US3234138A - Clear, uniform liquid detergent composition - Google Patents
Clear, uniform liquid detergent composition Download PDFInfo
- Publication number
- US3234138A US3234138A US378028A US37802864A US3234138A US 3234138 A US3234138 A US 3234138A US 378028 A US378028 A US 378028A US 37802864 A US37802864 A US 37802864A US 3234138 A US3234138 A US 3234138A
- Authority
- US
- United States
- Prior art keywords
- weight
- soap
- diethanolamide
- compositions
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 65
- 239000003599 detergent Substances 0.000 title claims abstract description 29
- 239000007788 liquid Substances 0.000 title claims description 23
- 239000000344 soap Substances 0.000 claims abstract description 46
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 8
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims abstract description 8
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims abstract description 7
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims abstract description 7
- ZZNDQCACFUJAKJ-UHFFFAOYSA-N 1-phenyltridecan-1-one Chemical compound CCCCCCCCCCCCC(=O)C1=CC=CC=C1 ZZNDQCACFUJAKJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- BPXGKRUSMCVZAF-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)decanamide Chemical compound CCCCCCCCCC(=O)N(CCO)CCO BPXGKRUSMCVZAF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- -1 ALKALI METAL FATTY ACID Chemical class 0.000 claims description 6
- 229940118783 capric diethanolamide Drugs 0.000 claims description 4
- FZQAYFWUOCXLKJ-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)octanamide Chemical compound CCCCCCCC(=O)N(CCO)CCO FZQAYFWUOCXLKJ-UHFFFAOYSA-N 0.000 claims description 4
- SKDZEPBJPGSFHS-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)tetradecanamide Chemical compound CCCCCCCCCCCCCC(=O)N(CCO)CCO SKDZEPBJPGSFHS-UHFFFAOYSA-N 0.000 claims description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 4
- LMVSBYPDMNAXPF-UHFFFAOYSA-N N-(decanoyl)ethanolamine Chemical compound CCCCCCCCCC(=O)NCCO LMVSBYPDMNAXPF-UHFFFAOYSA-N 0.000 claims description 3
- BOWVQLFMWHZBEF-KTKRTIGZSA-N oleoyl ethanolamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCO BOWVQLFMWHZBEF-KTKRTIGZSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 2
- 235000011009 potassium phosphates Nutrition 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 7
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 5
- 229910052708 sodium Inorganic materials 0.000 abstract description 5
- 239000011734 sodium Substances 0.000 abstract description 5
- 239000003760 tallow Substances 0.000 abstract description 4
- FIWQZURFGYXCEO-UHFFFAOYSA-M sodium;decanoate Chemical compound [Na+].CCCCCCCCCC([O-])=O FIWQZURFGYXCEO-UHFFFAOYSA-M 0.000 abstract description 3
- 239000000975 dye Substances 0.000 abstract description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 abstract description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 abstract description 2
- 239000003755 preservative agent Substances 0.000 abstract description 2
- 239000003381 stabilizer Substances 0.000 abstract description 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 229910000318 alkali metal phosphate Inorganic materials 0.000 abstract 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 abstract 1
- 239000003752 hydrotrope Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000009472 formulation Methods 0.000 description 5
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 5
- LPMBTLLQQJBUOO-KTKRTIGZSA-N (z)-n,n-bis(2-hydroxyethyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCO LPMBTLLQQJBUOO-KTKRTIGZSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- VJESJEJNMGVQLZ-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(=O)N(CCO)CCO VJESJEJNMGVQLZ-UHFFFAOYSA-N 0.000 description 2
- 229960005480 sodium caprylate Drugs 0.000 description 2
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 2
- 229940082004 sodium laurate Drugs 0.000 description 2
- BYKRNSHANADUFY-UHFFFAOYSA-M sodium octanoate Chemical compound [Na+].CCCCCCCC([O-])=O BYKRNSHANADUFY-UHFFFAOYSA-M 0.000 description 2
- 101100518501 Mus musculus Spp1 gene Proteins 0.000 description 1
