US3471343A - Process for the production of sinter iron materials - Google Patents

Process for the production of sinter iron materials Download PDF

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Publication number
US3471343A
US3471343A US547778A US3471343DA US3471343A US 3471343 A US3471343 A US 3471343A US 547778 A US547778 A US 547778A US 3471343D A US3471343D A US 3471343DA US 3471343 A US3471343 A US 3471343A
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United States
Prior art keywords
molybdenum
tons
cobalt
sintered
briquetting
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Expired - Lifetime
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US547778A
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English (en)
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Max Koehler
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Individual
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16KVALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
    • F16K25/00Details relating to contact between valve members and seats
    • F16K25/005Particular materials for seats or closure elements
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • C22C33/0257Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • C22C33/0285Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02FCYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F1/00Cylinders; Cylinder heads 
    • F02F1/18Other cylinders
    • F02F1/20Other cylinders characterised by constructional features providing for lubrication
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/12Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • F16C33/121Use of special materials

Definitions

  • This invention relates to wear resistant materials suitable for the production of sleeve valves and valve seating rings.
  • the present invention relates to a wear resistant material which is suitable for sleeve Valves and valve seating rings, said material being produced generally in accordance with my above referred-to method.
  • an addition of 0.5 to 5% of nickel is made to the sinter iron which contains approximately 1 to 4% of lead, before it is subjected to the described method.
  • the material produced in this manner is of increased forgeability and is therefore also particularly suited to the rolling, pressing and drawing of pipes.
  • the material has a coefficient of expansion which is in the range of that of cylinder heads made from light metals, so that the material is particularly suited for valve sleeves and valve seating rings.
  • the strength of the material when compared with a material having no addition of nickel, is increased by 20% and expansion is increased by approximately i.e. from 2% to 4%.
  • a sintered alloy material having the following composition:
  • the mate-rial should have an increased resistance to heat, i.e., sufiicient strength at temperatures up to 600 C. It has now been found quite unexpectedly that a material which has been subjected to the treatment described above has a heat resistance of over 200 Brinell up to 600 C., if in accordance with a preferred feature of the invention it contains, in addition to 1 to 4% of lead and 0.5 to 5% of nickel, amounts of cobalt and molybdenum in a ratio of from 8:1 prior to treatment, the molybdenum content amounting to 1.2 to 1.8%.
  • valve seating rings particularly suitable for metor vehicle exhausts can be produced from a material remainder iron, approximately 82% with the normal Sma l amount of impurities.
  • the mixed powder was subjected to briquetting at a pressure of 3.5 tons/cmf whereupon it was sintered at a temperature of 1100 C. in a neutral furnace atmosphere for three hours. Analysis of the unworked pieces revealed the following composition:
  • the unworked pieces were then subjected to a cold compression at a pressure of 12 tons/cmF, brought to a temperature of 830 C. for 15 minutes and t'hen quickly cooled and tempered for 30 minutes at 80 C., whereupon the Brinell strength of the material was approximately 250 kg./mm. at normal temperature (20 C.) and lower than 100 kg./mm. at a temperature of 600 C.
  • the specific gravity had risen from 6.7 to 7.3.
  • the bending limit was 46.3 kg./mm.
  • the sintered pieces were cooled, subjected to a cold compression at a pressure of 12 tons/cm. and heated for a. time period of 15 minutes to a temperature above the Ac 3-point; after quickly cooling they were finally tempered at temperatures of 580 C. for 30 minutes.
  • the Brinell strength of the material was about 320 kg./mm. at normal temperature (20 C.) and about 205 kg./mm. at a temperature of 600 C.
  • the sinter iron materials are generally briquetted at a pressure of from 3 to 5 tons/cm.
  • the briquette is typically sintered at a temperature of from 1050 C. to 1150 C. for a time period of approximately from 2 to 4 hours.
  • the sintered briquette is subsequently compressed at pressures from 10 to 15 tons/cm.
  • the final tempering step is conducted at temperatures of from 550 to 650 C. for a time period of from 20 to 40 minutes.
  • a method of producing sinter powder metal iron materials which includes the steps of: to the total of iron powder to be processed admixing of from 0.8 to 1.5 of graphite, of from 1 to 4% of lead, and of from 0.5 to 5% of nickel, adding cobalt and molybdenum thereto in mixture ranging from 9.6 to 14.4% of cobalt and from 1.2 to 1.8% of molybdenum for increasing heat resistant stability of the sinter materials up to substantially 600 C., briquetting the thus obtained mixture at a pressure of from 3 to 5 ton-s/cm. sintering the briquetted material at a temperature of from 1,050" C. to 1,150 C.
  • a sintered heat treated alloy material composed of from 0.8 to 1.5% of C, from 0.15 to 0.2% of Si, from 0.12 to 0.18% of Mn, from 0.02 to 0.03% of P, from 0.3 to 0.4% of Sn, from 0.5 to 1.0% of Cu, from 1.0 to 4.0% of Pb, from 0.5 to 5% of Ni, from 1.2 to 1.8% Mo, from 9.6 to 16.2% C0 and the remainder Fe.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Powder Metallurgy (AREA)
US547778A 1965-05-07 1966-05-05 Process for the production of sinter iron materials Expired - Lifetime US3471343A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1013165 1965-05-07

