US3287591A - Tantalum carbide incandescent lamp and method of manufacture thereof - Google Patents
Tantalum carbide incandescent lamp and method of manufacture thereof Download PDFInfo
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- US3287591A US3287591A US159100A US15910061A US3287591A US 3287591 A US3287591 A US 3287591A US 159100 A US159100 A US 159100A US 15910061 A US15910061 A US 15910061A US 3287591 A US3287591 A US 3287591A
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- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 title claims description 18
- 229910003468 tantalcarbide Inorganic materials 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000004568 cement Substances 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 25
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 13
- 229910002804 graphite Inorganic materials 0.000 description 11
- 239000010439 graphite Substances 0.000 description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
- 238000003466 welding Methods 0.000 description 10
- 239000000725 suspension Substances 0.000 description 7
- 238000005255 carburizing Methods 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052715 tantalum Inorganic materials 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000004323 axial length Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005493 welding type Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K3/00—Apparatus or processes adapted to the manufacture, installing, removal, or maintenance of incandescent lamps or parts thereof
- H01K3/02—Manufacture of incandescent bodies
Definitions
- This invention relates to incandescent lamps of the type having a filament coil of tantalum carbide or the like.
- the coil is generally made of a wire of tantalum metal, which is carburized after winding, resulting in a coil of tantalum carbide.
- the tantalum metal coil has heretofore been mounted in a lamp bulb or on a lamp stem before being carburized.
- the mounting can thus be done with the wire still metallic, before it is carburized to the brittle carbide.
- the filament does not have to be handled after the carburizing, for it is already in place on the lamp stem.
- the coils can be carburized before mounting, if the turns of the coil are filled with graphite powder to hold their shape during the process. A group of coils can then be carburized together in a furnace, and afterward mounted on lamp stems.
- the coil is a coiled-coil, that is a so-called minor coil of small diameter which in itself is wound to form a major coil of large diameter
- the graphite packing need only fill the minor coil and the spaces between turns of the major coil. filled.
- the minor coil can be first filled with a thin, water suspension of colloidal graphite, held' in the minor coil by surface tension, and the graphite powder then pushed into the coil to form a paste, which is afterward dried.
- the graphite powder can be placed in the coil in various ways, for example with a spatula, but I prefer to place a metal mandrel inside the major coil, and on that as an aXis, roll the coil in a layer of graphite powder of suflicient depth to allow filling of the coil.
- the coil after drying, can be heated at a suitable temperature for carburizing, in a proper atmosphere.
- the movement of the turns, which would take place in an unpacked coil, is now restricted by the graphite packing, which remains in place during the carburizing process.
- the orientation after carburizilng may be incorrect, and
- the legs can be of wire-shaped tantalum carbide, for example, and can be cemented to the lead-in wires as well as the coil.
- tantalum powder in a suitable binder such as a lacquer
- the lead-in wires can have a notch into which the legs can be inserted to be cemented, the notch being preferably formed by a V-shaped fork at the end of the lead-inwires. The notch will help to keep the leg in place until the cement is set by sintering.
- the carburized coil After the carburized coil is mounted on the support or lead-in wires, it is heated in an atmosphere of hydrogen and a hydrocarbon, by passing current through the coil. The heating can be carried to a temperature high enough for effective carburization. graphite will be removed by reacting with the hydrogen.
- the heating will also burn out the binder in the cement, alloy the tantalum and cobalt therein to some extent, carburize the tantalum powder, evaporate the excess cobalt, and give a sintered bond between the tantalum carbide coil and the tantalum metal support.
- the joint between the tantalum carbide leg andithe support wire can be arcwelded in an atmosphere of inert gas, such as argon. That type of welding avoids the shock to the tantalum carbidethat would occur if the legs were spotwelded by being contacted by electrodes or if they were clamped in the manner usual in the lamp art. Such a shock could destroy the brittle filament.
- the lead-in wire to which the legs are welded can be of molybdenum, at
- FIGURE 1 is a cross-sectional view, showing a filament coil of tantalum metal, with a packing of graphite powder, and ready to be carburized.
- FIGURE 2 shows the carburized filament, with legs
- the cement used can be a thin paste of.
- FIGURE 3 is a perspective view of a finished lamp mount according to the invention, before the mount is sealed into a lamp bulb.
