US3154660A - Arc-resistant electrical contact having a cadmium-copper, alloy surface - Google Patents
Arc-resistant electrical contact having a cadmium-copper, alloy surface Download PDFInfo
- Publication number
- US3154660A US3154660A US182497A US18249762A US3154660A US 3154660 A US3154660 A US 3154660A US 182497 A US182497 A US 182497A US 18249762 A US18249762 A US 18249762A US 3154660 A US3154660 A US 3154660A
- Authority
- US
- United States
- Prior art keywords
- cadmium
- copper
- contact
- alloy
- electrical contact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PLZFHNWCKKPCMI-UHFFFAOYSA-N cadmium copper Chemical compound [Cu].[Cd] PLZFHNWCKKPCMI-UHFFFAOYSA-N 0.000 title claims description 18
- 239000000956 alloy Substances 0.000 title description 5
- 229910045601 alloy Inorganic materials 0.000 title description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 30
- 229910052793 cadmium Inorganic materials 0.000 claims description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 24
- 229910052802 copper Inorganic materials 0.000 claims description 24
- 239000010949 copper Substances 0.000 claims description 24
- 239000010410 layer Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- 229910000925 Cd alloy Inorganic materials 0.000 description 13
- 238000009792 diffusion process Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 6
- 238000003466 welding Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000003332 Ilex aquifolium Nutrition 0.000 description 1
- 241000209027 Ilex aquifolium Species 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/025—Composite material having copper as the basic material
Definitions
- This invention relates to electrical contacts and is particularly concerned with contacts and method for making said contacts wherein an alloy material is provided adjacent the worlc'ng surface only of the contact which resists welding due to arcing.
- This application is a division of Serial No. 182,497 filed March 26, 1962.
- the main object of this invention to provide a contact and method for making the same which is resistant to welding due to arcing conditions and wherein the contact may be produced economically.
- a further object of the invention is to provide a contact and method for making the same wherein the contact is made from copper and has a working surface comprising a copper-cadmium alloy which is resistant to welding.
- FIG. 1 is a cross section of a copper contact showing a cadmium layer adjacent one surface only thereof for illustration purposes wherein the thickness of the layer is greatly exaggerated also for illustration purposes.
- FIG. 2 is a cross section of the same contact after diffusion of the cadmium layer into the copper and
- FIG. 3 is a view in perspective of a typical application of the contact mounted on a contact arm.
- contacts may be formed that have all of the desirable characteristics of the copper-cadmium alloy contacts and which may be produced quite reasonably, in fact, at only slightly more than the cost of pure copper contacts. This obviously is a great economic saving and in no way reduces the desirable characteristics found in the higher cost copper-cadmium alloy contacts.
- Such a copper-cadmium alloy surface may be produced by several procedures.
- One, and possibly the cheapest, method of producing this type of ice contact is to electroplate the surface of the copper contact with cadmium. This plated surface copper contact is then heated to cause diffusion of the cadmium into the copper to the desired depth. Control of the percentage of the cadmium may be obtained through the thickness of the cadmium layer and the temperature and the time of heating.
- Similar contacts can be produced by laminating cadmium foil with the copper or by merely placing cadmium foil in intimate contact with the copper contact. Also, cadmium powder may be briquetted onto the surface of a copper contact in the desired thickness, etc. Any of these expedients fall within the scope of my invention. For obvious reasons the electroplating method is the easiest to handle and will be described in detail.
- FIG. 1 shows a cross section of a copper blank and slug 20 with a cadmium plate 22 in place on the surface.
- the thickness of the plate 22 is greatly exaggerated in order to properly illustrate the invention.
- the cadmium plate 22 has been diffused into the copper blank 20 to form a contact 23 having a coppercadmium layer 24 integral therewith.
- the plating thickness should be about .0001" of cadmium. If any losses are caused by volatilization of the cadmium during diffusion, a slightly heavier plate should be applied. In all instances the thickness of the plate is best arrived at by trial in view of the diffusion procedures subsequently utilized to obtain the desired result.
- the assembly is heated to cause diffusion of the cadmium into the copper.
- the period of heating Will vary with the temperature and in accordance with the depth of diffusion and percentage of cadmium desired in the copper-cadmium alloy stratum. In general, if a .0001 electro-plate of cadmium is applied and is diffused to a depth of about .01" it will produce a copper alloy in this portion of the contact which will have about 1% cadmium therein. In most instances copper-cadmium alloys where cadmium ranges between .5% to 2% are useful with about 1% by weight being preferred.
- the temperature of the heating step may vary, for example, the blank with the cadmium thereon may be heated below the melting point of cadmium to cause dilfusion. In this instance, temperatures from about 500-575 F, may be used with complete satisfaction. On the other hand, if faster diffusion is desired this temperature may go upwards to about 900 F. which 'is well above the melting point of cadmium. It is obvious that as the temperature goes up the period of heating will be reduced. However, as the temperature goes up caution must be exercised to prevent excessive loss of cadmium due to vaporization thereof. In all instances the time of heating is best arrived at by trial to obtain the desired depth of diffusion and percentage of cadmium in the copper-cadmium alloy.
