US3288715A - Fabricating aluminum products with olefin lubricants - Google Patents

Fabricating aluminum products with olefin lubricants Download PDF

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Publication number
US3288715A
US3288715A US31852063A US3288715A US 3288715 A US3288715 A US 3288715A US 31852063 A US31852063 A US 31852063A US 3288715 A US3288715 A US 3288715A
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United States
Prior art keywords
aluminum
cutting
fabricating
olefins
olefinic
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Expired - Lifetime
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English (en)
Inventor
Robert S Owens
Pierre Leon E St
Robert V Klint
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General Electric Co
Original Assignee
General Electric Co
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Publication date
Application filed by General Electric Co filed Critical General Electric Co
Priority to US31852063 priority Critical patent/US3288715A/en
Priority to FR988127A priority patent/FR1407623A/fr
Priority to GB3847464A priority patent/GB1081135A/en
Priority to DEP1270A priority patent/DE1270724B/de
Priority to NL6412237A priority patent/NL6412237A/xx
Application granted granted Critical
Publication of US3288715A publication Critical patent/US3288715A/en
Anticipated expiration legal-status Critical
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C9/00—Cooling, heating or lubricating drawing material
    • B21C9/02—Selection of compositions therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0239—Lubricating
    • B21B45/0242—Lubricants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00—Extruding metal; Impact extrusion
    • B21C23/32—Lubrication of metal being extruded or of dies, or the like, e.g. physical state of lubricant, location where lubricant is applied
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C9/00—Cooling, heating or lubricating drawing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02—Well-defined hydrocarbons
    • C10M105/04—Well-defined hydrocarbons aliphatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/22—Carboxylic acids or their salts
    • C10M105/24—Carboxylic acids or their salts having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
    • C—CHEMISTRY; METALLURGY
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    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/50—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing halogen
    • C10M105/52—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing halogen containing carbon, hydrogen and halogen only
    • C—CHEMISTRY; METALLURGY
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    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/02—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a non-macromolecular organic compound
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    • C10M127/00—Lubricating compositions characterised by the additive being a non- macromolecular hydrocarbon
    • C10M127/02—Lubricating compositions characterised by the additive being a non- macromolecular hydrocarbon well-defined aliphatic
    • C—CHEMISTRY; METALLURGY
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    • C10M131/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen and halogen only
    • C10M131/04—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen and halogen only aliphatic
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    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B2003/001—Aluminium or its alloys
    • C—CHEMISTRY; METALLURGY
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T83/00—Cutting
    • Y10T83/04—Processes
    • Y10T83/0405—With preparatory or simultaneous ancillary treatment of work
    • Y10T83/0443—By fluid application

