US3150938A - Coating composition, method of application, and product thereof - Google Patents
Coating composition, method of application, and product thereof Download PDFInfo
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- US3150938A US3150938A US34871A US3487160A US3150938A US 3150938 A US3150938 A US 3150938A US 34871 A US34871 A US 34871A US 3487160 A US3487160 A US 3487160A US 3150938 A US3150938 A US 3150938A
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- 239000008199 coating composition Substances 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 13
- 238000000576 coating method Methods 0.000 claims description 43
- 239000011248 coating agent Substances 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 239000011651 chromium Substances 0.000 claims description 18
- 238000005474 detonation Methods 0.000 claims description 15
- 229910052804 chromium Inorganic materials 0.000 claims description 14
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 claims description 14
- 229910003470 tongbaite Inorganic materials 0.000 claims description 14
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229940107218 chromium Drugs 0.000 description 13
- 235000012721 chromium Nutrition 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 11
- 239000000463 material Substances 0.000 description 8
- 230000013011 mating Effects 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 230000001464 adherent effect Effects 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- -1 chromium carbides Chemical class 0.000 description 2
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/067—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/937—Sprayed metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/938—Vapor deposition or gas diffusion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/94—Pressure bonding, e.g. explosive
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12063—Nonparticulate metal component
- Y10T428/12139—Nonmetal particles in particulate component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12986—Adjacent functionally defined components
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coating By Spraying Or Casting (AREA)
Description
' J. F. PELTON ETAL 3,350,938 comma COMPOSITION METHOD OF APPLICATION AND PRODUCT THEREOF Filed June 9. 1960 Sept. 29 1964 INVENTORS JOHN, F .PELTON JOHN M.KOFFSKEY,JR.
M PM A TTORNE) United States Patent "ice v 3,150,938 COATING COMPOSITION, METHOD OF APPLI- CATION, AND PRODUCT THEREQF John F. Pelton and John M. Kotiskey, 51a, Indianapolis,
Ind., assignors to Union Carbide Corporation, a corporation of New York Y Filed June 9, 1960, Ser. No. 34,871 Claims. (Cl. 29-494) This invention relates to a specific coating composition,
to a method for applying same, and to the coated article so obtained. More particularly, it relates to such a composition capable of producing a coating having excellent high temperature wear and oxidation resistance. 1 There is a need in industry for coating materials that can withstand severe wear conditions at high temperatures. In particular, the aircraft industry requires coatings to protect wear surfaces in turbo-jet engines. The turbine blades, for example, undergo some distortion due to temperature expansion and contraction as well as to high velocity conditions. This distortion creates severe wear conditions on the contact surfaces between turbine blade spacers. Prior wear resistant coating materials, such as tungsten carbide with cobalt binder, have been unable to give adequate protection in this area. The prior coatings could not stand up under the high temperature wear and oxidizing conditions. An aluminum oxide coating, for example, is able to withstand the high temperature oxidizing conditions but its Wear resistance is not quite high enough, especially when mating with itself. It also is too brittle and does not have sufiicient bond strength.
It is accordingly the object of the present invention to provide a powder composition suitable for application by flame-plating techniques which result in coatings having good resistance at high temperatures to wear and oxidation.
The sole figure in the drawing is a photomicrograph at 500 diameter magnification showing the base material with the wear and oxidization resistant coating bonded thereto.
The objects of this invention are accomplished in general by a coating composition which comprises between about 70 and 90 weight percent chromium carbide (Cr C and lower carbides) and between about 30 and weight percent of a nickel-chromium alloy (80 percent nickel-20 percent chromium). This material can be applied as a coating to various base materials by means of the detonation plating process disclosed in United States Patent No. 2,714,563 or by other high temperature high velocity coating processes, such as the arc torch or jet burner disclosed in application Serial No. 706,099 and now abandoned, filed December 30, 1957, by Gage et al., and in Patent No. 2,861,900, filed May 2, 1955, by G. H. Smith et al. The actual composition of the resulting coating will be somewhat dilferent from the above starting composition due to changes brought about by heating during the coating process. For example, the coatings of this material applied by the detonation process, when using a starting composition of about 85 Weight percent chromium carbide and about weight percent of a nickelchromium alloy (80 percent Nipercent Cr) and an oxygen/carbon atomic ratio of 1.2 and nitrogen dilution of 46 volume percent have a general composition of about 10 weight percent Cr C 15 weight percent nickelchromium alloy, and the remainder 'a mixture of chromium carbides, chromium oxides, and chromium metal.
