US3266865A - Stretchable wool and wool-blend fabrics - Google Patents

Stretchable wool and wool-blend fabrics Download PDF

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US3266865A
US3266865A US182535A US18253562A US3266865A US 3266865 A US3266865 A US 3266865A US 182535 A US182535 A US 182535A US 18253562 A US18253562 A US 18253562A US 3266865 A US3266865 A US 3266865A
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fabric
wool
yarns
fabrics
warp
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US182535A
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Leslie A Runton
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JP Stevens and Co Inc
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JP Stevens and Co Inc
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Priority to BE630081D priority Critical patent/BE630081A/xx
Priority to NL290692D priority patent/NL290692A/xx
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Priority to US182535A priority patent/US3266865A/en
Priority to DE1963ST020438 priority patent/DE1460722B1/en
Priority to GB1167563A priority patent/GB1043402A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • D06C7/02Setting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B21/00Successive treatments of textile materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C2700/00Finishing or decoration of textile materials, except for bleaching, dyeing, printing, mercerising, washing or fulling
    • D06C2700/13Steaming or decatising of fabrics or yarns

Definitions

  • This invention relates to woven wool fabrics composed entirely or in part of wool which fabrics have characteristics hitherto unattainable and to methods of preparing the same,
  • An object of this invention is to provide fabrics cornposed wholly or partly of wool which possess recoverable stretch in at least one direction.
  • a further object of this invention is to provide fabrics composed wholly or partly of wool characterized by tailorability, excellent wrinkle recovery, good drape, shape retentivity, crease retention, and excellent hand.
  • a further object is to provide fabrics -wherein fiber migration and fuzzing in the conventional wool finishing operation and in the laundering and dry cleaning of the garments made from these fabrics is minimized whereby a clear definition of the individual yarns constituting the fabrics is retained in superior measure.
  • a further object of this invention is to provide a method of making wool and wool-containing fabrics characterized by recoverable stretch in at least one direction, by superior tailorability, excellent wrinkle recovery, good drape, crease retention, and shape retentivity.
  • the fabric which can consist entirely or partly of all-wool yarns or of yarn composed of a blend of at least wool with other staple fibers as received from the weaving stage, and with or without size and in dyed or undyed state, is impregnated with a solution of a chemical relaxing agent, for example, by being passed through such a solution and thereafter squeezed to removed excess liquid. It is then heated, for example, by exposure to steam while free from constraint in at least one direction.
  • the fabric is impregnated with a solution of the relaxing agent, and when the excess solution is removed by squeezing, it contains 100 to 130% of liquid on the dry weight of the fabric.
  • it is heated, for example, by steaming at a temperature between about 210 F. and 225 F. for a time ranging from 1/2 to 4 minutes. If a lower steam temperature is employed, the time needs to be prolonged to effect full relaxation; and conversely, if a higher steam temperature is utilized, a shorter time is required.
  • the amount of shrinkage in the weft-Wise direction can be regulated by controlling the amount of tension applied to the fabric in the warp direction while it is in the heating zone, for example, by increasing the amount of tension in the warp direction, the amount of shrinkage in the weft direction is increased.
  • the fabric is free from constraint in both weft and warp directions, it can be shrunk as much as 20% in each of the two directions.
  • the fabric After the heating yor relaxing step, it is desirable to cool the fabric immediately, such as by immersing it in cold water, by spraying with cold water, or by aspirating cool air through the fabric.
  • the impact of this cooling action serves to set the wool fibers in their relaxed or crimped state. Further stabilization of the fabric can be accomplishedby a subsequent treatment with any of the reagents known in the art for stabilizing relaxed keratin fibers.
  • the relaxing agents usable in the present invention are such well known reducing agents, for wool as the sultes, bisuliites, sulfoxylates, and hydrosulfites. These can be used as the alkali metal, ammonium, or organic amine salts. Other such reducing agents are substituted mercaptans, for example, mercaptoacids or mercapto-alcohols, the alkali metal boro-hydrides, and the alkali metal stannites.
  • the preferred relaxing agents are the aqueous solutions of organic amine sulites (or bisullites), such as those disclosed in U.S. Patent No. 2,437,965, and particularly a solution of monoethanolamine sulite in about 5% concentration.
  • stabilizing agents which can be employed following the relaxing and cooling steps in the present invention are dilute solutions of aliphatic carboxylic acids such as formic or acetic acid; mild alkalis such as dilute solutions of alkali metal carbonates; solutions of oxidants such as hydrogen peroxide or sodium persulfate; combinations of alkali and oxidants; solutions of multivalent metal salts, such as the water-soluble salts of zinc; or solutions or emulsions of alkaline dihalides of the type disclosed in U.S. Patent No. 2,434,562.
  • the particular stabilizing agent employed will depend upon the relaxing agent used originally in treating the wool or part-wool fabric in accordance with principles well known in the art. For example, if a sulte or bisulfite is employed as the relaxing agent, then a dilute solution of a carboxylic acid or a dilute solution of an alkali metal carbonate will be the preferred stabilizing agent.
  • the relaxing reagents employed in the present process are Well known in the art of imparting permanent set to all-wool fabrics in the iiat, pleated and creased form. These reagents have also been employed to relax specially constructed wool fabrics composed of high-twist yarns so as to develop crepe effects.
  • the high-twist worsted yarns which are necessary for making wool crepes have a singles twist factor (turns per inch per square root of the worsted count) greater than 4.5 and usually about 5.0.
  • FIGS. 1 and la when joined at the vertical lines a-a, together constitute a schematic sectional view of such apparatus
  • FIG. 2 is a plan view showing the fabric as Woven and prior to the shrinkage operation
  • FIG. 3 is a section taken on the line 3--3 of FIG. 2;
  • FIG. 4 is a plan view similar to FIG. 2 showing the fabric in finished contracted form
  • FIG. 5 is a section taken on the line 5 5 of FIG. 4.
  • FIGS. l and la of the drawings there is shown an apparatus for carrying out the present invention by a continuous process.
  • a strip of fabric of the type above described is fed from a supply roll 9 by feed rolls 11 into a J-box L2 where it for-ms a series of loose folds. It is withdrawn from the I-box 12 over a roll 13 and is introduced between guide rolls 14 into a tank 15 containing a relaxing solution of the type referred to above.
