US3304257A - Lubricants - Google Patents

Lubricants Download PDF

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Publication number
US3304257A
US3304257A US473190A US47319065A US3304257A US 3304257 A US3304257 A US 3304257A US 473190 A US473190 A US 473190A US 47319065 A US47319065 A US 47319065A US 3304257 A US3304257 A US 3304257A
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Prior art keywords
lubricants
aluminum
weight
phosphorous
lubricant
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US473190A
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English (en)
Inventor
Schanzer Wilhelm
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Molykote Produktions GmbH
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Molykote Produktions GmbH
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/02—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen and halogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06—Perfluoro polymers
    • C10M2213/062—Polytetrafluoroethylene [PTFE]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Definitions

  • This invention relates to novel lubricants which are particularly useful for cold-drawing and otherwise cold shaping metals without splintering the metal.
  • lubricants for metal drawing can be in the form of fluids, pastes, fatty materials as well as solid lubricants.
  • the important characteristic of the lubricants for this use is the reduction of the heating eifect caused by working the metal and this cooling can be accomplished by dissipating the heat at a rapid rate as well as by actual reduction of friction, etc.
  • soaps such as alkali metal and alkaline earth metal salts of higher fatty acids, 'boric acid and derivatives of boric acid in the form of solids, in aqueous systems, in oily systems and in paste-like preparations have been used as lubricants in the deep drawing of metals.
  • soaps such as alkali metal and alkaline earth metal salts of higher fatty acids, 'boric acid and derivatives of boric acid in the form of solids, in aqueous systems, in oily systems and in paste-like preparations have been used as lubricants in the deep drawing of metals.
  • inorganic solid lubricants with layer lattice structure.
  • the use of phosphate compounds in such lubricants is also known.
  • the primary object of this invention is to introduce a novel lubricant for use in deep drawing, forming and machining of metals.
  • Other objects and advantages of this invention are detailed in or will be apparent from this disclosure and appended claims.
  • the aluminum salts employed herein are formed from phosphorous-oxygen acids wherein the phosphorous is electropositive and is trior pentavalent.
  • phosphorous-oxygen acids wherein the phosphorous is electropositive and is trior pentavalent.
  • examples of such acids are ortho, pyroand meta-phosphoric acids, ortho-, pyroand meta-phosphorous acids and the known oligomeric and polymeric phosphorous-oxygen derivatives.
  • the aluminum salts of the phosphorous-oxygen acids can be employed in a wide variety of forms. They can be employed as dry lubricants alone or in mixture with other lubricants. When these salts are added to other lubricants, it is preferred that they be present to the extent of at least 1% by weight, based on the mixture. Thus, they can be mixed with extenders and/or other lubricating solid organic or inorganic carriers.
  • the aluminum salt can be mixed with polytetrafluoroethylene, polychlorotrifluoroethylene powders or with metal sulfide "ice lubricants and the mixture can be incorporated or worked into organic plastics.
  • the aluminum salts can be admixed with mineral oils and known synthetic lubricating oils as well as petroleum products to produce a variety of lubricants varying from fluids to pastes. Incorporation of the aluminum salt in a wax-like lubricant provides lubricating sticks which can be readily employed in a wide variety of applications. Lubricating greases and viscous natural and synthetic carriers can also be admixed with the aluminum salt to produce a grease or paste-like mass and the carrier may itself be a lubricant.
  • the aluminum salt can be uniformly distributed throughout the carrier or admixed ingredients in any manner desired. Generally the even distribution is more easily accomplished in the presence of viscosity-modifying materials or materials capable of effecting thixotropy.
  • the aluminum salts can, of course, be added to fluid carriers which can be inorganic or organic, natural or synthetic but should 'be of sufliciently low viscosity to accomm-odate the aluminum salt without forming a paste of viscous fluid.
  • fluid carriers as water, alcohols, mineral oils, polyester fluids, polyphenyl ether and the like can be employed.
  • the fluid carrier can be nonlubricating or it can be a lubricant which is relatively inferior, superior or equal to the aluminum salt. It is generally preferred to employ a lubricating fluid as a carrier if the ultimate product is to be in fluid form.
  • the fluids should contain dispersion stabilizers to insure a uniform product of uniform characteristics.
  • the aluminum phosphorous-oxygen compounds used as lubricants in the present invention can be used together with other lubricating materials and other compounds common in the lubricating art, as for example, emulsifiers to make articles easier to clean.
  • the corrosion inhibiting properties of the aluminum phosphates can be augmented by the addition of other corrosion inhibitors.
  • EXAMPLE 1 Aluminum phosphate in. water The friction scar area was measured on the Reichert friction and wear tester under 30 kg. load and 100 m. sliding contact. Water was employed as the lubricant and the resulting scar area had an average value (three measurements) of 32.6 sq. mm. A mixture of 5 parts by weight aluminum phosphate and 95 parts by weight water was employed as the lubricant and the test was repeated. The friction scar area had an average value (three measurements) of 7.3 sq. mm.
  • EXAMPLE 2 Aluminum phosphate in emulsions Following the procedure of Example 1, a mixture of parts by weight mineral oil, 9 parts water and 1 part emulsifying agent tested as a lubricant on the Reichert friction and wear tester gave an average friction scar area of 37.2 sq. mm. A mixture of par-ts of the mineral oil, Water, emulsifying agent mixture and 5 parts by weight of aluminum phosphate, similarly tested gave an average friction scar area of 22.9 sq. mm.
  • Aluminum phosphate in pastes A mineral oil was tested on the Almen-Wieland machine and thereafter 30 parts by Weight aluminum phosphate was mixed with 70 parts by weight of the mineral oil and the mixture was also tested on the Almen-Wieland machine.
  • the mineral oil had a loading capacity of 200 kg.
  • the mineral ioil-aluminum salt mixture had a loading capacity of 800 kg.
  • a lubricating composition containing at least 1 percent by Weight of an aluminum salt of an acid selected from the group consisting of phosphoric and phosphorous acids.
  • a fluid lubricant containing 21()% by weight of an aluminum phosphate 1.
  • a novel lubricant particularly useful for splinterfree cold met-a1 processing characterized by the presence of at least 1 percent by weight of an aluminum phosphate in the lubricant.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
US473190A 1964-07-22 1965-07-19 Lubricants Expired - Lifetime US3304257A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEM61844A DE1279272B (de) 1964-07-22 1964-07-22 Schmierstoffe

