US3314766A - Sulfur burner - Google Patents

Sulfur burner Download PDF

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US3314766A
US3314766A US328717A US32871763A US3314766A US 3314766 A US3314766 A US 3314766A US 328717 A US328717 A US 328717A US 32871763 A US32871763 A US 32871763A US 3314766 A US3314766 A US 3314766A
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sulphur
combustion
chamber
burner
gas
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US328717A
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Jyoti P Mukherji
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Walchandnagar Industries Ltd
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Walchandnagar Industries Ltd
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Priority claimed from GB4769863A external-priority patent/GB1035457A/en
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/48Sulfur dioxide; Sulfurous acid
    • C01B17/50Preparation of sulfur dioxide
    • C01B17/54Preparation of sulfur dioxide by burning elemental sulfur

Definitions

  • the feeder valve which regulates the level of the molten sulphur in the combustion chamber is operated by a valve rod.
  • the present invention has for its object improvements whereby (i) the supply of air to the combustion chamand (v) the feeder valve whereby the level of the molten sulphur is regulated, may be more conveniently operated.
  • one aspect of this invention consists of a sulphur burner which has, in combination a combustion chamber wherein the combustion of sulphur will take place over a pool of molten sulphur contained in the said combustion chamber, a gas chamber above the said combustion chamber, means whereby the level of the 3,314,766 Patented Apr. 18, 1967 the best possible combustion of sulphur.
  • the cylindrical wall of the combustion chamber is provided with fins which will help to dissipate heat faster and thus maintain the temperature of the combustion at a temperature which is not too high.
  • a further improvement according to this invention consists in providing a sight glass (corresponding to the observation pipe fitted on the wall of the sulphur burner already proposed) and in locating the said sight glass on top of the gas chamber. This new position gives a better sight of the phenomena taking place inside the gas chamber, as the said sight glass will be cooled by a constant stream of air moving downwards, thereby preventing the diffusion of the sulphur gas and the deposition of sulphur thereon.
  • the feeder valve of the sulphur burner is operated by a lever located at the bottom of the burner, instead of being operated by a valve rod. This is a more convenient arrangement from the operation point of View.
  • the gas outlet pipe of the gas chamber is located tangentially at the top of the said chamber, instead of being located at the bottom thereof.
  • the tangential arrangement of the primary and secondary air connections and of the gas outlet gives the gases a long spiral path inside the gas chamber thus helping to complete combustion of sulphur.
  • FIG. 1 is a diagrammatic elevation, partly in section of an improved sulphur burner according to this invention.
  • the said hopper 4 and the said feeder 7 are provided with a steam jacket 5 into which steam may be led through the inlet 3.
  • the steam jacket 5 is provided with a safety valve 23 and a condensate outlet 9.
  • the transfer of the molten sulphur from the hopper 4 to the feeder 7 is controlled by the hopper valve 6 which can be operated by the lever 2 and the transfer of the molten sulphur from the feeder 7 through the feed pipe is controlled by the feeder valve 8.
  • the feeder 7 is provided at its bottom with a feed pipe 14 which extends into the combustion chamber 15, and on the feed pipe 14 is rotatably mounted a level control L- shaped pipe 13 which communicates with the feed pipe 14.
  • the tips of the feed pipe 14 and the control pipe 13 will be substantially at the same level when the control pipe 13 is held in the vertical position.
  • the level of the terminal end of control pipe 13 can, however, be moved in the vertical plane by rotating handle attached to the level controlling shaft 24 the opposite end of which is secured to L-shaped pipe 13.
  • the said shaft 24 is introduced into the combustion chamber 15 through a stuffing box 11.
  • the combustion gases from the said combustion chamber will be able to enter the feed pipe 14 and, if the feeder valve 8 is open, the said gases wil enter the feeder 7 and cause the molten sulphur from the said feeder to descend into the combustion chamber 15 until the said tips are submerged in the molten sulphur in the combustion chamber.
  • the level control pipe 13 in the vertical plane, it will be possible to vary the level of the molten sulphur in the combustion chamber and to maintain it at any desired height.
  • the conical combustion trough 16 is positioned directly underneath the gas chamber 18 and, therefore, in the vapourization zone of the combustion chamber 15.
  • the combustion chamber 15 and the gas chamber 18 are joined through a constricted area 34. Since vapourization occurs only from the surface, it will be directly related to the area of the surface of the molten sulphur in the vapourization zone, and the said area in its turn will vary with the level of the molten surface maintained in the combustion chamber 15 around the conical trough 16.
