Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
  • D06M15/29—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing a N-methylol group or an etherified N-methylol group; containing a N-aminomethylene group; containing a N-sulfidomethylene group
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
  • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
  • C08F20/52—Amides or imides
  • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
  • C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
  • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
  • C08F220/10—Esters
  • C08F220/12—Esters of monohydric alcohols or phenols
• • C—CHEMISTRY; METALLURGY
  • C14—SKINS; HIDES; PELTS; LEATHER
  • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
  • C14C11/00—Surface finishing of leather
  • C14C11/003—Surface finishing of leather using macromolecular compounds

Definitions

• Aqueous leather coating dispersions are prepared from polymers of alkyl acrylates, acrylic acid and N-methylolmethacrylamide.
• the copolyrners are prepared using a critical weight ratio of at least 80% ethyl acrylate and not more than 15% by weight acrylic acid, and 1 to 5% by weight of N-methylolmethacrylamide.
• the invention disclosed in this application relates to copolymers of acrylates, acrylic acid and N-methylolmethacrylamide and aqueous dispersions of copolymers of this type.
• the invention also relates to leather whose surface has been coated with a copolymer of acrylates, acrylic acid and N-methylolmethacrylamide.
• copolymer dispersions produced by the copolymerization of water-insoluble monomers and polymerizable acids, such as acrylic or methacrylic acid, for the finishing of fibrous materials is well known. Films formed by dispersions of this type generally have good adhesion on the fibrous material. It is also well known that dispersions of copolymers in which large quantities of acrylic acid have been incorporated by polymerization can in some cases be made highly viscous by addition of aqueous ammonia.
• This possibility of thickening the dispersions is often very useful for the finishing of fibrous materials, because the filling efiect and the film forming power in crease with rising viscosity, and also because the viscous dispersions have less tendency to penetrate into the fibrous material.
• Dispersions prepared in the normal manner from copolymers of waterinsoluble monomers and large quantities of acrylic or methacrylic acid are, however, susceptible to the coagulating effect of mechanical and/or thermal stresses and to additions of electrolytes and pigments, and this susceptibility generally increases in proportion to the amount of acrylic or methacrylic acid which has been polymerized into the copolymer.
• Object of this invention are copolymers from acrylates, acrylic acid and N-methylolmethacrylamide which form stable dispersions in water.
• a further object of this invention are stable aqueous dispersions of copolymers from acrylates, acrylic acid and N-methylolmethacryiamide.
• Another object of this invention are aqueous dispersions of copolymers from acrylates, acrylic acid and N-methylolmethacrylamide which are useful for the finishing of fibrous materials, in particular the surface of leather.
• Another object of this invention is leather whose surface has been improved by treatment with aqueous dispersions of copolymers of acrylates, acrylic acid and N-methylolmethacrylamide.
• another object of the invention is to provide coatings and in particular leather finishes having an improved resistance to acetone and hot plating by treatment with copolymers of acrylates, acrylic acid and N-methylolmethacrylamide. Further objects of the invention will become apparent to those skilled in the art.
• copolymers of at least by weight of ethyl acrylate, 1 to 5% of N-methylolmethacrylamide and acrylic acid, and films prepared from them exhibit excellent resistance to acetone and hot plating, when the copolyrners contain at least 7.5% and particularly from 7.5 to 15% by weight of acrylic acid units. These copolymers are of particular interest in the finishing of leather.
• aqueous dispersions thus prepared have good stability, even when they contain a large proportion of acrylic acid.
• finishes on the treated fibrous materials have good resistance to solvents.
• the copolyiner dispersions are new. As described in the following, they can be prepared by copolymerization of the said monomers in aqueous emulsion.
• Suitable catalysts are the common peroxide-type compounds, e.g. persulfates such as potassium persulfate or ammonium per-sulfate, and redox systems or mixtures of various catalysts.
• Suitable emulsifying agents are the common surface-active substances, such as fatty acid salts, alkyl sulfonic acid salts, salts of sulfuric semi-esters of long chain alcohols, etc. These emulsifying agents can be used in mixtures With one another or together with protective colloids.