The advantages of these new coating compositions in resisting wear are shown in the following table which contpares relative wear of several coating combinations under high temperature high load conditions. These tests were run to determine the resistance to gross wear caused by galling and scoring. Test conditions were: 500 p.s.i.g. pressure on samples; relative rubbing speed between the 3,150,938 Patented fiept. 29, 1964 TABLE I 7 Comparative Wear for Combinations of Coatings in Mating Relation Loss in Temper- Coating ature at Thickness Test Piece l0- i1nehes/ Mating Materials 7. 2 CrsCz-(Ni-Cr) 7. 6 OraCz-(Ni-Or).. 1, 300 8.2 203 5. 3
3 WC-CraCz-Nll, 300 36 It can be seen from the above table that prior coating combinations of aluminum oxide, tungsten carbide-cobalt, and tungsten carbide-chromium carbide-nickel have excessive total wear at high temperatures and high load. The novel coating of the present invention has comparatively low total wear when mating with aluminum oxide and especially when mating with itself. This last property is quite important since it is most desirable to coat similar mating surfaces with the same material to simplify fabrication and replacement procedures.
This novel coatinghas also withstood severe oxidizing conditions up to at least 1800 F. without failure. Prior wear resistant coatings, such as tungsten carbide-cobalt fail due to oxidation above 1000 F.
The coating starting material is usually prepared by blending chromium carbide and nickel-chromium alloy powders of desired size suitable for coating (about 325 mesh and finer). A chromium and nickel powder mixture could be sustituted for the nickel-chromium alloy. The particular method of powder preparation used would depend primarily upon economic factors, such as availability of particular raw materials.
The following examples describe the application of this novel coating composition to a baseplate by the detonation plating process.
EXAMPLE I.APPLICATION OF AN 85 PERCENT CHRO- MIUM CARBIDE 15 PERCENT NICKEL-CHROMIUM ALLOY COATING Acetylene at 1.5 c.f.m., oxygen at 1.8 c.f.m., and nitrogen at 2.2 c.f.m. were introduced to a detonation gun to form a detonable mixture having an oxygen/ carbon atomic ratio of 1.2. Finely divided coating powder having a composition of 85 weight percent chromium carbide and 15 weight percent nickel-chromium alloy (80 percent nickel-20 percent chromium) suspended in a nitrogen carrier gas stream of 0.6 c.f.m. was introduced at a rate of 30-32 gram/min. to the barrel of the detonation gun. The detonable mixture thus surrounding the coating particles contained about 46 volume percent nitrogen. The detonation mixture was ignited at a rate of about four times per second and the coating powder was impinged on a metal baseplate to form a dense adherent coating composed of irregular shaped microscopic leaves interlocking and overlapping with each other. The coating has an average hardness of 800-850 VPN as measured with a 300 gram load and a modulus of rupture of 75,000 p.s.i.
EXAMPLE II.APPLICATION OF A PERCENT CHRO- MIUM CARBIDE 25 PERCENT NICKEL-CHROMIUM ALLOY COATING Acetylene at 1.13 c.f.m., oxygen at 1.35 c.f.m. and nitrogen at 3.02 c.f.m. were introduced to a detonation gun to form a detonatabie mixture having an oxygen/carbon atomic ratio of 1.2. Finely divided coating powder having a composition of 75 weight percent chromium carbide and 25 weight percent nickel-chromium alloy (80 percent nickel-20 percent chromium) suspended in a nitrogen carrier gas stream of 0.6 c.f.m. was introduced at a rate of 32 grams per minute to the barrel of the detonation gun. The detonatable mixture thus surrounding the coating particles contained about 60 volume percent nitrogen. The detonatable mixture was ignited at a rate of about four times per second, and the coating powder was impinged on a metal baseplate to form a dense adherent coating about 0.0050.096 inch thick composed of irregular shaped microscopic leaves interlocking and overlapping with each other. The coating had an average hardness of 775-825 VPN as measured with a 300 gram load. The coating has a modulus of rupture of about 82,000 psi. The final coating product has a general composition of about 30 weight percent Cr C 30 weight percent nickel-chromium alloy, and the remainder a mixture of chromium carbides, chromium oxides and chromium metal.
