US3203900A - Opaque liquid detergent compositions - Google Patents
Opaque liquid detergent compositions Download PDFInfo
- Publication number
- US3203900A US3203900A US132289A US13228961A US3203900A US 3203900 A US3203900 A US 3203900A US 132289 A US132289 A US 132289A US 13228961 A US13228961 A US 13228961A US 3203900 A US3203900 A US 3203900A
- Authority
- US
- United States
- Prior art keywords
- soap
- liquid
- tallow
- ammonium
- diethanolamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 title claims description 53
- 239000003599 detergent Substances 0.000 title claims description 40
- 239000000203 mixture Substances 0.000 title claims description 32
- 239000000344 soap Substances 0.000 claims description 78
- 239000003760 tallow Substances 0.000 claims description 35
- 239000011734 sodium Substances 0.000 claims description 17
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- MMBILEWCGWTAOV-UHFFFAOYSA-N N-(2-Hydroxypropyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)NCC(C)O MMBILEWCGWTAOV-UHFFFAOYSA-N 0.000 claims description 11
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 11
- ZZNDQCACFUJAKJ-UHFFFAOYSA-N 1-phenyltridecan-1-one Chemical compound CCCCCCCCCCCCC(=O)C1=CC=CC=C1 ZZNDQCACFUJAKJ-UHFFFAOYSA-N 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- LPMBTLLQQJBUOO-KTKRTIGZSA-N (z)-n,n-bis(2-hydroxyethyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCO LPMBTLLQQJBUOO-KTKRTIGZSA-N 0.000 claims description 4
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 claims description 4
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- SKDZEPBJPGSFHS-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)tetradecanamide Chemical compound CCCCCCCCCCCCCC(=O)N(CCO)CCO SKDZEPBJPGSFHS-UHFFFAOYSA-N 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 2
- 239000001205 polyphosphate Substances 0.000 claims description 2
- 235000011176 polyphosphates Nutrition 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 229910019142 PO4 Inorganic materials 0.000 description 10
- 239000010452 phosphate Substances 0.000 description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000908 ammonium hydroxide Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 239000008149 soap solution Substances 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical class CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GXWZIFBGFYTFQK-UHFFFAOYSA-K [K+].[K+].[K+].[K+].[O-]P([O-])([O-])=O Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])([O-])=O GXWZIFBGFYTFQK-UHFFFAOYSA-K 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- -1 sodium cations Chemical class 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
Definitions
- the present invention relates to liquid detergent compositions and more particularly to opaque liquid detergent compositions especially adapted for the cleansing of hard surfaces.
- opaque liquid detergent compositions While translucent or transparent liquid synthetic detergent compositions are known, the provision of opaque liquid detergent compositions is desirable in that such compositions present a more attractive and more viscous appearance which the consumer associates with greater cleansing power.
- the formulation of opaque liquid detergent compositions is not a simple matter. Thus if one attempts to prepare opaque liquid detergent compositions by adding opacifying agents to clear hard surface liquid cleansers, the resulting products are unsatisfactory due to their instability. This is brought on by the coagulation and separation of the opacifying agents from the liquid.
- an object of the present invention to provide opaque liquid detergent compositions especially adapted for the cleansing of hard surfaces. Another object is to prepare opaque liquid detergent compositions which are free of coagulation and phase separation and hence are stable.
- Suitable soaps are the salts of fatty acids having from 16 to 18 carbon atoms, for example, the sodium, potassium and ammonium salts of tallow fatty acids (40 iodine value), palmitic acid, oleic acid and stearic acid.
- the nonionic detergent may include the monoand di-lower alkylolamides of fatty acids having from 12 to 18 carbons, the condensation product of lauryl alcohol with about 5 moles of ethylene oxide, and nonylphenol condensed with from 1 to 5 moles of ethylene oxide.
- suitable alkylolamides include lauric diethanolamide (LDA), lauric isopropanolamide (LIPA), oleic diethanolamide (ODA), myristic diethanolamide (MDA), tallow diethanolamide (TDA) and lauric monoethanolamide (LMEA).
- the complex phosphate component may be tetrapotassium pyrophosphate or pentapotassium tripolyphosphate.
- compositions will vary with the specific phosphate, the nonionic detergent, the type of soap and its cation, and the 3,2033% Patented Aug. 31, 1965 lCe total concentration of soap and nonionic detergent. No general relationship can be established for combining soap, complex phosphate and nonionic detergent to give an opaque liquid.
