US3180912A - Methods and apparatus for spinning multicomponent filaments - Google Patents

Methods and apparatus for spinning multicomponent filaments Download PDF

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Publication number
US3180912A
US3180912A US204772A US20477262A US3180912A US 3180912 A US3180912 A US 3180912A US 204772 A US204772 A US 204772A US 20477262 A US20477262 A US 20477262A US 3180912 A US3180912 A US 3180912A
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US
United States
Prior art keywords
spinnerette
spinning
filaments
streams
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US204772A
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English (en)
Inventor
Jr Alvah L Rowe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE634069D priority Critical patent/BE634069A/xx
Priority to NL129117D priority patent/NL129117C/xx
Priority to NL294482D priority patent/NL294482A/xx
Priority to US204772A priority patent/US3180912A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Priority to NO149141A priority patent/NO117809B/no
Priority to DK300063AA priority patent/DK105353C/da
Priority to GB24988/63A priority patent/GB970230A/en
Priority to DE19631435553 priority patent/DE1435553A1/de
Priority to FR939197A priority patent/FR1361105A/fr
Priority to CH783863A priority patent/CH401344A/fr
Application granted granted Critical
Publication of US3180912A publication Critical patent/US3180912A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/32—Side-by-side structure; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00—Treatment of filament-forming or like material
    • D01D1/06—Feeding liquid to the spinning head
    • D01D1/065—Addition and mixing of substances to the spinning solution or to the melt; Homogenising
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/26—Composite fibers made of two or more materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
    • Y10S425/049—Spinnerette mixer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
    • Y10S425/217—Spinnerette forming conjugate, composite or hollow filaments