- an inert atmosphere should be used.
- reducing atmospheres are preferred although they are not always necessary. Cracked ammonia, dehumidified, incompletely burned natural gas, hydrogen or other well-known reducing atmospheres are all satisfactory.
- An electrical contact for use in an application where arcing normally occurs comprising; a solid copper contact having a copper-cadmium surface layer integrally formed therewith, said layer including diflFused cadmium in percentages of from 5% to 2% by Weight of the copper and extending within the contact to a depth of from .0005" to .03", the remainder of the contact being substantially pure copper.
- An electrical contact for use in an application where arcing normally occurs comprising; a solid copper contact having a copper-cadmium surface layer integrally 15 3,026,603
- said layer including diffused cadmium in percentages of about 1% by weight and extending within the contact to a depth of about .01, the remainder of the contact being substantially copper.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Contacts (AREA)
Description
Oct. 27, 1964 R. R. WITHERSPOON 3, 6
ARC-RESISTANT ELECTRICAL CONTACT HAVING A CADMIUM-COPPER, ALLOY SURFACE Filed March 26, 1962 INVENTOR Romeo 1? Mme/spoon His Afforney United States Patent ARC-RFEISTANT ELECTRICAL CONTACT HAV- ING A CADMIUM-COPPER, ALLOY SURFACE Romeo R. Witherspoon, Anderson, Ind., assignor to General Motors Corporation, Detroit, Mich, a corporation of Delaware Filed Mar. 26, 1962, Ser. No. 182,497 2 Claims. (Cl. 200166) This invention relates to electrical contacts and is particularly concerned with contacts and method for making said contacts wherein an alloy material is provided adjacent the worlc'ng surface only of the contact which resists welding due to arcing. This application is a division of Serial No. 182,497 filed March 26, 1962.
It is, therefore, the main object of this invention to provide a contact and method for making the same which is resistant to welding due to arcing conditions and wherein the contact may be produced economically.
A further object of the invention is to provide a contact and method for making the same wherein the contact is made from copper and has a working surface comprising a copper-cadmium alloy which is resistant to welding.
In carrying out the above object it is a further object of the invention to produce the copper-cadmium alloy adjacent the working surface only of contact through diffusion processes.
Further objects and advantages will be apparent, reference being had to the accompanying drawings, wherein FIG. 1 is a cross section of a copper contact showing a cadmium layer adjacent one surface only thereof for illustration purposes wherein the thickness of the layer is greatly exaggerated also for illustration purposes.
FIG. 2 is a cross section of the same contact after diffusion of the cadmium layer into the copper and FIG. 3 is a view in perspective of a typical application of the contact mounted on a contact arm.
In certain applications, for example in passenger car switches and the like, copper contacts are frequently used because of the ease of manufacture and relatively low cost thereof. These contacts have a tendency to weld together when small arcs are produced which nullify their other desirable characteristics. It has been found that a contact formed from a copper-cadmium alloy wherein the cadmium is in quantities of about 1% by weight of the contact, resists this welding efiect and produces a highly satisfactory contact which has a long life under the conditions of its environment. Contacts of this character are relatively expensive when compared to copper contacts due to the inclusion of the cadmium therein and, therefore, when used in the required numbers in passenger car applications, increase the overall cost of the electrical system.
I have found that contacts may be formed that have all of the desirable characteristics of the copper-cadmium alloy contacts and which may be produced quite reasonably, in fact, at only slightly more than the cost of pure copper contacts. This obviously is a great economic saving and in no way reduces the desirable characteristics found in the higher cost copper-cadmium alloy contacts.
Specifically, I have found that by producing the desired copper-cadmium alloy adjacent the working surface only of the copper contact, that all the desirable characteristics of the copper-cadmium alloy contact may be preserved. This surface alloy is very thin and may extend for a depth of from about .0005" to .03" with from .0005" to .015 from the surface of the contact being preferred.
I have found that such a copper-cadmium alloy surface may be produced by several procedures. One, and possibly the cheapest, method of producing this type of ice contact, is to electroplate the surface of the copper contact with cadmium. This plated surface copper contact is then heated to cause diffusion of the cadmium into the copper to the desired depth. Control of the percentage of the cadmium may be obtained through the thickness of the cadmium layer and the temperature and the time of heating.
Similar contacts can be produced by laminating cadmium foil with the copper or by merely placing cadmium foil in intimate contact with the copper contact. Also, cadmium powder may be briquetted onto the surface of a copper contact in the desired thickness, etc. Any of these expedients fall within the scope of my invention. For obvious reasons the electroplating method is the easiest to handle and will be described in detail.