- the degree of opacity also varies with the type of soap, the type of nonionic detergent and the concentration of phosphate, the liquids formed ranging from transparent cloudy liquids to transparent opaque liquids to very opaque liquids.
- a liquid is described as a transparent cloudy liquid if the outline of an object held behind a 4 ounce sample bottle of the liquid can be seen on looking through the liquid even after the liquid has been gently agitated. If an object held behind a 4 ounce sample bottle of the liquid can be seen on looking through the liquid which has stood overnight but it cannot be seen after gentle agitation of the liquid, due to its increase in opacity, the liquid is characterized as a transparent opaque liquid. If an object held behind a 4 ounce sample bottle of the liquid cannot be seen on looking through the liquid after allowing the liquid to stand overnight, the liquid is described as an opaque liquid.
- compositions of the present invention comprise a total of from about 3.5% to about 14% by weight of soap plus nonionic detergent, and from about 5% to about 20% TABLE I.LIQUID COMPOSITIONS CONSISTING OF LDA, TALLOW SOAP, TKPP AND WATER Percent by weight Ingredients.
- D 4 H a LDA- 4 4 Na tallowate Na laurate- TKPP Water Viscosity (cps) Description of composition:
- Example H is an opaque liquid detergent composition according to the present invention.
- compositions based on lauric isopropanolamide (LIPA), sodium tallow soap, tetrapotassium pyrophosphate (TKPP) and water are listed.
- Example M of the invention compared with Example L demonstrates that the soap, nonionic detergent and complex phosphate must be selected in accordance with the present invention in order to form an opaque liquid.
- the liquid compositions described herein were made by dissolving the soap in water or by neutralizing the fatty acid with an alkali metal or ammonium hydroxide to form soap.
- the nonionic detergent was then added to the soap solution followed by the complex phosphate which had been predissolved in water.
- the liquid compositions can also be made by adding the complex phosphate, predissolved in water, to the soap solution followed by the nonionic detergent. Heat was used when necessary todissolve the soap, to melt the nonionic detergent and to facilitate the mixing of the ingredients.
- An example of a formulation containing an anionic detergent, sequestering agent and perfume is as follows:
- Example N Ingredients: percent by weight Sodium dodecylbenzene sulfonate 1.25 Ammonium tallow soap (40 IV) 2.95 Lauric diethanolamide 2.85 Lauric isopropanolamide 1.00 Tetrapotassium pyrophosphate 10.00 Versene (ethylene diamine tetraacetic acidsequestering agent) 0.10 Perfume 0.15 Miscellaneous 0.40
- the dodecylbenzene sulfonic acids and tallow fatty acids used in this example were neutralized with 0.63 of ammonium hydroxide, assaying 28% NH:.;, and 1.13% of 50% sodium hydroxide solution.
- the ammonium and sodium cations are believed to be combined as shown in the above formulation.
- the ammonia gives the product an ammoniacal odor.
- Example 0 Ingredients: percent by weight Ammonium tallow soap (40 IV) 2.95 Lauric diethanolamide 2.85 Lauric isopropanolamide 1.00
- the pH of the foregoing composition was adjusted to 10.5 by addition of ammonium hydroxide.
- sodium pyrophosphate or sodium tripolyphosphate may be added to the compositions of the present invention. While it is difiicult, in view of the aforementioned variables to specify an exact limit for these additives, the amount can be at least that which is equivalent in sodium content to the amount of sodium soap in the formula, if the sodium soap is replaced by a potassium soap.
- 80:20 5-10 70:30 (SM-12% 60:40 7 /r-15 50:50 8%16% 40:60 10-17% 30:70 10-17 20 s0 1017%, 4 LDA-ammonium 3. 5 80:20 10 oleate soap. 20:80 15 5 LDA-ammonium 14 80:20 5-10 oleate soap. 20:80 5-10 LDA-ammonium 3. 5 80:20 5-10 palmitate soap. 70:30 7 A-15 60:40 10-20 20:80 20 7 LDA-a nmonium 14 80:20 5-10 palnntate soap. 60:40 8%15 20:80 15-20 8 LDA-ammonium 3. 5 80:20 5-10 stearate soap.
- palmitate soap 28:50 5-10 tallow ap- 2 0 5 2s LIPA-ammonium 14 00:40 5-10 25 55 NPE-l-ammonium 14 :70 5-10 palmitate soap. go 545 tallow soap.
