US3308786A - Fiber liquid treatment system - Google Patents
Fiber liquid treatment system Download PDFInfo
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- US3308786A US3308786A US293493A US29349363A US3308786A US 3308786 A US3308786 A US 3308786A US 293493 A US293493 A US 293493A US 29349363 A US29349363 A US 29349363A US 3308786 A US3308786 A US 3308786A
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- bottle
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- tank
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- valve
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/02—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
Definitions
- This invention relates to textile processing and more particularly to an improved system for effecting liquid treatment of textile fibers.
- an object of this invention to provide an efficient system for applying liquid to fibrous material during the manufacture of textiles that will not cause undue fogging of the manufacturing area.
- the figure is a generally diagrammatic view illustrating a preferred embodiment of the novel fluid spraying system.
- a conveyor adapted to carry material such as fibers 12 through various processing stations is shown being operable with power supplied to a co-nventional electric motor 14.
- This conveyor motor may be controlled by any conventional manner, such as automatic timing, work condition responsiveness or manual control.
- a conventional electromagnetic motor starter 16 is illustrated.
- the novel fiuid spraying system associated with the conveyor 10 comprises a reserve tank 18 for containing the uid to be used over an extended period of system operation.
- a suitable conduit 2t) is connected at one end to the tank 18 near the bottom thereof, and at the other end to a T fitting 24 provided in the bottom of a pressure bottle 22.
- a conduit 26 is connected to the remaining leg of the T 24, extends to a point adjacent the conveyor 10 and terminates in a sprayer 28 which may be of the reaction type or of any suitable design to allow fluid to be sprayed therefrom and directed onto the material moving by on the conveyor 10.
- a check valve 30 is interposed in the line to effectively preclude flow in the direction proceeding from the bottle 22 to the tank 18.
- the upper end 32 of the pressure bottle 22 is firice located at a level substantially even with the bottom of the reserve tank 18 and the spray head 28 is positioned above the upper liquid level of the reserve tank 18 for purposes more fully set forth hereinafter.
- a pressure line 34 is in communication with the upper end 32 of the bottle 22, the pressure line being connected to a supply of gas, preferably air, under pressure.
- gas preferably air
- the air may be most inexpensively supplied from the general manufacturing plant compressed air source, or from compressed air cylinders or the like.
- a three port two-position solenoid operated valve 42 is connected in the line,34 between the gage-regulator assembly 38, 40 and the pressure bottle 22. As shown, a first port 44 of the valve communicates with the bottle 22, a second port 46 communicates with the pressure source, and the third port 48 communicates through a conduit 50 to an exhaust filter 52.
- a solenoid 54 associated with the valve 42 is preferably connected to the conveyor motor 14 in a manner such that the solenoid is energized, by or when the conveyor motor is operated, to move the valve 42 from a first position wherein the bottle 22 is in communication with the exhaust conduit 50, to a second position wherein the bottle 22 is in communication with the pressure source (not shown).
- the solenoid 54 is deeled, the valve returns to the first position thereof.
- tint solution In the operation of the system to apply tint to fibers travelling on the conveyor 10, a quantity of tint solution is placed in the tank 18. With the conveyor motor off, the valve 42 is in its first position so that tint solution liows down through the conduit 20, through the T 24 and into the bottle 22. Under gravity feed the tint solution rises in the bottle, filling it. By having the upper end of the sprayer 28 above the maximum level of tint solution in the tank 18, the tint solution ⁇ is not inadvertently discharged from the sprayer 28 during gravity fill of the bottle 22.
- the solenoid 54 When the conveyor motor starts, as when it is desired to tint a quantity of fabric or fibers on the conveyor, the solenoid 54 is energized as explained above, thereby switching the valve 42 to its second position, connecting the bottle to the supply of air under pressure and closing off the exhaust line 50 to atmosphere.
- the air under pressure then acts downwardly on the upper surface of the tint solution in the bottle 22 forcing solution out through the T 24, through the conduit 26 and out of the sprayer 28 onto the material passing by on the conveyor 10.
