US3287591A - Tantalum carbide incandescent lamp and method of manufacture thereof - Google Patents

Tantalum carbide incandescent lamp and method of manufacture thereof Download PDF

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Publication number
US3287591A
US3287591A US159100A US15910061A US3287591A US 3287591 A US3287591 A US 3287591A US 159100 A US159100 A US 159100A US 15910061 A US15910061 A US 15910061A US 3287591 A US3287591 A US 3287591A
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United States
Prior art keywords
coil
legs
tantalum carbide
filament
lamp
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Expired - Lifetime
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US159100A
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English (en)
Inventor
Howard B Sloan
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GTE Sylvania Inc
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Sylvania Electric Products Inc
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Filing date
Publication date
Priority to DENDAT1248799D priority Critical patent/DE1248799B/de
Priority to BE625922D priority patent/BE625922A/xx
Application filed by Sylvania Electric Products Inc filed Critical Sylvania Electric Products Inc
Priority to US159100A priority patent/US3287591A/en
Priority to GB46795/62A priority patent/GB961640A/en
Priority to FR918390A priority patent/FR1341187A/fr
Application granted granted Critical
Publication of US3287591A publication Critical patent/US3287591A/en
Anticipated expiration legal-status Critical
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01K—ELECTRIC INCANDESCENT LAMPS
    • H01K3/00—Apparatus or processes adapted to the manufacture, installing, removal, or maintenance of incandescent lamps or parts thereof
    • H01K3/02—Manufacture of incandescent bodies