- a stable opaque liquid detergent composition in the tallow stoap 14 28:70 104715 form of an aqueous solution consisting essentially of: 31 t iiwssiif 3 3; (a) a Water-soluble soap selected from the group consist- 32 LltflfiA-ammonium 3.5 38 5 ing of sodium, potassium and ammonium salts of fatty a W soap M8 5 3 acids having from 16 to 18 carbon atoms, (b) from about 33 LMEA Onmm 14 28328 15 5% to about 20% by weight of a complex inorganic n 111105 313,.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE621529D BE621529A (en(2012)) | 1961-08-18 | ||
| US132289A US3203900A (en) | 1961-08-18 | 1961-08-18 | Opaque liquid detergent compositions |
| FR907204A FR1331208A (fr) | 1961-08-18 | 1962-08-17 | Compositions détergentes liquides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US132289A US3203900A (en) | 1961-08-18 | 1961-08-18 | Opaque liquid detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3203900A true US3203900A (en) | 1965-08-31 |
Family
ID=22453324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US132289A Expired - Lifetime US3203900A (en) | 1961-08-18 | 1961-08-18 | Opaque liquid detergent compositions |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US3203900A (en(2012)) |
| BE (1) | BE621529A (en(2012)) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3391083A (en) * | 1966-06-29 | 1968-07-02 | Monsanto Co | Surface active agents |
| US3471248A (en) * | 1962-05-03 | 1969-10-07 | Geigy Ag J R | Dye carrier compositions |
| US3900407A (en) * | 1972-12-14 | 1975-08-19 | Colgate Palmolive Co | Composition for cleaning and glazing furs |
| US4082684A (en) * | 1975-04-29 | 1978-04-04 | Lever Brothers Company | Liquid detergent |
| US4188306A (en) * | 1976-08-23 | 1980-02-12 | Colgate-Palmolive Company | Pumpable soap |
| US4446043A (en) * | 1981-09-01 | 1984-05-01 | Lever Brothers Company | Built liquid detergent compositions |
| US4613446A (en) * | 1985-03-13 | 1986-09-23 | Pennzoil Company | Gelled detergent composition and cleaning pads containing same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2560839A (en) * | 1947-07-24 | 1951-07-17 | Gen Aniline & Film Corp | Detergent composition |
| US2674580A (en) * | 1950-07-20 | 1954-04-06 | Colgate Palmolive Co | Liquid shampoo |
| US2920045A (en) * | 1955-09-06 | 1960-01-05 | Colgate Palmolive Co | Heavy duty liquid detergent compositions |
| US3021284A (en) * | 1958-10-30 | 1962-02-13 | Atlantic Refining Co | Liquid detergent compositions |
-
0
- BE BE621529D patent/BE621529A/xx unknown
-
1961
- 1961-08-18 US US132289A patent/US3203900A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2560839A (en) * | 1947-07-24 | 1951-07-17 | Gen Aniline & Film Corp | Detergent composition |
| US2674580A (en) * | 1950-07-20 | 1954-04-06 | Colgate Palmolive Co | Liquid shampoo |
| US2920045A (en) * | 1955-09-06 | 1960-01-05 | Colgate Palmolive Co | Heavy duty liquid detergent compositions |
| US3021284A (en) * | 1958-10-30 | 1962-02-13 | Atlantic Refining Co | Liquid detergent compositions |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3471248A (en) * | 1962-05-03 | 1969-10-07 | Geigy Ag J R | Dye carrier compositions |
| US3391083A (en) * | 1966-06-29 | 1968-07-02 | Monsanto Co | Surface active agents |
| US3900407A (en) * | 1972-12-14 | 1975-08-19 | Colgate Palmolive Co | Composition for cleaning and glazing furs |
| US4082684A (en) * | 1975-04-29 | 1978-04-04 | Lever Brothers Company | Liquid detergent |
| US4188306A (en) * | 1976-08-23 | 1980-02-12 | Colgate-Palmolive Company | Pumpable soap |
| US4446043A (en) * | 1981-09-01 | 1984-05-01 | Lever Brothers Company | Built liquid detergent compositions |
| US4613446A (en) * | 1985-03-13 | 1986-09-23 | Pennzoil Company | Gelled detergent composition and cleaning pads containing same |
Also Published As
| Publication number | Publication date |
|---|---|
| BE621529A (en(2012)) |
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