Definitions

  • a fairly recent development in the art of spinning is the production of filaments from two different spinning compositions to form filaments having variegated colors or varying compositions.
  • one side of the filaments is of one composition While the other side of the filament is a difierent composition.
  • the two compositions do not flow through the spinnerette hole together but fiow through alternately so that portions of the l ngth of the filament is one composition and the remainder of the filament is the other composition. If, in the latter case, compositions of different colors are used the formed filaments will be variegated in color. If the flow of each composition is cut oil sharply, the filament will have alternating portions of different colors, with fairly sharp lines of demarcation between adjacent colors.
  • Another object of this invention is to provide methods and apparatus for spinning a filament which Varies in color or composition along its length.
  • a further object of this invention is to provide methods and apparatus for spinning a filament of two colors or compositions wherein the flow of each filament through the spinnerette hole can be controlled.
  • Still another object of this invention is to provide methods and apparatus for spinning a filament of two colors or compositions wherein streams of one spinning composition are caarried by a stream of a second spinning composition to a spinnerette.
  • a still further object of this invention is to provide methods and apparatus for spinning filaments wherein substantially sinusoidal streams of one spinning composition are carried by a stream of another spinning composition to a spinnerette.
  • Yet another object of this invention is to provide methods and apparatus for spinning filaments wherein a movable spinnerette injects streams of one spinning composition into a large stream of another spinning composition leading to a fixed spinnerette.
  • Still another of this invention is to provide methods and apparatus for spinning filaments wherein an oscillated spinnerette positioned behind a fixed spinnerette injects substantially sinusoidal streams of one spinning composition into a stream of another spinning composition flowing to and through the fixed spinnerette.
  • a method illustrating one embodiment of the inven tion comprises moving a first spinning solution in a primary stream along a path and injecting a plurality of discrete secondary streams ofa second spinning solution into the primary stream, while at the same time moving the points of injection to vary the. configuration of the secondary streams. Filaments are then formed from the combined streams.
  • One embodiment of the present invention contemplates a spinning apparatus wherein a spinning solution is forced slowly through a chamber or cavity to a fixed spinnerette.
  • a moving spinnerette positioned in the cavity injects streams of another spinning composition into the cavity so that the spun filaments vary in color or composition along their length. Because of the high viscosity and slow rate or" fiow of the compositions, the injected streams reach the fixed spinnerette intact, i.e., the flow of the solution is laminar. This results in filaments having the above-described characteristics.
  • FIGURE 1 is a perspective view of one embodiment of the invention with portions cut away to show the structure of the movable spinnerette
  • FIGURE 2 is a perspective view of a fragment of the movable spinnerette showing the configuration of the streams delivered by this spinnerette,
  • FIGURE 3 is an enlarged view of a portion of one of the filaments showing the configuration of one type of junction of the two compositions in the filament,
  • FIGURE 4- is an enlarged view of a portion of one of the filaments showing the configuration of another type of junction
  • FIGURE 5 is an enlarged view of a portion of one of the filaments showing the result obtained when the movable spinnerette is so positioned that one of the injected streams flows through one of the spinnerette holes with the larger stream which carries the injected streams.
  • a spinning head or body 1 is shown provided with a cylindrical chamber or cavity 12.
  • a cap 13 threaded onto the body 11 holds a spinnerette 16 in a fixed position closing the cavity 12.
  • the spinerette 16 is provided with conventional holes whichare adapted to form filaments 17 when a spinning solution or composition is forced through the spinnerette.
  • a plurality of ports 29 leading to the end of the cavity or chamber opposite the fixed spinnerette 16 are connected through a pipe 21 to a pump 22 which is connected to a source 23 of spinning solution or composition.
  • the pump 22 delivers the spinning solution to the chamber or cavity 12, the solution then moving slowly along the cavity 12 to the spinnerette in. By adjusting thespeed of the,
  • the speed at which the spinning solution flows through the cavity 12. can be varied. Because of the high viscosity of the spinning solution and the large cross sectional area of the cavity 12, the spinning solution flows through the cavity 12 at a very slow rate of speed.
  • the block or body it is provided with a bore 26 which is concentric with the cavity 12 and in which is rotatably mounteda tube or pipe 27, a bearing 25; being provided for supporting one end of the tube 27.
  • the tube 27 extends into the cavity 12. and has attached thereto a second spinnerette 29 having the configuration best illustrated in FIGURES 1 and 2.
  • the second, or movable, spinnerette 29 includes a manifold 32 secured to the end of the tube 27 and having extending therefrom a plurality of arms 33.
  • Each of the arms 33 is tubular in configuration and is connected through the manifold 32 to the tube 27.
  • Each of the arms 33 is al o provided with a plurality of spaced holes Sdthrough which a second spinning solution or composition fiows into the larger stream fiowing from the ports 20 to the fixed spinnerette 16.
  • the second spinning solution which is different in color or chemical composition from the first solution, is supplied from a source 33 through a pump 39.
  • a pump 39 By adjusting the speed of the pump 39, the rate at which the second solution flows through the holes 36 into the cavity can be varied.
  • a seal 41 of a well known type is secured to the back of the block 11 to prevent leakage of the spinning solution along the tube 27.
  • a joint 43 is provided to permit oscillation of the movable spinnerette 29, one side 44 of the joint 43 being connected to a portion 27A of the tube 27 and the other side 43 being connected to the tube 27.
  • a lever 47 con nected to the side 45 of the joint 43 is connected to a mechanism 48 of a well known type which oscillates the side 45 and the tube 27, thereby oscillating the movable spinnerette 29.