- the coil 1 of metallic tantalum wire is a coiled-coil, that is the wire is coiled into a coil 2 of small diameter and this coil 2 itself then wound into a coil 3 of larger diameter.
- the tantalum wire had a diameter of 8.5 mils and the first coil was wound to an inside diameter of 14 mils.
- The'number of turns per inch in the first coil was 64
- the number of turns per inch in the second coil was 28, and the coil had an axial length of about 0.2 inch.
- the coil was dipped into a colloidal suspension of carbon, for example, the type known commercially as Aquadag, diluted with about half its volume of water.
- the colloidal suspension should preferably just fill the turns of the smaller diameter coil 2, and the spaces between adjacent turns of the major coil.
- the suspension can beapplied with a spatula, although painting the suspension onto the surface of the wire is often sufficient.
- a wire mandrel of steel, tungsten or other suitable material is inserted inside the larger diameter coiling, to make a loosely fitting axis around which the coil can turn freely, and the coil, while still wet with the suspension, is rolled in a layer of powdered graphite until the small diameter coil and the spaces between adjacent turns of the major coil are filled with the graphite powder and the colloidal suspension.
- the resultant filling 4, 5 is in the nature of a paste.
- the coil is then dried at room temperature or somewhat above but not high enough to boil the water in the paste.
- the use of a colloidal carbon suspension can be omitted and the coil filled directly with graphite powder.
- the presence of a small amount of liquid binder in the coil will greatly facilitate the application of the graphite powder.
- the carbon-packed coil is then placed in a graphite boat, covered with graphite powder, and heated in an electric furnace at a temperature of about 1800 C. for about '40 minutes, the temperature then being raised to about 2200 C. in about 5 minutes and the heating continued for about an additional hour and a quarter.
- An atmosphere of argon and hydrocarbon or other suitable atmosphere is present in the furnace during the heating.
- each end of the coil 1 is lain across an end of the corresponding leg 6, 7 and a quantity of cement 8, 9 placed around each junction, the cement being composed of 97% tantalum metal powder and 3% 8, 9 as shown in FIG. 3, similar to the above but contain-- ing 5% cobalt, is then placed around the junction of the leg 6 and the notch 12.
- the support wiresl4, 1-5 are molybdenum, molybdenum powder can be used instead of the tantalum and cobalt.
- the mount is placed in a bell jar (not shown) through which is flowing an atmosphere of hydrogen and hydrocarbon. About 9 amperes current is passed through the filament of about /2 minute to raise the temperature to about2600 C. This will set'the cement and sinter the tantalum carbide legs to the coil and leads. The current is reduced to about 7 or 8 amps (to reduce the temperature to about 2100? C.) and heating continued at constant voltage until the current becomes constant. There is usually a rise 'in'current before stability is reached, indicating a change in carbon content and density. This requires about 10 to 30 minutes.
- the joint between the leg and lead-in wire is then'arc 4- welded.
- the arc welding may also be applied to the joint 8, 9 between legs 6, 7 and coil 1 to fuse the cement at this point.
- the support wires 14, are welded respectively to the intermediate support wires 18, 19, the latter two wires being heldfixed by the ceramic button through which they pass and in which they are tightly held. This results in a firm positioning of the coil 1 in a rigid structure,
- the lead-in wires 32, 23 act as external contact prongs, being sealed through the glass header or disc 26, having the usual exhaust tube 27.
- the additional lead-in wires 28, 29 can help to position the resultant lamp in a sprocket, and can be used to carry a fuse wire, if one is desired in series with the filament, or to support a reflector in optical relationship to the coil 1.
- the opening 30 in button 20 can also carry a support for a reflector, if desired. Other suitable types of mount can be used.
- the lamp In arc-welding the legs, 8, 9 to the support wires 14, 15 the lamp can be placed in an inverted bell jar into which argon gas is flowed at the lower end, at a pressure slightly above atmosphere.
- the open end of the bell jar will be the top (because of its inverted position) and the lamp mount of FIG. 2 can be supported from the bottom of the bell jar, especially if the diameter of the jar is only slightly larger than that of the header 26.
- the argon can enter from a tube in the rounded bottom of the bell jar.