  • the level of the molten sulphur in the combustion chamber 15 the area of the surface of the molten sulphur in the vapourization zone, and consequently, the rate of vapourization and combustion of the sulphur may be varied without causing any fluctuation of the air supply for the purpose.
  • the conical trough 16 is jacketed on its underside so that a cooling fluid such as water or air can be supplied through a connection 16A and the hot fluid let out through outlet 16B.
  • a cooling fluid such as water or air
  • the air supply pipe 17 is fitted at the bottom of the gas chamber 18, so that the sulphur vapours produced in the vapourization zone may be intimately mixed with the air supply, for undergoing combustion in the gas chamber 18.
  • the air supply pipe 17, which is provided with a U- bend 17A, can effect, through the arm 173 a primary air supply in the region of the combustion trough 16, and through the arm 17C a secondary air supply in the region where the combustion of the primary products of combustion will be completed.
  • This arrangement of supplying air in two stages is advantageous, particularly where liquid or solid fuels are concerned.
  • the primary air helps to convert the solid or liquid fuel into primary products of combustion which are gaseous in nature, and the secondary air supplied at a later stage helps to complete the combustion.
  • An important advantage of this two stage system of supplying air is that the combustion process can be completed with much less excess air than it all the air had been supplied in a single stage as in the original invention.
  • Each of the arms 17A and 17B is provided with a regulating mechanism 29, which can be of any well known type such as a regulating valve, or a variable-opening orifice plate.
  • a regulating mechanism 29 can be of any well known type such as a regulating valve, or a variable-opening orifice plate.
  • the fins 32 help to dissipate the heat of the combustion chamber 15 fast and thereby make it possible to maintain the temperature of the said chamber at a level which is not too high.
  • the sight glass 19 being located on top of the gas chamber 18, gives a good sight of the phenomena taking place inside the gas chamber 18.
  • the said sight glass 19 is cooled by a air moving downwards, and no sulphur vapour can towards the glass and get deposited thereon.
  • the lever 1 located at the bottom of the burner, for operating the valve 8, is found to be a very convenient arrangement for raising the said valve 8.
  • a further improvement according to this invention resides in the location of the gas outlet pipe 20, which as shown in the accompanying drawings, is located tangentially at the top of the gas chamber 18, instead of extending vertically above the gas chamber 18, as in sulphur burners of known construction.
  • a sulphur burner comprising a combustion chamber having a substantially vertical cylindrical side wall and an upwardly extending conical base whereby an annulus is formed therebetween, said annulus increasing in size from the bottom to the top of said conical base, means for controlling the surface level of a pool of molten sulphur contained in said combustion chamber whereby the surface area of said molten sulphur surrounding said conical base may be controlled thereby controlling the rate of vaporization and combustion of said sulphur, a gas chamber above said combustion chamber wherein combustion of sulphur takes place over said pool of molten sulphur contained in said combustion chamber, said combustion and gas chambers being joined through a cylindrical member of restricted cross section, means for supplying primary and secondary air to said sulphur burner, said primary air being supplied tangentially adjacent to the surface of said molten sulphur and said secondary air being supplied tangentially at said restriction, and a gas outlet pipe located tangentially at the top of said gas chamber whereby the gases follow a spiral path through said
  • a sulphur burner as claimed in claim 1 wherein valve means are provided in both said primary and secondary air supply means whereby the proportion of primary and secondary air may be varied to obtain proper combustion of sulphur.
  • a sulphur burner as claimed in claim 1 wherein means is provided adjacent the underside of said conical bottom wall of said combustion chamber to cool said conical bottom wall, said means comprising a system for circulating a cooling fluid.
  • a sulphur burner as claimed in claim 1 wherein said means for controlling the surface level of said molten sulphur in said combustion chamber comprises an enclosed molten sulphur reservoir and a feed pipe extending downwardly from said reservoir into said combustion chamber and terminating therein, the effective horizontal level of said feed pipe in said combustion chamber being adjustable whereby the surface level of said molten sulphur in said combustion chamber may be controlled.
  • a sulphur burner as claimed in claim 1 which is provided with a sight glass located on top of the gas chamber of the sulphur burner, on which sight glass may References Cited by the Examiner UNITED STATES PATENTS 1,364,716 1/1921 Clayton 23-278 2,310,173 2/1943 Chatelain et a1 23-278 X 2,994,368 8/1961 Jensen et a1. 158-91 FOREIGN PATENTS 146,297 7/1962 Russia.

