US3227639A - Method of anodizing aluminum with electrolyte containing sulfophthalic acid - Google Patents
Method of anodizing aluminum with electrolyte containing sulfophthalic acid Download PDFInfo
- Publication number
- US3227639A US3227639A US147177A US14717761A US3227639A US 3227639 A US3227639 A US 3227639A US 147177 A US147177 A US 147177A US 14717761 A US14717761 A US 14717761A US 3227639 A US3227639 A US 3227639A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- acid
- sulfate
- per liter
- grams per
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/14—Producing integrally coloured layers
Definitions
- This invention relates to anodizing aluminum, and particularly to producing oxide coatings on an aluminum article by making the same anode in an electrolytic cell employing an aqueous acid electrolyte.
- aluminum includes high purity aluminum, aluminum in various commercial grades, and aluminum base alloys.
- Decorative and protective oxide coatings on aluminum have long been made by anodizing in electrolytes consisting of aqueous solutions of sulfuric acid. Such electrolytes are usually employed at a temperature near room temperature, and must be cooled to maintain such temperature.
- the coatings, as so produced, are usually relatively clear or colorless, although on some alloys they may be tinted or colored by some constituents.
- an electrolyte consisting essentially of at least one sult'ophthalic acid selected from the group consisting of 4-sulfophthalic acid and S-sulfoisophthalic acid, together with sulfate provided by at least one compound selected from the group consisting of sulfuric acid and water soluble sulfates and bisulfates, and water, may be advantageously used in an electrolytic cell for anodizing aluminum.
- the 4-sulfophthalic acid, or the S-sulfoisophthalic acid, or a mixture thereof, may be employed in a very small amount, e.g. less than 10 grams per liter, but prefer-ably at least 10 grams per liter or more are employed.
- the solution limit lies near 55 percent by weight, in the case of 4-sulfophthalic acid, for example, and even a substantial undissolved excess does not prevent anodizing.
- These sulfophthalic acids are more expensive than sulfuric acid, so larger amounts would not orinarily be preferred from a cost standpoint.
- the sulfuric acid, or equivalent sulfate, or mixtures thereof may likewise be employed in a very small amount, e.g. less than 1 gram per liter (calculated as H may be employed, but preferably at least 1 gram per liter or more is employed. Somewhat larger amounts will ordinarily be employed, since the voltage requirements for the same anodizing current density (with consequent ele-ctrical equipment, and electrolyte cooling cost factors to be considered) are reduced in such cases. However, for the production of colored coatings at or near room temperature, an amount less than 20 grams per liter is desirable, and very satisfactory results have been obtained when sulfuric acid or soluble sulfate is present in an amount of about 3 to 10 grams per liter.
- the sulfate content may be conveniently provided by sulfuric acid, an alkali metal or ammonium sulfate or bisulfate such as sodium sulfate, sodium bi-sulfate or ammonium bisulfate, a heavy metal sulfate or bisulfate such as ferrous sulfate, an organic sulfate or bisulfate such as aniline sulfate, or any other water soluble sulfate or bisulfate such as hydrazine sulfate. Double sulfates may also be used.
- an alkali metal or ammonium sulfate or bisulfate such as sodium sulfate, sodium bi-sulfate or ammonium bisulfate
- a heavy metal sulfate or bisulfate such as ferrous sulfate
- an organic sulfate or bisulfate such as aniline sulfate
- Electrolyte A Component Grams per liter 4-sulfop'hthalic acid Sulphuric acid 8 Water Balance Grams per Liter Component B C D 4-sulfophthalic acid 0 10 75 5-sulfoisophthalic acid 88 0 0 Sulfuric acid 7 1 Water Balance in each case
- electrolytes for use in accordance with the invention may beemployed ,under a wide variety of operating conditions.
- a temperature at or near room temperature, e.g. 75 B, may be employed.
- Current densities may extend over a wide range, for practical purposes as low as-9 amperes per square foot or even less, and as high as 144 amperes per square foot or even more, depending on size, shape and composition of the aluminum article.
- the current density is between 12 and 36amperes per square foot.
- the current may be either AC. or DC, or a current of undulating characteristics, but D.C. is quite satisfactory.
- Time of treatment depends upon current density and thickness of coating desired, as coating thickness is generally a function of anodizing current density and time.
- Abrasion resistant coatings for outdoor service are often made in a thickness of- 0.4 to 1 mil (0.0004 to 0.001 inches). However, coatings may be made in any substantial thickness desired, e.g. 0.1 mil or greater.
- Electrolyte A above mentioned has been operated at 75 F., at 24 amperes per square foot, with voltages starting at about 32 volts and generally extending upto about 70 volts over a 30 minute period, depending on the composition of the aluminum being coated, to produce abrasion resistant, colored oxide coatings on a variety of aluminum articles.