- the top or open end of the jar can be partially covered by a solid plate, an opening being left through which the welding electrode can be inserted.
- the lead-in wires are connected together and to one side of a 220 volt power line.
- the other side of the line can be connected to a pointed rod-like welding electrode of a suitable material, such as carbon or tungsten, of about inch in diameter, a current limiting resistance being connected in series with the electrode, from which an arc of about or inch is passed to the joint 16, 17 to be welded.
- a current of about 8 amperes is passed through the arc, and the welding requires only a few seconds.
- the arc welding in argon can also be done by other suitable methods.
- the arc welding makes an efiective permanent joint between the leg 6, 7 and the support wire 14, 15.
- the cement 16 may not become sufficiently hot to 'sinter the cement and set it properly, because the leadin wires 14, 15 are thicker than the filament of coil 1. For this reason arc welding is superior.
- the cement 8, 9 used to afiix the coil 1 to the legs 8, 9 is nearer the hot coil and so will be more readily heated to the sintering point. However, even there, an improvement is effected by arc welding.
- the lead-in wires 32, 23, 28, 29 can be of suitable 7 material well-known in the art, for sealing through the glass used, and the intermediate support wires 18, 19 can A be of 40 'mil diameter nickel.
- the support wires 14, 15 are of molybdenum wire 40 mils diameter. The whole mount is then a unitary assembly in which the filament coil of tantalum carbide is supported in a position fixed may be applied to the header 25 or its rigidly connected.
- a lamp bulb is then sealed at its open end to the rim 31 I of the header 25 to form a complete lamp, as in the previously-mentioned copending application of Howard B. Sloan and Sandford C. Peek.
- Various other suitable features of the filament mount of that application can be used with the device of the present invention as will be apparent to a person skilled in the art.
- the lamp can be filled with a suitable gas.
- the remaining graphite should be removed. This can be done in various ways, for example, by gently sand-blasting the coil with an airbrush carrying a stream of firm abrasive particles in a stream of air.
- a Pasche airbrush, with AEX air-erasing compound, has proven satisfactory.
- the abrasive can be a firm grit, such as alundum of particles of a size which can pass through about a ZOO-mesh standard sieve.
- the air pressure applied to the brush input can be of any suitable value, for example, about 50 pounds per square inch gauge pressure.
- Another method of removing the graphite is to put the coil in a container filled with Water and then apply a supersonic vibration.
- the specific coil described was wound so that the second coiling had an inside diameter of 30 mils.
- a lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from it, and a support wire cemented to the otherwire free end of said leg.
- a lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from the coil, and a support wire cemented and arc-Welded to the otherwise free end of said leg.
- a lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from the coil, and a molybdenum support wire cemented to the otherwise free end of said leg.
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Description
1966 H. B. SLOAN 3,287,591
TANTALUM CARBIDE INCANDESCENT LAMP AND METHOD OF MANUFACTURE THEREOF Filed Dec. 13, 1961 HOWARD B. SLOAN INVENTOR.
23W mw,
ATTORNEY United States Patent This invention relates to incandescent lamps of the type having a filament coil of tantalum carbide or the like. The coil is generally made of a wire of tantalum metal, which is carburized after winding, resulting in a coil of tantalum carbide.
Because of the brittleness of the carbide, the tantalum metal coil has heretofore been mounted in a lamp bulb or on a lamp stem before being carburized. The mounting can thus be done with the wire still metallic, before it is carburized to the brittle carbide. The filament does not have to be handled after the carburizing, for it is already in place on the lamp stem.
Such a procedure is not readily adaptable to high-speed machinery, because each coil has to be carburized separately, by passing current through the coil by either conduction or induction. The lamps or lamp stems, on which the metal coil is mounted, cannot be placed several at a time in a carburiz ing furnace, because the lamps and stems are usually of glass, which would melt long before the carburizing temperature was reached. Yet the coils cannot simply be placed in a furnace with the proper atmosphere and heated to carburization, because they expand more than 20% in volume during the process, apparently because of the re-crystallization in changing from the metal to the carbide, and this distorts the coil. The turns may move closer together in some places so as to touch and short-circuit, and farther apart in others, the kind of movement depending onthe initial stresses produced in each part of the wire during drawing and coiling, thus resulting in a haphazard disordered coil.