Description

April 18, 1967 J. P. MUKHERJI SULFUR BURNER Filed Dec. 6, 1963 A l I \u MW gLm United States Patent 3,314,766 SULFUR BURNER Jyoti P. Mukherji, Poona, India, assignor to Walchandnagar Industries Limited, Poona, Maharashtra, India, a corporation of India Filed Dec. 6, 1963, Ser. No. 328,717 7 Claims. (Cl. 23-278) combustion chamber. 1 Other features of the said sulphur burner are as fol-' ows:
(i) The supply of air to its combustion chamber is effected by meansof an air supplying pipe fitted at the bottom of the gas chamber of the burner.
(ii) The discharge of the gases from the gas chamber is effected through a vertical pipe fitted at the top of the said gas chamber.
(iii) An observation pipe is fitted to the cylindrical wall of the gas chamber, whereby the phenomena taking place inside the said gas chamber may be inspected.
(iv) The feeder valve which regulates the level of the molten sulphur in the combustion chamber is operated by a valve rod.
The present invention has for its object improvements whereby (i) the supply of air to the combustion chamand (v) the feeder valve whereby the level of the molten sulphur is regulated, may be more conveniently operated.
With this object in view one aspect of this invention consists of a sulphur burner which has, in combination a combustion chamber wherein the combustion of sulphur will take place over a pool of molten sulphur contained in the said combustion chamber, a gas chamber above the said combustion chamber, means whereby the level of the 3,314,766 Patented Apr. 18, 1967 the best possible combustion of sulphur.
By another improvement according to this invention, the cylindrical wall of the combustion chamber is provided with fins which will help to dissipate heat faster and thus maintain the temperature of the combustion at a temperature which is not too high.
A further improvement according to this invention consists in providing a sight glass (corresponding to the observation pipe fitted on the wall of the sulphur burner already proposed) and in locating the said sight glass on top of the gas chamber. This new position gives a better sight of the phenomena taking place inside the gas chamber, as the said sight glass will be cooled by a constant stream of air moving downwards, thereby preventing the diffusion of the sulphur gas and the deposition of sulphur thereon.
By a further improvement according to this invention, the feeder valve of the sulphur burner is operated by a lever located at the bottom of the burner, instead of being operated by a valve rod. This is a more convenient arrangement from the operation point of View.
As another improvement according to this invention, the gas outlet pipe of the gas chamber is located tangentially at the top of the said chamber, instead of being located at the bottom thereof. The tangential arrangement of the primary and secondary air connections and of the gas outlet gives the gases a long spiral path inside the gas chamber thus helping to complete combustion of sulphur.
These and other features of this invention will now be more particularly described with reference to the accompanying drawings, in which:
FIG. 1 is a diagrammatic elevation, partly in section of an improved sulphur burner according to this invention, and
(iv) an air supply pipe 17; and (v) a gas chamber 18 where combustion takes place.
The said hopper 4 and the said feeder 7 are provided with a steam jacket 5 into which steam may be led through the inlet 3. The steam jacket 5 is provided with a safety valve 23 and a condensate outlet 9.
The transfer of the molten sulphur from the hopper 4 to the feeder 7 is controlled by the hopper valve 6 which can be operated by the lever 2 and the transfer of the molten sulphur from the feeder 7 through the feed pipe is controlled by the feeder valve 8.
The feeder 7 is provided at its bottom with a feed pipe 14 which extends into the combustion chamber 15, and on the feed pipe 14 is rotatably mounted a level control L- shaped pipe 13 which communicates with the feed pipe 14.
Normally, the tips of the feed pipe 14 and the control pipe 13 will be substantially at the same level when the control pipe 13 is held in the vertical position. The level of the terminal end of control pipe 13 can, however, be moved in the vertical plane by rotating handle attached to the level controlling shaft 24 the opposite end of which is secured to L-shaped pipe 13. The said shaft 24 is introduced into the combustion chamber 15 through a stuffing box 11.
So long as the tip of the feed pipe 14 or of the level controlling pipe 13, is above the level of the molten sulphur in the combustion chamber 15, the combustion gases from the said combustion chamber will be able to enter the feed pipe 14 and, if the feeder valve 8 is open, the said gases wil enter the feeder 7 and cause the molten sulphur from the said feeder to descend into the combustion chamber 15 until the said tips are submerged in the molten sulphur in the combustion chamber. Thus, by moving the level control pipe 13 in the vertical plane, it will be possible to vary the level of the molten sulphur in the combustion chamber and to maintain it at any desired height.
The conical combustion trough 16 is positioned directly underneath the gas chamber 18 and, therefore, in the vapourization zone of the combustion chamber 15. The combustion chamber 15 and the gas chamber 18 are joined through a constricted area 34. Since vapourization occurs only from the surface, it will be directly related to the area of the surface of the molten sulphur in the vapourization zone, and the said area in its turn will vary with the level of the molten surface maintained in the combustion chamber 15 around the conical trough 16. Thus, by varying the level of the molten sulphur in the combustion chamber 15, the area of the surface of the molten sulphur in the vapourization zone, and consequently, the rate of vapourization and combustion of the sulphur may be varied without causing any fluctuation of the air supply for the purpose.