Definitions

  • compositions which we have found useful for the above purpose are long chain olefins (also hereinafter identified as olefins or olefinic compositions) of at least carbon atoms having the general formula (I) where R and R are members selected from the class consisting of hydrogen and fluorine, and additionally R is selected from the class consisting of the methyl, fluoromethyl, difluoromethyl and trifluoromethyl radicals, and R" is a monovalent straight chain saturated aliphatic radical selected from the class consisting of linear alkyl radicals having at least 8 carbon atoms and linear fluoroalkyl radicals having at least 8 carbon atoms. Preferably, R" does not exceed 35 carbon atoms, although longer chain radicals may be used.
  • Included among the normal compounds (as contrasted to branched chain compounds) represented by Formula I are, for instance, decene-l, dodecene-l, tetradecene-l, u-methyl tetradecene-l, dodecene-2, tetradecene-Z, pentadecene-l, hexadecene-l (cetene), a-methyl hexadecene-l, octadecene-l, octadecene-2, l-fluorotetradecene-l, 1,2-difluorotetradecene-l, l-fluorohexadecene-l, trifluoro-hexadecene-l, 1,l,l,Z-tetrafluorohexadecene-2, etc., as well as mixtures of such olefins obtained from the cracking of parafiin products
  • olefinic material which is a straight chain unsaturated aliphatic hydrocarbon having olefinic unsaturation in the 1- or 2-positions of a chain length of from 12 to 25 carbon atoms.
  • the aforesaid olefins can be used alone or as mixtures thereof, or they can be mixed with other diluents and extenders whose presence does not significantly affect the ability of the olefins to cause the improvement in fabrication of the aluminum.
  • the olefins can be mixed with mineral oils of lubricating viscosity, diester compositions, etc.
  • viscous olefins or solid olefins it may be advantageous to dissolve the latter olefins in suitable solvents such as benzene, toluene, chlorinated hydrocarbons, kerosene, etc., to give fluid compositions which can be employed in the fabricating of the aluminum parts or objects.
  • suitable solvents such as benzene, toluene, chlorinated hydrocarbons, kerosene, etc.
  • Aqueous emulsions of the olefinic compositions can also be used to advantage in the fabrication of aluminum.
  • the solution and compounding of the solid olefinic compositions in other normally employed lubricating fluids, such as mineral (including hydrocarbon) oils and diester compositions, to make fluid mixtures of the olefins is included within the scope of our invention.
  • Concentrations of olefins in the aforesaid solvents or other lubricating compositions ranging from about to 95 percent, by weight, of the total weight of the solution or mixture are advantageously used.
  • the olefins can be compounded into the form of greases where such greases can advantageously be applied to the surface of aluminum members which will be subsequently subjected to fabricating techniques.
  • Typical of the mineral or hydrocarbon oils with which the olefinic compositions may be mixed are those obtained from petroleum having viscosities of from 25 to 10,000 Saybolt Universal seconds (S.U.S.) and may be a single hydrocarbon or mixture of hydrocarbons.
  • Typical of the diester lubricants are those disclosed in US. Patents 2,450,221, Ashburn et al.; 2,450,222, Ashburn et al.; and 2,977,301, Bergen et al.
  • aluminum or aluminum composition is intended to include not only aluminum itself, but also compositions in which the aluminum is present in an amount equal to at least 50 percent of the total weight of the composition, as for instance, aluminum alloys, etc.
  • Typical examples of the various aluminum compositions (including aluminum alloys) that can be lubricated by our lubricants are those disclosed on pages 851-853 and 865-958 of Metals Handbook, vol.
  • fabricating member is intended to include metallic forming members used in the fabrication of aluminum products which have a hardness greater than aluminum. These include cutting tools, extrusion and drawing dies, milling rolls, stamping and forging equipment, etc. These fabricating members are generally made of ferrous materials such as iron, steel, chrome steel, etc. When employing cutting fabricating members, or dies for extrusion or drawing purposes, these fabricating members are usually of a harder material such as tungsten carbide.
  • accretion is intended to mean the build-up, whether temporary, permanent or continuing, of aluminum on the contacting surface of the fabricating member.
  • the fabricating member when it first contacts the aluminum surface, breaks through the aluminum oxide film thereon (which is almost always present), and thereafter makes contact with the fresh aluminum surface.
  • This fresh aluminum surface in turn comes into contact with the surface of the fabricating member and, unless a suitable lubricant is used, tends to accrete or weld to the contacting surface of the fabricating member.
  • the buildup in amount or in time will depend upon the force exerted by the fabricating member and any liquid which is used at the frictional interface between the fabricating member and the aluminum work piece. Unless ths accretion or build-up is prevented, the fabricating member will then impart to the aluminum work piece (undergoing fabrication) surface defects such as lack of lustre, pitting, galling, and in some instances, seizing of the aluminum work piece.
  • cold Working of aluminum or cold rolling is intended to mean that fabrication of aluminum which takes place at temperatures below 350 C. (see The Light Metals Industry, by Winifred Lewis, published by Temple Press, Ltd., Bowling Green Lane, London, England [1949], page 226).
  • the temperature of the rolls or the sheet or of the aluminum member undergoing fabrication should be below 350 C. and advantageously that temperature at which the olefinic composition will not volatilize or will be of maximum usefulness in the fabrication of the aluminum object.
  • EXAMPLE 1 In the following example and in the succeeding examples, various olefinic hydrocarbons were used as cutting fluids in machining aluminum. In addition, a saturated hydrocarbon such as cetane was employed for comparison purposes as was a commercially available wax cutting composition which was used (as recommended by the manufacturer) in a mixture of one part, by weight, of the cutting wax to 10 parts of a spindle oil.