  • the fabric strip 1t) passes in a succession of folds under a set of lower rolls 16 and over a roll 17, the former being immersed in the solution of tank 15.
  • the fabric 10 passes over a roll 18 into a tank 19 under a roll 20 which is submerged in the relaxing solution in the tank, thence over .a roll 21 to the bite of a pair of squeeze rolls 22 and 23.
  • a drain returns solution from the tank 19 to the tank 15.
  • the upper roll 22 is loaded so as to leave a pick up of about 100 to 130 percent of the fabric weight.
  • the lower roll 23 dips in-to the solution in a tank 19.
  • the fabric From the squeeze rolls 22 and 23 the fabric passes over a guide roll 24, under a control roll 25, over a guide roll 26 and under a guide roll Z7 into an autoclave 31 through a vestibule 33 having a seal 34 to minimize the escape of steam.
  • the control roll 25 actuates a control box 28 which is connected to control the drive of the rolls 22 and 23 in sequence to maintain the fabric strip entering the autoclave under a constant tension in the warp direction.
  • the fabric In the autoclave 31 the fabric passes around a series of upper rolls 35 and a series of lower rolls 36 in the form of a series of vertical loops. Steam is supplied to the space below the lower rolls 36 from a supply pipe 37 through a series of headers 38.
  • the steam which is at a temperature of about 210 to 225 F., is maintained at a slight pressure above atmospheric which in conjunction with seal 34 prevents the entrance of any air.
  • the fabric is unconned laterally so that it is free to shrink in width during this treatment while the rolls 35 and 36 hold the fabric flat and in unwrinkled condition.
  • the rolls 35 and 36 in the autoclave are driven at a predetermined rate by a suitable adjustable variable speed driven mechanism not shown.
  • the rate may be adjusted in .accordance wi-th the time which the fabric is to remain in the autoclave, which time is preferably in the range of 1/2 to 4 minutes.
  • the fabric passes from the autoclave through an exit vestibule 39 having a seal 40 around guide rolls 41, under a control roll 42 and over a guide roll 43 into a Afull width cloth scouring unit 60, known as a Williams unit, of standard construction having a series of upper rolls 46 and a series of lower rolls 47 around which the fabric passes in a series of loops 'between fixed plates 48 which lie closely adjacent the loops.
  • a spray of cold Water is supplied to the fabric in this scouring unit from a spray header 49. This spray immediately cools the fabric to a temperature to stop the chemical action, and also removes a large portion of the treating agent.
  • the scouring liquid is maintained in the scouring unit at a level slightly below the rolls 46 so that the fabric advances through this liquid as it feeds through the unit.
  • From theV scouring unit 60 the fabric passes over a guide roll 50 into the bite of a pair of feed rolls 51 and 52, the latter of which dips into the liquid in a tank 53 which drains into the scouring unit through an overflow 54.
  • the control roll 42 is adapted to control the rate of the feed rolls 51 and 52 so as to maintain the fabric under a constant tension in its passage through the apparatus.
  • the fabric passes through a series of units 60A, 60B and 60C which are substantially identical with the unit 60 and the corresponding parts of which have been given similar reference numbers with the suffixes added.
  • Each unit is followed by a pair of feed rolls 51a, 52a, Sib, 52h, 51C ⁇ and 52a ⁇ respectively.
  • Each pair of feed rolls is followed by a control unit composed of fixed rolls 41a, 41h and 41a, 43a, 43b and 43a 'and a movable control roll 42a, 42b and 42C respectively.
  • Each control roll is connected to control the rate of the preceding pair of feed rolls so as to maintain the fabric under a constant tension in the corresponding unit.
  • the unit 60A can contain a stabilizing agent of the type described above.
  • the unit 60B can contain a desizing ⁇ solution for removing any size remaining on the fabric. If the fabric is unsized or if it is not desired to remove the size, this unit may be omitted.
  • the unit 60C can contain wash water toy remove the stabilizing and desizing solutions.
  • the fabric From the unit 60C the fabric .passes under a roll 65 in la tank 66 containing rinse Water for a final rinse. Rinse Water is supplied from a spray header 67 onto the fabric as it enters and leaves the tank 6.6. From the tank 66 the fabric passes between a pair of squeeze rolls 68, thence to a folder 70 which may be ⁇ of standard construcytion and is adapted to lay the fabric in a series of folds 71. The fabric is then taken to a drying stage such as a slack loop dryer, not shown, or a slack tray dryer o-r a hot air dryer of any standard type, wherein the cloth is dried in a relaxed state.
  • a drying stage such as a slack loop dryer, not shown, or a slack tray dryer o-r a hot air dryer of any standard type, wherein the cloth is dried in a relaxed state.
  • this invention can be carried out by a batch process.
  • several of the conventional wool finishing machines can be used.
  • the fabric can be impregnated with the relaxing ⁇ solution and wound on the perforated drum of a decating machine together with a cotton leader cloth, care being taken to wind with a minimum of tension so that the fabric is free to shrin-k.
  • Steam is then blown through the penforations in the drum for about 2-4 minutes, and the fabric is then cooled by aspirating air through it by means of a vacuum pump for several minutes.
  • the fabric is then unwound, excess Water is removed by hydro-extraction, and the fabric is dried in a tension-free state in la slack loop drier or slack tray drier of the conventional design.
  • Another conventional wool finishing machine I which can be effectively employed for carrying ⁇ out this invention by a batch process is a pressure piece-dyeing machine wherein the fabric is Wound on a perforated roll with minimal tension without a leader cloth. 'I'he process can then be carried out in the same manner ⁇ as described above for a decating machine.
  • the fabric can be wound on the roll without being previously impregnated with the relaxing solution.
  • the wound roll of fabric in the machine is immersed in the relaxing solution which is then 4heated and circulated through the ⁇ fabric to effect the desired relaxation.
  • the fabric can t-hen be cooled ⁇ by replacing the relaxing solution with cold water, and thereafter a stabilizing solution can be circulated therethrough.
  • the fabric can then be subjected to the further steps of extraction and drying as mentioned above in connection with the decating machine.