Definitions

  • This invention relates to incandescent lamps of the type having a filament coil of tantalum carbide or the like.
  • the coil is generally made of a wire of tantalum metal, which is carburized after winding, resulting in a coil of tantalum carbide.
  • the tantalum metal coil has heretofore been mounted in a lamp bulb or on a lamp stem before being carburized.
  • the mounting can thus be done with the wire still metallic, before it is carburized to the brittle carbide.
  • the filament does not have to be handled after the carburizing, for it is already in place on the lamp stem.
  • the coils can be carburized before mounting, if the turns of the coil are filled with graphite powder to hold their shape during the process. A group of coils can then be carburized together in a furnace, and afterward mounted on lamp stems.
  • the coil is a coiled-coil, that is a so-called minor coil of small diameter which in itself is wound to form a major coil of large diameter
  • the graphite packing need only fill the minor coil and the spaces between turns of the major coil. filled.
  • the minor coil can be first filled with a thin, water suspension of colloidal graphite, held' in the minor coil by surface tension, and the graphite powder then pushed into the coil to form a paste, which is afterward dried.
  • the graphite powder can be placed in the coil in various ways, for example with a spatula, but I prefer to place a metal mandrel inside the major coil, and on that as an aXis, roll the coil in a layer of graphite powder of suflicient depth to allow filling of the coil.
  • the coil after drying, can be heated at a suitable temperature for carburizing, in a proper atmosphere.
  • the movement of the turns, which would take place in an unpacked coil, is now restricted by the graphite packing, which remains in place during the carburizing process.
  • the orientation after carburizilng may be incorrect, and
  • the legs can be of wire-shaped tantalum carbide, for example, and can be cemented to the lead-in wires as well as the coil.
  • tantalum powder in a suitable binder such as a lacquer
  • the lead-in wires can have a notch into which the legs can be inserted to be cemented, the notch being preferably formed by a V-shaped fork at the end of the lead-inwires. The notch will help to keep the leg in place until the cement is set by sintering.
  • the carburized coil After the carburized coil is mounted on the support or lead-in wires, it is heated in an atmosphere of hydrogen and a hydrocarbon, by passing current through the coil. The heating can be carried to a temperature high enough for effective carburization. graphite will be removed by reacting with the hydrogen.
  • the heating will also burn out the binder in the cement, alloy the tantalum and cobalt therein to some extent, carburize the tantalum powder, evaporate the excess cobalt, and give a sintered bond between the tantalum carbide coil and the tantalum metal support.
  • the joint between the tantalum carbide leg andithe support wire can be arcwelded in an atmosphere of inert gas, such as argon. That type of welding avoids the shock to the tantalum carbidethat would occur if the legs were spotwelded by being contacted by electrodes or if they were clamped in the manner usual in the lamp art. Such a shock could destroy the brittle filament.
  • the lead-in wire to which the legs are welded can be of molybdenum, at
  • FIGURE 1 is a cross-sectional view, showing a filament coil of tantalum metal, with a packing of graphite powder, and ready to be carburized.
  • FIGURE 2 shows the carburized filament, with legs
  • the cement used can be a thin paste of.
  • FIGURE 3 is a perspective view of a finished lamp mount according to the invention, before the mount is sealed into a lamp bulb.
  • the coil 1 of metallic tantalum wire is a coiled-coil, that is the wire is coiled into a coil 2 of small diameter and this coil 2 itself then wound into a coil 3 of larger diameter.
  • the tantalum wire had a diameter of 8.5 mils and the first coil was wound to an inside diameter of 14 mils.
  • The'number of turns per inch in the first coil was 64
  • the number of turns per inch in the second coil was 28, and the coil had an axial length of about 0.2 inch.
  • the coil was dipped into a colloidal suspension of carbon, for example, the type known commercially as Aquadag, diluted with about half its volume of water.
  • the colloidal suspension should preferably just fill the turns of the smaller diameter coil 2, and the spaces between adjacent turns of the major coil.
  • the suspension can beapplied with a spatula, although painting the suspension onto the surface of the wire is often sufficient.
  • a wire mandrel of steel, tungsten or other suitable material is inserted inside the larger diameter coiling, to make a loosely fitting axis around which the coil can turn freely, and the coil, while still wet with the suspension, is rolled in a layer of powdered graphite until the small diameter coil and the spaces between adjacent turns of the major coil are filled with the graphite powder and the colloidal suspension.
  • the resultant filling 4, 5 is in the nature of a paste.
  • the coil is then dried at room temperature or somewhat above but not high enough to boil the water in the paste.
  • the use of a colloidal carbon suspension can be omitted and the coil filled directly with graphite powder.
  • the presence of a small amount of liquid binder in the coil will greatly facilitate the application of the graphite powder.
  • the carbon-packed coil is then placed in a graphite boat, covered with graphite powder, and heated in an electric furnace at a temperature of about 1800 C. for about '40 minutes, the temperature then being raised to about 2200 C. in about 5 minutes and the heating continued for about an additional hour and a quarter.
  • An atmosphere of argon and hydrocarbon or other suitable atmosphere is present in the furnace during the heating.
  • each end of the coil 1 is lain across an end of the corresponding leg 6, 7 and a quantity of cement 8, 9 placed around each junction, the cement being composed of 97% tantalum metal powder and 3% 8, 9 as shown in FIG. 3, similar to the above but contain-- ing 5% cobalt, is then placed around the junction of the leg 6 and the notch 12.