• a particularly advantageous process for the production of these dispersions is to charge a vessel with water, polymerization catalysts, and if necessary, emulsifying agents and other auxiliary materials, and then to add the monomers at a pH value smaller than 5.5 at a rate corresponding to the progress of polymerization.
• the preferred emulsifying agents for this purpose are ammonium salts and/or alkali salts of sulfuric semi-esters of oxyalkylation products. They are placed in the polymerization vessel either before addition of the monomers or simultaneously or together with the monomers.
• Suitable alkali salts are in particular sodium and potassium salts.
• Oxyalkylation products in the present invention refers to materials which are produced by reaction of ethylene oxide or propylene oxide with higher alcohols, with higher carboxylic acids or their amides or imides and with alkylphenols or sulfonamides and sulfonirnides.
• Such salts of sulfuric semi-esters are well known emulsifying agents, and one method of producing them is to react saturated or unsaturated fatty alcohols or fatty acids with at least 12 carbon atoms or resin acids with 5 to 40 mole equivalents of ethylene oxide or propylene oxide, then sulfonate the oxyalkylation products and neutralize wholly or partially with alkali or ammonia,
• Suitable fatty alcohols, fatty acids or resin acids are, e.g., coconut oil alcohols,
• sperm oil alcohol wax alcohol
• sperm oil fatty acid stearic acid, oleic acid, ricinoleic acid, and abietic acid and corresponding products or paraflin wax oxidation.
• Mixtures of such materials are also suitable.
• fatty alcohols or carboxylic acids it is also possible to use amides of carboxylic acids, such as the amides of stearic, oleic, sperm oil or ricinoleic acid, or sulfonamides, such as sulfanilide and cyclohexylsulfamide.
• alkali salts or ammonium salts of sulfuric semi-esters which have been prepared in a similar manner from reaction products of alkylphenols whose straight-chain or branched alkyl residues contain 6 to 20 carbon atoms, with 9 to 60 mole equivalents or ethylene oxide or propylene oxide.
• Suitable alkylphenols are, e.g., isooctylphenols and isooctylnaphthols and decyland dodecylphenols and decyland dodecylnaphthols.
• emulsifying agents such as alkylsulfonates, sulfuric semi-esters of higher alcohols or non-ionic emulsifying agents, can of course also be employed together with the emulsifying agents mentioned above. In most cases, however, emulsions of copolymers of the indicated composition are obtained and these are less suitable from aspects of application.
• Auxiliaries in this case refers to the usual materials employed as additions, such as buffer substances and polymerization control substances.
• the proportion of acrylates should preferably be 'between 80 and 95% by weight.
• the esters of alkanols with 2 to 4 carbon atoms are of particular interest, and the copolymers of ethyl acrylate are particularly suitable for the finishing of leather.
• the proportion of acrylic acid should preferably be to 15% by weight, and the proportion of N-methylolmethacrylamide should preferably be 1 to 5% by weight.
• the copolymers may also contain up to 30% by weight, calculated on the total amount of monomers, of other monomers incorporated by polymerization.
• examples of such other monomers are methacrylates, maleic and fumaric esters, itaconic esters,-
• the proportion of these monomers should preferably not exceed 25% by weight, as these monomers should not cause any fundamental change of the properties of the copolymers of the three monomers which are absolutely necessary.
• the polymers may also contain up to 25% by weight, calculated on the quantity of N-methylolacrylamide, or other N-methylol compounds, such as' N-methylolacrylamide, N- methylolmaleinimide and N-methylolacryloyl urea incorporated by polymerization.
• Dispersions of polymers containing up to 25 by weight, calculated on the quantity of acrylic acid, of other short-chain ethylene-unsaturated monoand/or dicarboxylic acids, such as in particular methacrylic acid and also maleic acid, fumaric acid, or itaconic acid incorporated by polymerization are also suitable.
• dispersions of copolymers containing up to 70% by weight of methacrylic acid incorporated by polymerization, calculated on the amount of acrylic acid are also suitable.
• the quantity of ethylenically unsaturated acids incorporated by polymerization should, however, not exceed 15% by weight, calculated on the total amount of monomers.
• copolymers may, of course, be prepared from several of the acrylates mentioned above, for example 4 methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl and tertiary butyl acrylates in the proportions indicated above.
• copolymers containing 60 to 96.5% by weight, calculated on the total amount of monomers, of ethyl acrylate, 5 to 15% by weight, cal
• copolymers may contain up to 25% by weight, calculated on the amount of ethyl acrylate, of other polymerizable ethylenically unsaturated monomers, in particular methacrylates of alcohols with l to 4 carbon atoms, methyl, propyl, n-butyl, isobutyl, and tertiary butyl acrylate and acrylonitrile, and also maleic and fumaric esters, itaconic esters, vinyl acetate, vinyl chloride, and vinylidene chloride incorporated by polymerization.