  • a saturated hydrocarbon such as cetane was employed for comparison purposes as was a commercially available wax cutting composition which was used (as recommended by the manufacturer) in a mixture of one part, by weight, of the cutting wax to 10 parts of a spindle oil.
  • the equipment used for carrying out these tests comprised an Axelson lathe, 14 inch swing, with a 20-horsepower variable speed drive.
  • the cutting tool was a tungsten carbide cutting tool of 27.8 BH-N.
  • the aluminum used was 1100 aluminum (28 Al) 1 /8 inch diameter and 24 inches long.
  • Each of the cutting fluids was evaluated in the manner in which cutting fluids are usually used by turning the aluminum bar at cutting speeds l0 and 57 feet per minute using a depth cut of 0.10 inch and a feed of 0.01 inch per revolution.
  • a four channel Sanborn recorder measured the forces from the three-component lathe dynamometer.
  • the feed forces encountered as well as the surface profile of the machined aluminum were determined, and the center line average (CLA) roughness was measured. These measurements were made after the aluminum was fed at 0.01 inch per revolution, the depth of the cut was 0.10 inch and the cutting speed was at ft. per minute. Determined under these conditions was the aluminum in the dry state, and using cutting fluids composed essentially of cetane, cetene, and the aforementioned commercial cutting wax in spindle oil (same as in Example 1).
  • Table IV shows the results of the feed force in pounds (F and the roughness obtained in each instance with the smaller values of roughness being indicative of a more polished surface.
  • EXAMPLE 4 The reason it was necessary to make four passes was that available commercial lubricants would not allow the rolls to effect greater reduction per pass without rupture of the aluminum film or would harm the surface (because of pick up or accretion of the aluminum) thereby causing unattractive blemished surfaces. However, when the mixture of olefins described above was substituted for the commercial lubricant and otherwise employing the same rolling conditions, it was possible to reduce the 0.085 inch aluminum sheet to 0.025 inch in two passes in accordance with the schedule below without damaging the sheet, by closing the space between the rolls with no need for additional power than was previously used in the four passes.
  • EXAMPLE 5 This example illustrates the effect of using other unsaturated organic compounds in place of the olefinic compounds of the present invention. More particularly, employing the equipment and type of aluminum described in Example 1, oleic acid (which has olefinic unsaturation in the middle of the molecule rather than the terminal unsaturation of the compounds used in the present invention);
  • an unsaturated polyester specifically a vegetable oil consisting essentially of glycerides of fatty acids in which, for the most part, the fatty acid residues were linoleic acid, oleic acid, and hexadecanoic acid (all of which are unsaturated acid residues), and small amounts of acid residues from palmitic acid, myristic, and stearic acids; as
  • Example 2 The comparison of the effects of using each of the above fluids was based mainly on the type of chip which was obtained by the cutting tool.
  • the ideal chip is one which is continuous in length without a built-up edge and is formed by continuous deformation of the metal ahead of the tool, without fracture, followed by smooth flow of the chip up the tool face. This type of chip is associated with low friction between the chip and the tool and is the most desirable type of chip from the point of view of finish, power consumption, and tool life.
  • the chips obtained with the other fluids namely the vegetable oil, the cetane, kerosene and oleic acid
  • the surface of the machined aluminum was quite rough and in some instances (such as with the cetane) appeared to be chewed up from the cutting tool; concurrently, there was a tendency for build-up along the edges of the cut sample, resulting from accretion of the particles of aluminum, indicating high resistance to sliding of the chip up the tool face.
  • Aluminum products made in accordance with the present invention can be used as electrical conductors, as foils and sheets for wrapping and packaging, as protective barriers, for instance, in construction of buildings, as decorative moldings for decorative purposes, etc.
  • the process for rolling aluminum which comprises supplying to the interface between the milling rolls and the aluminum being rolled, a film consisting essentially of a monomeric olefin having the general formula where R is selected from the class consisting of hydrogen and the methyl radical, and R" is a monovalent alkyl radical having from 8 to 20 carbon atoms in which substantially all of the carbons of the alkyl radical are in a straight chain.
  • the monomeric olefin is a mixture of linear straight chain olefinic hydrocarbons having carbon chain lengths of from C to C substantially all of the carbons of the linear olefinic hydrocarbons being in a straight chain.
  • the olefinic composition is a mixture of linear olefinic hydrocarbons having carbon chain lengths of from C to C substantially all of the carbons of the linear olefinic hydrocarbons being in a straight chain.
  • the process for cutting an aluminum work piece with a cutting tool which comprises interposing at the frictional interface between the cutting tool and the work piece a lubricant consisting essentially of .a mixture of linear straight chain olefinic hydrocarbons having carbon chain lengths of from C to C substantially all of the carbons of the olefinic hydrocarbons being in a straight chain, and thereafter reducing the size of the aluminum work piece by means of the cutting tool while maintaining the aforesaid mixture of hydrocarbons during such cutting action at the frictional interface.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)
US31852063 1963-10-24 1963-10-24 Fabricating aluminum products with olefin lubricants Expired - Lifetime US3288715A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US31852063 US3288715A (en) 1963-10-24 1963-10-24 Fabricating aluminum products with olefin lubricants
FR988127A FR1407623A (fr) 1963-10-24 1964-09-15 Procédé de fabrication de produits d'aluminium
GB3847464A GB1081135A (en) 1963-10-24 1964-09-21 Process for fabricating aluminum
DEP1270A DE1270724B (de) 1963-10-24 1964-10-21 Verwendung von Olefinen oder Mischungen von Olefinen als Schmiermittel zur spanlosen und spanabhebenden Bearbeitung von Aluminium
NL6412237A NL6412237A (de) 1963-10-24 1964-10-21

