US3519456A - Transfer materials - Google Patents
Transfer materials Download PDFInfo
- Publication number
- US3519456A US3519456A US429904A US3519456DA US3519456A US 3519456 A US3519456 A US 3519456A US 429904 A US429904 A US 429904A US 3519456D A US3519456D A US 3519456DA US 3519456 A US3519456 A US 3519456A
- Authority
- US
- United States
- Prior art keywords
- parts
- indicia
- carrier sheet
- transfer
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 57
- 239000000976 ink Substances 0.000 description 34
- 239000000203 mixture Substances 0.000 description 29
- 238000009472 formulation Methods 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- 230000001070 adhesive effect Effects 0.000 description 14
- 239000006185 dispersion Substances 0.000 description 13
- 239000000049 pigment Substances 0.000 description 13
- 239000000853 adhesive Substances 0.000 description 12
- 239000000123 paper Substances 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 10
- 239000001993 wax Substances 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 8
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 8
- -1 polyethylene Polymers 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 7
- 235000019241 carbon black Nutrition 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000004200 microcrystalline wax Substances 0.000 description 6
- 235000019808 microcrystalline wax Nutrition 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 239000004447 silicone coating Substances 0.000 description 6
- 235000013311 vegetables Nutrition 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 239000003849 aromatic solvent Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000011086 glassine Substances 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229920001249 ethyl cellulose Polymers 0.000 description 3
- 235000019325 ethyl cellulose Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 150000003505 terpenes Chemical class 0.000 description 3
- 235000007586 terpenes Nutrition 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920000896 Ethulose Polymers 0.000 description 2
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 230000019612 pigmentation Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- UFFRSDWQMJYQNE-UHFFFAOYSA-N 6-azaniumylhexylazanium;hexanedioate Chemical compound [NH3+]CCCCCC[NH3+].[O-]C(=O)CCCCC([O-])=O UFFRSDWQMJYQNE-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- 229920002494 Zein Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920001291 polyvinyl halide Polymers 0.000 description 1
- 229920002102 polyvinyl toluene Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 239000001038 titanium pigment Substances 0.000 description 1
- 125000005628 tolylene group Chemical group 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000005019 zein Substances 0.000 description 1
- 229940093612 zein Drugs 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/10—Duplicating or marking methods; Sheet materials for use therein by using carbon paper or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1733—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
- B44C1/1737—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff on a substrate unsuitable for direct deposition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
- Y10T428/24901—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material including coloring matter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
Definitions
- This invention relates to transfer materials by which term is meant sheet materials which comprise a carrier sheet carrying, on a surface thereof, a layer, or one or more printed indicia (herein called the transferable material), which while adherent to the carrier sheet can be released therefrom and transferred to a desired receptor surface when required.
- Transfer materials are known and commercially produced which comprise essentially a carrier sheet, transferable material on a surface thereof, and a low-tack pres. sure sensitive adhesive superimposed over the transferable material, the whole so constructed that when such transfer material is laid down with the adhesive in contact with a desired receptor surface, the transferable layer will not, under light pressure, such as ordinary finger pressure, e.g. less than 2 p.s.i. transfer to the receptor surface but will, nevertheless, transfer on application of substantial pressure, e.g. that applied by rubbing the back surface of the transfer material, in the region of the transferable material which is to be transferred, with a stylus or the like.
- Such materials are described in British patent specifications Nos. 906,9'34 and 959,670.
- the transferable material consists of a plurality of indicia, e.g. the letters of the alphabet, numbers, mathematical signs, codes and the like, which may be separately and bodily transferred to a desired receptor surface as required so that, for example, words may be built up on the receptor surface by the successive transference of letters from the transfer material.
- indicia e.g. the letters of the alphabet, numbers, mathematical signs, codes and the like
- bodily transfer is meant that the whole indicium transfers leaving no part of it on the carrier sheet.
- a transfer material which comprises a carrier sheet and, superimposed on a face of said sheet a layer of one or more indicia in a transferable material which is an ink itself containing a pressure sensitive adhesive ingredient, the said transferable material having a surface of low tack and the adhesive properties of the transferable material being so balanced in relation to the surface of the carrier sheet and a receptor sheet that when the transfer material is laid down with the transferable material surface in'contact with a receptor sheet the layer or indicia of transferable material does not transfer bodily under light pressure, e.g. normal finger pressure, but does transfer under the application of substantial pressure applied to the back surface of the carrier sheet e.g. by rubbing with a stylus, in the region of the transferable material to be transferred, at a pressure above 50 p.s.i.