Publications (1)

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US3471343A true US3471343A (en) 1969-10-07

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ID=11133918

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US547778A Expired - Lifetime US3471343A (en) 1965-05-07 1966-05-05 Process for the production of sinter iron materials

Country Status (4)

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US (1) US3471343A (en, 2012)
BE (1) BE680620A (en, 2012)
GB (1) GB1088588A (en, 2012)
SE (1) SE309676B (en, 2012)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3711341A (en) * 1970-05-04 1973-01-16 Ibm Method of making sintered metal ultrasonic bonding tips
US3793691A (en) * 1971-09-02 1974-02-26 Nippon Piston Ring Co Ltd Thermal and abrasion resistant sintered alloy
US3795961A (en) * 1971-09-02 1974-03-12 Nippon Piston Ring Co Ltd Thermal and abrasion resistant sintered alloy
DE2401315A1 (de) * 1973-01-11 1974-07-18 Honda Motor Co Ltd Ventilsitzmaterial fuer eine brennkraftmaschine
US3837816A (en) * 1972-09-05 1974-09-24 Nippon Piston Ring Co Ltd Thermal and abrasion resistant sintered alloy
US3856478A (en) * 1971-12-22 1974-12-24 Mitsubishi Motors Corp Fe-Mo-C-{8 Cr{9 {0 SINTERED ALLOYS FOR VALVE SEATS
US3948652A (en) * 1971-05-18 1976-04-06 Siemens Aktiengesellschaft Contact material for high-power vacuum circuit breakers
US3977838A (en) * 1973-06-11 1976-08-31 Toyota Jidosha Kogyo Kabushiki Kaisha Anti-wear ferrous sintered alloy
US4049429A (en) * 1973-03-29 1977-09-20 The International Nickel Company, Inc. Ferritic alloys of low flow stress for P/M forgings
US4251274A (en) * 1978-06-29 1981-02-17 Bleistahl G.M.B.H. Metal powder composition
DE3227549A1 (de) * 1982-07-23 1984-01-26 Schunk & Ebe Gmbh, 6301 Heuchelheim Werkstoff zur pulvermetallurgischen herstellung von ventilsitzringen
DE3413593C1 (de) * 1984-04-11 1985-11-07 Bleistahl GmbH, 5802 Wetter Verfahren zur Herstellung von Ventilsitzringen
US4696696A (en) * 1985-06-17 1987-09-29 Nippon Piston Ring Co., Ltd. Sintered alloy having improved wear resistance property
US5256184A (en) * 1991-04-15 1993-10-26 Trw Inc. Machinable and wear resistant valve seat insert alloy

