US3494727A - Microbe resistant roof - Google Patents

Microbe resistant roof Download PDF

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Publication number
US3494727A
US3494727A US689218A US3494727DA US3494727A US 3494727 A US3494727 A US 3494727A US 689218 A US689218 A US 689218A US 3494727D A US3494727D A US 3494727DA US 3494727 A US3494727 A US 3494727A
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Prior art keywords
roof
chips
copper
metallic
lead
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US689218A
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Stanley L Rapaport
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STANLEY L RAPAPORT
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STANLEY L RAPAPORT
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D13/00Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage; Sky-lights
    • E04D13/002Provisions for preventing vegetational growth, e.g. fungi, algae or moss
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31815Of bituminous or tarry residue
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/8305Miscellaneous [e.g., treated surfaces, etc.]

Definitions

  • FIG. 1 MICROBE RESISTANT ROOF Filed Nov. 17, 1967 FIG. 1
  • a roofing material having incorporated therein particles of metallic elements capable of forming biocidal ionic solutions. The periodic formation of such solutions by rain or dew prevents the darkening of roofs by killing the fungus or bacteria.
  • the present invention comprises a roofing material having embedded therein small particles, or chips, of at least one metallic element.
  • the element is selected from those 'ng microbioeida ions,.Thereafter, normal weathering will resfilt m the pro notion of such ions which will be spread over the surface of the roof by the action of rain or dew.
  • FIG. 1 illustrates a portion of an asphalt shingle roof
  • FIG. 2 is an enlarged view of a portion of the roof of FIG. 1;
  • FIG. 3 illustrates a portion of a rock-tar roof
  • FIG. 4 is an enlarged portion of the roof of FIG. 3.
  • the ions of a number of metallic elements have been found to have microbiocidal characteristics. These elements include, for example, copper, lead, and zinc.
  • the objects of the present invention are achieved by incorporating the particles of one or more of such metallic elements directly into the roofing material. They may be included, for example, in the body or coating of an as phalt shingle roof during production of the shingles. In a tar or rock-tar roof, they may be incorporated by admixture into the roofing ingredients either prior to their application or during their application on the roof surface.
  • the effectiveness of the metallic inclusions may be synergistically increased by including two different metals. If one such metal is 'electronegative with respect to the other, galvanic action will take place, accelerating corrosion of the anodic metal when exposed to moisture. Suitable combinations of metals would include, for example, erea a in itoawith' particular reference to FIGS. 1 and 2 there is illustrated a roof comprising shingles 1. Embedded in the matrix of each of the shingles 1 are metallic copper chips 3 and metallic lead chips 4. As pointed out above, such particles form electrical couples which accelerate corrosion and thus result in an increased release of ions over that obtainable from either metal alone.
  • FIGS. 3 and 4 A modification of the invention is illustrated in FIGS. 3 and 4 wherein a rock-tar roof 2 has embedded therein copper chips 3 and lead chips 4.
  • the present invention is not limited to the specific elements set forth but includes roofing materials having particle inclusions of any metals capable of releasing ions which are microbiocidal to the particular micro-organisms involved. It will also be apparent that the individual particles may be composite in nature. In other words, each particle may include both copper and lead or both zinc and iron. Various other modifications of this invention will be apparent to those skilled in the art. Accordingly: the foregoing description is to be construed as illustrative only, rather than limiting. This invention is limited only by the scope of the following claims.
  • a roofing material having embedded therein visually observable chips of metallic elements, the ions of said metallic elements being capable of producing microbio cidal effects on microbes coming into contact with said roofing material.
  • each of said chips r 2,927,052 1/1960 Moudry 204"-1571 0 3,197,313 7/1965 Greiner 106-45 is a bimetallic admixture of copper and lead.