• Aqueous dispersions of these copolymers can also be used advantageously for the surface coating of leather.
• the content of copolymers in the dispersions may vary within wide limits. After preparation of the dispersions it should preferably be between 30 and 50% by weight. When the viscosity is measured at 20 C. in accordance with DIN 53211, the dispersions of the copolymers at pH values between 2 and 6 and a copolymer concentration of 40% by weight show a flow-out rate of 10 to 20 seconds in a Ford cup with an orifice of 4 mm. diameter. Before or during their application, the dispersions may be diluted and/or additional materials may be added if necessary.
• the degree of dilution depends on the specific some cases be sufficient if the'mixture used consisting of' copolymer dispersion and the usual additional materials has a copolymer concentration of only 1% by weight.
• dispersions containing 10 to 20% by weight, calculated on the total weight of dispersion, of copolymer are used for the preparation of mixtures which are suitable for'the surface coating of leather and which consist of dispersion and the usual additional materials.
• higher concentrations, i.e., up to 50% by weight, or lower concentrations, i.e., down to 5% by weight, of copolymer in the dispersion may be of advantage.
• copolymers themselves are of high-molecular weightand film-forming. They can be characterized by the elongation at rupture of films of the copolymers. Films of the copolymers show an ultimate elongation of 250 to l000%, measured according to DIN 53371.
• polymers containing to by weight of ethyl acrylate, 5 to 15% by weight of acrylic acid, and 1 to 5% by weight of N-methylolmethacrylamide form from aqueous dispersions containing up to 50% by weight of copolymer, even at room temperature, films with an ultimate elongation of 500 to 800%, measured in accordance with DIN 53371.
• Such copolymers are of par- 7 ticular interest and are therefore preferred.
• those copolymers and films prepared from them which contain at least 7.5% and particularly 7.5 to 15% of acrylic acid units are markedly superior to those which contain only 5% or less of acrylic acid units with regard to resistance to acetone and hot plating.
• Films of the copolymers also have a tensile strength of 10 to kg./sq. cm., measured in accordance with DIN 53371. When immersed in water at room temperature for 5 hours, they absorb 1 to 40% of their weight of water. Films of copolymers containing 80 to 95% by weight of ethyl acrylate, 5 to 15% by weight of acrylic acid, and 1 to 5% by weight of N-rnethylolmethacrylamide show an exceptionally useful water absorption. When immersed for 5 hours in water at room tempera ture, they absorb 1 to 10 by Weight. This is an advantage particularly in the use of the copolymer dispersions for the coating of leather surfaces. 7
• the dispersions are eminently suitable for the permanent finishing of fibrous materials consisting of an arranged or random systems of natural and/or man-made fibers. They are particularly suitable as bonding agents for fibrous webs and felts and for the permanent finishing of textiles, because they yield finishes with exceptionally good resistance to solvents when subjected to a thermal after-treatment. Used as textile finishes the dispersions yield, for instance, finishings which are resistant to solvents, tearing, and wet rubbing.
• the leather finishes thus obtained are characterized by their exceptional lustre, excellent break, elasticity, fastness to hot plating, and resistance to abrasion and acetone. Dispersions thickened with aqueous ammonia solutions are useful mainly for the finishing of split leather.
• aqueous dispersions of copolymers containing 80 to 95% by weight of ethyl acrylate, to 15%, especially 7.5 to 15%, by weight of acrylic acid, and 1 to 5% by weight of N-methylolmethacrylamide are particularly suitable.
• EXAMPLE 1 A mixture containing 150 parts of distilled Water, 0.6 part of potassium persulfate, 1.5 parts of a 35% by weight aqueous solution (1) of the sodium salt of a. sulfonated reaction product of isooctylphenol with 25 mole equivalents of ethylene oxide, prepared in the usual manner, and 24 parts of a 50% by weight aqueous solution (2) of the sodium salt of a sulfonated castor oil, prepared in the usual manner, is heated to 80 C.
• a solution of 0.2 part of potassium persulfate in parts of water is then added to the reaction mixture, and the temperature is maintained at 80- C. for a further 30 minutes.
• About 10 parts of water and Volatile components of the reaction mixture are then distilled over at 90 C. in a stream of nitrogen, and the mixture is allowed to cool.
• the dispersion obtained has a pH of 3.
• this dispersion 150 parts of this dispersion are mixed with a mixture containing 50 parts of a 10% by weight aqueous casein solution, 45 parts of iron oxide pigment and 200 parts of water, and the mixture is brushed on grain leather.