  • the present invention is applicable to all types of woven wool and partwlool fabrics, consisting of two sets of yarns, namely, weft and warp yarns, except creped fabrics, containing 6 inches, and they contained 65 threads per inch in the warp and 54 picks per inch in the filling. All the pieces were rope-scoured in a conventional manner; piece A was then finished in a conventional manner, by beck-dyeing, tenter drying, shearing, decating, and pressing. Pieces B and at least 30% wool in one set of yarns, the remainder 5 being synthetic or natural staple fibers such as polyester, C were treated by the process of this invention by the conpolyamide, acrylic, rayon, or cotton fibers.
  • the yarns in the other set can be sion of 30 pounds, using the apparatus shown in FIGS. composed entirely of the aforementioned synthetic or 10 1 and la.
  • the relaxing agent was an lS-to-l aqueous n'atunal (non-wool) staple iibers. solution of monoethanolamine sullite, and the steaming Obviously the weft yarns and warp yarns may be woven time was 21/2 minutes, the temperature in the autoclave under the same tension and may have the same number being 212-218 F.
  • a 0.2% soluof yarns per inch if equal stretch is desired in both direction of formic acid was employed.
  • the nishing was tions or the filler yarns may be woven under a greater completed lby beck-dyeing, drying in a slack tray dryer, tension than .the warp yarns, :and vice versa, depending and semi-decating.
  • Piece D was treated by the process on the product desired. of ⁇ this invention by the batch method described above, The following table gives further illustrative examples using a Burlington pressure piece-dyeing machine. The of specific yarn sizes and weaves which are suitable for fabric was impregnated with a 2 0tol aqueous solution the above purpose.
  • Example I Four pieces of plain-weave, 7-71/2 oz. tropical worsted mens suiting fabric, containing 48% wool and 52% Daeronl polyester fiber, were woven from undyed j/igs worsted counts yarn with 18 turns per inch of 'twist in both warp and filling (twist factor 3.2). In two of these pieces, A and B, the Warp yarn was spun on the worsted system, and the filling yarn on the cotton system. In the ⁇ other two pieces, C and D, both sets of yarn were spun on the cotton system. l
  • the width of all the pieces was 63 wetting agent, and passed through a pair of squeeze rolls to reduce the pick up to 110%.
  • the Wet piece was loosely wrapped on the perforated drum, and steam was then blown through it for 4 minutes, the machine being open to the atmosphere.
  • the steam was blown through the loosely wound fabric, there was suflicient freedom from constraint to permit the fabric to shrink extensively in the filling direction; and to a limited extent in the warp direction.
  • the piece was cooled by filling the machine with cold water, which was then drained. The piece was unwound from the drum, extracted, and dried in a slack loop dryer. The whole process was then repeated. The finishing was completed in the manner described for pieces B and C.
  • the Width of the fabrics was then measured, and their stretchability in both yarn directions was determined in the following manner: swatches of fabric were cut 24 inches long in the test direction and 8 inches wide in the other direction, and were exposed to standard atmosphere of relative humidity, 70 F. for a minimum of 4 hours. Two marks, parallel to the short sides ⁇ of each swatch were made 18 inches apart. One short edge of the swatch was then attached to a 6-inch-wide hanging clamp, and another clamp of the same width was attached to the lower, free-hanging, end of the swatch. A weight was then added to the lower clamp which, added to the weight of the clamp itself, created a total load of 5 lbs. The distance between the tWo marks in the fabric was then measured, and the percentage extension of the fabric calculated. The results obtained with the four fabrics are recorded in the table below, together with their nished 65 widths.
  • Example 2 Three stock-dyed, plain-weave, all wool worsted fabrics were woven and scoured. Their construction details are given in the table below:
  • the three pieces were treated according to the process of this invention by the batch method described above.
  • a fabric comprising a set of warp yarns and a set of weft yarns wherein one of said sets of yarns includes wool, and
  • the crimp being a planar crimp such that the fabric may be stretched by at least 6% and will return to its original state when the stretching force is released, said fabric having the stretch property in one direction only.
  • the yarns of one of said sets being composed essentially of wool
  • said wool being in the highly crimped and bulked state characteristic of a yarn which has been highly twisted and shrunken in the presence of a stabilizagent which is capable of reacting with the wool to set the yarn in its contracted state whereby the fabric is capable of stretching by at least 6% and of returning to its contracted state when the stretch force is released, said fabric having the stretch property in one direction only.
  • a chemically stabilized woven fabric having highly crimped wool yarns extending in one direction of the fabric, the crimp in said wool yarns being a planar crimp of a magnitude such that the fabric may be stretched by at least 6% in the direction of the crimp in said wool yarns and will return to its original state when stretching force is released, said fabric having the stretch property in one direction only.
  • a fabric comprising a set of warp yarns and a set of weft yarns wherein one of said sets of yarns is composed essentially of wool land is highly crimped as it passes under and over yarns of the other set and is permanently set in the crimped state, the crimp being a planar crimp such that the fabric may be stretched by at least 6% in the direction of said one set of yarns and will return to its original state when the stretching force is released, said vfabric having the stretch property in one direction only.
  • a woven wool fabric comprising a set of warp yarns and a set of weft yarns wherein one of said sets of wool yarns is highly crimped as it passes under and over yarns of the other set and is permanently set in the crimped state, the crimp being a planar crimp such that the wool fabric may be stretched by at least 6% in the direction of said one set of yarns and will return to its original state when the stretching force is released, said fabric having the stretch property in one direction only.
  • a wool fabric as defined in claim 11 wherein said planar crimp is such that the iwool fabric may be stretched from 6 to 25% in one direction and will return to its original state when the stretching force is released.
  • a woven fabric having a substantially smooth surface and comprising a set of weft yarns and a set of warp yarns, some of the yarns in one of said sets being composed essentially of wool, said w-ool being in a highly crimped and bulked state and permanently set in said state, the crimp in said wool yarns being a planar crimp such that the fabric is capable of stretching from 6% to 25% and of returning to its contracted state when the stretching force is released, said fabric having the stretch property in one direction only.