  • the streams leaving the holes 36 will define generally sinusoidal paths. Since the viscosities of both spinning solutions are very high and since the rate of How of the solutions through the cavity 12 is very low, the streams leaving the holes do not lose their shape or configuration before reaching the spinnerette 16. Thus, the main stream of spinning solution carries a plurality of much smaller but well defined streams of a different composition. The configurations of these discrete smaller streams is illustrated in FIGURE 2. This multitude of small streams carried by the larger stream cause the spun filaments to have alternate portions 52 and 53 of different colors or chemical compositions. The rate of oscillation of the spinnerette 29 will determine the wave length of the sinusoidal paths or streams which will, in turn, determine the lengths of the portions 52 and 53.
  • FIGURES 3 and 4 illustrate some of the junctions that can be obtained with the apparatus of the present invention.
  • the spinnerette 29 is oscillated at a speed sufficient to cause the small streams to quickly cross the holes in the spinnerette 16.
  • This type of junction can also be obtained by oscillating the spinnerette through a greater amplitude.
  • the spinnerette 29 is oscillated at a slower rate or through a smaller amplitude, so that the small stream of spinning composition takes a longer period of time to cross the hole in the spinnerette 16.
  • the spinnerette 29 In forming the filament of FIGURE the spinnerette 29 is held stationary and in a position so that one composition flows through one side of the hole in the spinnerette 16 while the other composition or solution flows through the other side of the hole. This results in a conjugate filament.
  • this device can be used to form filaments which vary in appearance from those shown in FIGURE 1 to that shown in FIGURE 5. In fact, the device has been used to produce this range of filaments.
  • the method of the invention involves the injection of discrete, small streams of one spinning solution into a large stream of another spinning solution. Because of the laminary flow of the two solutions, each small stream remains intact until it reaches the point where filaments are formed from the combined streams.
  • the configurations of these streams can be varied. For example, if these points of injection are rotated about a line normal to the plane at which the filaments are formed, each small stream will define a helix. Oscillation of the points of injection about this line causes the smaller streams to have substantially sinusoidal configurations (actually, the configuration of each small stream is that of a sine wave inscribed on a cylinder).
  • a process for forming filaments comprising advancand forming filaments from the combined primary and secondary streams.
  • a process for forming filaments comprising forming a primary stream of a first spinning solution, injecting into said primary stream a plurality of discrete secondary streams of a second spinning solution, said secondary streams being injected at points lying in a plane normal to the direction of flow of the primary stream, oscillating said points about an axis normal to said plane to change the locations of the secondary streams in the primary stream, and forming filaments from the combined primary and secondary streams.
  • a process for forming filaments comprising forming a generally cylindrical primary stream of a first spinning solution, injecting into said primary stream a plurality of secondary streams of a second spinning solution, said secondary streams being injected at points lying in a plane normal to the axis of the generally cylindrical primary stream, continually oscillating said points about said axis to continually change the locations of said secondary streams in said primary stream, and forming filaments from the combined primary and secondary streams.
  • a process for forming filaments comprising forming a primary stream of a first spinning solution, injecting into the primary stream a plurality of discrete secondary streams of a second spinning solution, said secondary streams being injected into the primary stream at points lying in a plane normal to the direction of flow of said plimary stream, moving said points of injection to change the locations of the secondary streams in the primary stream, adjusting the rates of flow of the primary and secondary streams to vary the size of said secondary streams, and forming filaments from the combined primary and secondary streams.
  • An apparatus for spinning filaments comprising a body having a chamber therein, a first spinnerette mounted in the body to close the chamber therein, a second spinnerette mounted in said chamber for movement about an axis normal to said first spinnerette, said second spinnerette having a plurality of radially extended arms having holes therein, means for forcing a second spinning solution through the holes in said arms and into the chamber, and means for moving said second spinnerette on said axis.
  • An apparatus for spinning filaments comprising a body having a chamber therein, a first spinnerette mounted on the body to close the chamber, means for forcing a first spinning solution through the chamber to the first spinnerette, a manifold rotatably mounted in the chamber on an axis normal to said first spinnerette, a plurality of radially extended hollow elements attached to the manifold and having apertures therein, means for forcing a second spinning solution through the manifold and the radially extended elements, and means for moving the manifold through an are.
  • An apparatus for spinning a filament comprising a body having a cylindrical recess therein, a spinnerette mounted on the body to close the recess, said body having therein a plurality of ports leading to the end of the recess remote from the first spinnerette, a first source of spinning solution, a first pump for forcing spinning solution from said first source through the ports into the recess, said body also having therein a bore concentric with said recess, a tube rotatably mounted in the bore, a manifold secured to the tube and positioned in the recess adjacent to the ports, a plurality of tubular members secured to the manifold and extending radially therefrom, said tubular members being interconnected with the tube through the manifold and having therein a plurality of apertures facing the spinnerette, a second source of spinning solution, a second pump connected between the second source and the tube for forcing spinning solution from said second source through the tube and the radially extended tubular members, and means connected to the tube for oscillating said
  • An apparatus for forming multi-component filaments comprising a first spinnerette; a second spinnerette spaced from the first spinnerette; means surrounding the spinnerettes to form a housing enclosing the space between the spinnerettes, first means for forcing a first spinning composition through the first spinnerette, the