- MMBILEWCGWTAOV-UHFFFAOYSA-N N-(2-Hydroxypropyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)NCC(C)O MMBILEWCGWTAOV-UHFFFAOYSA-N 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- JHIXEZNTXMFXEK-UHFFFAOYSA-N N-(tetradecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCC(=O)NCCO JHIXEZNTXMFXEK-UHFFFAOYSA-N 0.000 description 1
- PHGJEIHYTQIKOX-UHFFFAOYSA-L [Na+].[Na+].CCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O Chemical compound [Na+].[Na+].CCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PHGJEIHYTQIKOX-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 description 1
- QPXWUAQRJLSJRT-UHFFFAOYSA-N diethoxyphosphinothioyl diethyl phosphate Chemical compound CCOP(=O)(OCC)OP(=S)(OCC)OCC QPXWUAQRJLSJRT-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- LJUFLKJWXJBZSY-UHFFFAOYSA-L disodium;hexadecanoate;octadecanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O LJUFLKJWXJBZSY-UHFFFAOYSA-L 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- XGZOMURMPLSSKQ-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)N(CCO)CCO XGZOMURMPLSSKQ-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- BLGUIMKBRCQORR-UHFFFAOYSA-M potassium;hexanoate Chemical compound [K+].CCCCCC([O-])=O BLGUIMKBRCQORR-UHFFFAOYSA-M 0.000 description 1
- RLEFZEWKMQQZOA-UHFFFAOYSA-M potassium;octanoate Chemical compound [K+].CCCCCCCC([O-])=O RLEFZEWKMQQZOA-UHFFFAOYSA-M 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- UDWXLZLRRVQONG-UHFFFAOYSA-M sodium hexanoate Chemical compound [Na+].CCCCCC([O-])=O UDWXLZLRRVQONG-UHFFFAOYSA-M 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
Definitions
- the present invention pertains to detergent compositions, and more particularly to liquid detergent composi tions especially adapted: forthe cleansing of hard surfaces.
- Liquid detergent compositions for the cleansing of hard surfaces should be uniform in order to achieve optimum cleaning and customer acceptance.
- cleansers are formulated from an ethanolamide nonionic detergent and an inorganic phosphate in an aqueous medium, the resulting formulations are not uniform liquids, but rather they are heterogeneous liquids or'gels or solids. If high molecular weight soaps, i.e., alkali metal salts of fatty acids having at least 16 carbon atoms, are added to such formulations in an attempt to make them uniform liquids, the resulting formulations are still not uniform liquids.
- Examples 1 through 4 show detergent formulations containing an inorganic phosphate and an ethanolamide nonionic detergent in water and Examples 5 through 8 show such compositions to which a high molecular weight soap has been added. All of the formulations of Examples 1 through 8 were heterogeneous" liquids or gels or solids at room temperature of about-80 F. The amounts of the components are expressed in percent by weight of the compositions.
- hard surfaceliquidcleansers which are substantially clear and uniform and have a viscosity which can be varied from about 3 centipoises to about 10,000 centipoises.
- compositions of the invention are substantially clear uniform liquid detergent compositions consisting essentially of anaqueous solution of an inorganic phosphate, an ethanolamide nonionic detergent, and at least one low molecular weight soap or at least one low molecular weight soap plus at least one high molecular weight soap.
- compositions of the invention because the resulting compositions are heterogeneous liquids or gels or solids. at room temperature: lauric monoethanolamide, myristic monoethanolamide, tallow monoethanolamide, stearic diethanolamide and lauric isopropanolamide.
- the low molecular weight soap component acts as a hydrotrope to solubilize the ethanolamide nonionic detergent in the presence of the, inorganic phosphate and to solubilize any high molecular weight soap present in the compositions.
- the low molecular weight soap component is a water-soluble alkali metal fatty acid soap One or more of.
- low molecular weight soaps having from 6 to 14 carbon atoms.
- low molecular weight soaps may be present in the compositions.
- Typical useful low molecular weight soaps include sodium and potassium caproate, caprylate, caprate, laurate, and myristate.
- the remaining essential component of the compositions' is the solvent medium, namely water.