  • a chemically stabilized woven fabric having highly crimped wool containing yarns extending in one direction of the fabric, the crimp in said wool containing yarns being a planar crimp of a magnitude such that the fabric may be stretched by at least 9.2% in the direction of the crimp in said wool containing yarns and Will return to its original state when the stretching force is released, said fabric having the aforesaid stretch property in one direction only.
  • a chemically stabilized woven fabric having highly crimped wool containing yarns extending in one direction of the fabric, the crimp in said wool containing yarns being a planar crimp of a magnitude such that the fabric may be stretched by at least 13.5% in the direction of the crimp in said wool containing yarns and -will return to its original state when the stretching for-ce is released, said fabric having the aforesaid stretch property in one direction only.

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Description

Aug. 16, 1966 L. A. RUNTON STRETCHABLE WOOL AND WOOL-BLEND FABRICS Filed March 26, 1962 CONT/Q04 /28 90x v2 Sheets-Sheet l As wo VEN UumlD .u' y L l@ INI/ENTOR.
Aug- 16, 1966 L. A. RUNTQN 3,266,865
STRETGHABLE WOOL AND WOOL-BLEND FABRICS CONTROL E'S/Z//V AS STA BILIZED E//VSE WM5/Lacan@ United States Patent O 3,266,865 STRETCHABLE WL AND WOOL-BLEND FABRICS Leslie A. Renton, Middle Haddam, Conn., assignor to J. P. Stevens d; Co., liuc., New York, NX., a corporation of Delaware Filed Mar. 26, 1962, Ser. No. 182,535 16 Claims. (Cl. 8-123) This application is a continuation-impart of copending applications Serial No. 75,394, iiled December 12, 1960, now abandoned; Serial No. 118,217, iiled May 9, 1961, now U.S. Patent 3,077,655, and Serial No. 151,827, filed November 13, 1961, now abandoned.
This invention relates to woven wool fabrics composed entirely or in part of wool which fabrics have characteristics hitherto unattainable and to methods of preparing the same,
An object of this invention is to provide fabrics cornposed wholly or partly of wool which possess recoverable stretch in at least one direction.
A further object of this invention is to provide fabrics composed wholly or partly of wool characterized by tailorability, excellent wrinkle recovery, good drape, shape retentivity, crease retention, and excellent hand.
A further object is to provide fabrics -wherein fiber migration and fuzzing in the conventional wool finishing operation and in the laundering and dry cleaning of the garments made from these fabrics is minimized whereby a clear definition of the individual yarns constituting the fabrics is retained in superior measure.
A further object of this invention is to provide a method of making wool and wool-containing fabrics characterized by recoverable stretch in at least one direction, by superior tailorability, excellent wrinkle recovery, good drape, crease retention, and shape retentivity.
Other objects of this invention will be apparent from the following description, examples and claims.
In accordance with this invention, the fabric, which can consist entirely or partly of all-wool yarns or of yarn composed of a blend of at least wool with other staple fibers as received from the weaving stage, and with or without size and in dyed or undyed state, is impregnated with a solution of a chemical relaxing agent, for example, by being passed through such a solution and thereafter squeezed to removed excess liquid. It is then heated, for example, by exposure to steam while free from constraint in at least one direction.
More specifically, the fabric is impregnated with a solution of the relaxing agent, and when the excess solution is removed by squeezing, it contains 100 to 130% of liquid on the dry weight of the fabric. In order to permit full relaxation of the impregnated fabric, it is heated, for example, by steaming at a temperature between about 210 F. and 225 F. for a time ranging from 1/2 to 4 minutes. If a lower steam temperature is employed, the time needs to be prolonged to effect full relaxation; and conversely, if a higher steam temperature is utilized, a shorter time is required.
When a fabric containing Wool fibers is impregnated with a relaxing agent and is heated in the presence of moisture, the wool fibers relax to develop a high degree of planar crimp in the yarns, whereby the yarns, and consequently the fabric shrinks in the direction which is free from constraint. For example, if the fabric is free from tension or constraint in the filling direction, it can be shrunk weftwise in the heating step zone as much as 6 to 25% without appreciable shrinkage in the warpwise direction. The amount of shrinkage in the weft-Wise direction, and consequently the amount of recoverable ice stretch, can be regulated by controlling the amount of tension applied to the fabric in the warp direction while it is in the heating zone, for example, by increasing the amount of tension in the warp direction, the amount of shrinkage in the weft direction is increased.
On the other hand, if the fabric is free from constraint in both weft and warp directions, it can be shrunk as much as 20% in each of the two directions.
After the heating yor relaxing step, it is desirable to cool the fabric immediately, such as by immersing it in cold water, by spraying with cold water, or by aspirating cool air through the fabric. The impact of this cooling action serves to set the wool fibers in their relaxed or crimped state. Further stabilization of the fabric can be accomplishedby a subsequent treatment with any of the reagents known in the art for stabilizing relaxed keratin fibers.
Representative of the relaxing agents usable in the present invention are such well known reducing agents, for wool as the sultes, bisuliites, sulfoxylates, and hydrosulfites. These can be used as the alkali metal, ammonium, or organic amine salts. Other such reducing agents are substituted mercaptans, for example, mercaptoacids or mercapto-alcohols, the alkali metal boro-hydrides, and the alkali metal stannites. However, the preferred relaxing agents are the aqueous solutions of organic amine sulites (or bisullites), such as those disclosed in U.S. Patent No. 2,437,965, and particularly a solution of monoethanolamine sulite in about 5% concentration.
Representative of the stabilizing agents which can be employed following the relaxing and cooling steps in the present invention are dilute solutions of aliphatic carboxylic acids such as formic or acetic acid; mild alkalis such as dilute solutions of alkali metal carbonates; solutions of oxidants such as hydrogen peroxide or sodium persulfate; combinations of alkali and oxidants; solutions of multivalent metal salts, such as the water-soluble salts of zinc; or solutions or emulsions of alkaline dihalides of the type disclosed in U.S. Patent No. 2,434,562.
The particular stabilizing agent employed will depend upon the relaxing agent used originally in treating the wool or part-wool fabric in accordance with principles well known in the art. For example, if a sulte or bisulfite is employed as the relaxing agent, then a dilute solution of a carboxylic acid or a dilute solution of an alkali metal carbonate will be the preferred stabilizing agent.