- the colored coatings produced on various types of aluminum it is noted that Electrolyte A, operated under the conditions just noted, for time suflicient to produce coatings about 1 mil thick, produced the following results as to color:
- Color stability of the colored coatings was very high when tested in the Fade-O-Meter after 1000 hours of exposure. Lighter and darker shades of these colors were obtained with thinner and thicker coatings, respectively. Similar results were obtained on 6061-T6 and 6063-T alloys with Electroyte B and the same operating conditions.
- an abrasion resistance value of 400 grams per mill was obtained by the ASTM D658-44 method of test.
- Coatings produced in accordance with the invention may be sealed, or dyed or pigmented and sealed, by conventional procedures.
- dyes or pigments may be used to modify the colors produced by the anodizing methods described herein.
- Etching or brightening treatments may be given the aluminum surfaces prior to anodizing, when desired.
- a method of anodizing aluminum comprising making an aluminum article anode in an electrolyte consisting essentially of at least 10 grams per liter of at least one sulfophthalic acid selected from the group consisting of 4-sulfophthalic acid and 5-sulfoisophthalic acid, at least 1 gram per liter and less than 20 grams per liter of sulfate (calculated as H provided by at least one compound selected from the group consisting of sulfuric acid and water soluble sulfates and bisulfates, and water, the ratio of sulfophthalic acid to sulfate (calculated as H 50 being at least 7:1,
- the current density is maintained between about 9 and 144 amperes per square foot for a time sufficient to .produce a colored anodic oxide coating at least 0.4
- sulfophthalic acid is 4-sulfophthalic acid in an amount of at least 50 grams per liter, and the sulfate is provided by sulfuric acid.
- sulfophthalic acid is 5-sulfoisophthalic acid in an amount of at least 50 grams per liter, and the sulfate is provided by sulfuric acid.
- a method of anodizing aluminum comprising making an aluminum article anode in an electrolyte consisting essentially of about 70 to grams per liter of 4-sulfophthalic acid, about 3 to 10 grams per liter of sulfate (calculated as H 50 provided by at least one compound selected from the group consisting of sulfuric acid and water soluble sulfates and bisulfates, and water,
- the current density is maintained between about 12 and 36-amperes per square foot
- a method of anodizing aluminum comprising making an aluminum article anode in an electrolyte consisting essentially of about 70 to 130 grams per liter of 5-sulfois0phthalic acid, about 3 to 10 grams per liter of sulfate (calculated as H 50 provided by at least one compound selected from the group consisting of sulfuric acid and water soluble sulfates and bisulfates, and water,
- the current density is maintained between about 12 and 36 amperes per square foot
- a method of anodizing aluminum comprising making an aluminum article anode in an oxide coating productive electrolyte consisting essentially of at least 10 grams per liter of sulfophthalic acid, about 1 to 20 grams per liter of sulfate (calculated as H 80 and water, for a time sutficient to produce a colored anodic oxide coatmg.
- a method of anodizing aluminum comprising making an aluminum article anode in an electrolyte con sisting essentially of at least 10 grams per liter of sulfophthalic acid consisting essentially of 4-sulfophthalic acid, at least 1 gram per liter and less than 20 grams per liter of sulfate (calculated as H 50 provided by at least one compound selected from the group consisting of sulfuric acid and water soluble sulfates and bisulfates, and water,
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US147177A US3227639A (en) | 1961-10-24 | 1961-10-24 | Method of anodizing aluminum with electrolyte containing sulfophthalic acid |
DE19621260266 DE1260266C2 (de) | 1961-10-24 | 1962-08-24 | Verfahren zum anodischen oxydieren von aluminium und aluminiumlegierungen |
GB33995/62A GB962048A (en) | 1961-10-24 | 1962-09-05 | Improvements relating to the anodizing of aluminum |
CH1247762A CH437960A (de) | 1961-10-24 | 1962-10-24 | Elektrolyt zum Anodisieren von Aluminium und Aluminiumlegierungen |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US147177A US3227639A (en) | 1961-10-24 | 1961-10-24 | Method of anodizing aluminum with electrolyte containing sulfophthalic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
US3227639A true US3227639A (en) | 1966-01-04 |
Family
ID=22520558
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US147177A Expired - Lifetime US3227639A (en) | 1961-10-24 | 1961-10-24 | Method of anodizing aluminum with electrolyte containing sulfophthalic acid |
Country Status (4)
Country | Link |
---|---|
US (1) | US3227639A (de) |