- the amounts of the components present in the compositions will vary depending upon the specific phosphate, ethanolamide nonionic detergent, and low molecular weight soap employed in formulating the compositions. In general, however, as the amount of phosphate is increased, the amount of low molecular weight soap must also be increased except for the shorter chain length low molecular weight soaps. Also as a general rule the amount of low molecular weight soap and ethanolamide nonionic detergent is increased when shorter chain length.
- low molecular weight soaps are used.
- a further general principle in determining the amounts of the components present in the compositions of the invention is that as the amount of phosphate is increased, the longer chain length low molecular weight soaps become less effective as hydrotropes or solubilizing agents.
- the amount of phosphate is from about 5% to about 20% by weight, andpreferably about 10% by weight, of the composition.
- the amount of low molecular weight soap' isfrom about 1% to about 15% by weight of the composition.
- the amount of caprylic monoethanolamide or capric monoethanolamide is from about 1.5% to about 7% by weight of the composition
- the amount of oleic monoethanolamide is from about 1.5% to about 13% by weight of the composition
- the amount of caprylic diethanolamide, capric diethanolamide, lauric diethanolamide, myristic diethanolamide, palmitic diethanolamide or oleic diethanolamide is from about 1.5% to about 16% by weight of the composition.
- the above amounts of phosphate, soap and ethanolamide are further adjusted to maintain. the composition substantially clear and uniform.
- liquid detergent compositions of the invention will have a viscosity as low as about 3 or 4 centipoises.
- Such compositions are thin liquids which have the advantage of spreading rapidly in use.
- Such thin liquids however, have some disadvantages in that they drip from the spoutof the container on pouring and give the false impression of being watery and weak. While.
- the high molecular weight soap increases the viscosity of the compositions and-con tributes of the detergency and grease emulsification-propertiesthereof. They also serve to provide the proper suds desirable in a hard surface cleanser.
- the high molecular weight soap component is a watersoluhle alkali metal fatty acid soap having at least r16 carbon atoms and'in general from 16'to 18 carbon atoms. Typical examples thereof are sodium and potassium palmitate, stearate and ole'aten If desired, one or 'more of such .highmolecular weight soaps can beused.
- soaps produced from the naturally occurring mixture of fatty acids present in tallow can be utilized.
- the high molecular weight soap component constitutes a. small amount .of the compositions. In general, theamount is not higher than about 10% by Weightrofthe composition. Usually the amount thereof is not over about 5% by weight. molecular weight soap component is from about 1% to about'4% byweight. l
- compositions of the invention can also be present in the compositions of the invention.
- compatible adjuvants can also be present in the compositions of the invention. Typical of such materials are perfumes, dyes, preservatives, wetting agents, 5 30 storage stabilizers, and auxiliary hydrotropes.
- compositions are-readily prepared by merely mix-. ing the components thereoftogether.
- compositions of the invention 1 will be further illustrated by the following examples.- In theseexamples 35 the amounts of the components are'expresed in percent by weight of the total composition. All of the composi-;
- Examples 42 .and43 in Table 8 depict the 'use of penta- In Table .4 below Examples- 18 throughv :23 illustrate. the" use .of sodium caprate' as thel-hydrotropeiin tetr'a-.-
- compositions can contain more than one low molecu-l' larweight soap as the vhydrotrope component, thereof.
- Examples 56 through 60 further show the use of a high molecular weight soap, namely sodium palmitate, to form high viscosity, substantially clear, uniform liquid detergent compositions.
- a high molecular weight soap namely sodium palmitate
- Example 61 demonstrates that the compositions can contain various compatible adjuvants.
- a substantially clear, uniform liquid detergent composition consisting essentially of an aqueous solution of (1) from about 5% to about 20% by weight of a potassium phosphate selected from the group consisting of tetrapotassium pyrophosphate and Collaborationapotassium tripolyphosphate (2) from about 1% to about 15% by weight of a water-soluble alkali metal fatty acid soap having from 6 to 14 carbon atoms, and (3) an ethanolamide nonionic detergent selected from the group consisting of (a) from about 1.5% to about 7% by weight of caprylic monoethanolamide, and capric monoethanolamide, (b) from about 1.5% to about 13% by weight of oleic monoethanolamide and (c) from about 1.5% to about 16% by weight of caprylic diethanolamide, capric diethanolamide, lauric diethanolamide, myristic diethanolamide, palmitic diethanolamide and oleic diethanolamide; the above amounts of phosphate, soap and ethanolamide being adjusted to maintain the composition substantially clear and uniform.