- the carrier sheet should be one having a surface from which the transferable material (adhesive ink) may be bodily removed by application of pressure or by localised stretching of the carrier sheet.
- Suitable carrier sheets are, for example, sheets consisting of glassine or vegetable parchment, or papers such as glassine, vegetable parchment, kraft, sulphate or the like coated or impregnated with a cured polymethyl siloxane, or a Werner type chromium complex such as the stearic acid or myristic acid complex, or alternatively a plastic film such as polyethylene, polytetrafiuoroethylene, polypropylene, cellulose acetate, cellulose acetate butyrate, cellulose nitrate, ethyl cellulose, polycarbonate, polystyrene-butadiene, polyvinyl chloride, polyvinyl acetate, polyvinylidene chloride or copolymers or polyesters such as polyethylene terephthalate or hexamethylene diamine adipate.
- plastic film such as polyethylene, polytetrafiuoroethylene, polypropylene, cellulose acetate, cellulose acetate butyrate, cellulose nitrate
- the pre ferred carrier sheet is vegetable parchment treated with a coating of methylpolysiloxane of a non-migrating type.
- carrier sheet should be transparent or translucent since this makes for ease in location of the transfer material in use. It is to be understood that the term carrier sheet is used herein to include a carrier tape.
- the transferable material comprises ink ingredients including a proportion of a wax.
- Suitable waxes are carnauba wax, microcrystalline wax, oxidised microcrystalline wax, polythene wax, candolilla, beeswax, hydrogenated castor oil, montan wax, paraffin wax, carboxylic acids, esters or amides or polymers of these and long chain alcohols and polyglycols.
- transferable material which consists essentially of ink ingredients and wax may usefully be employed, as above noted, the inclusion of a wax in an ink composition generally tends to reduce the tensile strength of the composition. Accordingly, in using products so made it is important that the transfer pressure should be applied over the whole of the area of the material to be transferred; omission of any area may result in that area not being caused to adhere to the receptor surface. In certain forms of the product this is not a disadvantage, e.g. where the indicia consist of closely spaced small shading dots or lines and the material is used to transfer such dots or lines only over a precisely selected area.
- the indicia are of greater size, eg letters or numerals
- it is preferred that the indicia should transfer even though strokes of a stylus may be slightly spaced apart during the transfer operation, and not cover every part of the area of the indicium and to achieve this result it is desirable that the transferable material should have a higher tensile strength.
- the transferable material is formed of an ink which includes a tacky pressure-sensitive adhesive component together with a waxy or other non-tacky deformable component, the proportion of the non-tacky component being sufiicient to reduce the tack of the final composition to a level at which it will not adhere to a receptor surface under slight or finger pressure, the said composition further including a proportion of a high tensile strength polymer.
- the tacky component may, for example, be a tacky acrylic or methacrylic ester or acid polymer or copolymer, a vinyl ether or ester, terpene, cresylic, maleic, or phenolic resin, or natural or synthetic rubbers such as neoprene or isoprene or cyclised rubber, or chlorinated rubber or such materials containing non-volatile plasticisers such as saturated polyesters, or non drying alkyds, or mixtures thereof.
- a tacky acrylic or methacrylic ester or acid polymer or copolymer a vinyl ether or ester, terpene, cresylic, maleic, or phenolic resin
- natural or synthetic rubbers such as neoprene or isoprene or cyclised rubber, or chlorinated rubber or such materials containing non-volatile plasticisers such as saturated polyesters, or non drying alkyds, or mixtures thereof.
- the non-tacky component may, for example, be a high melting point long chain hydrocarbon, or carboxylic acid ester or amide thereof, or polymers of any of these, or a long chain alcohol or a polyglycol, or a natural wax.
- Preferred high tensile strength polymers for use in this form of the invention are polyvinyl butyral or ethyl cellulose.