- the magnitude of the pressure employed is generally quite low so that no problem is created by air dissolving in the solution to be sprayed. The exact pressure used will depend on the desired spraying volume and force.
- the size of the pressure bottle 22 is chosen so that it will not become entirely depleted of fluid during any particular run of the conveyor.
- the bottle 22 can conveniently be an accumulator tank of the variety associated with household shallow well pumps.
- the check valve 30, of course, prevents the air pressure from causing a back flow of solution to the tank 18 during the spraying portion of the cycle.
- the spraying cycle continues inoperation with the conveying cycle to operate on successive batches of articles.
- aV tank adapted to receive a supply of liquid to be sprayed; a pressure bottle positioned lower than the tank adapted to receive a smaller quantity of liquid from the tank; conduit means communicating the tank to the bottle; a spray hea-d; a chec-k valve interposed in the conduit means and arranged to allow uid ow only in a direction proceeding from the tank to the bottle; conduit means communicating the bottle to the spray head; conduit means connecting a source of gas under pressure to said pressure bottle; valve means interposed in the last-mentioned conduit means to selectively communicate said gas pressure sourceY to the bottle so as to supply liquid therefrom to the sprayer, the last-mentioned valve comprising a three port, two-position valve having a lirst position wherein the bottle is communicated to the atmosphere and excluded from communication with the source of gas pressure so that uid flows from the tank into the bottle displacing air from the bottle through the valve, and a second position wherein the bottle is communicated to
- the combination comprising: a tank adapted to receive a supply of liquid to be sprayed; a pressure bottle positioned lower than the tank and adapted to receive a smaller quantity of liquid fromV the tank; conduit means communicating the tank to the bottle; a spray'head; a check valve interposed in the conduit means and arranged to allow uid flow only in a direction proceeding from the tank to the bottle; conduit means communicating the bottle to the spray head; conduit means connecting a source of gas under pressure to said pressure bottle; valve means interposed in the last-mentioned conduit means to selectively communicate said gas pressure source to the bottle so as to supply liquid therefrom to the sprayer, the last-mentioned valve comprising a three port, two-position valve having a irst position wherein the bottle is communicated to the atmosphere and excluded from communication with the source of gas pressure so that fluid iiows from the tank into the bottle displacing air from the bottle through the valve, and a second position wherein the bottle is communicated to the source of gas pressure and excluded from
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment Of Fiber Materials (AREA)
Description
arch 14, w67 c. s. WISE ETAL.
FIBER LIQUID TREATMENT SYSTEM Filed July 8, 1955 a ATTORNEYS United States Patent 3,308,786 FIBER LIQUID TREA'IMENT SYSTEM Cecil S. Wise, Dallas, and Ralph H. Rhyne, Gastonia,
N.C., assignors to Fiber Controls Corporation, Gastonia, N.C., a corporation of North Carolina Filed July 8, 1953, Ser. No. 293,493 2 Claims. (Cl. 118-11) This invention relates to textile processing and more particularly to an improved system for effecting liquid treatment of textile fibers.
In the textile industry various solutions are often applied to fibers during stages of the manufacture of completed articles. These solutions have traditionally included tints, oils, anti-static solutions and the like, and one preferred method of applying these solutions has been by atomization. Generally, this has been accomplished by pumping the liquid to be applied to a spray nozzle where it is combined with air under pressure and atomized adjacent the textile fibers. It has been found that the use of air causes small droplets of the liquid to be borne throughout the processing area causing contamination of the air, unwanted coloration of other fibers, equipment and personnel, and consequent economicv loss.
It is, therefore, an object of this invention to provide an efficient system for applying liquid to fibrous material during the manufacture of textiles that will not cause undue fogging of the manufacturing area.
It is a further object of this invention to provide a system for supplying a spray of liquid to an intermittently advancing conveyor surface having means responsive to the operation of the conveyor to replenish the liquid supply during non-operating periods.
It is yet another object of this invention to provide a device for spraying fluid under pressure without employing mechanical pumping means.
These and other objects of this invention will appear and be more thoroughly set forth in the following detailed explanation in which specific reference is made to the attached drawing in which an embodiment of the novel fiuid spraying system is shown, not to limit the scope of the invention in any way, but in order that the principles thereof mivht be more easily understood.