- composition as set forth in claim 1 which also contains an amount up to about 10% by weight of a water-soluble alkali metal fatty acid soap having from lto 18 carbon atoms.
- composition as set forth in claim 1 wherein the ethanolamide is lauric diethanolamide.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL263962D NL263962A (enrdf_load_stackoverflow) | 1964-06-25 | ||
| GB611/61A GB969966A (en) | 1964-06-25 | 1961-01-06 | Liquid detergent composition |
| FR856467A FR1292330A (fr) | 1964-06-25 | 1961-03-22 | Compositions détergentes liquides |
| US378028A US3234138A (en) | 1964-06-25 | 1964-06-25 | Clear, uniform liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US378028A US3234138A (en) | 1964-06-25 | 1964-06-25 | Clear, uniform liquid detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3234138A true US3234138A (en) | 1966-02-08 |
Family
ID=23491437
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US378028A Expired - Lifetime US3234138A (en) | 1964-06-25 | 1964-06-25 | Clear, uniform liquid detergent composition |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3234138A (enrdf_load_stackoverflow) |
| FR (1) | FR1292330A (enrdf_load_stackoverflow) |
| GB (1) | GB969966A (enrdf_load_stackoverflow) |
| NL (1) | NL263962A (enrdf_load_stackoverflow) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3440057A (en) * | 1966-08-18 | 1969-04-22 | Thomas F Mcfadden | Fermented malt beverages chemically preserved |
| US4486329A (en) * | 1983-10-17 | 1984-12-04 | Colgate-Palmolive Company | Liquid all-purpose cleaner |
| US5075026A (en) * | 1986-05-21 | 1991-12-24 | Colgate-Palmolive Company | Microemulsion all purpose liquid cleaning composition |
| US5510110A (en) * | 1993-06-04 | 1996-04-23 | W. Neudorff Gmbh Kg | Chemical mollusc barrier |
| US5700331A (en) * | 1996-06-14 | 1997-12-23 | Colgate-Palmolive Co. | Thickened cleaning composition |
| US5703028A (en) * | 1996-06-14 | 1997-12-30 | Colgate-Palmolive Co | Liquid crystal detergent compositions based on anionic sulfonate-ether sulfate mixtures |
| US5714454A (en) * | 1996-08-07 | 1998-02-03 | Colgate-Palmolive Co. | Light duty liquid cleaning compositions comprising alkyl sulroglycerides |
| US5719114A (en) * | 1996-06-28 | 1998-02-17 | Colgate Palmolive Company | Cleaning composition in various liquid forms comprising acaricidal agents |
| US5723431A (en) * | 1989-09-22 | 1998-03-03 | Colgate-Palmolive Co. | Liquid crystal compositions |
| US5741769A (en) * | 1994-11-23 | 1998-04-21 | Colgate Palmolive Company | Microemulsion light duty liquid cleaning compositions |
| US5756441A (en) * | 1996-08-07 | 1998-05-26 | Colgate Palmolive Company | High foaming nonionic surfactant based liquid detergent |
| US5759290A (en) * | 1996-06-13 | 1998-06-02 | Colgate Palmolive Company | Liquid crystal compositions |
| US5763386A (en) * | 1993-08-04 | 1998-06-09 | Colgate Palmolive Company | Microemulsion all purpose liquid cleaning compositions comprising ethoxylated polyhydric alcohols with at least partial esters thereof, and optional dralkyl sulfosuccinate |
| US5834417A (en) * | 1996-06-13 | 1998-11-10 | Colgate Palmolive Co. | Light duty liquid cleaning compositions |
| US5880078A (en) * | 1997-09-04 | 1999-03-09 | The United States Of America As Represented By The Secretary Of The Navy | Non-solvent, general use exterior aircraft cleaner |
| US6159925A (en) * | 2000-04-06 | 2000-12-12 | Colgate-Palmolive Co. | Acidic liquid crystal compositions |