Moreover, handling the brittle filament after it is carburized, and any attempt to attach it to lead-in and support wires in a lamp at that stage in the process, is likely to destroy the brittle coil entirely.
These problems become even more acute when the filament is wound into a coiled-coil, the type of winding most commonly used in modern lamp practice.
I have discovered, however, that the coils can be carburized before mounting, if the turns of the coil are filled with graphite powder to hold their shape during the process. A group of coils can then be carburized together in a furnace, and afterward mounted on lamp stems.
When the coil is a coiled-coil, that is a so-called minor coil of small diameter which in itself is wound to form a major coil of large diameter, the graphite packing need only fill the minor coil and the spaces between turns of the major coil. filled. In such cases, the minor coil can be first filled with a thin, water suspension of colloidal graphite, held' in the minor coil by surface tension, and the graphite powder then pushed into the coil to form a paste, which is afterward dried. The graphite powder can be placed in the coil in various ways, for example with a spatula, but I prefer to place a metal mandrel inside the major coil, and on that as an aXis, roll the coil in a layer of graphite powder of suflicient depth to allow filling of the coil.
The coil, after drying, can be heated at a suitable temperature for carburizing, in a proper atmosphere. The movement of the turns, which would take place in an unpacked coil, is now restricted by the graphite packing, which remains in place during the carburizing process.
For reasons to be explained, it is best to use coils which The inside of the major coil need not be do not have the outwardly extending legs which are customary in lamp practice. The usual tungsten filament coils have had uncoiled legs extending along or parallel to the extended longitudinal axis of the coil, or when a coiled-coil was used, the main or middle part of the coil was a coiled-coil and the legs simply single coils. legs maintain their position satisfactorily in the tungsten filament generally used theretofore, and the position of the coil can even be adjusted after mounting, if necessary, by bending the legs. With tantalum carbide, however,
such bending of the legs after mounting is impossible, because of the brittleness of the material, and jwhile the configuration of the coil can be maintained by having it packed with graphite during carburi'zation, as described above, the orientation of the legs is difficult to mainatin.
The orientation after carburizilng may be incorrect, and
bending them to the correct configuration is then impossible.
In a further aspect of my invention, therefor, I carburize the" coils without legs, then attach legs to the ends of the coil afterward, for example by cementing them in place. The legs can be of wire-shaped tantalum carbide, for example, and can be cemented to the lead-in wires as well as the coil. tantalum powder in a suitable binder, such as a lacquer,
a small amount of cobalt powder being mixed with the tantalum to make the cement more effective.
The lead-in wires can have a notch into which the legs can be inserted to be cemented, the notch being preferably formed by a V-shaped fork at the end of the lead-inwires. The notch will help to keep the leg in place until the cement is set by sintering.
Afterthe carburized coil is mounted on the support or lead-in wires, it is heated in an atmosphere of hydrogen and a hydrocarbon, by passing current through the coil. The heating can be carried to a temperature high enough for effective carburization. graphite will be removed by reacting with the hydrogen.
The heating will also burn out the binder in the cement, alloy the tantalum and cobalt therein to some extent, carburize the tantalum powder, evaporate the excess cobalt, and give a sintered bond between the tantalum carbide coil and the tantalum metal support.
To make the bond even stronger, I have discovered that the joint between the tantalum carbide leg andithe support wire can be arcwelded in an atmosphere of inert gas, such as argon. That type of welding avoids the shock to the tantalum carbidethat would occur if the legs were spotwelded by being contacted by electrodes or if they were clamped in the manner usual in the lamp art. Such a shock could destroy the brittle filament. The lead-in wire to which the legs are welded can be of molybdenum, at
Other objects, advantages and feaures o'f the invention will be apparent from the following specification, taken in conjunction with the accompanying'drawings, in which: FIGURE 1 is a cross-sectional view, showing a filament coil of tantalum metal, with a packing of graphite powder, and ready to be carburized.
FIGURE 2 shows the carburized filament, with legs The The cement used can be a thin paste of.
Any adhering particles of attached'and readyrto be inserted into the notches at the ends of the lead-in wires; and
FIGURE 3 is a perspective view of a finished lamp mount according to the invention, before the mount is sealed into a lamp bulb.