The relaxing reagents employed in the present process are Well known in the art of imparting permanent set to all-wool fabrics in the iiat, pleated and creased form. These reagents have also been employed to relax specially constructed wool fabrics composed of high-twist yarns so as to develop crepe effects. The high-twist worsted yarns which are necessary for making wool crepes have a singles twist factor (turns per inch per square root of the worsted count) greater than 4.5 and usually about 5.0. However, I have made the surprising discovery that when wool and wool-containing fabrics constructed of conventional twist yarns, that is, with a twist factor ranging from 1.5 to 4.0 are treated by the process of this invention, fabrics are obtained which are characterized (a) by possessing recoverable stretch in at least one direction; (b) by having a clear smooth surface rather than either a creped or fuzzy surface, and (c) by exhibiting highly desirable characteristics with respect to tailorability, hand, crease resistance, wrinkle recovery, and shape retention.
It will be apparent from the foregoing description that the process of this invention can be carried out either as a continuous or a batch process. An apparatus suitable for carrying out the present invention by a continuous process is illustrated in the accompanying drawings wherein:
FIGS. 1 and la, when joined at the vertical lines a-a, together constitute a schematic sectional view of such apparatus;
FIG. 2 is a plan view showing the fabric as Woven and prior to the shrinkage operation;
FIG. 3 is a section taken on the line 3--3 of FIG. 2;
FIG. 4 is a plan view similar to FIG. 2 showing the fabric in finished contracted form; and
FIG. 5 is a section taken on the line 5 5 of FIG. 4.
With reference to FIGS. l and la of the drawings, there is shown an apparatus for carrying out the present invention by a continuous process. A strip of fabric of the type above described is fed from a supply roll 9 by feed rolls 11 into a J-box L2 where it for-ms a series of loose folds. It is withdrawn from the I-box 12 over a roll 13 and is introduced between guide rolls 14 into a tank 15 containing a relaxing solution of the type referred to above. The fabric strip 1t) passes in a succession of folds under a set of lower rolls 16 and over a roll 17, the former being immersed in the solution of tank 15.
From the tank the fabric 10 passes over a roll 18 into a tank 19 under a roll 20 which is submerged in the relaxing solution in the tank, thence over .a roll 21 to the bite of a pair of squeeze rolls 22 and 23. A drain returns solution from the tank 19 to the tank 15.
The upper roll 22 is loaded so as to leave a pick up of about 100 to 130 percent of the fabric weight. The lower roll 23 dips in-to the solution in a tank 19.
From the squeeze rolls 22 and 23 the fabric passes over a guide roll 24, under a control roll 25, over a guide roll 26 and under a guide roll Z7 into an autoclave 31 through a vestibule 33 having a seal 34 to minimize the escape of steam. The control roll 25 actuates a control box 28 which is connected to control the drive of the rolls 22 and 23 in sequence to maintain the fabric strip entering the autoclave under a constant tension in the warp direction. In the autoclave 31 the fabric passes around a series of upper rolls 35 and a series of lower rolls 36 in the form of a series of vertical loops. Steam is supplied to the space below the lower rolls 36 from a supply pipe 37 through a series of headers 38.
In the autoclave the steam, which is at a temperature of about 210 to 225 F., is maintained at a slight pressure above atmospheric which in conjunction with seal 34 prevents the entrance of any air. The fabric is unconned laterally so that it is free to shrink in width during this treatment while the rolls 35 and 36 hold the fabric flat and in unwrinkled condition.
The rolls 35 and 36 in the autoclave are driven at a predetermined rate by a suitable adjustable variable speed driven mechanism not shown. The rate may be adjusted in .accordance wi-th the time which the fabric is to remain in the autoclave, which time is preferably in the range of 1/2 to 4 minutes.
The fabric passes from the autoclave through an exit vestibule 39 having a seal 40 around guide rolls 41, under a control roll 42 and over a guide roll 43 into a Afull width cloth scouring unit 60, known as a Williams unit, of standard construction having a series of upper rolls 46 and a series of lower rolls 47 around which the fabric passes in a series of loops 'between fixed plates 48 which lie closely adjacent the loops. A spray of cold Water is supplied to the fabric in this scouring unit from a spray header 49. This spray immediately cools the fabric to a temperature to stop the chemical action, and also removes a large portion of the treating agent.
The scouring liquid is maintained in the scouring unit at a level slightly below the rolls 46 so that the fabric advances through this liquid as it feeds through the unit. From theV scouring unit 60 the fabric passes over a guide roll 50 into the bite of a pair of feed rolls 51 and 52, the latter of which dips into the liquid in a tank 53 which drains into the scouring unit through an overflow 54. The control roll 42 is adapted to control the rate of the feed rolls 51 and 52 so as to maintain the fabric under a constant tension in its passage through the apparatus.
From the feed rolls 51 fand 52 .the fabric passes through a series of units 60A, 60B and 60C which are substantially identical with the unit 60 and the corresponding parts of which have been given similar reference numbers with the suffixes added. Each unit is followed by a pair of feed rolls 51a, 52a, Sib, 52h, 51C `and 52a` respectively. Each pair of feed rolls is followed by a control unit composed of fixed rolls 41a, 41h and 41a, 43a, 43b and 43a 'and a movable control roll 42a, 42b and 42C respectively. Each control roll is connected to control the rate of the preceding pair of feed rolls so as to maintain the fabric under a constant tension in the corresponding unit.
The unit 60A can contain a stabilizing agent of the type described above. The unit 60B can contain a desizing `solution for removing any size remaining on the fabric. If the fabric is unsized or if it is not desired to remove the size, this unit may be omitted. The unit 60C can contain wash water toy remove the stabilizing and desizing solutions.
From the unit 60C the fabric .passes under a roll 65 in la tank 66 containing rinse Water for a final rinse. Rinse Water is supplied from a spray header 67 onto the fabric as it enters and leaves the tank 6.6. From the tank 66 the fabric passes between a pair of squeeze rolls 68, thence to a folder 70 which may be `of standard construcytion and is adapted to lay the fabric in a series of folds 71. The fabric is then taken to a drying stage such as a slack loop dryer, not shown, or a slack tray dryer o-r a hot air dryer of any standard type, wherein the cloth is dried in a relaxed state.