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3389105A (en) * 1965-03-05 1968-06-18 Alcan Metal Powders Inc Flake metal powders coated with fluorocarbon resin
US3499504A (en) * 1968-08-15 1970-03-10 Gen Electric Lubricated movable and interacting components for use in machines and a method for forming and breaking in such components
US3536622A (en) * 1967-12-11 1970-10-27 Sinclair Research Inc Biodegradable emulsifiable lubricant compositions
JPH02133495A (ja) * 1988-11-15 1990-05-22 Idemitsu Kosan Co Ltd 塑性加工用潤滑油剤
EP0369320A1 (de) * 1988-11-15 1990-05-23 Idemitsu Kosan Company Limited Schmierölzusammensetzung
EP0484542A1 (de) * 1990-05-14 1992-05-13 Idemitsu Kosan Company Limited Schmierstoffzusammensetzung für die metallbearbeitung
JPH05255678A (ja) * 1992-12-24 1993-10-05 Idemitsu Kosan Co Ltd 切削・研削用潤滑油剤
US5432152A (en) * 1993-06-01 1995-07-11 Albemarle Corporation Invert drilling fluid
US5716911A (en) * 1990-10-26 1998-02-10 Virginia Tech Intellectual Property, Inc. Method for reducing friction and wear of rubbing surfaces using anti-wear compounds in gaseous phase
WO1998006799A1 (en) * 1996-08-14 1998-02-19 Castrol Limited Lubricant for metal forming
US20050120548A1 (en) * 2003-12-09 2005-06-09 James Rohl Apparatus and method for cutting electrode foil layers
US20080053185A1 (en) * 2006-08-30 2008-03-06 Cardiac Pacemakers Inc. System and method for die cutting manifold including a lubrication channel