- Other suitable materials are cellulose nitrate; cellulose acetate; cellulose acetobutyrate; ethyl cellulose, ethylhydroxyethyl cellulose; alkyds and alkyds modified or copolymerised with a drying oil, styrene, urethane, vinyl, silicone or acrylic resin; polyvinyl-halides, -esters-acetals and alcohols; polyurethanes; epoxy polymers; epoxy phenolic, epoxy-polyamide and catalysed epoxy resins and copolymers; urea-, melamine-, and benzoguanamino-formaldehyde polymers; chlorinated and isomerised rubber; polystyrene and polyvinyl toluene; polysiloxanes and silicone containing polymers; polyacrylates, polymeth
- the ink consists essentially of a tacky component and a non tacky component as aforesaid, a high tensile strength polymer, and a pigment.
- the ingredients may be applied as a solution, dispersion or emulsion in organic solvent medium or water, the solvent or water being dried out after application.
- the indicia may be of any kind, e.g. letters, numerals, symbols, line drawings or the like. Particularly useful products are those in which the ink is applied as a texture pattern extending substantially over the whole area of the carrier sheet, i.e. so that the whole transferable layer is of said texture pattern.
- texture patterns may be for example an array of dots, shading lines, parallel or crossed, or irregular paterns, to simulate grain, textile fibre mat or other texture appearances.
- the indicia will only transfer where the pressure is applied so that localised areas of the texture pattern may be transferred.
- an outline drawing of a figure wearing a skirt may be treated with a transfer material according to this invention which carries a pattern simulating textile finish by applying transfer pressure only within the confines of the skirt outline so as to transfer the textile pattern to the skirt portion only of the drawing. Since in this case the transfer is required to be closely limited to the area over which the pressure has been applied it is desirable to employ an ink of suitable level of cohensiveness (as referred to later herein) in order that the layer'should fracture at the margins of the pressed area.
- a method for the production of a transfer material which comprises applying to a carrier sheet a layer, or indicia, in transferable material which has, or is enabled to develop, a tacky surface sufiicient to enable it to adhere to a receptor surface under substantial pressure while the face of the transferable material originally in contact with the carrier sheet is or becomes substantially non-tacky. It will be appreciated that the merit of this technique is that there is substantially no tendency for the transferred indicia to pick up dirt on their surface.
- any convenient pigment well known for use in printing inks may be used in the ink formulations of the present invention including pigments modified by coating the pigment particles with surface active agents to improve dispersability and increase covering power. It will be appreciated that changes in pigmentation whether utilising unmodified materials or materials modified as aforesaid will involve other formulation changes in order to provide inks possessing the desirable properties for the transferable material of this invention.
- Pigments of particular value are carbon blacks and titanium compounds whilst modified pigments of particular interest are those in which the pigment particles are coated with aluminum or zinc stearates of amides of stearic acid.
- Transfer materials of particular value are obtained when employing inks formulated Within the range encompassed by the following formulations in conjunction with the carrier sheets of vegetable parchment having a silicone coating.
- the dried ink will contain the first four only of the specified ingredients in the indicated relative parts by weight. It will be appreciated that alternative pigmentation will necessitate other variations in composition of the foregoing formulations and such variations should be made in cognisance of the working behaviour of the ink and the ultimate properties desirable in the transferable indicia.
- the cohesiveness refers to the property of the ink film when present on the carrier film in its normal condition for use as a transfer material. This range of formulations are very suitable for use when 5 the carrier sheet is in the form of a tape as there arises no trouble due to oif-setting when the tape is rolled.