As already noted, this invention can be carried out by a batch process. For this purpose, several of the conventional wool finishing machines can be used. For example, the fabric can be impregnated with the relaxing `solution and wound on the perforated drum of a decating machine together with a cotton leader cloth, care being taken to wind with a minimum of tension so that the fabric is free to shrin-k. Steam is then blown through the penforations in the drum for about 2-4 minutes, and the fabric is then cooled by aspirating air through it by means of a vacuum pump for several minutes. The fabric is then unwound, excess Water is removed by hydro-extraction, and the fabric is dried in a tension-free state in la slack loop drier or slack tray drier of the conventional design.
Another conventional wool finishing machine Iwhich can be effectively employed for carrying `out this invention by a batch process is a pressure piece-dyeing machine wherein the fabric is Wound on a perforated roll with minimal tension without a leader cloth. 'I'he process can then be carried out in the same manner `as described above for a decating machine. Alternatively, the fabric can be wound on the roll without being previously impregnated with the relaxing solution. In this instance, the wound roll of fabric in the machine is immersed in the relaxing solution which is then 4heated and circulated through the `fabric to effect the desired relaxation. The fabric can t-hen be cooled `by replacing the relaxing solution with cold water, and thereafter a stabilizing solution can be circulated therethrough. The fabric can then be subjected to the further steps of extraction and drying as mentioned above in connection with the decating machine.
It is to be understoiod that Whether ya biatch or continuous process is employed with the present invention, the fabric either be-fore or after drying may be subjected to other standard finishing steps, such as dyeing or the like. I
It is to be further understood that the present invention is applicable to all types of woven wool and partwlool fabrics, consisting of two sets of yarns, namely, weft and warp yarns, except creped fabrics, containing 6 inches, and they contained 65 threads per inch in the warp and 54 picks per inch in the filling. All the pieces were rope-scoured in a conventional manner; piece A was then finished in a conventional manner, by beck-dyeing, tenter drying, shearing, decating, and pressing. Pieces B and at least 30% wool in one set of yarns, the remainder 5 being synthetic or natural staple fibers such as polyester, C were treated by the process of this invention by the conpolyamide, acrylic, rayon, or cotton fibers. It will be tinuous method described above, the fabric being free evident that when stretch in only one set of yarns or in from constraint in the filling direction with a warp ten- Ione direction is desired, the yarns in the other set can be sion of 30 pounds, using the apparatus shown in FIGS. composed entirely of the aforementioned synthetic or 10 1 and la. The relaxing agent was an lS-to-l aqueous n'atunal (non-wool) staple iibers. solution of monoethanolamine sullite, and the steaming Obviously the weft yarns and warp yarns may be woven time was 21/2 minutes, the temperature in the autoclave under the same tension and may have the same number being 212-218 F. In the stabilizing step, a 0.2% soluof yarns per inch if equal stretch is desired in both direction of formic acid was employed. The nishing was tions or the filler yarns may be woven under a greater completed lby beck-dyeing, drying in a slack tray dryer, tension than .the warp yarns, :and vice versa, depending and semi-decating. Piece D was treated by the process on the product desired. of `this invention by the batch method described above, The following table gives further illustrative examples using a Burlington pressure piece-dyeing machine. The of specific yarn sizes and weaves which are suitable for fabric was impregnated with a 2 0tol aqueous solution the above purpose. of monoethanolamine suliite containing a small amount of Turns per inch Yarn Size Warp Ends, per inch Weft Ends, per inch of S Twist Singles Z-Ily Worsted Counts Before After Before After 14 2/6os 49 6o 42 51 2o 2/60s es 74 es 77 1sV z/sos 6s 72 52 64 17 2/4os 53.5 5s 48 59 s 2/2os 3s 42 4o 44 While the above examples have indicated two-ply yarns it will'be evident that singlesyarns of the equivalent sizes may be used for either warp` or weft, or both, in place of the two-ply yarns specified, in which case the twist of the singles yarns will be within the ranges set forth for the equivalent singles yarns in the examples.
It is also contemplated by this invention that with fab- -rics of certain constnuction if complete relaxation is permitted to take place, the stretch will be greater than desired. Consequently, with such fabrics it will be desirable to limit the amount of contraction iby holding to the desirable range of 6-25% This can be accomplished, for example, Iby clamping it in a tentering frame in such a manner that the fabric is free to contract to the desired limited extent and subjecting the fabric to the heating step while in this condition.
The following examples will furher illustrate my invention and enable others skilled in the art to understand the invention more completely. However, it is to be understood that my invention is not limited to the particular conditions and materials recited in these examples.
Example I Four pieces of plain-weave, 7-71/2 oz. tropical worsted mens suiting fabric, containing 48% wool and 52% Daeronl polyester fiber, were woven from undyed j/igs worsted counts yarn with 18 turns per inch of 'twist in both warp and filling (twist factor 3.2). In two of these pieces, A and B, the Warp yarn was spun on the worsted system, and the filling yarn on the cotton system. In the `other two pieces, C and D, both sets of yarn were spun on the cotton system. l
In the greige state, the width of all the pieces was 63 wetting agent, and passed through a pair of squeeze rolls to reduce the pick up to 110%. The Wet piece was loosely wrapped on the perforated drum, and steam was then blown through it for 4 minutes, the machine being open to the atmosphere. When the steam was blown through the loosely wound fabric, there was suflicient freedom from constraint to permit the fabric to shrink extensively in the filling direction; and to a limited extent in the warp direction. Following steaming, the piece was cooled by filling the machine with cold water, which was then drained. The piece was unwound from the drum, extracted, and dried in a slack loop dryer. The whole process was then repeated. The finishing was completed in the manner described for pieces B and C.
