB42971/65A GB1162135A (en) 1965-10-11 1965-10-11 Improvements in the Development of Light-Sensitive Silver Halide Emulsions

Publications (1)

Publication Number Publication Date
US3523797A true US3523797A (en) 1970-08-11

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ID=10426777

Family Applications (1)

Application Number Title Priority Date Filing Date
US584655A Expired - Lifetime US3523797A (en) 1965-10-11 1966-10-06 Development of light-sensitive silver halide emulsions

Country Status (6)

Country Link
US (1) US3523797A (es)
BE (1) BE688062A (es)
DE (1) DE1522400A1 (es)
FR (1) FR1496595A (es)
GB (1) GB1162135A (es)
NL (1) NL6614230A (es)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4038075A (en) * 1975-01-22 1977-07-26 Agfa-Gevaert N.V. Development of photographic silver halide material
US4072526A (en) * 1975-01-22 1978-02-07 Agfa-Gevaert, N.V. Development of photographic silver halide material
US4072523A (en) * 1975-01-22 1978-02-07 Agfa-Gevaert, N.V. Development of photographic silver halide material
US4975354A (en) * 1988-10-11 1990-12-04 Eastman Kodak Company Photographic element comprising an ethyleneoxy-substituted amino compound and process adapted to provide high constrast development
WO2004055146A1 (ja) * 2002-12-16 2004-07-01 Kao Corporation 洗浄剤組成物

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0642931B1 (en) * 1993-09-02 1999-04-21 Tomoegawa Paper Co. Ltd. Desensitizing solution for lithographic platemaking

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3307948A (en) * 1964-06-02 1967-03-07 Gevaert Photo Prod Nv Development accelerators

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3307948A (en) * 1964-06-02 1967-03-07 Gevaert Photo Prod Nv Development accelerators

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4038075A (en) * 1975-01-22 1977-07-26 Agfa-Gevaert N.V. Development of photographic silver halide material
US4072526A (en) * 1975-01-22 1978-02-07 Agfa-Gevaert, N.V. Development of photographic silver halide material
US4072523A (en) * 1975-01-22 1978-02-07 Agfa-Gevaert, N.V. Development of photographic silver halide material
US4975354A (en) * 1988-10-11 1990-12-04 Eastman Kodak Company Photographic element comprising an ethyleneoxy-substituted amino compound and process adapted to provide high constrast development
WO2004055146A1 (ja) * 2002-12-16 2004-07-01 Kao Corporation 洗浄剤組成物
US20060252665A1 (en) * 2002-12-16 2006-11-09 Atsushi Tanaka Detergent composition
US7566688B2 (en) * 2002-12-16 2009-07-28 Kao Corporation Detergent composition

Also Published As

Publication number Publication date
DE1522400A1 (de) 1969-11-20
BE688062A (es) 1967-04-11
NL6614230A (es) 1967-03-28
FR1496595A (fr) 1967-09-29
GB1162135A (en) 1969-08-20

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