- EXAMPLE 1 A carrier sheet consisting of paper having a silicone coating, is printed with indicia. in ink of the following formulation:
- Polyvinyl butyral solution (216% solids) in butanol-- 30-65 parts preferably 31.5 parts Microcrystalline wax dispersion (40% in white spirit) 20-5 parts preferably 44.5 parts Polyvinylethyl ether dispersion 70% in benzene-20 parts preferably 19 parts Pigment, carbon black-4-8 parts preferably 5 .0 parts
- EXAMPLE 2 A carrier sheet consisting of paper having a silicone coating is printed with ink of the following formulation:
- EXAMPLE 3 A carrier sheet consisting of paper having a silicone coating is printed with indicia in ink of the following formulation:
- Aqueous paraffin wax emulsion (50% )65-85 parts preferably 76.5 parts
- Aqueous polyvinyl ethyl ether dispersion (50%)- 5-15 parts preferably 9.0 parts
- Polyisobutylene rubber latex (60% in water)--3-15 parts preferably 4.5 parts
- Aqueous carbon black dispersion (10%)l0-20 parts preferably 10.0 parts
- EXAMPLE 4 A carrier sheet consisting of paper having a Werner type complex coating is printed with indicia in ink of the following formulation:
- EXAMPLE 5 A carrier sheet consisting of paper having a Werner type complex coating is printed with indicia in ink of the following formulation:
- Microcrystalline wax dispersion (40%) in aliphatic and/or aromatic solvents 37.7 Polyvinyl butyral 26% in *butanol 31.3 Polyvinyl ethyl ether 70% in toluene 9.9 Titanium dioxide 21.1
- EXAMPLE 8 A carrier sheet consisting of polyethylene film is printed with indicia in ink of the following formulation:
- the following ingredients are mixed to form a disand the whole dispersed on a triple roll mill.
- plasticiser di-isobutylphthalate
- EXAMPLE 9 A carrier sheet consisting of paper having a silicone coating is printed with indicia in ink of the following formulaton:
- This dispersion is mixed with the following:
- plasticiser di-isobutylphthalate
- a carrier sheet consisting of polythene fihn is printed with indicia in ink of the following formulation, the ingredients being mixed and dispersed on a triple roll mill.
- a transfer material which comprises a carrier sheet having a release surface and, superimposed on a face of said sheet, indicia formed of a transferable cohesive ink composition
- a transferable cohesive ink composition comprising a mixture of about 11.5 to about 14.5 parts by weight of a polyvinyl butyl ether as a tacky pressure sensitive component, about 17.5 to about 18.5 parts by weight of a microcrystalline wax as a low tack deformable component, about 8 to about 8.5 parts by weight of a polyvinyl butyral as ahigh tensile strength polymer and about 4 to about 5 parts by weight of a pigment
- said transferable cohesive ink composition having a surface of low tack and the adhesive properties of said transferable cohesive ink composition being such that when said transfer material is laid down with said transferable cohesive ink composition surface in contact with a receptor sheet, said indicia formed of said transferable cohesive ink composition does not transfer bodily'under a pressure less than 2 p.s.i.
- a transfer material according to claim 1 wherein the transferable material is a layer constituting a texture pattern extending substantially over the Whole area of the carrier sheet.
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
- Decoration By Transfer Pictures (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Folding Of Thin Sheet-Like Materials, Special Discharging Devices, And Others (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4749/64A GB1046411A (en) | 1964-02-04 | 1964-02-04 | Transfer materials |
GB2721864 | 1964-07-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3519456A true US3519456A (en) | 1970-07-07 |
Family
ID=26239344
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US429904A Expired - Lifetime US3519456A (en) | 1964-02-04 | 1965-02-02 | Transfer materials |
Country Status (10)