  • the support wiresl4, 1-5 are molybdenum, molybdenum powder can be used instead of the tantalum and cobalt.
  • the mount is placed in a bell jar (not shown) through which is flowing an atmosphere of hydrogen and hydrocarbon. About 9 amperes current is passed through the filament of about /2 minute to raise the temperature to about2600 C. This will set'the cement and sinter the tantalum carbide legs to the coil and leads. The current is reduced to about 7 or 8 amps (to reduce the temperature to about 2100? C.) and heating continued at constant voltage until the current becomes constant. There is usually a rise 'in'current before stability is reached, indicating a change in carbon content and density. This requires about 10 to 30 minutes.
  • the joint between the leg and lead-in wire is then'arc 4- welded.
  • the arc welding may also be applied to the joint 8, 9 between legs 6, 7 and coil 1 to fuse the cement at this point.
  • the support wires 14, are welded respectively to the intermediate support wires 18, 19, the latter two wires being heldfixed by the ceramic button through which they pass and in which they are tightly held. This results in a firm positioning of the coil 1 in a rigid structure,
  • the lead-in wires 32, 23 act as external contact prongs, being sealed through the glass header or disc 26, having the usual exhaust tube 27.
  • the additional lead-in wires 28, 29 can help to position the resultant lamp in a sprocket, and can be used to carry a fuse wire, if one is desired in series with the filament, or to support a reflector in optical relationship to the coil 1.
  • the opening 30 in button 20 can also carry a support for a reflector, if desired. Other suitable types of mount can be used.
  • the lamp In arc-welding the legs, 8, 9 to the support wires 14, 15 the lamp can be placed in an inverted bell jar into which argon gas is flowed at the lower end, at a pressure slightly above atmosphere.
  • the open end of the bell jar will be the top (because of its inverted position) and the lamp mount of FIG. 2 can be supported from the bottom of the bell jar, especially if the diameter of the jar is only slightly larger than that of the header 26.
  • the argon can enter from a tube in the rounded bottom of the bell jar.
  • the top or open end of the jar can be partially covered by a solid plate, an opening being left through which the welding electrode can be inserted.
  • the lead-in wires are connected together and to one side of a 220 volt power line.
  • the other side of the line can be connected to a pointed rod-like welding electrode of a suitable material, such as carbon or tungsten, of about inch in diameter, a current limiting resistance being connected in series with the electrode, from which an arc of about or inch is passed to the joint 16, 17 to be welded.
  • a current of about 8 amperes is passed through the arc, and the welding requires only a few seconds.
  • the arc welding in argon can also be done by other suitable methods.
  • the arc welding makes an efiective permanent joint between the leg 6, 7 and the support wire 14, 15.
  • the cement 16 may not become sufficiently hot to 'sinter the cement and set it properly, because the leadin wires 14, 15 are thicker than the filament of coil 1. For this reason arc welding is superior.
  • the cement 8, 9 used to afiix the coil 1 to the legs 8, 9 is nearer the hot coil and so will be more readily heated to the sintering point. However, even there, an improvement is effected by arc welding.
  • the lead-in wires 32, 23, 28, 29 can be of suitable 7 material well-known in the art, for sealing through the glass used, and the intermediate support wires 18, 19 can A be of 40 'mil diameter nickel.
  • the support wires 14, 15 are of molybdenum wire 40 mils diameter. The whole mount is then a unitary assembly in which the filament coil of tantalum carbide is supported in a position fixed may be applied to the header 25 or its rigidly connected.
  • a lamp bulb is then sealed at its open end to the rim 31 I of the header 25 to form a complete lamp, as in the previously-mentioned copending application of Howard B. Sloan and Sandford C. Peek.
  • Various other suitable features of the filament mount of that application can be used with the device of the present invention as will be apparent to a person skilled in the art.
  • the lamp can be filled with a suitable gas.
  • the remaining graphite should be removed. This can be done in various ways, for example, by gently sand-blasting the coil with an airbrush carrying a stream of firm abrasive particles in a stream of air.
  • a Pasche airbrush, with AEX air-erasing compound, has proven satisfactory.
  • the abrasive can be a firm grit, such as alundum of particles of a size which can pass through about a ZOO-mesh standard sieve.
  • the air pressure applied to the brush input can be of any suitable value, for example, about 50 pounds per square inch gauge pressure.
  • Another method of removing the graphite is to put the coil in a container filled with Water and then apply a supersonic vibration.
  • the specific coil described was wound so that the second coiling had an inside diameter of 30 mils.
  • a lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from it, and a support wire cemented to the otherwire free end of said leg.
  • a lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from the coil, and a support wire cemented and arc-Welded to the otherwise free end of said leg.
  • a lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from the coil, and a molybdenum support wire cemented to the otherwise free end of said leg.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Furnace Details (AREA)
  • Carbon And Carbon Compounds (AREA)
US159100A 1961-12-13 1961-12-13 Tantalum carbide incandescent lamp and method of manufacture thereof Expired - Lifetime US3287591A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DENDAT1248799D DE1248799B (en)) 1961-12-13
BE625922D BE625922A (en)) 1961-12-13
US159100A US3287591A (en) 1961-12-13 1961-12-13 Tantalum carbide incandescent lamp and method of manufacture thereof
GB46795/62A GB961640A (en) 1961-12-13 1962-12-11 Incandescent lamp
FR918390A FR1341187A (fr) 1961-12-13 1962-12-12 Lampe à incandescence