As an additional means of controlling the vapourization of the molten sulphur, the conical trough 16 is jacketed on its underside so that a cooling fluid such as water or air can be supplied through a connection 16A and the hot fluid let out through outlet 16B.
The air supply pipe 17 is fitted at the bottom of the gas chamber 18, so that the sulphur vapours produced in the vapourization zone may be intimately mixed with the air supply, for undergoing combustion in the gas chamber 18.
The operation of the sulphur burner described above will now be described:
The air supply pipe 17, which is provided with a U- bend 17A, can effect, through the arm 173 a primary air supply in the region of the combustion trough 16, and through the arm 17C a secondary air supply in the region where the combustion of the primary products of combustion will be completed. This arrangement of supplying air in two stages is advantageous, particularly where liquid or solid fuels are concerned. The primary air helps to convert the solid or liquid fuel into primary products of combustion which are gaseous in nature, and the secondary air supplied at a later stage helps to complete the combustion. An important advantage of this two stage system of supplying air is that the combustion process can be completed with much less excess air than it all the air had been supplied in a single stage as in the original invention.
Each of the arms 17A and 17B is provided with a regulating mechanism 29, which can be of any well known type such as a regulating valve, or a variable-opening orifice plate. As a result of having two such regulating mechanisms, the proportions of the primary air and the secondary air can be more effectively varied so as to obtain the best possible combustion of sulphur.
The fins 32 help to dissipate the heat of the combustion chamber 15 fast and thereby make it possible to maintain the temperature of the said chamber at a level which is not too high.
The sight glass 19 being located on top of the gas chamber 18, gives a good sight of the phenomena taking place inside the gas chamber 18.
The said sight glass 19 is cooled by a air moving downwards, and no sulphur vapour can towards the glass and get deposited thereon.
The lever 1 located at the bottom of the burner, for operating the valve 8, is found to be a very convenient arrangement for raising the said valve 8.
A further improvement according to this invention resides in the location of the gas outlet pipe 20, which as shown in the accompanying drawings, is located tangentially at the top of the gas chamber 18, instead of extending vertically above the gas chamber 18, as in sulphur burners of known construction.
What I claim is:
1. A sulphur burner comprising a combustion chamber having a substantially vertical cylindrical side wall and an upwardly extending conical base whereby an annulus is formed therebetween, said annulus increasing in size from the bottom to the top of said conical base, means for controlling the surface level of a pool of molten sulphur contained in said combustion chamber whereby the surface area of said molten sulphur surrounding said conical base may be controlled thereby controlling the rate of vaporization and combustion of said sulphur, a gas chamber above said combustion chamber wherein combustion of sulphur takes place over said pool of molten sulphur contained in said combustion chamber, said combustion and gas chambers being joined through a cylindrical member of restricted cross section, means for supplying primary and secondary air to said sulphur burner, said primary air being supplied tangentially adjacent to the surface of said molten sulphur and said secondary air being supplied tangentially at said restriction, and a gas outlet pipe located tangentially at the top of said gas chamber whereby the gases follow a spiral path through said burner during combustion.
2. A sulphur burner as claimed in claim 1 wherein valve means are provided in both said primary and secondary air supply means whereby the proportion of primary and secondary air may be varied to obtain proper combustion of sulphur.
3. A sulphur burner as claimed in claim 1 wherein the walls of said sulphur burner are provided with fins to dissipate the heat and thereby lower the temperature of said burner.
4. A sulphur burner as claimed in claim 1 wherein means is provided adjacent the underside of said conical bottom wall of said combustion chamber to cool said conical bottom wall, said means comprising a system for circulating a cooling fluid.
5. A sulphur burner as claimed in claim 1 wherein said means for controlling the surface level of said molten sulphur in said combustion chamber comprises an enclosed molten sulphur reservoir and a feed pipe extending downwardly from said reservoir into said combustion chamber and terminating therein, the effective horizontal level of said feed pipe in said combustion chamber being adjustable whereby the surface level of said molten sulphur in said combustion chamber may be controlled.
constant stream of diffuse rotation of said L-shaped pipe.
7. A sulphur burner as claimed in claim 1 which is provided with a sight glass located on top of the gas chamber of the sulphur burner, on which sight glass may References Cited by the Examiner UNITED STATES PATENTS 1,364,716 1/1921 Clayton 23-278 2,310,173 2/1943 Chatelain et a1 23-278 X 2,994,368 8/1961 Jensen et a1. 158-91 FOREIGN PATENTS 146,297 7/1962 Russia.
be blown a steady stream of cool air to prevent the dep- 10 MORRIS WOLK Examinerosition of sublimed sulphur.
JAMES H. TAYMAN, JR., Examiner.