It is noted that the above Example II employed a nitrogen content of about 60 volume percent in the detonation gun barrel. This is the preferred operating condition for applying the high binder content composition on turbine blades since the resulting lower flame temperature aids in retaining an increased amount of binder in the coating product. The high binder content composition of the latter example results in a more impact resistant coating and also in a higher modulus of rupture and would be used for applications where those qualities were of paramount importance.
The above examples illustrate the use of the instant novel coating compositions with a detonation gun; however, it should be reiterated that the said compositions can be used with equal success with other flame-plating processes such as the arc torch and the jet burner. The specific coating composition ratios by weight of chromium carbide, chromium, and nickel disclosed represent a definite advance in the art of coatings which have high temperature wear and oxidation resistance.
It is to be understood that the novel coating composition may contain between about 70-90 weight percent chromium carbide and between about 3() weight percent of a nickel-chromium alloy (80 percent nickel-20 percent chromium) without affecting the utility of the coating as disclosed. However, the ratios set forth in xi. the above examples represent the preferred embodiments.
This application is a continuation-in-part application of our application Serial No. 738,299, filed May 28, 1958, and now abandoned.
What is claimed is:
1. A coating composition which comprises between about and 90 percent by weight of powdered chromium carbide, between about 8 and 24 percent by weight of powdered nickel and the remainder being powdered chromium.
2. A coating composition which comprises about 85 percent by weight of powdered chromium carbide, 12 percent by weight of powdered nickel and the remainder being powdered chromium.
3. A coating composition which comprises about percent by weight of powdered chromium carbide, 20 percent by weight of powdered nickel and 5 percent by weight of powdered chromium.
4. A method of applying a high temperature wear and oxidation resistant coating which comprises introducing a finely divided powder comprising about 75 percent by weight of powdered chromium carbide, about 20 percent by weight of powdered nickel and about 5 percent by weight of powdered chromium into a detonation gun, surrounding such composition with a detonable fuelc-xidant mixture having an oxygen/ carbon atomic ratio of about 1.2 and containing about 60 volume percent nitrogen; igniting such detonable mixture to form a detonation, and impinging the coating composition onto a body to be coated by means of the high temperature high velocity gas stream and shock wave attendant with such detonation.
5. An article of manufacture made according to claim 4 wherein the coating in such body has a lamellar structure of interlocking and overlapping microscopic leaves bonded to each other and to said body.
References Cited in the file of this patent UNITED STATES PATENTS 2,067,166 Balke Jan. 12, 1937 2,128,146 Hinnuber Aug. 23, 1938 2,581,252 Goetzel et al. Jan. 1, 1952 2,714,563 Poorman et al. Aug. 2, 1955 2,753,621 Wellborn July 10, 1956 FOREIGN PATENTS 318,524 Switzerland Feb. 28, 1957
Claims (2)
- 4. A METHOD OF APPLYIG A HIGH TEMPERATURE WEAR AND OXIDATION RESISTANT COATING WHICH COMPRISES INTRODUCING A FINELY DIVIDED POWDER COMPRISING ABOUT 75 PERCENT BY WEIGHT OF POWDERED CHROMIUM CARBIDE, ABOUT 20 PERCENT BY WEIGHT OF POWDERED NICKEL AND ABOUT 5 PERCENT BY WEIGHT OF POWDERED CHROMIUM INTO A DETONATION GUN, SUROUNDING SUCH COMPOSITION WITH A DETONABLE FUELOXIDANT MIXTURE HAVING AN OXYGEN/CARBON ATOMIC RATIO OF ABOUT 1.2 AND CONTAINING ABOUT 60 VOLUME PERCENT NITROGEN; IGNITING SUCH DETONABLE MIXTURE TO FORM A DETONATION, AND IMPINGING THE COATING COMPOSITION ONTO A BODY TO BE COATED BY MEANS OF THE HIGH TEMPERATURE HIGH VELOCITY