The Width of the fabrics was then measured, and their stretchability in both yarn directions was determined in the following manner: swatches of fabric were cut 24 inches long in the test direction and 8 inches wide in the other direction, and were exposed to standard atmosphere of relative humidity, 70 F. for a minimum of 4 hours. Two marks, parallel to the short sides `of each swatch were made 18 inches apart. One short edge of the swatch was then attached to a 6-inch-wide hanging clamp, and another clamp of the same width was attached to the lower, free-hanging, end of the swatch. A weight was then added to the lower clamp which, added to the weight of the clamp itself, created a total load of 5 lbs. The distance between the tWo marks in the fabric was then measured, and the percentage extension of the fabric calculated. The results obtained with the four fabrics are recorded in the table below, together with their nished 65 widths.
Stretch, percent Finished Width (inches) Filling Warp Fabric:
A-Worsted warp, no treatment 60 3. 9 2. 8 B-Worsted warp continuous process 56 9. 2 3. 3 C-Cotton-spun warp, continuous process 57 7. 2 3. 6 D-Cotton-spun warp, batch process 57 7. 2 3.6
7 The stretch was in all cases completely recovered when the load was removed from the swatch. The swatches were then subjected successively to three treating steps: (a) relaxation by 30 minutes immersion in water at 80- through the roll for three minutes and the fabric was then cooled by sucking cold air inwards, by means of a pump, for two minutes. The pieces were unwou-iid from the roll, extracted to about 60% pickeup, and dried in a 85 F.; (b) dry-cleaning, in accordance with Federal spec- 5 slack tray dryer. The process was repeated, and the iiication CCC-T-l91b, CS-5944; and (c) laundering in pieces were semi-decated. The finished widths and the a domestic agitator washer, at 105 F., with a 3 minute recoverable stretch of the fabrics are given in the table sudsing cycle, in a total load of 3 lbs. The stretch was below: redetermined after each of the three steps, and was found to lbe unchanged by the iirst two steps, and slightly re- 10 Finished Stretch, percent duced 4by the third. (Wldth inches) Aftter relaxation, dry cleaning, and laundering fabrics Filling Warp had a smooth iinish equal to Fabric A. Relaxation, dry cleaning, and laundering caused a considerable increase in Fabrics; the surface fuzziness and loss of clarity of finish in Fabric E g; Eig' A. Fabrics B, C and D were less effected by these treat- 62 9.2 4.2 ments than Fabric A.
It is well known that wool-containin fabrics com osed Wholly of yarns Spun on 1he Cotton Sysem when rgshed The tilling stretch remained essentially unchanged after according to the prior art, have the undesirable characrelaxatlon gry'lean'meg nd lrundermg; the Warp stretch teristics of indistinct iinish, with the yarns merging into was some-w, at mca? y t e treatments: each other, and having surface fuzziness. It is therefore In addition to then Stretch chaiacterlstlc .Fabncs E particularly remarkable that Fabrics C and D, nished in ind Cf; vleri also oable for he1r-clear msh 'afllor accordance with my invention, were equal in clarity of t e; lsloht ll. goo rape an resistance to wrm mg finished Fabric A which was composed partly of worstedat 1g uml ny' E l 3 spun yarns. xamp e In addition to their stretch and superior surface iinish, Four pieces of all-wool fabric were processed by the Fabrics B, C, and D possessed a softer hand, a better continuous process described above, using the device drape anda greater resistance to wrinkling at high relative shown in FIGS. 1 and 1a and the treatment conditions humidity, than Fabric A. All these characteristics are given in Example 1 except that the warp tension was 25 conductive to the production of more easily tailorable, pounds instead of 30 pounds. The composition and conbetter fitting, more pleasing, and better wearing garments. struction details of the fabrics are given below:
Pieces Fabric type H I K L Mens Dress Mens Womens suiting sulting annel Dyeing Piece ,Piece Top Piece Weave Plain Plain Plain 2/1twill Yarn counts:
Warp- 1/24s Wst ,5% run 2/50s Wst 44run Filling 2/50's Wst 1/20s Wst... 2/50s Wst 44run Singles, yarn twist, tpi, warp 16 1 1 Singles yarn twist, tpi, illin 13 Worsted twist factor, warp 3.8 Worsted twist factor, filling 2.9- Threads per inch, finished 41 Picks per inch, nished Width, inches, linished 5812 Weight, ozsJyd., finished 9% Example 2 Three stock-dyed, plain-weave, all wool worsted fabrics were woven and scoured. Their construction details are given in the table below:
Pieces E F G Worsted yarn counts, warp and filling 2/57s 2/40's- 2/50s Singles yarn twist, turns per inch, warp and filling Singles twist factor Threads per inch, gr Picks per inch, greige. Width, inches, greige Weight, ozs./yd. finished The three pieces were treated according to the process of this invention by the batch method described above. The pieces were impregnated with a 20:1 solution of monoetha-nolamine suliite containing a small amount of wetting agent, squeezed to a pick-up of 110%, and loosely wrapped with a cotton leader cloth on the perforated drum of a decatirlg machine, Steam was blown outward The recoverable stretch of these fabrics lis given in the table below:
Stretch, percent Filling Warp Fabrics:
will be understood that various other modifications will be apparent to and can readily be made by those skilled in the art without departing from the scope and spirit of the invention. Accordingly, it is not intended that the scope of the claims appended hereto be limited to the examples and description set forth herein but rather that the claims be construed as encompassing all the features of patentable novelty which reside in the present invention including all features which would be treated as patentable equivalents thereof by those skilled in the art to which the invention pertains.
What I claim is:
1. A fabric comprising a set of warp yarns and a set of weft yarns wherein one of said sets of yarns includes wool, and
is highly crimped as it passes under and over yarns of the other set, and
is permanently set in the crimped state, the crimp being a planar crimp such that the fabric may be stretched by at least 6% and will return to its original state when the stretching force is released, said fabric having the stretch property in one direction only.
2. A fabric as set forth in claim 1 wherein said yarns are 20s to 66s plied yarns having a singles twist of from 12 to 22 turns per inch and a ply twist of from 8 to 14 turns per inch, the twist varying inversely with the yarn size.
3. The fabric set forth in claim 1 wherein the fabric contains from 42 to 74 warp yarns per inch and from 44 to 77 weft yarns per inch when in the relaxed state.
4. A woven fabric comprising a set of weft yarns and a set of warp yarns,
the yarns of one of said sets being composed essentially of wool,
said wool being in the highly crimped and bulked state characteristic of a yarn which has been highly twisted and shrunken in the presence of a stabilizagent which is capable of reacting with the wool to set the yarn in its contracted state whereby the fabric is capable of stretching by at least 6% and of returning to its contracted state when the stretch force is released, said fabric having the stretch property in one direction only.