In the drawing:
The figure is a generally diagrammatic view illustrating a preferred embodiment of the novel fluid spraying system.
A conveyor adapted to carry material such as fibers 12 through various processing stations is shown being operable with power supplied to a co-nventional electric motor 14. This conveyor motor may be controlled by any conventional manner, such as automatic timing, work condition responsiveness or manual control. A conventional electromagnetic motor starter 16 is illustrated.
The novel fiuid spraying system associated with the conveyor 10 comprises a reserve tank 18 for containing the uid to be used over an extended period of system operation. A suitable conduit 2t) is connected at one end to the tank 18 near the bottom thereof, and at the other end to a T fitting 24 provided in the bottom of a pressure bottle 22.
A conduit 26 is connected to the remaining leg of the T 24, extends to a point adjacent the conveyor 10 and terminates in a sprayer 28 which may be of the reaction type or of any suitable design to allow fluid to be sprayed therefrom and directed onto the material moving by on the conveyor 10. As shown, a check valve 30 is interposed in the line to effectively preclude flow in the direction proceeding from the bottle 22 to the tank 18.
According to the preferred embodiment of the present invention, the upper end 32 of the pressure bottle 22 is firice located at a level substantially even with the bottom of the reserve tank 18 and the spray head 28 is positioned above the upper liquid level of the reserve tank 18 for purposes more fully set forth hereinafter.
A pressure line 34 is in communication with the upper end 32 of the bottle 22, the pressure line being connected to a supply of gas, preferably air, under pressure. The air may be most inexpensively supplied from the general manufacturing plant compressed air source, or from compressed air cylinders or the like.
Interposed in the line 34 is a conventional pressure gage 38 and pressure regulator 40. A three port two-position solenoid operated valve 42 is connected in the line,34 between the gage- regulator assembly 38, 40 and the pressure bottle 22. As shown, a first port 44 of the valve communicates with the bottle 22, a second port 46 communicates with the pressure source, and the third port 48 communicates through a conduit 50 to an exhaust filter 52.
A solenoid 54 associated with the valve 42 is preferably connected to the conveyor motor 14 in a manner such that the solenoid is energized, by or when the conveyor motor is operated, to move the valve 42 from a first position wherein the bottle 22 is in communication with the exhaust conduit 50, to a second position wherein the bottle 22 is in communication with the pressure source (not shown). When the conveyor motor 14 is stopped and the solenoid 54 is deenergied, the valve returns to the first position thereof.
In the operation of the system to apply tint to fibers travelling on the conveyor 10, a quantity of tint solution is placed in the tank 18. With the conveyor motor off, the valve 42 is in its first position so that tint solution liows down through the conduit 20, through the T 24 and into the bottle 22. Under gravity feed the tint solution rises in the bottle, filling it. By having the upper end of the sprayer 28 above the maximum level of tint solution in the tank 18, the tint solution` is not inadvertently discharged from the sprayer 28 during gravity fill of the bottle 22.
When the conveyor motor starts, as when it is desired to tint a quantity of fabric or fibers on the conveyor, the solenoid 54 is energized as explained above, thereby switching the valve 42 to its second position, connecting the bottle to the supply of air under pressure and closing off the exhaust line 50 to atmosphere. The air under pressure then acts downwardly on the upper surface of the tint solution in the bottle 22 forcing solution out through the T 24, through the conduit 26 and out of the sprayer 28 onto the material passing by on the conveyor 10. The magnitude of the pressure employed is generally quite low so that no problem is created by air dissolving in the solution to be sprayed. The exact pressure used will depend on the desired spraying volume and force.
In practice, the size of the pressure bottle 22 is chosen so that it will not become entirely depleted of fluid during any particular run of the conveyor. The bottle 22 can conveniently be an accumulator tank of the variety associated with household shallow well pumps. The check valve 30, of course, prevents the air pressure from causing a back flow of solution to the tank 18 during the spraying portion of the cycle.