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2551639A (en) * 1947-07-22 1951-05-08 Socony Vacuum Oil Co Inc Reaction of olefins and halogenated alkanes
DE878431C (de) * 1942-03-03 1953-06-01 Dortmunder Paraffinwerke G M B Kuehl- und Schleifmittel fuer Metalle, insbesondere Leichtmetalle und ihre Legierungen
GB696960A (en) * 1949-11-05 1953-09-09 Bataafsche Petroleum Improvements in and relating to metal-working lubricants
US3167511A (en) * 1961-04-13 1965-01-26 Socony Mobil Oil Co Inc Metal working lubricant
US3208941A (en) * 1962-03-19 1965-09-28 Gen Electric Olefin-unsaturated ester lubricants

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE878431C (de) * 1942-03-03 1953-06-01 Dortmunder Paraffinwerke G M B Kuehl- und Schleifmittel fuer Metalle, insbesondere Leichtmetalle und ihre Legierungen
US2551639A (en) * 1947-07-22 1951-05-08 Socony Vacuum Oil Co Inc Reaction of olefins and halogenated alkanes
GB696960A (en) * 1949-11-05 1953-09-09 Bataafsche Petroleum Improvements in and relating to metal-working lubricants
US3167511A (en) * 1961-04-13 1965-01-26 Socony Mobil Oil Co Inc Metal working lubricant
US3208941A (en) * 1962-03-19 1965-09-28 Gen Electric Olefin-unsaturated ester lubricants

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3389105A (en) * 1965-03-05 1968-06-18 Alcan Metal Powders Inc Flake metal powders coated with fluorocarbon resin
US3536622A (en) * 1967-12-11 1970-10-27 Sinclair Research Inc Biodegradable emulsifiable lubricant compositions
US3499504A (en) * 1968-08-15 1970-03-10 Gen Electric Lubricated movable and interacting components for use in machines and a method for forming and breaking in such components
EP0579272A3 (de) * 1988-11-15 1994-02-09 Idemitsu Kosan Company Limited Schmierölzusammensetzung
JPH02133495A (ja) * 1988-11-15 1990-05-22 Idemitsu Kosan Co Ltd 塑性加工用潤滑油剤
EP0369320A1 (de) * 1988-11-15 1990-05-23 Idemitsu Kosan Company Limited Schmierölzusammensetzung
US5072067A (en) * 1988-11-15 1991-12-10 Idemitsu Kosan Company Limited Lubricating oil composition
EP0579272A2 (de) * 1988-11-15 1994-01-19 Idemitsu Kosan Company Limited Schmierölzusammensetzung
EP0484542A1 (de) * 1990-05-14 1992-05-13 Idemitsu Kosan Company Limited Schmierstoffzusammensetzung für die metallbearbeitung
EP0484542A4 (en) * 1990-05-14 1992-10-21 Idemitsu Kosan Company Limited Lubricant composition for metal working
US5716911A (en) * 1990-10-26 1998-02-10 Virginia Tech Intellectual Property, Inc. Method for reducing friction and wear of rubbing surfaces using anti-wear compounds in gaseous phase
JPH05255678A (ja) * 1992-12-24 1993-10-05 Idemitsu Kosan Co Ltd 切削・研削用潤滑油剤
US5432152A (en) * 1993-06-01 1995-07-11 Albemarle Corporation Invert drilling fluid
WO1998006799A1 (en) * 1996-08-14 1998-02-19 Castrol Limited Lubricant for metal forming
US20050120548A1 (en) * 2003-12-09 2005-06-09 James Rohl Apparatus and method for cutting electrode foil layers
US8033202B2 (en) * 2003-12-09 2011-10-11 Cardiac Pacemakers, Inc. Apparatus and method for cutting electrode foil layers
US20080053185A1 (en) * 2006-08-30 2008-03-06 Cardiac Pacemakers Inc. System and method for die cutting manifold including a lubrication channel

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Publication number Publication date
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DE1270724B (de) 1968-06-20
NL6412237A (de) 1965-04-26

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