- 5. AN ARTICLE OF MANUFACTURE MADE ACCORDING TO CLAIM 4 WHEREIN THE COATING IN SUCH BODY HAS A LAMELLAR STRUCTURE OF INTERLOCKING AND OVERLAPPING MICROSCOPIC LEAVES BONDED TO EACH OTHER AND TO SAID BODY.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB17661/59A GB886560A (en) | 1958-05-28 | 1959-05-25 | Improvements in and relating to coating alloys and the coating of materials |
| US34871A US3150938A (en) | 1958-05-28 | 1960-06-09 | Coating composition, method of application, and product thereof |
| FR862907A FR1300784A (en) | 1958-05-28 | 1961-05-25 | Coating composition and method of application |
| GB19913/61A GB929205A (en) | 1958-05-28 | 1961-06-02 | Improvements in and relating to coating compositions |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US886560XA | 1958-05-28 | 1958-05-28 | |
| US34871A US3150938A (en) | 1958-05-28 | 1960-06-09 | Coating composition, method of application, and product thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3150938A true US3150938A (en) | 1964-09-29 |
Family
ID=61021555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US34871A Expired - Lifetime US3150938A (en) | 1958-05-28 | 1960-06-09 | Coating composition, method of application, and product thereof |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3150938A (en) |
| FR (1) | FR1300784A (en) |
| GB (2) | GB886560A (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3230097A (en) * | 1962-05-31 | 1966-01-18 | Gen Electric | Coating composition |
| US3473943A (en) * | 1963-04-10 | 1969-10-21 | Asahi Chemical Ind | Explosive coating of metallic substrates with powder |
| DE1671130B1 (en) * | 1965-01-18 | 1972-05-25 | Union Carbide Corp | METHOD FOR MANUFACTURING OVERCOATS |
| US3881910A (en) * | 1973-08-15 | 1975-05-06 | Union Carbide Corp | Chromium-chromium carbide powder |
| US3941903A (en) * | 1972-11-17 | 1976-03-02 | Union Carbide Corporation | Wear-resistant bearing material and a process for making it |
| DE2603640A1 (en) * | 1975-01-31 | 1976-08-05 | Union Carbide Corp | TWO-LAYER COVER |
| US4075376A (en) * | 1975-04-11 | 1978-02-21 | Eutectic Corporation | Boiler tube coating and method for applying the same |
| US4163071A (en) * | 1977-07-05 | 1979-07-31 | Union Carbide Corp | Method for forming hard wear-resistant coatings |
| US4275124A (en) * | 1978-10-10 | 1981-06-23 | United Technologies Corporation | Carbon bearing MCrAlY coating |
| US4275090A (en) * | 1978-10-10 | 1981-06-23 | United Technologies Corporation | Process for carbon bearing MCrAlY coating |
| US4334927A (en) * | 1980-12-08 | 1982-06-15 | Hyde Glenn F | Piston ring coatings |
| WO1983001917A1 (en) * | 1981-11-27 | 1983-06-09 | Gte Prod Corp | Nickel-chromium carbide powder and sintering method |
| US4471008A (en) * | 1981-08-21 | 1984-09-11 | Mtu Motoren-Und-Turbinen Union Munchen Gmbh | Metal intermediate layer and method of making it |
| US4606948A (en) * | 1984-06-04 | 1986-08-19 | Sherritt Gordon Mines Limited | Process for the production of nickel-chromium/chromium carbide coatings on substrates |
| US4826734A (en) * | 1988-03-03 | 1989-05-02 | Union Carbide Corporation | Tungsten carbide-cobalt coatings for various articles |
| US4902539A (en) * | 1987-10-21 | 1990-02-20 | Union Carbide Corporation | Fuel-oxidant mixture for detonation gun flame-plating |
| US4999255A (en) * | 1989-11-27 | 1991-03-12 | Union Carbide Coatings Service Technology Corporation | Tungsten chromium carbide-nickel coatings for various articles |
| US5006371A (en) * | 1988-02-08 | 1991-04-09 | Air Products And Chemicals, Inc. | Low temperature chemical vapor deposition method for forming tungsten and tungsten carbide |
| US5024901A (en) * | 1988-02-08 | 1991-06-18 | Air Products And Chemicals, Inc. | Method for depositing highly erosive and abrasive wear resistant composite coating system on a substrate |