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US159100A US3287591A (en) 1961-12-13 1961-12-13 Tantalum carbide incandescent lamp and method of manufacture thereof

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US3287591A true US3287591A (en) 1966-11-22

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3548244A (en) * 1968-07-01 1970-12-15 British Lighting Ind Ltd Lamp having twin filaments and integral filament legs mounted in a bridge
US3633062A (en) * 1968-05-28 1972-01-04 Ise Electronics Corp Direct-heated cathode electrodes with cathode shield for electron guns
US3792224A (en) * 1971-07-19 1974-02-12 Westinghouse Electric Corp Method for making non-tangling beaded filament coils
US3824421A (en) * 1971-09-09 1974-07-16 Philips Corp Electric filament lamp
US4032809A (en) * 1966-03-21 1977-06-28 Westinghouse Electric Corporation Tantalum carbide or tantalum-alloy carbide filament mounting and method
US4878866A (en) * 1986-07-14 1989-11-07 Denki Kagaku Kogyo Kabushiki Kaisha Thermionic cathode structure
US5148080A (en) * 1990-01-16 1992-09-15 Hilux Development Incandescent lamp filament incorporating hafnium
US5777435A (en) * 1995-10-20 1998-07-07 U.S. Philips Corporation Electric lamp having a current conductor with a kinked longitudinal portion
WO2007063008A3 (de) * 2005-11-30 2007-10-11 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Halogenglühlampe mit carbidhaltigem leuchtkörper
US20100181907A1 (en) * 2007-06-20 2010-07-22 Koninklijke Philips Electronics N.V. Tantalum carbide filament lamp and process for the production thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US479360A (en) * 1892-07-19 Henry green
US2175345A (en) * 1935-07-12 1939-10-10 Gen Electric Electric gaseous discharge device
US2327031A (en) * 1942-08-10 1943-08-17 Gen Electric Stem and mount construction
US2434478A (en) * 1943-12-22 1948-01-13 Westinghouse Electric Corp Incandescent electric lamp and method
US2542656A (en) * 1941-01-31 1951-02-20 Hartford Nat Bank & Trust Co Indirectly heated cathode
US2716714A (en) * 1951-08-20 1955-08-30 Westinghouse Electric Corp Incandescent electric lamp
US2961568A (en) * 1957-11-14 1960-11-22 Gen Electric Filament joint for incandescent lamps
US3022438A (en) * 1959-09-10 1962-02-20 Polaroid Corp Electric lamps

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US479360A (en) * 1892-07-19 Henry green
US2175345A (en) * 1935-07-12 1939-10-10 Gen Electric Electric gaseous discharge device
US2542656A (en) * 1941-01-31 1951-02-20 Hartford Nat Bank & Trust Co Indirectly heated cathode
US2327031A (en) * 1942-08-10 1943-08-17 Gen Electric Stem and mount construction
US2434478A (en) * 1943-12-22 1948-01-13 Westinghouse Electric Corp Incandescent electric lamp and method
US2716714A (en) * 1951-08-20 1955-08-30 Westinghouse Electric Corp Incandescent electric lamp
US2961568A (en) * 1957-11-14 1960-11-22 Gen Electric Filament joint for incandescent lamps
US3022438A (en) * 1959-09-10 1962-02-20 Polaroid Corp Electric lamps

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032809A (en) * 1966-03-21 1977-06-28 Westinghouse Electric Corporation Tantalum carbide or tantalum-alloy carbide filament mounting and method
US3633062A (en) * 1968-05-28 1972-01-04 Ise Electronics Corp Direct-heated cathode electrodes with cathode shield for electron guns
US3548244A (en) * 1968-07-01 1970-12-15 British Lighting Ind Ltd Lamp having twin filaments and integral filament legs mounted in a bridge
US3792224A (en) * 1971-07-19 1974-02-12 Westinghouse Electric Corp Method for making non-tangling beaded filament coils
US3824421A (en) * 1971-09-09 1974-07-16 Philips Corp Electric filament lamp
US4878866A (en) * 1986-07-14 1989-11-07 Denki Kagaku Kogyo Kabushiki Kaisha Thermionic cathode structure
US5148080A (en) * 1990-01-16 1992-09-15 Hilux Development Incandescent lamp filament incorporating hafnium
US5777435A (en) * 1995-10-20 1998-07-07 U.S. Philips Corporation Electric lamp having a current conductor with a kinked longitudinal portion
WO2007063008A3 (de) * 2005-11-30 2007-10-11 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Halogenglühlampe mit carbidhaltigem leuchtkörper
US20100181907A1 (en) * 2007-06-20 2010-07-22 Koninklijke Philips Electronics N.V. Tantalum carbide filament lamp and process for the production thereof

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DE1248799B (en))
GB961640A (en) 1964-06-24
BE625922A (en))

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