In FIGURE 1,'the coil 1 of metallic tantalum wire is a coiled-coil, that is the wire is coiled into a coil 2 of small diameter and this coil 2 itself then wound into a coil 3 of larger diameter. In one coil according to the invention, the tantalum wire had a diameter of 8.5 mils and the first coil was wound to an inside diameter of 14 mils. The'number of turns per inch in the first coil was 64, the number of turns per inch in the second coil was 28, and the coil had an axial length of about 0.2 inch. After being wound, the coil was dipped into a colloidal suspension of carbon, for example, the type known commercially as Aquadag, diluted with about half its volume of water.
The colloidal suspension should preferably just fill the turns of the smaller diameter coil 2, and the spaces between adjacent turns of the major coil. The suspension can beapplied with a spatula, although painting the suspension onto the surface of the wire is often sufficient. A wire mandrel of steel, tungsten or other suitable material is inserted inside the larger diameter coiling, to make a loosely fitting axis around which the coil can turn freely, and the coil, while still wet with the suspension, is rolled in a layer of powdered graphite until the small diameter coil and the spaces between adjacent turns of the major coil are filled with the graphite powder and the colloidal suspension. The resultant filling 4, 5 is in the nature of a paste. The coil is then dried at room temperature or somewhat above but not high enough to boil the water in the paste.
If desired, the use of a colloidal carbon suspension can be omitted and the coil filled directly with graphite powder. The presence of a small amount of liquid binder in the coil will greatly facilitate the application of the graphite powder.
The carbon-packed coil is then placed in a graphite boat, covered with graphite powder, and heated in an electric furnace at a temperature of about 1800 C. for about '40 minutes, the temperature then being raised to about 2200 C. in about 5 minutes and the heating continued for about an additional hour and a quarter. An atmosphere of argon and hydrocarbon or other suitable atmosphere is present in the furnace during the heating.
After the coil is taken out of the furnace the remaining graphite is removed, and each end of the coil 1 is lain across an end of the corresponding leg 6, 7 and a quantity of cement 8, 9 placed around each junction, the cement being composed of 97% tantalum metal powder and 3% 8, 9 as shown in FIG. 3, similar to the above but contain-- ing 5% cobalt, is then placed around the junction of the leg 6 and the notch 12. If the support wiresl4, 1-5 are molybdenum, molybdenum powder can be used instead of the tantalum and cobalt.
The mount is placed in a bell jar (not shown) through which is flowing an atmosphere of hydrogen and hydrocarbon. About 9 amperes current is passed through the filament of about /2 minute to raise the temperature to about2600 C. This will set'the cement and sinter the tantalum carbide legs to the coil and leads. The current is reduced to about 7 or 8 amps (to reduce the temperature to about 2100? C.) and heating continued at constant voltage until the current becomes constant. There is usually a rise 'in'current before stability is reached, indicating a change in carbon content and density. This requires about 10 to 30 minutes.
The joint between the leg and lead-in wire is then'arc 4- welded. The arc welding may also be applied to the joint 8, 9 between legs 6, 7 and coil 1 to fuse the cement at this point.
The support wires 14, are welded respectively to the intermediate support wires 18, 19, the latter two wires being heldfixed by the ceramic button through which they pass and in which they are tightly held. This results in a firm positioning of the coil 1 in a rigid structure,
with the ends 21, 22 of intermediate support wires 18, 19, being merchanically and electrically connected to the rigid lead-in wires 32, 23, through the vibration-damping spiral rolls 24, 25 of nickel wire mesh, for example by welding, as in copending patent application Serial No. 62,678, filed October 14, 1960, now Patent No. 3,114,069, by Howard B. Sloan and Sandford C. Peek.
The lead-in wires 32, 23 act as external contact prongs, being sealed through the glass header or disc 26, having the usual exhaust tube 27. The additional lead-in wires 28, 29 can help to position the resultant lamp in a sprocket, and can be used to carry a fuse wire, if one is desired in series with the filament, or to support a reflector in optical relationship to the coil 1. The opening 30 in button 20 can also carry a support for a reflector, if desired. Other suitable types of mount can be used.