• the coating is dried and then plated at 60-80 C. at a pressure of 100 atm. with the aid of a standard leather plating machine.
• a leather finish is obtained which has a very good surface lustre, and good covering power, abrasion resistance and fastness to hot plating.
• the leather finish also has substantially good resistance to acetone.
• the dispersion can be thickened very extensively by addition of ammonia, and it can be used in the thickened condition for the finishing of split leather.
• EXAMPLE 2 In a manner analogous to that described in Example 1, 85.5 parts of ethyl acrylate, 13 parts of acrylic acid and 1.5 parts of N-methylolmethacrylamide are polymerized in an aqueous emulsion in such a manner that a 40% by weight aqueous dispersion of a copolymer of these monomers is obtained.
• the dispersion obtained (referred to in the following as Dispersion D) is very suitable for the surface coating of leather.
• the leather is then dried and plated.
• a mixture H of parts of Dispersion D, 400 parts of water, 100 parts of casein pigment finish C, 50 parts of 17% by weight aqueous casein solution having pH 8, and 5 parts of a mixture of equal parts of water and sulfated castor oil is then applied to the bottomed surface of the leather, again by plush-padding.
• Another coating of mixture 11 is sprayed on the treated surface.
• the coating is fixed by treatment with a fixing solution B containing 300 parts of a 35% by weight aqueous formaldehyde solution, 650 parts of water, and 50 parts of 33% by weight acetic acid.
• a mixture 111 containing 150 parts of a 17% by weight aqueous casein solution having pH 8, 835 parts of Water, and 15 parts of a mixture of equal parts of water and sulfated castor oil is then sprayed on the treated surface of the leather. After drying, the coating is again fixed with the fixing mixture B; this is followed by plating.
• the leather obtained has a smooth hand and good fastness to wet and dry rubbing. It can be used for the production of shoes, in which application it withstands plating temperatures of at least 150 C.
• Dispersion E is very suitable for the surface coating of leather.
• a mixture 1 containing 200 parts of Dispersion E, 100 parts of the casein pigment finish C described in Example 2 and 400 parts of water is plush-padded as an undercoat to the grain side of corrected grain side leather. This is followed by drying and plating.
• EXAMPLE 4 In a manner analogous to that described in Example 1, a 40% by weight aqueous dispersion of a copolymer is prepared from 80 parts of ethyl acrylate, 14 parts of acrylic acid, 4 parts of acrylonitrile and 2 parts of N- rnethylolmethacrylamide. A dispersion, referred to in the following as Dispersion G, is obtained which is very suitable for the surface coating of leather.
• a mixture I containing 50 parts of Dispersion G, 2.5 parts of borax, 970 parts of water, 20 parts of a 20% by Weight wax emulsion and 30 parts of a pigment finish containing parts of carbon black, 10 parts of casein and 10 parts of a mixture of equal parts of Water and sulfated castor oil is plush-padded on the calf leather. After drying and polishing, another amount of mixture I is plush-padded onto the treated surface of the leather, and then dried in the air. A further amount of mixture I is then sprayed on. The coatings are fixed by treatment with the fixing mixture B described in Example 2, and dried.
• a mixture II containing 80 parts of a by Weight aqueous casein solution having pH 8, 860 parts of water and 10 parts of a mixture of equal parts of water and sulfated castor oil is then applied by spraying. This coating is also fixed by treatment with fixing mixture B. After drying and glazing, a leather is obtained which has a supple hand, high luster, very fine break and good aging resistance. r a
• Dispersion H A dispersion, referred to in the following as Dispersion H, is obtained which is very suitable for the surface coating of leather.

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Organic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• General Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Treatment And Processing Of Natural Fur Or Leather (AREA)
• Paints Or Removers (AREA)

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Citations (6)

• 0
  • NL NL278787D patent/NL278787A/xx unknown
• 1961
  • 1961-05-24 DE DE19611419373 patent/DE1419373A1/de not_active Ceased
• 1962
  • 1962-05-18 CH CH1027362A patent/CH408416A/de unknown
  • 1962-05-18 CH CH605262A patent/CH402803A/de unknown
  • 1962-05-23 GB GB1980062A patent/GB950153A/en not_active Expired
  • 1962-05-24 BE BE618056A patent/BE618056A/fr unknown
  • 1962-05-24 FR FR898666A patent/FR1325985A/fr not_active Expired
  • 1962-05-24 AT AT425962A patent/AT238678B/de active
• 1966
  • 1966-08-24 US US57453866 patent/US3361695A/en not_active Expired - Lifetime

Patent Citations (6)

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