When the run is finished and the conveyor stops, the solenoid 54 is deenergized as outlined above and the valve 42 returns to its former position, thereby cutting off the air pressure and opening the exhaust conduit 50 to atmosphere through the exhaust filter 52. Tint solution again flows from the tank 18 into the bottle 22, displacing air outwardly through the line 50 and through the filter 52, which effectively prevents any solution which 3 might be entrained in the air being exhausted from escap- .ing into the work area.
In like manner, the spraying cycle continues inoperation with the conveying cycle to operate on successive batches of articles.
Although the device has been primarilydescribed for ruse in conjunction with spraying tint solution on textile iibers, it should be realized that other liquids can advantageously be sprayed using the apparatus of this invention Ion such diverse textile and non-textile articles as cloth, silver, rovings, yarn, non-woven textiles, felt fiber glass, synthetic fibers, mineral wooland the like.
- The lack of addition of atomizing air to the solution being sprayed substantially reduces the likelihood of fog formation in the work area, and the fact that no pumps are necessary for the operation of the system substantially reduces the initial and maintenance costs thereof.
It should now be apparent that the system, as fully explained above, accomplishes the objects of the invention as set forth herein and that, although many modifications of the embodiment shown will be apparent to a person skilled in the art, all embodiments of the invention exhibiting the principles thereof should be embraced within the spirit and scope of the claims appended hereto.
What is claimed is:
1. The combination comprising: aV tank adapted to receive a supply of liquid to be sprayed; a pressure bottle positioned lower than the tank adapted to receive a smaller quantity of liquid from the tank; conduit means communicating the tank to the bottle; a spray hea-d; a chec-k valve interposed in the conduit means and arranged to allow uid ow only in a direction proceeding from the tank to the bottle; conduit means communicating the bottle to the spray head; conduit means connecting a source of gas under pressure to said pressure bottle; valve means interposed in the last-mentioned conduit means to selectively communicate said gas pressure sourceY to the bottle so as to supply liquid therefrom to the sprayer, the last-mentioned valve comprising a three port, two-position valve having a lirst position wherein the bottle is communicated to the atmosphere and excluded from communication with the source of gas pressure so that uid flows from the tank into the bottle displacing air from the bottle through the valve, and a second position wherein the bottle is communicated to the source of gas pressure and excluded from communication with the atmosphere so that the gas expels the liquid from the bottle and out through the sprayer; an article conveyor; an intermittently operating electric motor operatively connected to said conveyor for advancing said conveyor, valve operating means for said three port, two-position valve operatively connected in circuit with said motor to be energized when the motor operates and deenergized when the motor does not operate so that the sprayer will spray liquid as the conveyor advances due to operation of said electric motor and the liquid supply in the bottle will be replen- Y 4 ished when the conveyor is at rest as said electric motor is inoperative.
2. The combination comprising: a tank adapted to receive a supply of liquid to be sprayed; a pressure bottle positioned lower than the tank and adapted to receive a smaller quantity of liquid fromV the tank; conduit means communicating the tank to the bottle; a spray'head; a check valve interposed in the conduit means and arranged to allow uid flow only in a direction proceeding from the tank to the bottle; conduit means communicating the bottle to the spray head; conduit means connecting a source of gas under pressure to said pressure bottle; valve means interposed in the last-mentioned conduit means to selectively communicate said gas pressure source to the bottle so as to supply liquid therefrom to the sprayer, the last-mentioned valve comprising a three port, two-position valve having a irst position wherein the bottle is communicated to the atmosphere and excluded from communication with the source of gas pressure so that fluid iiows from the tank into the bottle displacing air from the bottle through the valve, and a second position wherein the bottle is communicated to the source of gas pressure and excluded from communication with the atmosphere so that the gas expels the liquid from the bottle and out through the sprayer; a solenoid operatively connected to the three port, two-position valve and adapted to move the valve between the iirst and second positions in response to electric energization of the solenoid; an article conveyor; an intermittently operating electric motor for advancing said conveyor, said solenoid being operatively connected in circuit with said motor to be energized when the motor operates and deenergized when the rn-otor does not operate so that the sprayer will spray liquid as the conveyor motor operates and the liquid supply in the bottle will be replenished when the conveyor motor is inoperative; the conveyor carrying articles; the sprayer being adjacent the conveyor and directed toward the conveyor as to spray liquid toward the conveyor and on the articles carried thereby.