| US5075129A (en) * | 1989-11-27 | 1991-12-24 | Union Carbide Coatings Service Technology Corporation | Method of producing tungsten chromium carbide-nickel coatings having particles containing three times by weight more chromium than tungsten |
| US5137422A (en) * | 1990-10-18 | 1992-08-11 | Union Carbide Coatings Service Technology Corporation | Process for producing chromium carbide-nickel base age hardenable alloy coatings and coated articles so produced |
| US5223332A (en) * | 1990-05-31 | 1993-06-29 | Praxair S.T. Technology, Inc. | Duplex coatings for various substrates |
| US5419976A (en) * | 1993-12-08 | 1995-05-30 | Dulin; Bruce E. | Thermal spray powder of tungsten carbide and chromium carbide |
| US5839880A (en) * | 1992-03-18 | 1998-11-24 | Hitachi, Ltd. | Bearing unit, drainage pump and hydraulic turbine each incorporating the bearing unit, and method of manufacturing the bearing unit |
| US5906896A (en) * | 1991-07-12 | 1999-05-25 | Praxair S.T. Technology, Inc. | Rotary seal member coated with a chromium carbide-age hardenable nickel base alloy |
| US20090208662A1 (en) * | 2004-11-04 | 2009-08-20 | United Technologies Corporation | Methods for Repairing a Workpiece |
| US20190040960A1 (en) * | 2017-08-07 | 2019-02-07 | Kst Plant Company | Metal seat ball valve apparatus provided with micro-alloying layer, and method for manufacturing same |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4666733A (en) * | 1985-09-17 | 1987-05-19 | Electric Power Research Institute | Method of heat treating of wear resistant coatings and compositions useful therefor |
| US8530050B2 (en) | 2007-05-22 | 2013-09-10 | United Technologies Corporation | Wear resistant coating |
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| US2067166A (en) * | 1933-03-06 | 1937-01-12 | Ramet Corp | Tantalum carbide alloy |
| US2128146A (en) * | 1935-08-07 | 1938-08-23 | Gen Electric | Sintered hard metal alloys |
| US2581252A (en) * | 1947-12-31 | 1952-01-01 | Sintercast Corp America | Powder metallurgy articles |
| US2714563A (en) * | 1952-03-07 | 1955-08-02 | Union Carbide & Carbon Corp | Method and apparatus utilizing detonation waves for spraying and other purposes |
| US2753621A (en) * | 1953-02-11 | 1956-07-10 | Firth Sterling Inc | Sintered carbide compositions and method of making the same |
| CH318524A (en) * | 1952-06-27 | 1957-01-15 | Eisen & Stahlind Ag | Wear-resistant and corrosion-resistant article and method for its manufacture |
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-
1960
- 1960-06-09 US US34871A patent/US3150938A/en not_active Expired - Lifetime
-
1961
- 1961-05-25 FR FR862907A patent/FR1300784A/en not_active Expired
- 1961-06-02 GB GB19913/61A patent/GB929205A/en not_active Expired
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2067166A (en) * | 1933-03-06 | 1937-01-12 | Ramet Corp | Tantalum carbide alloy |
| US2128146A (en) * | 1935-08-07 | 1938-08-23 | Gen Electric | Sintered hard metal alloys |
| US2581252A (en) * | 1947-12-31 | 1952-01-01 | Sintercast Corp America | Powder metallurgy articles |
| US2714563A (en) * | 1952-03-07 | 1955-08-02 | Union Carbide & Carbon Corp | Method and apparatus utilizing detonation waves for spraying and other purposes |
| CH318524A (en) * | 1952-06-27 | 1957-01-15 | Eisen & Stahlind Ag | Wear-resistant and corrosion-resistant article and method for its manufacture |
| US2753621A (en) * | 1953-02-11 | 1956-07-10 | Firth Sterling Inc | Sintered carbide compositions and method of making the same |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3230097A (en) * | 1962-05-31 | 1966-01-18 | Gen Electric | Coating composition |
| US3473943A (en) * | 1963-04-10 | 1969-10-21 | Asahi Chemical Ind | Explosive coating of metallic substrates with powder |
| DE1671130B1 (en) * | 1965-01-18 | 1972-05-25 | Union Carbide Corp | METHOD FOR MANUFACTURING OVERCOATS |
| US3941903A (en) * | 1972-11-17 | 1976-03-02 | Union Carbide Corporation | Wear-resistant bearing material and a process for making it |