Publications (1)

Publication Number Publication Date
US3304257A true US3304257A (en) 1967-02-14

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ID=7310258

Family Applications (1)

Application Number Title Priority Date Filing Date
US473190A Expired - Lifetime US3304257A (en) 1964-07-22 1965-07-19 Lubricants

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US (1) US3304257A (de)
CH (1) CH460222A (de)
DE (1) DE1279272B (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3994847A (en) * 1974-12-30 1976-11-30 Ball Corporation Aqueous dispersion of polyphenylene sulfide metal phosphate binder and solid lubricant for glass molds coating
US4003867A (en) * 1974-06-12 1977-01-18 Acheson Industries, Inc. Glass mold coating dispersion of aluminum phosphate and resinous agent, pigment, stabilizer and dispersing agents
US4927549A (en) * 1988-05-31 1990-05-22 Egis Gyogyszergyar Lubricant of lubricating oil basis for lubricating rotating and/or sliding surfaces and process for preparing same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1932454A (en) * 1929-11-30 1933-10-31 Electro Metallurg Co Metal drawing
US2588234A (en) * 1950-10-31 1952-03-04 John A Henricks Method of drawing metal
US3186945A (en) * 1960-04-14 1965-06-01 Alpha Molykote Corp High temperature lubricants

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2807583A (en) * 1951-12-18 1957-09-24 American Chain & Cable Co Lubricant for bowden wire mechanisms

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1932454A (en) * 1929-11-30 1933-10-31 Electro Metallurg Co Metal drawing
US2588234A (en) * 1950-10-31 1952-03-04 John A Henricks Method of drawing metal
US3186945A (en) * 1960-04-14 1965-06-01 Alpha Molykote Corp High temperature lubricants

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003867A (en) * 1974-06-12 1977-01-18 Acheson Industries, Inc. Glass mold coating dispersion of aluminum phosphate and resinous agent, pigment, stabilizer and dispersing agents
US3994847A (en) * 1974-12-30 1976-11-30 Ball Corporation Aqueous dispersion of polyphenylene sulfide metal phosphate binder and solid lubricant for glass molds coating
US4927549A (en) * 1988-05-31 1990-05-22 Egis Gyogyszergyar Lubricant of lubricating oil basis for lubricating rotating and/or sliding surfaces and process for preparing same

Also Published As

Publication number Publication date
DE1279272B (de) 1968-10-03
CH460222A (de) 1968-07-31

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