References Cited by the Examiner UNITED STATES PATENTS 818,481 4/1906 Spencer 222-373 1,103,939 7/1914 Catron 222-373 1,615,909 2/1927 Nance.
2,319,459 5/1943 Johnson 239-373 X 2,669,941 2/ 1954 Stafford 222-373 X 2,873,483 2/195'9 Lytton 118-11 X 2,946,475 7/1960 Rockelman 137-197 X 3,033,911 5/1962 Duddy 137-197 3,085,582 4/1963 Slosman 118-8 X FOREIGN PATENTS 496,526 9/ 1953 Can-ada;
DANIEL BLUM, Primary Examiner,
Claims (1)
1. THE COMBINATION COMPRISING: A TANK ADAPTED TO RECEIVE A SUPPLY OF LIQUID TO BE SPRAYED; A PRESSURE BOTTLE POSITIONED LOWER THAN THE TANK ADAPTED TO RECEIVE A SMALLER QUANTITY OF LIQUID FROM THE TANK; CONDUIT MEANS COMMUNICATING THE TANK TO THE BOTTLE; A SPRAY HEAD; A CHECK VALVE INTERPOSED IN THE CONDUIT MEANS AND ARRANGED TO ALLOW FLUID FLOW ONLY IN A DIRECTION PROCEEDING FROM THE TANK TO THE BOTTLE; CONDUIT MEANS COMMUNICATING THE BOTTLE TO THE SPRAY HEAD; CONDUIT MEANS CONNECTING A SOURCE OF GAS UNDER PRESSURE TO SAID PRESSURE BOTTLE; VALVE MEANS INTERPOSED IN THE LAST-MENTIONED CONDUIT MEANS TO SELECTIVELY COMMUNICATE SAID GAS PRESSURE SOURCE TO THE BOTTLE SO AS TO SUPPLY LIQUID THEREFROM TO THE SPRAYER, THE LAST-MENTIONED VALVE COMPRISING A THREE PORT, TWO-POSITION VALVE HAVING A FIRST POSITION WHEREIN THE BOTTLE IS COMMUNICATED TO THE ATMOSPHERE AND EXCLUDED FROM COMMUNICATION WITH THE SOURCE OF GAS PRESSURE SO THAT FLUID FLOWS FROM THE TANK INTO THE BOTTLE DISPLACING AIR FROM THE BOTTLE THROUGH THE VALLVE, AND A SECOND POSITION WHEREIN THE BOTTLE IS COMMUNICATED TO THE SOURCE OF GAS PRESSURE AND EXCLUDED FROM COMMUNICATION WITH THE ATMOSPHERE SO THAT THE GAS EXPELS THE LIQUID FROM THE BOTTLE AND OUT THROUGH THE SPRAYER; AN ARTICLE CONVEYOR; AN INTERMITTENTLY OPERATING ELECTRIC MOTOR OPERATIVELY CONNECTED TO SAID CONVEYOR FOR ADVANCING SAID CONVEYOR, VALVE OPERATING MEANS FOR SAID THREE PORT, TWO-POSITION VALVE OPERATIVELY CONNECTED IN CIRCUIT WITH SAID MOTOR TO BE ENERGIZED WHEN THE MOTOR OPERATES AND DEENERGIZED WHEN THE MOTOR DOES NOT OPERATE SO THAT THE SPRAYER WILL SPRAY LIQUID AS THE CONVEYOR ADVANCES DUE TO OPERATION OF SAID ELECTRIC MOTOR AND THE LIQUID SUPPLY IN THE BOTTLE WILL BE REPLENISHED WHEN THE CONVEYOR IS AT REST AS SAID ELECTRIC MOTOR IS INOPERATIVE.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US293493A US3308786A (en) | 1963-07-08 | 1963-07-08 | Fiber liquid treatment system |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US293493A US3308786A (en) | 1963-07-08 | 1963-07-08 | Fiber liquid treatment system |
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US3308786A true US3308786A (en) | 1967-03-14 |
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US293493A Expired - Lifetime US3308786A (en) | 1963-07-08 | 1963-07-08 | Fiber liquid treatment system |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3495743A (en) * | 1968-04-22 | 1970-02-17 | Community Linen Rental Service | Automatic addition of liquid chemicals in laundries |
EP0445541A2 (en) * | 1990-03-08 | 1991-09-11 | Zinser Textilmaschinen GmbH | Method and apparatus for supplying liquid treating agent to running yarns at the workstations of a spinning machine |