In arc-welding the legs, 8, 9 to the support wires 14, 15 the lamp can be placed in an inverted bell jar into which argon gas is flowed at the lower end, at a pressure slightly above atmosphere. The open end of the bell jar will be the top (because of its inverted position) and the lamp mount of FIG. 2 can be supported from the bottom of the bell jar, especially if the diameter of the jar is only slightly larger than that of the header 26. The argon can enter from a tube in the rounded bottom of the bell jar. The top or open end of the jar can be partially covered by a solid plate, an opening being left through which the welding electrode can be inserted.
The lead-in wires are connected together and to one side of a 220 volt power line. The other side of the line can be connected to a pointed rod-like welding electrode of a suitable material, such as carbon or tungsten, of about inch in diameter, a current limiting resistance being connected in series with the electrode, from which an arc of about or inch is passed to the joint 16, 17 to be welded. A current of about 8 amperes is passed through the arc, and the welding requires only a few seconds. The arc welding in argon can also be done by other suitable methods.
The arc welding makes an efiective permanent joint between the leg 6, 7 and the support wire 14, 15. When the joint is simply heated by passage of current through it and coil 7, the cement 16 may not become sufficiently hot to 'sinter the cement and set it properly, because the leadin wires 14, 15 are thicker than the filament of coil 1. For this reason arc welding is superior.
The cement 8, 9 used to afiix the coil 1 to the legs 8, 9 is nearer the hot coil and so will be more readily heated to the sintering point. However, even there, an improvement is effected by arc welding.
The lead-in wires 32, 23, 28, 29 can be of suitable 7 material well-known in the art, for sealing through the glass used, and the intermediate support wires 18, 19 can A be of 40 'mil diameter nickel. The support wires 14, 15 are of molybdenum wire 40 mils diameter. The whole mount is then a unitary assembly in which the filament coil of tantalum carbide is supported in a position fixed may be applied to the header 25 or its rigidly connected.
parts. 1
A lamp bulb is then sealed at its open end to the rim 31 I of the header 25 to form a complete lamp, as in the previously-mentioned copending application of Howard B. Sloan and Sandford C. Peek. Various other suitable features of the filament mount of that application can be used with the device of the present invention as will be apparent to a person skilled in the art. The lamp can be filled with a suitable gas.
As previously stated, after the graphite packed coil is taken out of the carburizing furnace, the remaining graphite should be removed. This can be done in various ways, for example, by gently sand-blasting the coil with an airbrush carrying a stream of firm abrasive particles in a stream of air. A Pasche airbrush, with AEX air-erasing compound, has proven satisfactory. The abrasive can be a firm grit, such as alundum of particles of a size which can pass through about a ZOO-mesh standard sieve. The air pressure applied to the brush input can be of any suitable value, for example, about 50 pounds per square inch gauge pressure.
Another method of removing the graphite is to put the coil in a container filled with Water and then apply a supersonic vibration. The specific coil described was wound so that the second coiling had an inside diameter of 30 mils.
The temperature given in the foregoing specification are so-called brightness temperatures, that is temperatures measured with a pyrometer. Although a particular embodiment of the invention has been described in detail above, the description is merely by way of illustration and not by way of limitation. Various modifications of the invention will be apparent to a person skilled in the art upon reading the foregoing specification.
What I claim is:
1. A lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from it, and a support wire cemented to the otherwire free end of said leg.
2. A lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from the coil, and a support wire cemented and arc-Welded to the otherwise free end of said leg.
3. A lamp mount including a tantalum carbide coil, a leg cemented to each end of said coil and extending outwardly from the coil, and a molybdenum support wire cemented to the otherwise free end of said leg.
4. The method of making an electric lamp mount, said method comprising fixing the ends of a tantalum carbide filament coil to outwardly extending legs by a cement of tantalum carbide powder in a binder, cementing a different portion of said legs to filament support wires, and then heating the resultant mount at a temperature sufficient to carburize said coil in an atmosphere of a hydrocarbon and hydrogen and to remove the binder and sinter the cement'to bond the coil to the legs, and the legs to the support wires.