Description

,1. '2 g :5 g w Feb. 10,1970 s, L RAPAPQRT 3,494,727
. MICROBE RESISTANT ROOF Filed Nov. 17, 1967 FIG. 1
L/ L 1 L] 7 L 7 L %l L 7 7? L /1 L 7 FIG. 2
i 0 X o 0, 0 0* o United States Patent ABSTRACT OF THE DISCLOSURE A roofing material having incorporated therein particles of metallic elements capable of forming biocidal ionic solutions. The periodic formation of such solutions by rain or dew prevents the darkening of roofs by killing the fungus or bacteria.
BACKGROUND OF THE INVENTION This is a continuation-in-part of my copending application Ser. No. 398,623, filed Sept. 23, 1964 and now abandoned for Intrinsically Microbe Resistant Roofs.
In many tropical and semi-tropical areas it is quite common for roofs to be subject to a dark discoloration with age. While the exact cause of this phenomenon is not known, it is believed to be the result of biological action, such as microbial or fungal growths. The discoloration may be due to the growth itself or may be produced indirectly as a result of the organisms metabolic products. When the proper conditions exist, the discoloration can be so extreme as to change a white roof to black in a period of a few years. Northerly exposed roofs change more rapidly than southerly exposed roofs and the color change appears to be more pronounced in some neighborhoods than in others. The change affects roofs of all colors and, in all known instances, the color changes are toward black. The blackening is not only unsightly but ample, the water run-off pattern is free of the darkening.
This is probably due to the growth-retarding effect of the ions of slightly soluble salts of these elements. It has been suggested that thin metallic strips, such as copper, be mounted on shingled roofs to prevent such darkening. However, the application of such strips complicates the laying of a roof and thereby increases its expense. Furthermore, it is believed that a synergistic etfect may be achieved by use of two separate metallic elements in rather close physical conjunction. Accordingly, it is a primary object of the present invention to provide a roofing material which is itself biocidal without the application of extraneous elements. Another object is to provide such a roof in which the biocidal effect is enhanced to a greater degree than is possible by the use of any single metallic element.
SUMMARY OF THE INVENTION The present invention comprises a roofing material having embedded therein small particles, or chips, of at least one metallic element. The element is selected from those 'ng microbioeida ions,.Thereafter, normal weathering will resfilt m the pro notion of such ions which will be spread over the surface of the roof by the action of rain or dew.
3,494,727 Patented Feb. 10, 1976 BRIEF DESCRIPTION OF THE DRAWING For a further understanding of the present invention, attention is directed to the following description, the appended claims and the figures of the attached drawing, wherein:
FIG. 1 illustrates a portion of an asphalt shingle roof;
FIG. 2 is an enlarged view of a portion of the roof of FIG. 1;
FIG. 3 illustrates a portion of a rock-tar roof; and
FIG. 4 is an enlarged portion of the roof of FIG. 3.
DESCRIPTION OF THE PREFERRED EMBODIMENTS The ions of a number of metallic elements have been found to have microbiocidal characteristics. These elements include, for example, copper, lead, and zinc. The objects of the present invention are achieved by incorporating the particles of one or more of such metallic elements directly into the roofing material. They may be included, for example, in the body or coating of an as phalt shingle roof during production of the shingles. In a tar or rock-tar roof, they may be incorporated by admixture into the roofing ingredients either prior to their application or during their application on the roof surface.
The effectiveness of the metallic inclusions may be synergistically increased by including two different metals. If one such metal is 'electronegative with respect to the other, galvanic action will take place, accelerating corrosion of the anodic metal when exposed to moisture. Suitable combinations of metals would include, for example, erea a in itoawith' particular reference to FIGS. 1 and 2 there is illustrated a roof comprising shingles 1. Embedded in the matrix of each of the shingles 1 are metallic copper chips 3 and metallic lead chips 4. As pointed out above, such particles form electrical couples which accelerate corrosion and thus result in an increased release of ions over that obtainable from either metal alone.
A modification of the invention is illustrated in FIGS. 3 and 4 wherein a rock-tar roof 2 has embedded therein copper chips 3 and lead chips 4.
It is to be understood that the present invention is not limited to the specific elements set forth but includes roofing materials having particle inclusions of any metals capable of releasing ions which are microbiocidal to the particular micro-organisms involved. It will also be apparent that the individual particles may be composite in nature. In other words, each particle may include both copper and lead or both zinc and iron. Various other modifications of this invention will be apparent to those skilled in the art. Accordingly: the foregoing description is to be construed as illustrative only, rather than limiting. This invention is limited only by the scope of the following claims.
What is claimed is:
1. A roofing material having embedded therein visually observable chips of metallic elements, the ions of said metallic elements being capable of producing microbio cidal effects on microbes coming into contact with said roofing material.
2. The material of claim 1 wherein said chips are copper.