Referring to the drawings, FIG. 1 shows a cross section of a copper blank and slug 20 with a cadmium plate 22 in place on the surface. The thickness of the plate 22 is greatly exaggerated in order to properly illustrate the invention.
In FIG. 2 the cadmium plate 22 has been diffused into the copper blank 20 to form a contact 23 having a coppercadmium layer 24 integral therewith. I have discovered that in order to obtain approximately a 1% cadmium alloy that the plating thickness should be about .0001" of cadmium. If any losses are caused by volatilization of the cadmium during diffusion, a slightly heavier plate should be applied. In all instances the thickness of the plate is best arrived at by trial in view of the diffusion procedures subsequently utilized to obtain the desired result. In this connection, after the plating 22 has been applied to the copper blank 24), the assembly is heated to cause diffusion of the cadmium into the copper. The period of heating Will vary with the temperature and in accordance with the depth of diffusion and percentage of cadmium desired in the copper-cadmium alloy stratum. In general, if a .0001 electro-plate of cadmium is applied and is diffused to a depth of about .01" it will produce a copper alloy in this portion of the contact which will have about 1% cadmium therein. In most instances copper-cadmium alloys where cadmium ranges between .5% to 2% are useful with about 1% by weight being preferred.
The temperature of the heating step may vary, for example, the blank with the cadmium thereon may be heated below the melting point of cadmium to cause dilfusion. In this instance, temperatures from about 500-575 F, may be used with complete satisfaction. On the other hand, if faster diffusion is desired this temperature may go upwards to about 900 F. which 'is well above the melting point of cadmium. It is obvious that as the temperature goes up the period of heating will be reduced. However, as the temperature goes up caution must be exercised to prevent excessive loss of cadmium due to vaporization thereof. In all instances the time of heating is best arrived at by trial to obtain the desired depth of diffusion and percentage of cadmium in the copper-cadmium alloy.
During the heating of the contacts, an inert atmosphere should be used. In this connection, reducing atmospheres are preferred although they are not always necessary. Cracked ammonia, dehumidified, incompletely burned natural gas, hydrogen or other well-known reducing atmospheres are all satisfactory.
It is understood that the invention may be practiced to obtain any desired depth of penetration of the cadmium and to obtain varying percentages of cadmium in the copper-cadmium alloy layer as is desired and the procedures to accomplish these ends will be obvious to those skilled in the art in view of the disclosure herein.
While the embodiments of the present invention as herein disclosed, constitute preferred forms, it is to be understood that other forms might be adopted.
What is claimed is as follows:
1. An electrical contact for use in an application where arcing normally occurs comprising; a solid copper contact having a copper-cadmium surface layer integrally formed therewith, said layer including diflFused cadmium in percentages of from 5% to 2% by Weight of the copper and extending within the contact to a depth of from .0005" to .03", the remainder of the contact being substantially pure copper.
2. An electrical contact for use in an application where arcing normally occurs comprising; a solid copper contact having a copper-cadmium surface layer integrally 15 3,026,603
formed therewith, said layer including diffused cadmium in percentages of about 1% by weight and extending within the contact to a depth of about .01, the remainder of the contact being substantially copper.
References Cited in the file of this patent UNITED STATES PATENTS 1,395,269 Gebauer Nov. 1, 1921 1,820,699 Hartman Aug. 25, 1931 2,216,510 Burns Oct. 1, 1940 2,360,522 Shobert et a1 Oct. 17 1944 2,425,053 Swinehart Aug. 5, 1947 2,730,594 Page Jan. 10, 1956 2,770,700 Holm et al Nov. 13, 1956 Zysk et al. Mar. 27, 1962
Claims (1)
1. AN ELECTRICAL CONTACT FOR USE IN AN APPLICATION WHERE ARCING NORMALLY OCCURS COMPRISING; A SOLID COPPER CONTACT HAVING A COPPER-CADMIUM SURFACE LAYER INTEGRALLY FORMED THEREWITH, SAID LAYER INCLUDING DIFFUSED CADMIUM IN PERCENTAGES OF FROM .5% TO 2% BY WEIGHT OF THE COPPER AND EXTENDING WITHIN THE CONTACT TO A DEPTH OF FROM .0005" TO .03", THE REMAINDER OF THE CONTACT BEING SUBSTANTIALLY PURE COPPER.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US182497A US3154660A (en) | 1962-03-26 | 1962-03-26 | Arc-resistant electrical contact having a cadmium-copper, alloy surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US182497A US3154660A (en) | 1962-03-26 | 1962-03-26 | Arc-resistant electrical contact having a cadmium-copper, alloy surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3154660A true US3154660A (en) | 1964-10-27 |