References Cited by the Examiner UNITED STATES PATENTS 479,360 7/ 1892 Green 3 13-271 2,175,345 10/1939 Gaidies et a1 2925.17 2,327,031 8/ 1943 Fantur 313271 2,434,478 1/ 1948 Allen 3 13-271 2,542,656 2/1951 Gall 29-25.17 2,716,714 8/1955 Adams et al 313271 2,961,568 11/1960 Pertwee 313271 3,022,438 2/ 1962 Cooper 313222 JOHN W. HUC'KERT, Primary Examiner.
GEORGE WESTBY, R. F. POLISSACK,
J. D. KALLAM, Assistant Examiners.
Claims (2)
1. A LAMP MOUNT INCLUDING A TANTALUM CARBIDE COIL, A LEG CEMENTED TO EACH END OF SAID COIL AND EXTENDING OUTWARDLY FROM IT, AND A SUPPORT WIRE CEMENTED TO THE OTHERWIRE FREE END OF SAID LEG.
4. THE METHOD OF MAKING AN ELECTRIC LAMP MOUNT, SAID METHOD COMPRISING FIXING THE ENDS OF A TANTALUM CARBIDE FILAMENT COIL TO OUTWARDLY EXTENDING LEGS BY A CEMENT OF TANTALUM CARBIDE POWDER IN A BINDER, CEMENTING A DIFFERENT PORTION OF SAID LEGS TO FILAMENT SUPPORT WIRES, AND THEN HEATING THE RESULTANT MOUNT AT A TEMPERATURE SUFFICIENT TO CARBURIZE SAID COIL IN AN ATMOSPHERE OF A HYDROCARBON AND HYDROGEN AND TO REMOVE THE BINDER AND SINTER THE CEMENT TO BOND THE COIL TO THE LEGS, AND THE LEGS TO THE SUPPORT WIRES.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DENDAT1248799D DE1248799B (en) | 1961-12-13 | ||
BE625922D BE625922A (en) | 1961-12-13 | ||
US159100A US3287591A (en) | 1961-12-13 | 1961-12-13 | Tantalum carbide incandescent lamp and method of manufacture thereof |
GB46795/62A GB961640A (en) | 1961-12-13 | 1962-12-11 | Incandescent lamp |
FR918390A FR1341187A (en) | 1961-12-13 | 1962-12-12 | Incandescent lamp |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US159100A US3287591A (en) | 1961-12-13 | 1961-12-13 | Tantalum carbide incandescent lamp and method of manufacture thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
US3287591A true US3287591A (en) | 1966-11-22 |
Family
ID=22571087
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US159100A Expired - Lifetime US3287591A (en) | 1961-12-13 | 1961-12-13 | Tantalum carbide incandescent lamp and method of manufacture thereof |
Country Status (4)
Country | Link |
---|---|
US (1) | US3287591A (en) |
BE (1) | BE625922A (en) |
DE (1) | DE1248799B (en) |
GB (1) | GB961640A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3548244A (en) * | 1968-07-01 | 1970-12-15 | British Lighting Ind Ltd | Lamp having twin filaments and integral filament legs mounted in a bridge |
US3633062A (en) * | 1968-05-28 | 1972-01-04 | Ise Electronics Corp | Direct-heated cathode electrodes with cathode shield for electron guns |
US3792224A (en) * | 1971-07-19 | 1974-02-12 | Westinghouse Electric Corp | Method for making non-tangling beaded filament coils |
US3824421A (en) * | 1971-09-09 | 1974-07-16 | Philips Corp | Electric filament lamp |
US4032809A (en) * | 1966-03-21 | 1977-06-28 | Westinghouse Electric Corporation | Tantalum carbide or tantalum-alloy carbide filament mounting and method |
US4878866A (en) * | 1986-07-14 | 1989-11-07 | Denki Kagaku Kogyo Kabushiki Kaisha | Thermionic cathode structure |
US5148080A (en) * | 1990-01-16 | 1992-09-15 | Hilux Development | Incandescent lamp filament incorporating hafnium |
US5777435A (en) * | 1995-10-20 | 1998-07-07 | U.S. Philips Corporation | Electric lamp having a current conductor with a kinked longitudinal portion |
WO2007063008A2 (en) * | 2005-11-30 | 2007-06-07 | Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH | Halogen light bulb comprising a carbide-containing filament |
US20100181907A1 (en) * | 2007-06-20 | 2010-07-22 | Koninklijke Philips Electronics N.V. | Tantalum carbide filament lamp and process for the production thereof |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US479360A (en) * | 1892-07-19 | Henry green | ||
