US3270038A - Sulphonation of organic compounds - Google Patents

Sulphonation of organic compounds Download PDF

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Publication number
US3270038A
US3270038A US197508A US19750862A US3270038A US 3270038 A US3270038 A US 3270038A US 197508 A US197508 A US 197508A US 19750862 A US19750862 A US 19750862A US 3270038 A US3270038 A US 3270038A
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US
United States
Prior art keywords
zone
sulfur trioxide
organic compound
sulfonatable
low pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US197508A
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English (en)
Inventor
Marshall Philip
John M Blakeway
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Application granted granted Critical
Publication of US3270038A publication Critical patent/US3270038A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/02—Formation or introduction of functional groups containing sulfur of sulfo or sulfonyldioxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
    • C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US197508A 1961-05-26 1962-05-24 Sulphonation of organic compounds Expired - Lifetime US3270038A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB19157/61A GB975914A (en) 1961-05-26 1961-05-26 Sulphonation of organic compounds

Publications (1)

Publication Number Publication Date
US3270038A true US3270038A (en) 1966-08-30

Family

ID=10124710

Family Applications (1)

Application Number Title Priority Date Filing Date
US197508A Expired - Lifetime US3270038A (en) 1961-05-26 1962-05-24 Sulphonation of organic compounds

Country Status (9)

Country Link
US (1) US3270038A (pt)
BE (1) BE617968A (pt)
CH (1) CH401031A (pt)
DE (1) DE1179196B (pt)
DK (1) DK117825B (pt)
ES (2) ES277408A1 (pt)
FR (1) FR1330937A (pt)
GB (1) GB975914A (pt)
NL (1) NL278901A (pt)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3412143A (en) * 1965-06-21 1968-11-19 Pillsbury Co Process for the production of amine salts of sulfamic acid
US3482947A (en) * 1966-07-14 1969-12-09 Procter & Gamble Feed device for a film reactor
US3535339A (en) * 1965-12-17 1970-10-20 Procter & Gamble Process and apparatus for the continuous reaction of organic compounds with undiluted sulfur trioxide
US3865861A (en) * 1967-04-25 1975-02-11 Albright & Wilson Sulphation of secondary alcohols
US3931273A (en) * 1970-02-23 1976-01-06 Costruzioni Meccaniche G. Mazzoni S.P.A. Method for sulphonatizing and sulphatizing organic compounds with sulphur trioxide and apparatus therefor
US3941810A (en) * 1972-10-30 1976-03-02 Adolf Koebner Sulfonation of aromatic compounds in the presence of solvents
DE2502254A1 (de) * 1975-01-17 1976-07-22 Marathon Oil Co Verfahren zum herstellen von erdoelsulfonat
US4002431A (en) * 1975-12-19 1977-01-11 United Technologies Corporation Nitrous oxide decomposition reactor
JPS5363346A (en) * 1976-11-17 1978-06-06 Cosmo Co Ltd Sulfonation of aromatic cpds.
US4097242A (en) * 1975-07-21 1978-06-27 Kao Soap Co., Ltd. Sulfonation apparatus
US4102911A (en) * 1967-06-26 1978-07-25 Kao Soap Co., Ltd. Sulfonating or sulfating method
US4113438A (en) * 1976-05-27 1978-09-12 The Chemithon Corporation Sulfonating apparatus
US4144266A (en) * 1973-07-05 1979-03-13 Marathon Oil Company Sulfonation of crude oils to produce petroleum sulfonates
US4390474A (en) * 1974-10-16 1983-06-28 Stepan Chemical Company Sulfonation petroleum composition
US4390475A (en) * 1979-07-06 1983-06-28 Lion Corporation Thin film type sulfonation process of alkylbenzene
US4560517A (en) * 1979-03-22 1985-12-24 Marathon Oil Company Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates
US4614623A (en) * 1974-01-04 1986-09-30 Marathon Oil Company Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates
US4879399A (en) * 1986-01-15 1989-11-07 Sandoz Ltd. Ether sulfates of a mixture of branched 1-decanols
US4980087A (en) * 1986-01-15 1990-12-25 Sandoz Ltd. Ether sulfates of a mixture of branched 1-decanols

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1563994A (en) * 1975-05-15 1980-04-02 Albright & Wilson Sulph(on)ation process and mixer
GB2155474A (en) * 1984-03-13 1985-09-25 Procter & Gamble Process for the continuous reaction of organic compounds with sulfur trioxide
GB9008406D0 (en) * 1990-04-12 1990-06-13 Albright & Wilson Process for producing phosphorous acid

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL27274C (pt) *
US2174760A (en) * 1934-04-19 1939-10-03 Ig Farbenindustrie Ag Condensation products derived from carboxylic acids and method of producing them
US2290167A (en) * 1939-08-14 1942-07-21 Solvay Process Co Preparation of sulphonation derivatives
US2371284A (en) * 1945-03-13 Preparation of sulphated fatty
US2634287A (en) * 1948-04-01 1953-04-07 Monsanto Chemicals Process for sulfation of aliphatic alcohols
US2665197A (en) * 1950-08-03 1954-01-05 Rowland Ernest Edward Polymerization control apparatus
US2730433A (en) * 1954-11-02 1956-01-10 Du Pont Spray mixer
US2828331A (en) * 1956-09-26 1958-03-25 Pure Oil Co Sulfonation of petroleum oils
US2865958A (en) * 1956-07-17 1958-12-23 Shell Dev Sulfonation process
US2872297A (en) * 1955-01-11 1959-02-03 Flo Mix Fertilizers Corp Apparatus for converting liquid anhydrous ammonia to aqua ammonia
US2923728A (en) * 1957-11-19 1960-02-02 Du Pont Process of reacting organic compounds with sulfur trioxide