| US6384010B1 (en) | 2000-06-15 | 2002-05-07 | S.C. Johnson & Son, Inc. | All purpose cleaner with low organic solvent content |
| US8785366B2 (en) | 2008-05-23 | 2014-07-22 | Colgate-Palmolive Company | Liquid cleaning compositions and methods |
| WO2015018567A3 (de) * | 2013-08-06 | 2015-05-21 | Evonik Industries Ag | Formulierung enthaltend caprylsäureethanolamid und/oder caprinsäureethanolamid in kombination mit einem tensid |
| US11013248B2 (en) | 2012-05-25 | 2021-05-25 | Kraft Foods Group Brands Llc | Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1335646C (en) * | 1988-06-13 | 1995-05-23 | Guido Clemens Van Den Brom | Liquid detergent compositions |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2527076A (en) * | 1947-02-24 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2560839A (en) * | 1947-07-24 | 1951-07-17 | Gen Aniline & Film Corp | Detergent composition |
| US2859182A (en) * | 1956-11-02 | 1958-11-04 | Lever Brothers Ltd | Heavy duty liquid detergent composition |
| US2860107A (en) * | 1957-07-25 | 1958-11-11 | Lever Brothers Ltd | Controlled sudsing heavy duty liquid detergent |
| US2913416A (en) * | 1955-03-04 | 1959-11-17 | Rohm & Haas | Liquid detergent composition |
| US3001944A (en) * | 1957-07-12 | 1961-09-26 | Colgate Palmolive Co | Controlling viscosity of synthetic detergent-soap shampoos |
-
0
- NL NL263962D patent/NL263962A/xx unknown
-
1961
- 1961-01-06 GB GB611/61A patent/GB969966A/en not_active Expired
- 1961-03-22 FR FR856467A patent/FR1292330A/fr not_active Expired
-
1964
- 1964-06-25 US US378028A patent/US3234138A/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2527076A (en) * | 1947-02-24 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2560839A (en) * | 1947-07-24 | 1951-07-17 | Gen Aniline & Film Corp | Detergent composition |
| US2913416A (en) * | 1955-03-04 | 1959-11-17 | Rohm & Haas | Liquid detergent composition |
| US2859182A (en) * | 1956-11-02 | 1958-11-04 | Lever Brothers Ltd | Heavy duty liquid detergent composition |
| US3001944A (en) * | 1957-07-12 | 1961-09-26 | Colgate Palmolive Co | Controlling viscosity of synthetic detergent-soap shampoos |
| US2860107A (en) * | 1957-07-25 | 1958-11-11 | Lever Brothers Ltd | Controlled sudsing heavy duty liquid detergent |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3440057A (en) * | 1966-08-18 | 1969-04-22 | Thomas F Mcfadden | Fermented malt beverages chemically preserved |
| US4486329A (en) * | 1983-10-17 | 1984-12-04 | Colgate-Palmolive Company | Liquid all-purpose cleaner |
| US5075026A (en) * | 1986-05-21 | 1991-12-24 | Colgate-Palmolive Company | Microemulsion all purpose liquid cleaning composition |
| US5723431A (en) * | 1989-09-22 | 1998-03-03 | Colgate-Palmolive Co. | Liquid crystal compositions |
| US5510110A (en) * | 1993-06-04 | 1996-04-23 | W. Neudorff Gmbh Kg | Chemical mollusc barrier |
| US5763386A (en) * | 1993-08-04 | 1998-06-09 | Colgate Palmolive Company | Microemulsion all purpose liquid cleaning compositions comprising ethoxylated polyhydric alcohols with at least partial esters thereof, and optional dralkyl sulfosuccinate |
| US5741769A (en) * | 1994-11-23 | 1998-04-21 | Colgate Palmolive Company | Microemulsion light duty liquid cleaning compositions |
| US5834417A (en) * | 1996-06-13 | 1998-11-10 | Colgate Palmolive Co. | Light duty liquid cleaning compositions |
| US5759290A (en) * | 1996-06-13 | 1998-06-02 | Colgate Palmolive Company | Liquid crystal compositions |