3. The material of claim 1 wherein said chips are lead.
4. The material of claim 1 wherein said chips are zinc.
a 4i The material of claim 1 wherein said material is References Cited a shingle. q
The material of claim 1 wherein said chips are 7 UNITED STA'TES PATENTS zinc and including additional chips of iron. 2, 9 9/ 1938 Easllng 117-158 *1. The material of claim ll wherein each of said chips r 2,927,052 1/1960 Moudry 204"-1571 0 3,197,313 7/1965 Greiner 106-45 is a bimetallic admixture of copper and lead.
U1. 1 he material of clalm 1 whereln each of said chips MORRIS O. WOLK Primary Examiner a bimetallic admixture oi zinc and iron.
The material of claim 1 wherein said elements are B. S. RICHMAN, Assistant Examiner selected from the group consisting of copper, lead, zinc, 10 and combinations thereof.
llll. The material of claim 9 wherein some of said 21-2, 58; 52-517; lO6-15;117168; l61224, 271; chips are copper and others are lead. 424-131, 140, 145
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Cited By (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3884706A (en) * 1972-10-25 1975-05-20 Gaf Corp Algicidal roofing granules
US3888682A (en) * 1972-10-25 1975-06-10 Gaf Corp Algicidal post treated roofing granules
US3888176A (en) * 1972-10-25 1975-06-10 Gaf Corp Algicidal post treated roofing granules
US3888684A (en) * 1972-10-25 1975-06-10 Gaf Corp Algicidal roofing granules
US3894877A (en) * 1972-10-25 1975-07-15 Gaf Corp Roofing granules with enhanced algicidal post treatment
US4088810A (en) * 1973-05-07 1978-05-09 Minnesota Mining And Manufacturing Company Alkali metal silicate-zinc hydroxychloride coating composition
US4202858A (en) * 1978-03-17 1980-05-13 Gary Bruce Moss killer
US4276732A (en) * 1979-08-24 1981-07-07 Sharon G. Nielsen Device for killing moss
US4416854A (en) * 1979-08-24 1983-11-22 Sharon G. Nielsen Method for killing water borne microorganisms
US4554862A (en) * 1984-06-21 1985-11-26 Air Vent Inc. Roof ridge ventilator for retarding microbe growth in shingle roofs
US4610783A (en) * 1982-11-04 1986-09-09 Paul Hudson Control of algae in re-circulating water systems
FR2601684A1 (en) * 1986-07-15 1988-01-22 Tech Tuiles Briques Centre Process for preventing the proliferation of plants on an article made of nonmetallic porous material, especially a building roof unit
EP0318830A1 (en) * 1987-12-02 1989-06-07 Grillo-Werke Ag Treatment of roofings and concrete surfaces against the growth of fungi and seaweeds
US4936898A (en) * 1986-04-09 1990-06-26 Nielsen James W Atomized elemental moss killer
US4937995A (en) * 1988-06-16 1990-07-03 Carlisle Corporation Noninvasively identifiable membrane roof system
GB2245922A (en) * 1990-06-05 1992-01-15 Colebrand Ltd A tile or sheeting
US5216864A (en) * 1991-10-31 1993-06-08 Chicago Metallic Corporation Unique zinc alloy strip design for the inhibition of moss and fungus
US5356664A (en) * 1992-09-15 1994-10-18 Minnesota Mining And Manufacturing Company Method of inhibiting algae growth on asphalt shingles
US5357726A (en) * 1989-02-02 1994-10-25 Chemfab Corporation Composite materials for structural end uses
US5411803A (en) * 1992-09-15 1995-05-02 Minnesota Mining And Manufacturing Company Granular materials having an improved ceramic coating, methods of preparing same, and composite sheets including same
EP0727542A1 (en) * 1995-02-15 1996-08-21 Hugo Weber Roof panel and method for its manufacturing
DE19904648A1 (en) * 1999-02-05 2000-08-31 Alexander Faller Roof covering treated with agent for prevention of plant growth, especially copper compound, useful for avoidance of premature roof damage
EP0869228A3 (en) * 1997-04-01 2000-10-25 Hugo Weber Roof cleaning panel
US6214466B1 (en) 1999-07-28 2001-04-10 Isp Investments Inc. Algae-resistant roofing granules
DE19954752A1 (en) * 1999-10-22 2001-04-26 Viktor Rein Device for prevention and removal of deposits on roof coverings, especially roof tiles, has elements of metal or metal compound fitted by fastening device on ridge or other highest-most point of roof
US20030091795A1 (en) * 2000-06-08 2003-05-15 Matti Kiik Metal flake-surfaced roofing materials
US20040139886A1 (en) * 2003-01-21 2004-07-22 Isp Investments Inc. Low pigments costs algae-retardant roofing granule products containing metallic copper
US20040247831A1 (en) * 2003-06-04 2004-12-09 Nakagawa Chemical Inc. Decorative sheet
US20050183220A1 (en) * 2002-08-11 2005-08-25 Hugo Weber Cleaning system designed to be installed on a surface that is exposed to poor weather conditions
US20060035582A1 (en) * 2004-08-10 2006-02-16 Collister Kenneth F Ridge vent with biocidal source
US20060194023A1 (en) * 2005-02-25 2006-08-31 Teng Yihsien H Algae resistant shingle
DE102005027625A1 (en) * 2005-06-15 2007-01-04 Aktiv-First Gmbh Mechanism for preventing or killing of vegetation on a sloped sloped brick- and reed roof, comprises two different metal surface elements formed with perforation holes, napped texture and water storage folding
US20070020436A1 (en) * 2005-02-25 2007-01-25 Teng Yihsien H Roofing shingle containing algae inhibiting metallic particles
US20080131664A1 (en) * 2006-07-26 2008-06-05 Teng Yihsien H Roofing shingle having agglomerated microorganism resistant granules
US20090117329A1 (en) * 2000-06-08 2009-05-07 Leitch Olan T Colored Metal Flake Surfaced Roofing Materials
US7788870B1 (en) 2006-12-20 2010-09-07 David Spencer Method and roofing strip for retarding moss, fungi, and algae growth on roofs
US8703166B1 (en) 2011-01-20 2014-04-22 John Flynn Systems and methods for reducing microbial growth
US10000931B1 (en) 2016-12-13 2018-06-19 Daniel T. Daugherty Apparatus and method for moss remediation
US11105097B2 (en) 2019-12-19 2021-08-31 Eraserspacer Llc Roofing panel for concealing a biocidal source