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
US204772A 1962-06-25 1962-06-25 Methods and apparatus for spinning multicomponent filaments Expired - Lifetime US3180912A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
BE634069D BE634069A (fi) 1962-06-25
NL129117D NL129117C (fi) 1962-06-25
NL294482D NL294482A (fi) 1962-06-25
US204772A US3180912A (en) 1962-06-25 1962-06-25 Methods and apparatus for spinning multicomponent filaments
NO149141A NO117809B (fi) 1962-06-25 1963-06-24
DK300063AA DK105353C (da) 1962-06-25 1963-06-24 Apparat til spinding af filamenter bestående af to komponenter.
GB24988/63A GB970230A (en) 1962-06-25 1963-06-24 Methods and apparatus for spinning filaments
DE19631435553 DE1435553A1 (de) 1962-06-25 1963-06-25 Verfahren und Vorrichtung zum Spinnen endloser Faeden
FR939197A FR1361105A (fr) 1962-06-25 1963-06-25 Procédé et appareils pour filer des filaments
CH783863A CH401344A (fr) 1962-06-25 1963-06-25 Procédé pour former des filaments composés et appareil pour sa mise en oeuvre

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US204772A US3180912A (en) 1962-06-25 1962-06-25 Methods and apparatus for spinning multicomponent filaments

Publications (1)

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US3180912A true US3180912A (en) 1965-04-27

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US204772A Expired - Lifetime US3180912A (en) 1962-06-25 1962-06-25 Methods and apparatus for spinning multicomponent filaments

Country Status (8)

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US (1) US3180912A (fi)
BE (1) BE634069A (fi)
CH (1) CH401344A (fi)
DE (1) DE1435553A1 (fi)
DK (1) DK105353C (fi)
GB (1) GB970230A (fi)
NL (2) NL294482A (fi)
NO (1) NO117809B (fi)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3318987A (en) * 1963-09-09 1967-05-09 Monsanto Co Method of multi-component spinning
US3371139A (en) * 1964-12-22 1968-02-27 Monsanto Co Process and apparatus for producing self-texturing fibers
US3453688A (en) * 1967-02-28 1969-07-08 Monsanto Co Filament extrusion apparatus
US3461492A (en) * 1967-03-03 1969-08-19 Monsanto Co Segmented fiber apparatus
US4002795A (en) * 1974-03-25 1977-01-11 Rhone-Poulenc-Textile Crimped yarns and method for making them
US4182601A (en) * 1977-08-20 1980-01-08 The General Engineering Co. (Radcliffe) Limited Extrusion apparatus
US4373886A (en) * 1976-10-14 1983-02-15 Karl Hehl Apparatus for injecting confluent streams of plastic material into an injection molding die
US4451420A (en) * 1981-02-25 1984-05-29 Keuchel Herbert W Syntactic phase extrusion
US4786243A (en) * 1986-05-15 1988-11-22 Nabisco Brands, Inc. Apparatus for forming an edible product
US4828780A (en) * 1987-12-01 1989-05-09 Killon Extruders, Inc. Method for encapsulating extruding materials
US4835000A (en) * 1986-05-15 1989-05-30 Nabisco Brands, Inc. Method for forming an edible product
EP0678599A1 (en) * 1994-04-21 1995-10-25 Basf Corporation A cam pump for the production of alternating sequences of polymer flow pulses
US5516476A (en) * 1994-11-08 1996-05-14 Hills, Inc, Process for making a fiber containing an additive
US5656304A (en) * 1994-04-21 1997-08-12 Basf Corporation Apparatus for melt mixing and spinning synthetic polymers
US5955116A (en) * 1993-11-24 1999-09-21 Nabisco Technology Company Method and apparatus for production of multi-flavored and multi-colored chewing gum
US20030203176A1 (en) * 2001-06-28 2003-10-30 Primex Plastics Corporation Apparatus and method for co-extruding multi color plastics
US20080031988A1 (en) * 2005-08-22 2008-02-07 Reading Bakery Systems, Inc. Rotating Nozzle Die Machine for Extrusion of Two or More Types of Dough