| US5700331A (en) * | 1996-06-14 | 1997-12-23 | Colgate-Palmolive Co. | Thickened cleaning composition |
| US5703028A (en) * | 1996-06-14 | 1997-12-30 | Colgate-Palmolive Co | Liquid crystal detergent compositions based on anionic sulfonate-ether sulfate mixtures |
| US5719114A (en) * | 1996-06-28 | 1998-02-17 | Colgate Palmolive Company | Cleaning composition in various liquid forms comprising acaricidal agents |
| US5756441A (en) * | 1996-08-07 | 1998-05-26 | Colgate Palmolive Company | High foaming nonionic surfactant based liquid detergent |
| US5714454A (en) * | 1996-08-07 | 1998-02-03 | Colgate-Palmolive Co. | Light duty liquid cleaning compositions comprising alkyl sulroglycerides |
| US5880078A (en) * | 1997-09-04 | 1999-03-09 | The United States Of America As Represented By The Secretary Of The Navy | Non-solvent, general use exterior aircraft cleaner |
| US5916372A (en) * | 1997-09-04 | 1999-06-29 | The United States Of America As Represented By The Secretary Of The Navy | Non-solvent, general use exterior aircraft cleaner |
| US6159925A (en) * | 2000-04-06 | 2000-12-12 | Colgate-Palmolive Co. | Acidic liquid crystal compositions |
| US6384010B1 (en) | 2000-06-15 | 2002-05-07 | S.C. Johnson & Son, Inc. | All purpose cleaner with low organic solvent content |
| US8785366B2 (en) | 2008-05-23 | 2014-07-22 | Colgate-Palmolive Company | Liquid cleaning compositions and methods |
| US11013248B2 (en) | 2012-05-25 | 2021-05-25 | Kraft Foods Group Brands Llc | Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings |
| WO2015018567A3 (de) * | 2013-08-06 | 2015-05-21 | Evonik Industries Ag | Formulierung enthaltend caprylsäureethanolamid und/oder caprinsäureethanolamid in kombination mit einem tensid |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1292330A (fr) | 1962-05-04 |
| GB969966A (en) | 1964-09-16 |
| NL263962A (enrdf_load_stackoverflow) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3234138A (en) | Clear, uniform liquid detergent composition | |
| US4071463A (en) | Stable cleaning agents of hypochlorite bleach and detergent | |
| US3156655A (en) | Heavy duty liquid detergent composition | |
| US5281354A (en) | Liquid cleanser composition | |
| US2920045A (en) | Heavy duty liquid detergent compositions | |
| US3701735A (en) | Automatic dishwashing compositions | |
| US3931033A (en) | Liquid foam-regulated nonionic detergent compositions | |
| CA1321334C (en) | Liquid cleaners | |
| US4597887A (en) | Germicidal hard surface cleaning composition | |
| US2581677A (en) | Phosphate detergent composition in | |
| US3231504A (en) | Liquid detergent compositions | |
| DE69307737T3 (de) | Verbesserungen in allzweckreinigerzusammensetzungen | |
| JPH05509343A (ja) | 漂白性液体洗剤 | |
| GB994705A (en) | Anti-bacterial compositions | |
| GB1105905A (en) | Detergent-hydrotrope compositions | |
| JP2999262B2 (ja) | 液体洗剤 | |
| US3101324A (en) | Liquid detergent composition | |
| US2947702A (en) | Liquid detergent compositions | |
| US2831815A (en) | Detergent compositions | |
| US3816351A (en) | Industrial car wash composition | |
| US3282852A (en) | Heavy duty liquid detergents | |
| US3203900A (en) | Opaque liquid detergent compositions | |
| GB1169551A (en) | Detergent Bar | |
| US3594324A (en) | Detergent composition containing a synergistic combination of emc and gelatin as soil suspension agents | |
| US2992993A (en) | Liquid detergent compositions |