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2129659A (en) * 1936-07-22 1938-09-13 Newton P Easling Insectproof paper
US2927052A (en) * 1953-03-20 1960-03-01 Us Movidyn Corp Process of producing oligodynamic metal biocides
US3197313A (en) * 1962-04-16 1965-07-27 Johns Manville Asbestos-cement products

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2129659A (en) * 1936-07-22 1938-09-13 Newton P Easling Insectproof paper
US2927052A (en) * 1953-03-20 1960-03-01 Us Movidyn Corp Process of producing oligodynamic metal biocides
US3197313A (en) * 1962-04-16 1965-07-27 Johns Manville Asbestos-cement products

Cited By (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3884706A (en) * 1972-10-25 1975-05-20 Gaf Corp Algicidal roofing granules
US3888682A (en) * 1972-10-25 1975-06-10 Gaf Corp Algicidal post treated roofing granules
US3888176A (en) * 1972-10-25 1975-06-10 Gaf Corp Algicidal post treated roofing granules
US3888684A (en) * 1972-10-25 1975-06-10 Gaf Corp Algicidal roofing granules
US3894877A (en) * 1972-10-25 1975-07-15 Gaf Corp Roofing granules with enhanced algicidal post treatment
US4088810A (en) * 1973-05-07 1978-05-09 Minnesota Mining And Manufacturing Company Alkali metal silicate-zinc hydroxychloride coating composition
US4202858A (en) * 1978-03-17 1980-05-13 Gary Bruce Moss killer
US4276732A (en) * 1979-08-24 1981-07-07 Sharon G. Nielsen Device for killing moss
US4416854A (en) * 1979-08-24 1983-11-22 Sharon G. Nielsen Method for killing water borne microorganisms
US4610783A (en) * 1982-11-04 1986-09-09 Paul Hudson Control of algae in re-circulating water systems
US4554862A (en) * 1984-06-21 1985-11-26 Air Vent Inc. Roof ridge ventilator for retarding microbe growth in shingle roofs
US4936898A (en) * 1986-04-09 1990-06-26 Nielsen James W Atomized elemental moss killer
FR2601684A1 (en) * 1986-07-15 1988-01-22 Tech Tuiles Briques Centre Process for preventing the proliferation of plants on an article made of nonmetallic porous material, especially a building roof unit
EP0318830A1 (en) * 1987-12-02 1989-06-07 Grillo-Werke Ag Treatment of roofings and concrete surfaces against the growth of fungi and seaweeds
US4937995A (en) * 1988-06-16 1990-07-03 Carlisle Corporation Noninvasively identifiable membrane roof system
US5357726A (en) * 1989-02-02 1994-10-25 Chemfab Corporation Composite materials for structural end uses
GB2245922A (en) * 1990-06-05 1992-01-15 Colebrand Ltd A tile or sheeting
US5216864A (en) * 1991-10-31 1993-06-08 Chicago Metallic Corporation Unique zinc alloy strip design for the inhibition of moss and fungus
US5356664A (en) * 1992-09-15 1994-10-18 Minnesota Mining And Manufacturing Company Method of inhibiting algae growth on asphalt shingles
US5411803A (en) * 1992-09-15 1995-05-02 Minnesota Mining And Manufacturing Company Granular materials having an improved ceramic coating, methods of preparing same, and composite sheets including same
EP0727542A1 (en) * 1995-02-15 1996-08-21 Hugo Weber Roof panel and method for its manufacturing