Country | Link |
---|---|
US (1) | US3519456A (en, 2012) |
BE (1) | BE659042A (en, 2012) |
CH (1) | CH428417A (en, 2012) |
DE (1) | DE1546568B1 (en, 2012) |
DK (1) | DK122645B (en, 2012) |
ES (1) | ES308986A1 (en, 2012) |
FR (1) | FR1423437A (en, 2012) |
GB (1) | GB1046411A (en, 2012) |
IL (1) | IL22865A (en, 2012) |
NL (1) | NL6501368A (en, 2012) |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3924026A (en) * | 1974-01-28 | 1975-12-02 | Henry S Penfield | Image preservation and transfer process |
US3942621A (en) * | 1970-04-28 | 1976-03-09 | Mac Karlan | Method of and article for masking |
US3974014A (en) * | 1974-07-10 | 1976-08-10 | Hallmark Cards, Incorporated | Method for transferring design image to wax articles |
US4028165A (en) * | 1976-06-14 | 1977-06-07 | Rosenfeld Jerome E | Dry transfer product and process |
US4188139A (en) * | 1976-05-10 | 1980-02-12 | Ing. C. Olivetti & C., S.P.A. | Method and apparatus for correctably printing characters with sublimable ink |
US4190417A (en) * | 1976-11-11 | 1980-02-26 | Mobay Chemical Corporation | Process for dyeing and printing sheets |
US4222973A (en) * | 1978-07-10 | 1980-09-16 | The Mead Corporation | Process for producing casting release paper and product |
US4275104A (en) * | 1978-05-31 | 1981-06-23 | International Hona Nv | Dry transfer system |
US4308633A (en) * | 1979-07-02 | 1982-01-05 | Huffel Phillip L Van | Wax applicator laminate |
US4426169A (en) | 1980-09-09 | 1984-01-17 | Franz Buttner Ag | Typewriting ribbon with adhesively correctable print |
US4453839A (en) * | 1982-06-15 | 1984-06-12 | International Business Machines Corporation | Laminated thermal transfer medium for lift-off correction and embodiment with resistive layer composition including lubricating contact graphite coating |
US4454179A (en) * | 1982-05-10 | 1984-06-12 | Minnesota Mining And Manufacturing Company | Dry transfer article |
US4465389A (en) * | 1981-09-21 | 1984-08-14 | Ing. C. Olivetti & C., S.P.A. | Thermosensitive inked element for non-impact printers |
US4500218A (en) * | 1981-06-05 | 1985-02-19 | Toho-Polymer Kabushika Kaisha | Keyboard key with embedded top character |
US4547088A (en) * | 1980-06-26 | 1985-10-15 | International Business Machines Corporation | Correctable thermal transfer printing ribbon |
US5242725A (en) * | 1989-07-28 | 1993-09-07 | Pelikan Ag | Multilayer flexible marking band or tape |
US5672413A (en) * | 1995-09-27 | 1997-09-30 | Rexam Graphics Incorporated | Element and associated process for use with inkjet hot melt inks for thermal image transfer |
US5766398A (en) * | 1993-09-03 | 1998-06-16 | Rexam Graphics Incorporated | Ink jet imaging process |
US5795425A (en) * | 1993-09-03 | 1998-08-18 | Rexam Graphics Incorporated | Ink jet imaging process and recording element for use therein |
US5916666A (en) * | 1996-08-09 | 1999-06-29 | The West Carrollton Parchment Company | Decorative sheet and method of making the same |
US5985078A (en) * | 1991-10-17 | 1999-11-16 | Suess; Joachim | Method of producing marking on a surface by means of laser radiation and use of an embossing foil in such a method |
US6001482A (en) * | 1993-09-03 | 1999-12-14 | Rexam Graphics, Inc. | Ink jet receptor element having a protective layer |
EP1375189A1 (de) * | 2002-06-27 | 2004-01-02 | AutoTec Digital AG | Verfahren zur Herstellung einer Bildübertragungsfolie |
US20050126691A1 (en) * | 2002-12-24 | 2005-06-16 | Nobuo Sugino | Transfer method and adhesive for transfer |
US20060185585A1 (en) * | 2005-02-09 | 2006-08-24 | Mclean Salahedin B | Ski and snowboard waxing apparatus and method of use |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1577617A (en) * | 1976-11-05 | 1980-10-29 | Letraset International Ltd | Dry transfer materials |
FR2434710A1 (fr) * | 1978-09-04 | 1980-03-28 | Rosenfeld Jerome | Materiau et procede de transfert a sec de signes sur une surface receptrice |
US4260664A (en) * | 1978-11-27 | 1981-04-07 | Columbia Ribbon & Carbon Mfg. Co., Inc. | Transfer elements and process |