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE834245C (de) * 1948-07-17 1952-03-17 Innovations Chimiques Sinnova Verfahren und Vorrichtung zur kontinuierlichen Sulfonierung bzw. Veresterung organischer Verbindungen mittels Chlorsulfonsaeure
DE1095817B (de) * 1956-07-17 1960-12-29 Iashellia Res Ltd Kontinuierliches Verfahren und Vorrichtung zum Sulfonieren von mit Schwefeltrioxyd sulfonierbaren organischen Fluessigkeiten

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL27274C (pt) *
US2371284A (en) * 1945-03-13 Preparation of sulphated fatty
US2174760A (en) * 1934-04-19 1939-10-03 Ig Farbenindustrie Ag Condensation products derived from carboxylic acids and method of producing them
US2290167A (en) * 1939-08-14 1942-07-21 Solvay Process Co Preparation of sulphonation derivatives
US2634287A (en) * 1948-04-01 1953-04-07 Monsanto Chemicals Process for sulfation of aliphatic alcohols
US2665197A (en) * 1950-08-03 1954-01-05 Rowland Ernest Edward Polymerization control apparatus
US2730433A (en) * 1954-11-02 1956-01-10 Du Pont Spray mixer
US2872297A (en) * 1955-01-11 1959-02-03 Flo Mix Fertilizers Corp Apparatus for converting liquid anhydrous ammonia to aqua ammonia
US2865958A (en) * 1956-07-17 1958-12-23 Shell Dev Sulfonation process
US2828331A (en) * 1956-09-26 1958-03-25 Pure Oil Co Sulfonation of petroleum oils
US2923728A (en) * 1957-11-19 1960-02-02 Du Pont Process of reacting organic compounds with sulfur trioxide

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3412143A (en) * 1965-06-21 1968-11-19 Pillsbury Co Process for the production of amine salts of sulfamic acid
US3535339A (en) * 1965-12-17 1970-10-20 Procter & Gamble Process and apparatus for the continuous reaction of organic compounds with undiluted sulfur trioxide
US3482947A (en) * 1966-07-14 1969-12-09 Procter & Gamble Feed device for a film reactor
US3865861A (en) * 1967-04-25 1975-02-11 Albright & Wilson Sulphation of secondary alcohols
US4102911A (en) * 1967-06-26 1978-07-25 Kao Soap Co., Ltd. Sulfonating or sulfating method
US3931273A (en) * 1970-02-23 1976-01-06 Costruzioni Meccaniche G. Mazzoni S.P.A. Method for sulphonatizing and sulphatizing organic compounds with sulphur trioxide and apparatus therefor
US3941810A (en) * 1972-10-30 1976-03-02 Adolf Koebner Sulfonation of aromatic compounds in the presence of solvents
US3946037A (en) * 1972-10-30 1976-03-23 Adolf Koebner Sulfonation of aromatic compounds
US4147638A (en) * 1973-07-05 1979-04-03 Marathon Oil Company Sulfonation of crude oils to produce petroleum sulfonates
US4144266A (en) * 1973-07-05 1979-03-13 Marathon Oil Company Sulfonation of crude oils to produce petroleum sulfonates
US4614623A (en) * 1974-01-04 1986-09-30 Marathon Oil Company Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates
US4390474A (en) * 1974-10-16 1983-06-28 Stepan Chemical Company Sulfonation petroleum composition
DE2502254A1 (de) * 1975-01-17 1976-07-22 Marathon Oil Co Verfahren zum herstellen von erdoelsulfonat
US4097242A (en) * 1975-07-21 1978-06-27 Kao Soap Co., Ltd. Sulfonation apparatus
US4002431A (en) * 1975-12-19 1977-01-11 United Technologies Corporation Nitrous oxide decomposition reactor
US4113438A (en) * 1976-05-27 1978-09-12 The Chemithon Corporation Sulfonating apparatus
JPS5363346A (en) * 1976-11-17 1978-06-06 Cosmo Co Ltd Sulfonation of aromatic cpds.
JPS6045185B2 (ja) * 1976-11-17 1985-10-08 丸善石油株式会社 芳香族化合物のスルホン化方法
US4560517A (en) * 1979-03-22 1985-12-24 Marathon Oil Company Sulfonation of crude oils with gaseous SO3 to produce petroleum sulfonates
US4390475A (en) * 1979-07-06 1983-06-28 Lion Corporation Thin film type sulfonation process of alkylbenzene
US4879399A (en) * 1986-01-15 1989-11-07 Sandoz Ltd. Ether sulfates of a mixture of branched 1-decanols
US4980087A (en) * 1986-01-15 1990-12-25 Sandoz Ltd. Ether sulfates of a mixture of branched 1-decanols

Also Published As

Publication number Publication date
FR1330937A (fr) 1963-06-28
GB975914A (en) 1964-11-25
ES280186A1 (es) 1962-11-16
ES277408A1 (es) 1962-12-01
DK117825B (da) 1970-06-08
NL278901A (pt)
CH401031A (de) 1965-10-31
BE617968A (pt)
DE1179196B (de) 1964-10-08

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