US2175345A (en) * | 1935-07-12 | 1939-10-10 | Gen Electric | Electric gaseous discharge device |
US2327031A (en) * | 1942-08-10 | 1943-08-17 | Gen Electric | Stem and mount construction |
US2434478A (en) * | 1943-12-22 | 1948-01-13 | Westinghouse Electric Corp | Incandescent electric lamp and method |
US2542656A (en) * | 1941-01-31 | 1951-02-20 | Hartford Nat Bank & Trust Co | Indirectly heated cathode |
US2716714A (en) * | 1951-08-20 | 1955-08-30 | Westinghouse Electric Corp | Incandescent electric lamp |
US2961568A (en) * | 1957-11-14 | 1960-11-22 | Gen Electric | Filament joint for incandescent lamps |
US3022438A (en) * | 1959-09-10 | 1962-02-20 | Polaroid Corp | Electric lamps |
-
0
- DE DENDAT1248799D patent/DE1248799B/de active Pending
- BE BE625922D patent/BE625922A/xx unknown
-
1961
- 1961-12-13 US US159100A patent/US3287591A/en not_active Expired - Lifetime
-
1962
- 1962-12-11 GB GB46795/62A patent/GB961640A/en not_active Expired
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US479360A (en) * | 1892-07-19 | Henry green | ||
US2175345A (en) * | 1935-07-12 | 1939-10-10 | Gen Electric | Electric gaseous discharge device |
US2542656A (en) * | 1941-01-31 | 1951-02-20 | Hartford Nat Bank & Trust Co | Indirectly heated cathode |
US2327031A (en) * | 1942-08-10 | 1943-08-17 | Gen Electric | Stem and mount construction |
US2434478A (en) * | 1943-12-22 | 1948-01-13 | Westinghouse Electric Corp | Incandescent electric lamp and method |
US2716714A (en) * | 1951-08-20 | 1955-08-30 | Westinghouse Electric Corp | Incandescent electric lamp |
US2961568A (en) * | 1957-11-14 | 1960-11-22 | Gen Electric | Filament joint for incandescent lamps |
US3022438A (en) * | 1959-09-10 | 1962-02-20 | Polaroid Corp | Electric lamps |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4032809A (en) * | 1966-03-21 | 1977-06-28 | Westinghouse Electric Corporation | Tantalum carbide or tantalum-alloy carbide filament mounting and method |
US3633062A (en) * | 1968-05-28 | 1972-01-04 | Ise Electronics Corp | Direct-heated cathode electrodes with cathode shield for electron guns |
US3548244A (en) * | 1968-07-01 | 1970-12-15 | British Lighting Ind Ltd | Lamp having twin filaments and integral filament legs mounted in a bridge |
US3792224A (en) * | 1971-07-19 | 1974-02-12 | Westinghouse Electric Corp | Method for making non-tangling beaded filament coils |
US3824421A (en) * | 1971-09-09 | 1974-07-16 | Philips Corp | Electric filament lamp |
US4878866A (en) * | 1986-07-14 | 1989-11-07 | Denki Kagaku Kogyo Kabushiki Kaisha | Thermionic cathode structure |
US5148080A (en) * | 1990-01-16 | 1992-09-15 | Hilux Development | Incandescent lamp filament incorporating hafnium |
US5777435A (en) * | 1995-10-20 | 1998-07-07 | U.S. Philips Corporation | Electric lamp having a current conductor with a kinked longitudinal portion |
WO2007063008A2 (en) * | 2005-11-30 | 2007-06-07 | Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH | Halogen light bulb comprising a carbide-containing filament |
WO2007063008A3 (en) * | 2005-11-30 | 2007-10-11 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Halogen light bulb comprising a carbide-containing filament |
US20100181907A1 (en) * | 2007-06-20 | 2010-07-22 | Koninklijke Philips Electronics N.V. | Tantalum carbide filament lamp and process for the production thereof |
Also Published As
Publication number | Publication date |
---|---|
DE1248799B (en) | |
BE625922A (en) | |
GB961640A (en) | 1964-06-24 |
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