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2315565A (en) * 1940-09-14 1943-04-06 Wilson H A Co Bimetallic element
US2741827A (en) * 1950-12-22 1956-04-17 August H Schilling Process for the manufacture of piston rings by powder metallurgy and articles obtained thereby
US2759810A (en) * 1950-10-20 1956-08-21 Koehler Max Articles of sintered iron and method of making same
US2816052A (en) * 1953-11-07 1957-12-10 Hoesch Westfalenhutte Ag Method of manufacturing ribbed steel rods
US2842471A (en) * 1950-12-22 1958-07-08 August H Schilling Powder metallurgy and piston rings obtained thereby
US2882190A (en) * 1954-07-19 1959-04-14 Gen Motors Corp Method of forming a sintered powdered metal piston ring
US3093519A (en) * 1961-01-03 1963-06-11 Int Nickel Co Age-hardenable, martensitic iron-base alloys

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2315565A (en) * 1940-09-14 1943-04-06 Wilson H A Co Bimetallic element
US2759810A (en) * 1950-10-20 1956-08-21 Koehler Max Articles of sintered iron and method of making same
US2741827A (en) * 1950-12-22 1956-04-17 August H Schilling Process for the manufacture of piston rings by powder metallurgy and articles obtained thereby
US2842471A (en) * 1950-12-22 1958-07-08 August H Schilling Powder metallurgy and piston rings obtained thereby
US2816052A (en) * 1953-11-07 1957-12-10 Hoesch Westfalenhutte Ag Method of manufacturing ribbed steel rods
US2882190A (en) * 1954-07-19 1959-04-14 Gen Motors Corp Method of forming a sintered powdered metal piston ring
US3093519A (en) * 1961-01-03 1963-06-11 Int Nickel Co Age-hardenable, martensitic iron-base alloys

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3711341A (en) * 1970-05-04 1973-01-16 Ibm Method of making sintered metal ultrasonic bonding tips
US3948652A (en) * 1971-05-18 1976-04-06 Siemens Aktiengesellschaft Contact material for high-power vacuum circuit breakers
US3793691A (en) * 1971-09-02 1974-02-26 Nippon Piston Ring Co Ltd Thermal and abrasion resistant sintered alloy
US3795961A (en) * 1971-09-02 1974-03-12 Nippon Piston Ring Co Ltd Thermal and abrasion resistant sintered alloy
US3856478A (en) * 1971-12-22 1974-12-24 Mitsubishi Motors Corp Fe-Mo-C-{8 Cr{9 {0 SINTERED ALLOYS FOR VALVE SEATS
US3837816A (en) * 1972-09-05 1974-09-24 Nippon Piston Ring Co Ltd Thermal and abrasion resistant sintered alloy
DE2401315A1 (de) * 1973-01-11 1974-07-18 Honda Motor Co Ltd Ventilsitzmaterial fuer eine brennkraftmaschine
US4049429A (en) * 1973-03-29 1977-09-20 The International Nickel Company, Inc. Ferritic alloys of low flow stress for P/M forgings
US3977838A (en) * 1973-06-11 1976-08-31 Toyota Jidosha Kogyo Kabushiki Kaisha Anti-wear ferrous sintered alloy
US4251274A (en) * 1978-06-29 1981-02-17 Bleistahl G.M.B.H. Metal powder composition
DE3227549A1 (de) * 1982-07-23 1984-01-26 Schunk & Ebe Gmbh, 6301 Heuchelheim Werkstoff zur pulvermetallurgischen herstellung von ventilsitzringen
DE3413593C1 (de) * 1984-04-11 1985-11-07 Bleistahl GmbH, 5802 Wetter Verfahren zur Herstellung von Ventilsitzringen
US4696696A (en) * 1985-06-17 1987-09-29 Nippon Piston Ring Co., Ltd. Sintered alloy having improved wear resistance property
US5256184A (en) * 1991-04-15 1993-10-26 Trw Inc. Machinable and wear resistant valve seat insert alloy

Also Published As

Publication number Publication date
BE680620A (en, 2012) 1966-10-17
SE309676B (en, 2012) 1969-03-31
GB1088588A (en) 1967-10-25

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