Claims (1)

1. A SULPHUR BURNER COMPRISING A CUMBOUSTION CHAMBER HAVING A SUBSTANTIALLY VERTICAL CYLINDRICAL SIDE WALL AND AN UPWARDLY EXTENDING CONICAL BASE WHEREBY AN ANNULUS IS FORMED THEREBETWEEN, SAID ANNULUS INCREASING IN SIZE FROM THE BOTTOM TO THE TOP OF SAID CONICAL BASE, MEANS FOR CONTROLLING THE SURFACE LEVEL OF A POOL OF MOLTEN SULPHUR CONTAINED IN SAID COMBUSTION CHAMBER WHEREBY THE SURFACE AREA OF SAID MOLTEN SULPHUR SURROUNDING SAID CONICAL BASE MAY BE CONTROLLED THEREBY CONTROLLING THE RATE OF VAPORIZATION AND COMBUSTION OF SAID SULPHUR, A GAS CHAMBER ABOVE SAID COMBUSTION CHAMBER WHEREIN COMBUSTION OF SULPHUR TAKES PLACE OVER SAID POOL OF MOLTEN SULPHUR CONTAINED IN SAID COMBUSTION CHAMBR, SAID COMBUSTION AND GAS CHAMBRS BEING JOINED THROUGH A CYLINDRICAL MEMBER OF RESTRICTED CROSS SECTION, MEANS FOR SUPPLYING PRIMARY AND SECONDARY AIR TO SAID SULPHUR BURNER, SAID PROMARY AIR BEING SUPPLIED TANGENTIALLY ADJACENT TO THE SURFACE OF SAID MOLTEN SULPHUR AND SAID SECONDARY AIR BEING SUPPLIED TANGENTIALLY AT SAID RESTRICTION, AND A GAS OUTLET PIPE LOCATED TANGENTIALLY AT THE TOP OF SAID GAS CHAMBER WHEREBY THE GASES FOLLOW A SPIRAL PATH THROUGH SAID BURNER DURING COMBUSTION.
US328717A 1963-12-03 1963-12-06 Sulfur burner Expired - Lifetime US3314766A (en)