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1110398B (de) * 1959-10-13 1961-07-06 Rehau Plastiks Vorrichtung zur Herstellung von stranggepressten Kunststofferzeugnissen mit mehrfarbigen Oberflaecheneffekten

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1110398B (de) * 1959-10-13 1961-07-06 Rehau Plastiks Vorrichtung zur Herstellung von stranggepressten Kunststofferzeugnissen mit mehrfarbigen Oberflaecheneffekten

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3318987A (en) * 1963-09-09 1967-05-09 Monsanto Co Method of multi-component spinning
US3371139A (en) * 1964-12-22 1968-02-27 Monsanto Co Process and apparatus for producing self-texturing fibers
US3453688A (en) * 1967-02-28 1969-07-08 Monsanto Co Filament extrusion apparatus
US3461492A (en) * 1967-03-03 1969-08-19 Monsanto Co Segmented fiber apparatus
US4002795A (en) * 1974-03-25 1977-01-11 Rhone-Poulenc-Textile Crimped yarns and method for making them
US4373886A (en) * 1976-10-14 1983-02-15 Karl Hehl Apparatus for injecting confluent streams of plastic material into an injection molding die
US4182601A (en) * 1977-08-20 1980-01-08 The General Engineering Co. (Radcliffe) Limited Extrusion apparatus
US4451420A (en) * 1981-02-25 1984-05-29 Keuchel Herbert W Syntactic phase extrusion
US4835000A (en) * 1986-05-15 1989-05-30 Nabisco Brands, Inc. Method for forming an edible product
US4786243A (en) * 1986-05-15 1988-11-22 Nabisco Brands, Inc. Apparatus for forming an edible product
US4828780A (en) * 1987-12-01 1989-05-09 Killon Extruders, Inc. Method for encapsulating extruding materials
US5955116A (en) * 1993-11-24 1999-09-21 Nabisco Technology Company Method and apparatus for production of multi-flavored and multi-colored chewing gum
EP0678599A1 (en) * 1994-04-21 1995-10-25 Basf Corporation A cam pump for the production of alternating sequences of polymer flow pulses
US5507631A (en) * 1994-04-21 1996-04-16 Basf Corporation Cam pump for the production of alternating sequences of polymer flow pulses
US5656304A (en) * 1994-04-21 1997-08-12 Basf Corporation Apparatus for melt mixing and spinning synthetic polymers
US5516476A (en) * 1994-11-08 1996-05-14 Hills, Inc, Process for making a fiber containing an additive
US5851562A (en) * 1994-11-08 1998-12-22 Hills, Inc. Instant mixer spin pack
US20030203176A1 (en) * 2001-06-28 2003-10-30 Primex Plastics Corporation Apparatus and method for co-extruding multi color plastics
US7381357B2 (en) * 2001-06-28 2008-06-03 Primex Plastics Corporation Apparatus and method for co-extruding multi color plastics
US20080031988A1 (en) * 2005-08-22 2008-02-07 Reading Bakery Systems, Inc. Rotating Nozzle Die Machine for Extrusion of Two or More Types of Dough
US8177542B2 (en) * 2005-08-22 2012-05-15 Reading Bakery Systems Rotating nozzle die machine for extrusion of two or more types of dough

Also Published As

Publication number Publication date
CH401344A (fr) 1965-10-31
BE634069A (fi)
NL294482A (fi)
NO117809B (fi) 1969-09-29
DE1435553A1 (de) 1969-03-20
NL129117C (fi)
GB970230A (en) 1964-09-16
DK105353C (da) 1966-09-19

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