EP0869228A3 (en) * 1997-04-01 2000-10-25 Hugo Weber Roof cleaning panel
DE19904648A1 (en) * 1999-02-05 2000-08-31 Alexander Faller Roof covering treated with agent for prevention of plant growth, especially copper compound, useful for avoidance of premature roof damage
US6214466B1 (en) 1999-07-28 2001-04-10 Isp Investments Inc. Algae-resistant roofing granules
DE19954752A1 (en) * 1999-10-22 2001-04-26 Viktor Rein Device for prevention and removal of deposits on roof coverings, especially roof tiles, has elements of metal or metal compound fitted by fastening device on ridge or other highest-most point of roof
US20030091795A1 (en) * 2000-06-08 2003-05-15 Matti Kiik Metal flake-surfaced roofing materials
US8197893B2 (en) 2000-06-08 2012-06-12 Building Materials Investment Corporation Colored metal flake surfaced roofing materials
US20090291260A1 (en) * 2000-06-08 2009-11-26 Matti Kiik Metal Flake-Surfaced Roofing Materials
US20090117329A1 (en) * 2000-06-08 2009-05-07 Leitch Olan T Colored Metal Flake Surfaced Roofing Materials
US20050183220A1 (en) * 2002-08-11 2005-08-25 Hugo Weber Cleaning system designed to be installed on a surface that is exposed to poor weather conditions
WO2004037723A3 (en) * 2002-10-21 2004-06-03 Elk Premium Building Prod Inc Metal flake-surfaced roofing materials
WO2004037723A2 (en) * 2002-10-21 2004-05-06 Elk Premium Building Products, Inc. Metal flake-surfaced roofing materials
US6838152B2 (en) 2003-01-21 2005-01-04 Isp Investments Inc. Low pigments costs algae-retardant roofing granule products containing metallic copper
US20040139886A1 (en) * 2003-01-21 2004-07-22 Isp Investments Inc. Low pigments costs algae-retardant roofing granule products containing metallic copper
US20040247831A1 (en) * 2003-06-04 2004-12-09 Nakagawa Chemical Inc. Decorative sheet
US20060035582A1 (en) * 2004-08-10 2006-02-16 Collister Kenneth F Ridge vent with biocidal source
US8333639B2 (en) 2004-08-10 2012-12-18 Collister Kenneth F Ridge vent with biocidal source
US20070020436A1 (en) * 2005-02-25 2007-01-25 Teng Yihsien H Roofing shingle containing algae inhibiting metallic particles
US20060194023A1 (en) * 2005-02-25 2006-08-31 Teng Yihsien H Algae resistant shingle
DE102005027625A1 (en) * 2005-06-15 2007-01-04 Aktiv-First Gmbh Mechanism for preventing or killing of vegetation on a sloped sloped brick- and reed roof, comprises two different metal surface elements formed with perforation holes, napped texture and water storage folding
US20080131664A1 (en) * 2006-07-26 2008-06-05 Teng Yihsien H Roofing shingle having agglomerated microorganism resistant granules
US7788870B1 (en) 2006-12-20 2010-09-07 David Spencer Method and roofing strip for retarding moss, fungi, and algae growth on roofs
US8703166B1 (en) 2011-01-20 2014-04-22 John Flynn Systems and methods for reducing microbial growth
US10000931B1 (en) 2016-12-13 2018-06-19 Daniel T. Daugherty Apparatus and method for moss remediation
US11105097B2 (en) 2019-12-19 2021-08-31 Eraserspacer Llc Roofing panel for concealing a biocidal source

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