NL8005935A (nl) * | 1980-10-29 | 1982-05-17 | Nordipa A G | Overdraagbaar lakvel, alsmede werkwijze voor het vervaardigen daarvan. |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2139068A (en) * | 1936-05-08 | 1938-12-06 | Michelin & Cie | Transfer sheet for decorating rubber |
US2263196A (en) * | 1939-09-02 | 1941-11-18 | M F Donovan | Impression medium |
US3031327A (en) * | 1959-11-20 | 1962-04-24 | Columbia Ribbon & Carbon | Method of preparing transfer sheets |
US3036924A (en) * | 1959-10-01 | 1962-05-29 | Columbia Ribbon & Carbon | Duplicating ink compositions and transfer elements prepared therefrom |
US3131106A (en) * | 1960-06-24 | 1964-04-28 | Letraset International Ltd | Adhesive transfers |
US3212913A (en) * | 1965-03-31 | 1965-10-19 | Letraset International Ltd | Adhesive transfers |
US3368989A (en) * | 1963-07-02 | 1968-02-13 | Pacific Ind Inc | Image transfer compositions comprising ethylene-vinyl acetate or ethyleneethyl acrylate copolymer, wax and incompatible plasticizer |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2941916A (en) * | 1956-10-19 | 1960-06-21 | Meyercord Co | Heat resistant decalcomania transfer and method of making and using the same |
GB906934A (en) * | 1958-01-21 | 1962-09-26 | Letraset International Ltd | Improvements in or relating to methods of and means for the production of designs |
DE1855366U (de) * | 1962-02-09 | 1962-07-19 | Oskar Vangerow | Folienbahn zum einmaligen uebertragen von aufdrucken auf oberflaechen. |
NL133939C (en, 2012) * | 1962-03-21 |
-
1964
- 1964-02-04 GB GB4749/64A patent/GB1046411A/en not_active Expired
-
1965
- 1965-01-28 IL IL22865A patent/IL22865A/xx unknown
- 1965-01-28 DE DE19651546568 patent/DE1546568B1/de active Pending
- 1965-01-29 BE BE659042A patent/BE659042A/xx unknown
- 1965-02-01 CH CH133365A patent/CH428417A/de unknown
- 1965-02-02 US US429904A patent/US3519456A/en not_active Expired - Lifetime
- 1965-02-03 DK DK55865AA patent/DK122645B/da unknown
- 1965-02-03 FR FR4215A patent/FR1423437A/fr not_active Expired
- 1965-02-03 NL NL6501368A patent/NL6501368A/xx unknown
- 1965-02-04 ES ES0308986A patent/ES308986A1/es not_active Expired
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2139068A (en) * | 1936-05-08 | 1938-12-06 | Michelin & Cie | Transfer sheet for decorating rubber |
US2263196A (en) * | 1939-09-02 | 1941-11-18 | M F Donovan | Impression medium |
US3036924A (en) * | 1959-10-01 | 1962-05-29 | Columbia Ribbon & Carbon | Duplicating ink compositions and transfer elements prepared therefrom |
US3031327A (en) * | 1959-11-20 | 1962-04-24 | Columbia Ribbon & Carbon | Method of preparing transfer sheets |
US3131106A (en) * | 1960-06-24 | 1964-04-28 | Letraset International Ltd | Adhesive transfers |
US3368989A (en) * | 1963-07-02 | 1968-02-13 | Pacific Ind Inc | Image transfer compositions comprising ethylene-vinyl acetate or ethyleneethyl acrylate copolymer, wax and incompatible plasticizer |
US3212913A (en) * | 1965-03-31 | 1965-10-19 | Letraset International Ltd | Adhesive transfers |
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3942621A (en) * | 1970-04-28 | 1976-03-09 | Mac Karlan | Method of and article for masking |
US3924026A (en) * | 1974-01-28 | 1975-12-02 | Henry S Penfield | Image preservation and transfer process |
US3974014A (en) * | 1974-07-10 | 1976-08-10 | Hallmark Cards, Incorporated | Method for transferring design image to wax articles |
US4188139A (en) * | 1976-05-10 | 1980-02-12 | Ing. C. Olivetti & C., S.P.A. | Method and apparatus for correctably printing characters with sublimable ink |
US4028165A (en) * | 1976-06-14 | 1977-06-07 | Rosenfeld Jerome E | Dry transfer product and process |
US4111734A (en) * | 1976-06-14 | 1978-09-05 | Rosenfeld Jerome E | Dry transfer product and process for using same |
US4190417A (en) * | 1976-11-11 | 1980-02-26 | Mobay Chemical Corporation | Process for dyeing and printing sheets |