5. A chemically stabilized woven fabric having highly crimped wool yarns extending in one direction of the fabric, the crimp in said wool yarns being a planar crimp of a magnitude such that the fabric may be stretched by at least 6% in the direction of the crimp in said wool yarns and will return to its original state when stretching force is released, said fabric having the stretch property in one direction only.
6. The fabric as defined in claim 5 wherein said wool yarns have a worsted twist factor of about 1.5 to 4.0.
7. A fabric comprising a set of warp yarns and a set of weft yarns wherein one of said sets of yarns is composed essentially of wool land is highly crimped as it passes under and over yarns of the other set and is permanently set in the crimped state, the crimp being a planar crimp such that the fabric may be stretched by at least 6% in the direction of said one set of yarns and will return to its original state when the stretching force is released, said vfabric having the stretch property in one direction only.
8. The fabric as defined in claim 7 wherein said wool yarns have a worsted twist factor of about 1.5 to 4.0'.
9. The fabric as dened in claim 7 wherein said wool yarns form at least 30% by weight of the fabric.
10. The woven fabric as defined in claim 7 wherein the remainder of the fabric consists of thermoplastic fibers.
11. A woven wool fabric comprising a set of warp yarns and a set of weft yarns wherein one of said sets of wool yarns is highly crimped as it passes under and over yarns of the other set and is permanently set in the crimped state, the crimp being a planar crimp such that the wool fabric may be stretched by at least 6% in the direction of said one set of yarns and will return to its original state when the stretching force is released, said fabric having the stretch property in one direction only.
12.. A wool fabric as defined in claim 11 wherein said planar crimp is such that the iwool fabric may be stretched from 6 to 25% in one direction and will return to its original state when the stretching force is released.
13. The wool fabric of claim. 11 wherein the wool yarns have a worsted twist factor of about 1.5 to 4.0.
14. A woven fabric having a substantially smooth surface and comprising a set of weft yarns and a set of warp yarns, some of the yarns in one of said sets being composed essentially of wool, said w-ool being in a highly crimped and bulked state and permanently set in said state, the crimp in said wool yarns being a planar crimp such that the fabric is capable of stretching from 6% to 25% and of returning to its contracted state when the stretching force is released, said fabric having the stretch property in one direction only.
15. A chemically stabilized woven fabric having highly crimped wool containing yarns extending in one direction of the fabric, the crimp in said wool containing yarns being a planar crimp of a magnitude such that the fabric may be stretched by at least 9.2% in the direction of the crimp in said wool containing yarns and Will return to its original state when the stretching force is released, said fabric having the aforesaid stretch property in one direction only.
16. A chemically stabilized woven fabric having highly crimped wool containing yarns extending in one direction of the fabric, the crimp in said wool containing yarns being a planar crimp of a magnitude such that the fabric may be stretched by at least 13.5% in the direction of the crimp in said wool containing yarns and -will return to its original state when the stretching for-ce is released, said fabric having the aforesaid stretch property in one direction only.
References Cited by the Examiner ROBERT R. MACKEY, Primary Examiner.
RUSSELL C. MADER, DONALD W. PARKER,
- Examiners.
L. K. RIMRODT, Assistant Examiner.

Claims (1)

1. A FABRIC COMPRISING A SET OF WRAP YARNS AND A SET OF WEFT YARNS WHEREIN ONE OF SAID SETS OF YARNS INCLUDES WOOL, AND IS HIGHLY CRIMPED AS IT PASSES UNDER AND OVER YARNS OF THE OTHER SET, AND IS PERMANENTLY SET IN THE CRIMPED STATE, THE CRIMP BEING A PLANAR CRIMP SUCH THAT THE FABRIC MAY BE STRETCHED BY AT LEAST 6% AND WILL RETURN TO IS ORIGINAL STATE WHEN THE STRETCHING FORCE IS RELEASED, SAID FABRIC HAVING THE STRETCH PROPERTY IN ONE DIRECTION ONLY.
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DE1963ST020438 DE1460722B1 (en) 1962-03-26 1963-03-23 Process for finishing fabric webs in which a fabric is strongly tensioned in the direction of one group of threads and relieved in the direction of the other group of threads
GB1167563A GB1043402A (en) 1962-03-26 1963-03-25 Wool and wool-blend fabrics and method of making the same

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US3504712A (en) * 1964-11-24 1970-04-07 Deering Milliken Res Corp Woven stretch fabric
US3528763A (en) * 1964-08-03 1970-09-15 Stevens & Co Inc J P Producing stretch fabric through use of chemical modifiers and a plurality of tension zones
US6418598B1 (en) * 1998-09-10 2002-07-16 Chargeurs Boisssy Method of manufacturing an elastic all-fiber polyester cloth
US20090159149A1 (en) * 2005-06-10 2009-06-25 Textronics, Inc. Surface functional electro-textile with functionality modulation capability, methods for making the same, and applications incorporating the same
EP3779031A4 (en) * 2018-04-03 2022-09-21 Spiber Inc. High-density woven fabric and method for manufacturing same

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US3528763A (en) * 1964-08-03 1970-09-15 Stevens & Co Inc J P Producing stretch fabric through use of chemical modifiers and a plurality of tension zones
US3504712A (en) * 1964-11-24 1970-04-07 Deering Milliken Res Corp Woven stretch fabric
US6418598B1 (en) * 1998-09-10 2002-07-16 Chargeurs Boisssy Method of manufacturing an elastic all-fiber polyester cloth
US20090159149A1 (en) * 2005-06-10 2009-06-25 Textronics, Inc. Surface functional electro-textile with functionality modulation capability, methods for making the same, and applications incorporating the same
US7849888B2 (en) * 2005-06-10 2010-12-14 Textronics, Inc. Surface functional electro-textile with functionality modulation capability, methods for making the same, and applications incorporating the same
EP3779031A4 (en) * 2018-04-03 2022-09-21 Spiber Inc. High-density woven fabric and method for manufacturing same

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