| US3881910A (en) * | 1973-08-15 | 1975-05-06 | Union Carbide Corp | Chromium-chromium carbide powder |
| DE2603640A1 (en) * | 1975-01-31 | 1976-08-05 | Union Carbide Corp | TWO-LAYER COVER |
| US4075376A (en) * | 1975-04-11 | 1978-02-21 | Eutectic Corporation | Boiler tube coating and method for applying the same |
| US4163071A (en) * | 1977-07-05 | 1979-07-31 | Union Carbide Corp | Method for forming hard wear-resistant coatings |
| US4275124A (en) * | 1978-10-10 | 1981-06-23 | United Technologies Corporation | Carbon bearing MCrAlY coating |
| US4275090A (en) * | 1978-10-10 | 1981-06-23 | United Technologies Corporation | Process for carbon bearing MCrAlY coating |
| US4334927A (en) * | 1980-12-08 | 1982-06-15 | Hyde Glenn F | Piston ring coatings |
| US4471008A (en) * | 1981-08-21 | 1984-09-11 | Mtu Motoren-Und-Turbinen Union Munchen Gmbh | Metal intermediate layer and method of making it |
| WO1983001917A1 (en) * | 1981-11-27 | 1983-06-09 | Gte Prod Corp | Nickel-chromium carbide powder and sintering method |
| US4606948A (en) * | 1984-06-04 | 1986-08-19 | Sherritt Gordon Mines Limited | Process for the production of nickel-chromium/chromium carbide coatings on substrates |
| US4902539A (en) * | 1987-10-21 | 1990-02-20 | Union Carbide Corporation | Fuel-oxidant mixture for detonation gun flame-plating |
| US5006371A (en) * | 1988-02-08 | 1991-04-09 | Air Products And Chemicals, Inc. | Low temperature chemical vapor deposition method for forming tungsten and tungsten carbide |
| US5024901A (en) * | 1988-02-08 | 1991-06-18 | Air Products And Chemicals, Inc. | Method for depositing highly erosive and abrasive wear resistant composite coating system on a substrate |
| US4826734A (en) * | 1988-03-03 | 1989-05-02 | Union Carbide Corporation | Tungsten carbide-cobalt coatings for various articles |
| US4999255A (en) * | 1989-11-27 | 1991-03-12 | Union Carbide Coatings Service Technology Corporation | Tungsten chromium carbide-nickel coatings for various articles |
| US5075129A (en) * | 1989-11-27 | 1991-12-24 | Union Carbide Coatings Service Technology Corporation | Method of producing tungsten chromium carbide-nickel coatings having particles containing three times by weight more chromium than tungsten |
| AU638182B2 (en) * | 1989-11-27 | 1993-06-17 | Union Carbide Coatings Service Technology Corp. | Process for producing tungsten chromium carbide-nickel coatings for various articles |
| US5223332A (en) * | 1990-05-31 | 1993-06-29 | Praxair S.T. Technology, Inc. | Duplex coatings for various substrates |
| US5137422A (en) * | 1990-10-18 | 1992-08-11 | Union Carbide Coatings Service Technology Corporation | Process for producing chromium carbide-nickel base age hardenable alloy coatings and coated articles so produced |
| AU643837B2 (en) * | 1990-10-18 | 1993-11-25 | Union Carbide Coatings Service Technology Corp. | Process for producing chromiun carbide-nickle base age hardenable alloy coatings and coated articles so produced |
| US5906896A (en) * | 1991-07-12 | 1999-05-25 | Praxair S.T. Technology, Inc. | Rotary seal member coated with a chromium carbide-age hardenable nickel base alloy |
| US5839880A (en) * | 1992-03-18 | 1998-11-24 | Hitachi, Ltd. | Bearing unit, drainage pump and hydraulic turbine each incorporating the bearing unit, and method of manufacturing the bearing unit |
| US5419976A (en) * | 1993-12-08 | 1995-05-30 | Dulin; Bruce E. | Thermal spray powder of tungsten carbide and chromium carbide |
| US20090208662A1 (en) * | 2004-11-04 | 2009-08-20 | United Technologies Corporation | Methods for Repairing a Workpiece |
| US20190040960A1 (en) * | 2017-08-07 | 2019-02-07 | Kst Plant Company | Metal seat ball valve apparatus provided with micro-alloying layer, and method for manufacturing same |
Also Published As
| Publication number | Publication date |
|---|---|
| GB929205A (en) | 1963-06-19 |
| GB886560A (en) | 1962-01-10 |
| FR1300784A (en) | 1962-08-10 |
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