US4275104A (en) * | 1978-05-31 | 1981-06-23 | International Hona Nv | Dry transfer system |
US4222973A (en) * | 1978-07-10 | 1980-09-16 | The Mead Corporation | Process for producing casting release paper and product |
US4308633A (en) * | 1979-07-02 | 1982-01-05 | Huffel Phillip L Van | Wax applicator laminate |
US4547088A (en) * | 1980-06-26 | 1985-10-15 | International Business Machines Corporation | Correctable thermal transfer printing ribbon |
US4426169A (en) | 1980-09-09 | 1984-01-17 | Franz Buttner Ag | Typewriting ribbon with adhesively correctable print |
US4500218A (en) * | 1981-06-05 | 1985-02-19 | Toho-Polymer Kabushika Kaisha | Keyboard key with embedded top character |
US4465389A (en) * | 1981-09-21 | 1984-08-14 | Ing. C. Olivetti & C., S.P.A. | Thermosensitive inked element for non-impact printers |
US4454179A (en) * | 1982-05-10 | 1984-06-12 | Minnesota Mining And Manufacturing Company | Dry transfer article |
US4453839A (en) * | 1982-06-15 | 1984-06-12 | International Business Machines Corporation | Laminated thermal transfer medium for lift-off correction and embodiment with resistive layer composition including lubricating contact graphite coating |
US5242725A (en) * | 1989-07-28 | 1993-09-07 | Pelikan Ag | Multilayer flexible marking band or tape |
US5985078A (en) * | 1991-10-17 | 1999-11-16 | Suess; Joachim | Method of producing marking on a surface by means of laser radiation and use of an embossing foil in such a method |
US6165593A (en) * | 1993-09-03 | 2000-12-26 | Rexam Graphics Incorporated | Ink jet imaging process and recording element for use therein |
US5766398A (en) * | 1993-09-03 | 1998-06-16 | Rexam Graphics Incorporated | Ink jet imaging process |
US5795425A (en) * | 1993-09-03 | 1998-08-18 | Rexam Graphics Incorporated | Ink jet imaging process and recording element for use therein |
US5837375A (en) * | 1993-09-03 | 1998-11-17 | Rexham Graphics Incorporated | Ink jet imaging process and recording element for use therein |
US6001482A (en) * | 1993-09-03 | 1999-12-14 | Rexam Graphics, Inc. | Ink jet receptor element having a protective layer |
US5672413A (en) * | 1995-09-27 | 1997-09-30 | Rexam Graphics Incorporated | Element and associated process for use with inkjet hot melt inks for thermal image transfer |
US5916666A (en) * | 1996-08-09 | 1999-06-29 | The West Carrollton Parchment Company | Decorative sheet and method of making the same |
EP1375189A1 (de) * | 2002-06-27 | 2004-01-02 | AutoTec Digital AG | Verfahren zur Herstellung einer Bildübertragungsfolie |
CH695991A5 (de) * | 2002-06-27 | 2006-11-15 | Autotec Digital Ag | Verfahren zur Herstellung einer Bildübertragungsfolie. |
US20050126691A1 (en) * | 2002-12-24 | 2005-06-16 | Nobuo Sugino | Transfer method and adhesive for transfer |
US20060185585A1 (en) * | 2005-02-09 | 2006-08-24 | Mclean Salahedin B | Ski and snowboard waxing apparatus and method of use |
Also Published As
Publication number | Publication date |
---|---|
FR1423437A (fr) | 1966-01-03 |
DK122645B (da) | 1972-03-27 |
NL6501368A (en, 2012) | 1965-08-05 |
ES308986A1 (es) | 1965-07-01 |
BE659042A (en, 2012) | 1965-05-17 |
DE1546568B1 (de) | 1970-10-15 |
CH428417A (de) | 1967-01-15 |
IL22865A (en) | 1968-07-25 |
GB1046411A (en) | 1966-10-26 |
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Legal Events
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AS | Assignment |
Owner name: ESSELTE PENDAFLEX CORPORATION Free format text: MERGER;ASSIGNOR:LETRASET USA INC. (INTO);REEL/FRAME:004148/0349 Effective date: 19830330 Owner name: ESSELTE PENDAFLEX CORPORATION A CA CORP Free format text: MERGER;ASSIGNOR:LETRASET USA INC. (INTO);REEL/FRAME:004148/0349 Effective date: 19830330 |
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Owner name: ESSELTE PENDAFLEX CORPORATION Free format text: MERGER;ASSIGNORS:ESSELTE BOORUM & PEASE INC.;ESSELTE PENDAFLEX CORPORATION, (MERGED INTO);ESSELTE BOORUM & PEASE INC, (CHANGED INTO);REEL/FRAME:004616/0555 Effective date: 19851223 |