US20040018182A1 (en) * | 1997-04-30 | 2004-01-29 | Hans Klingemann | Thymidine kinase expressing natural killer cell lines and methods of use |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US818481A (en) * | 1903-09-16 | 1906-04-24 | Guilford L Spencer | Apparatus for measuring and delivering liquids. |
US1103939A (en) * | 1913-04-08 | 1914-07-21 | John James Catron | Fluid-dispensing apparatus. |
US1615909A (en) * | 1926-06-19 | 1927-02-01 | Nance Sidney Allen | Flue |
US2319459A (en) * | 1940-12-11 | 1943-05-18 | Willard Macmillan | Apparatus for vaporizing and applying liquids |
CA496526A (en) * | 1953-09-29 | Taco Heaters | Automatic air valve | |
US2669941A (en) * | 1949-12-15 | 1954-02-23 | John W Stafford | Continuous liquid pumping system |
US2873483A (en) * | 1954-01-08 | 1959-02-17 | Fiber Controls Corp | Fiber tinter |
US2946475A (en) * | 1957-03-26 | 1960-07-26 | Harold J Rockelman | Gasoline trap |
US3033911A (en) * | 1958-07-30 | 1962-05-08 | Electric Storage Battery Co | Vent plug |
US3085582A (en) * | 1962-04-30 | 1963-04-16 | United States Steel Corp | Method and apparatus for controlling the bulk density of coal |
-
1963
- 1963-07-08 US US293493A patent/US3308786A/en not_active Expired - Lifetime
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA496526A (en) * | 1953-09-29 | Taco Heaters | Automatic air valve | |
US818481A (en) * | 1903-09-16 | 1906-04-24 | Guilford L Spencer | Apparatus for measuring and delivering liquids. |
US1103939A (en) * | 1913-04-08 | 1914-07-21 | John James Catron | Fluid-dispensing apparatus. |
US1615909A (en) * | 1926-06-19 | 1927-02-01 | Nance Sidney Allen | Flue |
US2319459A (en) * | 1940-12-11 | 1943-05-18 | Willard Macmillan | Apparatus for vaporizing and applying liquids |
US2669941A (en) * | 1949-12-15 | 1954-02-23 | John W Stafford | Continuous liquid pumping system |
US2873483A (en) * | 1954-01-08 | 1959-02-17 | Fiber Controls Corp | Fiber tinter |
US2946475A (en) * | 1957-03-26 | 1960-07-26 | Harold J Rockelman | Gasoline trap |
US3033911A (en) * | 1958-07-30 | 1962-05-08 | Electric Storage Battery Co | Vent plug |
US3085582A (en) * | 1962-04-30 | 1963-04-16 | United States Steel Corp | Method and apparatus for controlling the bulk density of coal |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3495743A (en) * | 1968-04-22 | 1970-02-17 | Community Linen Rental Service | Automatic addition of liquid chemicals in laundries |
EP0445541A2 (en) * | 1990-03-08 | 1991-09-11 | Zinser Textilmaschinen GmbH | Method and apparatus for supplying liquid treating agent to running yarns at the workstations of a spinning machine |
EP0445541A3 (en) * | 1990-03-08 | 1991-12-04 | Zinser Textilmaschinen Gmbh | Method and apparatus for supplying liquid treating agent to running yarns at the workstations of a spinning machine |
US20040018182A1 (en) * | 1997-04-30 | 2004-01-29 | Hans Klingemann | Thymidine kinase expressing natural killer cell lines and methods of use |
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