Family
ID=22668733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US182497A Expired - Lifetime US3154660A (en) | 1962-03-26 | 1962-03-26 | Arc-resistant electrical contact having a cadmium-copper, alloy surface |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3154660A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3688067A (en) * | 1971-02-08 | 1972-08-29 | Chugai Electric Ind Co Ltd | Composite silver cadmium oxide alloy contact with silver cadium surface |
| US4803322A (en) * | 1984-05-19 | 1989-02-07 | Chugai Denki Kogyo K.K. | Electrical contacts for electric breakers |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1395269A (en) * | 1917-05-17 | 1921-10-25 | Charles L Gebauer | Metallic article |
| US1820699A (en) * | 1929-10-11 | 1931-08-25 | Westinghouse Electric & Mfg Co | Brushholder |
| US2216510A (en) * | 1938-08-16 | 1940-10-01 | Wilson H A Co | Method of making contacts |
| US2360522A (en) * | 1943-11-22 | 1944-10-17 | Stackpole Carbon Co | Manufacture of electric contacts |
| US2425053A (en) * | 1944-06-23 | 1947-08-05 | Cutler Hammer Inc | Silver-backed nonwelding contact and method of making the same |
| US2730594A (en) * | 1952-12-26 | 1956-01-10 | Gen Electric | Electric contact |
| US2770700A (en) * | 1953-03-12 | 1956-11-13 | Stackpole Carbon Co | Direct current electric switching contacts |
| US3026603A (en) * | 1958-10-13 | 1962-03-27 | Kelsey Hayes Co | Method of making electrical contacts and the like |
-
1962
- 1962-03-26 US US182497A patent/US3154660A/en not_active Expired - Lifetime
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1395269A (en) * | 1917-05-17 | 1921-10-25 | Charles L Gebauer | Metallic article |
| US1820699A (en) * | 1929-10-11 | 1931-08-25 | Westinghouse Electric & Mfg Co | Brushholder |
| US2216510A (en) * | 1938-08-16 | 1940-10-01 | Wilson H A Co | Method of making contacts |
| US2360522A (en) * | 1943-11-22 | 1944-10-17 | Stackpole Carbon Co | Manufacture of electric contacts |
| US2425053A (en) * | 1944-06-23 | 1947-08-05 | Cutler Hammer Inc | Silver-backed nonwelding contact and method of making the same |
| US2730594A (en) * | 1952-12-26 | 1956-01-10 | Gen Electric | Electric contact |
| US2770700A (en) * | 1953-03-12 | 1956-11-13 | Stackpole Carbon Co | Direct current electric switching contacts |
| US3026603A (en) * | 1958-10-13 | 1962-03-27 | Kelsey Hayes Co | Method of making electrical contacts and the like |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3688067A (en) * | 1971-02-08 | 1972-08-29 | Chugai Electric Ind Co Ltd | Composite silver cadmium oxide alloy contact with silver cadium surface |
| US4803322A (en) * | 1984-05-19 | 1989-02-07 | Chugai Denki Kogyo K.K. | Electrical contacts for electric breakers |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2396101A (en) | Electrical contact | |
| US4105828A (en) | Low-current contact construction | |
| GB915559A (en) | Improvements in vacuum type circuit interrupters | |
| US2474038A (en) | Composite metal | |
| EP0031159A1 (en) | Electrical contact | |
| US3785810A (en) | Silver-metal oxide composite and method of manufacturing the same | |
| US2365249A (en) | Electrical contact element | |
| US3472654A (en) | Silver base alloy for making electrical contacts | |
| US3114631A (en) | Silver composition | |
| US2241262A (en) | Electrical contact | |
| US3154660A (en) | Arc-resistant electrical contact having a cadmium-copper, alloy surface | |
| US2796346A (en) | Electrical contact material | |
| US3985512A (en) | Telluride containing impregnated electric contact material | |
| US2925647A (en) | Method of making electrical contacts | |
| US2370400A (en) | Contact materials | |
| US3305324A (en) | Tungsten powder bodies infiltrated with copper-titanium-bismuth or copper-titanium-tin | |
| US3574570A (en) | Composite contact structure for connection to an aluminum support | |
| US3337338A (en) | Tungsten powder bodies infiltrated with copper-titanium bismuth or copper-titanium-tin | |
| US3097965A (en) | Conductive wire coating alloys, wires coated therewith and process for improving solderability therefor | |
| US3311729A (en) | Electrical contact and method of forming the same | |
| US2244771A (en) | Composite conductor and contact between conductors | |
| US2673167A (en) | Electric contact | |
| US3353933A (en) | Tungsten powder bodies infiltrated with copper-titanium alloys | |
| US2474039A (en) | Method of forming composite metal having a nickel-plated beryllium-copper base and gold or silver bonded thereto by a copper-plated iron sheet | |
| US2360522A (en) | Manufacture of electric contacts |