CH (1) | CH437960A (de) |
DE (1) | DE1260266C2 (de) |
GB (1) | GB962048A (de) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3280013A (en) * | 1964-06-02 | 1966-10-18 | Aluminum Co Of America | Anodizing electrolyte and process |
US3328274A (en) * | 1966-11-25 | 1967-06-27 | Kaiser Aluminium Chem Corp | Method of anodizing aluminum |
US3331759A (en) * | 1967-07-18 | Method of manufacturing a soled elec- trolytic capacitor using an alkali metal biphthalate | ||
US3370943A (en) * | 1965-11-04 | 1968-02-27 | Kaiser Aluminium Chem Corp | Aluminum alloy |
US3384561A (en) * | 1965-02-15 | 1968-05-21 | Olin Mathieson | Process and electrolyte for coloring aluminum |
US3411994A (en) * | 1965-09-07 | 1968-11-19 | Horizons Inc | Aluminum anodizing process and product thereof |
US3425918A (en) * | 1965-11-12 | 1969-02-04 | Alusuisse | Electrolyte for the production of selfcolored anodic oxide layers on aluminum and aluminum alloys |
US3818566A (en) * | 1970-05-14 | 1974-06-25 | Aluminum Co Of America | Aluminum alloy products and surface treatment |
US3849263A (en) * | 1969-06-25 | 1974-11-19 | O Gedde | Process for electrolytically colouring of aluminium which has previously been anodically oxidized |
US4022670A (en) * | 1975-07-16 | 1977-05-10 | Swiss Aluminium Ltd. | Process for preparation of lithographic printing plates |
US4060462A (en) * | 1976-10-21 | 1977-11-29 | Aluminum Company Of America | Color anodizing of aluminum |
US4177299A (en) * | 1978-01-27 | 1979-12-04 | Swiss Aluminium Ltd. | Aluminum or aluminum alloy article and process |
EP0689096A1 (de) | 1994-06-16 | 1995-12-27 | Eastman Kodak Company | Lithographische Druckplatten mit einer oleophilen Abbildungsschicht |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6583091B2 (en) | 2001-07-13 | 2003-06-24 | Exxonmobil Research And Engineering Company | Method for inhibiting corrosion using 4-sulfophthalic acid |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2233785A (en) * | 1935-12-11 | 1941-03-04 | Sherka Chemical Co Inc | Process for the manufacture of oxide layers on aluminum and aluminum alloys and to electrolytes therefor |
US3031387A (en) * | 1958-04-14 | 1962-04-24 | Kaiser Aluminium Chem Corp | Anodic oxidation of aluminum |
-
1961
- 1961-10-24 US US147177A patent/US3227639A/en not_active Expired - Lifetime
-
1962
- 1962-08-24 DE DE19621260266 patent/DE1260266C2/de not_active Expired
- 1962-09-05 GB GB33995/62A patent/GB962048A/en not_active Expired
- 1962-10-24 CH CH1247762A patent/CH437960A/de unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2233785A (en) * | 1935-12-11 | 1941-03-04 | Sherka Chemical Co Inc | Process for the manufacture of oxide layers on aluminum and aluminum alloys and to electrolytes therefor |
US3031387A (en) * | 1958-04-14 | 1962-04-24 | Kaiser Aluminium Chem Corp | Anodic oxidation of aluminum |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3331759A (en) * | 1967-07-18 | Method of manufacturing a soled elec- trolytic capacitor using an alkali metal biphthalate | ||
US3280013A (en) * | 1964-06-02 | 1966-10-18 | Aluminum Co Of America | Anodizing electrolyte and process |
US3384561A (en) * | 1965-02-15 | 1968-05-21 | Olin Mathieson | Process and electrolyte for coloring aluminum |
US3411994A (en) * | 1965-09-07 | 1968-11-19 | Horizons Inc | Aluminum anodizing process and product thereof |
US3475167A (en) * | 1965-11-04 | 1969-10-28 | Kaiser Aluminium Chem Corp | Aluminum alloy for color anodizing |
US3370943A (en) * | 1965-11-04 | 1968-02-27 | Kaiser Aluminium Chem Corp | Aluminum alloy |
US3425918A (en) * | 1965-11-12 | 1969-02-04 | Alusuisse | Electrolyte for the production of selfcolored anodic oxide layers on aluminum and aluminum alloys |
US3328274A (en) * | 1966-11-25 | 1967-06-27 | Kaiser Aluminium Chem Corp | Method of anodizing aluminum |
US3849263A (en) * | 1969-06-25 | 1974-11-19 | O Gedde | Process for electrolytically colouring of aluminium which has previously been anodically oxidized |
US3818566A (en) * | 1970-05-14 | 1974-06-25 | Aluminum Co Of America | Aluminum alloy products and surface treatment |
US4022670A (en) * | 1975-07-16 | 1977-05-10 | Swiss Aluminium Ltd. | Process for preparation of lithographic printing plates |
US4060462A (en) * | 1976-10-21 | 1977-11-29 | Aluminum Company Of America | Color anodizing of aluminum |
US4177299A (en) * | 1978-01-27 | 1979-12-04 | Swiss Aluminium Ltd. | Aluminum or aluminum alloy article and process |
EP0689096A1 (de) | 1994-06-16 | 1995-12-27 | Eastman Kodak Company | Lithographische Druckplatten mit einer oleophilen Abbildungsschicht |
Also Published As
Publication number | Publication date |
---|---|
DE1260266C2 (de) | 1973-01-04 |
CH437960A (de) | 1967-06-15 |
GB962048A (en) | 1964-06-24 |
DE1260266B (de) | 1973-01-04 |
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