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GB4769863A GB1035457A (en) 1963-12-03 1963-12-03 Improvements in or relating to sulphur burners
US328717A US3314766A (en) 1963-12-03 1963-12-06 Sulfur burner

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3519397A (en) * 1967-06-27 1970-07-07 Leonid Alexandrovich Bogdanov Furnace for obtaining sulphur dioxide
DE1667429B1 (en) * 1967-09-28 1971-07-29 Tsni I Pk Kotloturbinnij I Im FURNACE FOR THE PRODUCTION OF SULFUR DIOXIDE
FR2211397A1 (en) * 1972-12-26 1974-07-19 Chemsoil Corp
US4039289A (en) * 1971-02-08 1977-08-02 Chemsoil Corporation Sulphur-burning and gaseous products absorption system and components therefor
US4526771A (en) * 1981-05-08 1985-07-02 International Environmental, Inc. Sulfurous acid generator
US6248299B1 (en) 1997-07-07 2001-06-19 Edward Jackson Open system sulfurous acid generator
US6500391B1 (en) 1998-08-07 2002-12-31 Edward Jackson Sulphurous acid generator with air injector
US20030211018A1 (en) * 1997-07-07 2003-11-13 Jackson Edward W. Open system sulphurous acid generator with plume demister
US6689326B1 (en) 1997-07-07 2004-02-10 Aapa Trust Method and apparatus for introducing sulphur dioxide into aqueous solutions
US7182919B2 (en) 1998-08-07 2007-02-27 Edward Jackson Sulphurous acid generator with air injector

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1364716A (en) * 1920-04-02 1921-01-04 Clayton Thomas Adam Apparatus for the manufacture of oxygen compounds of sulfur
US2310173A (en) * 1939-06-07 1943-02-02 Freeport Sulphur Co Method and apparatus for providing a controlled supply of sulphur combustion gases
US2994368A (en) * 1959-08-04 1961-08-01 Preway Inc Fire ring

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1364716A (en) * 1920-04-02 1921-01-04 Clayton Thomas Adam Apparatus for the manufacture of oxygen compounds of sulfur
US2310173A (en) * 1939-06-07 1943-02-02 Freeport Sulphur Co Method and apparatus for providing a controlled supply of sulphur combustion gases
US2994368A (en) * 1959-08-04 1961-08-01 Preway Inc Fire ring

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3519397A (en) * 1967-06-27 1970-07-07 Leonid Alexandrovich Bogdanov Furnace for obtaining sulphur dioxide
DE1667429B1 (en) * 1967-09-28 1971-07-29 Tsni I Pk Kotloturbinnij I Im FURNACE FOR THE PRODUCTION OF SULFUR DIOXIDE
US4039289A (en) * 1971-02-08 1977-08-02 Chemsoil Corporation Sulphur-burning and gaseous products absorption system and components therefor
FR2211397A1 (en) * 1972-12-26 1974-07-19 Chemsoil Corp
US3907510A (en) * 1972-12-26 1975-09-23 Chemsoil Corp System for burning sulfur and absorbing sulfur dioxide in water
US4526771A (en) * 1981-05-08 1985-07-02 International Environmental, Inc. Sulfurous acid generator
US6248299B1 (en) 1997-07-07 2001-06-19 Edward Jackson Open system sulfurous acid generator
US6506347B1 (en) 1997-07-07 2003-01-14 Aapa Trust Open system sulphurous acid generator
US20030211018A1 (en) * 1997-07-07 2003-11-13 Jackson Edward W. Open system sulphurous acid generator with plume demister
US6689326B1 (en) 1997-07-07 2004-02-10 Aapa Trust Method and apparatus for introducing sulphur dioxide into aqueous solutions
US7141220B2 (en) 1997-07-07 2006-11-28 Jackson Edward W Open system sulphurous acid generator
USRE42239E1 (en) 1997-07-07 2011-03-22 Jackson Edward W Open system sulphurous acid generator
US6500391B1 (en) 1998-08-07 2002-12-31 Edward Jackson Sulphurous acid generator with air injector
US7182919B2 (en) 1998-08-07 2007-02-27 Edward Jackson Sulphurous acid generator with air injector

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