US3137632A - Chlorophyll dentifrice compositions - Google Patents

Chlorophyll dentifrice compositions Download PDF

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Publication number
US3137632A
US3137632A US272525A US27252552A US3137632A US 3137632 A US3137632 A US 3137632A US 272525 A US272525 A US 272525A US 27252552 A US27252552 A US 27252552A US 3137632 A US3137632 A US 3137632A
Authority
US
United States
Prior art keywords
acid
water soluble
chlorophyll
water
compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US272525A
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English (en)
Inventor
Schiraldi Robert Joseph
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE516996D priority Critical patent/BE516996A/xx
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Priority to US272525A priority patent/US3137632A/en
Priority to GB28159/52A priority patent/GB708232A/en
Priority to FR1066412D priority patent/FR1066412A/fr
Priority to CH316281D priority patent/CH316281A/de
Priority to DEC6922A priority patent/DE968516C/de
Application granted granted Critical
Publication of US3137632A publication Critical patent/US3137632A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/24—Phosphorous; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/733—Alginic acid; Salts thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/58—Metal complex; Coordination compounds

Definitions

  • Chlorophyll the green coloring material found in plants, is a water insoluble phytyl methyl ester of a porphyrin derivative.
  • the water insoluble material may be converted to a water soluble material by saponification, for example, with a water soluble alkali metal base.
  • the product thus obtained is a water soluble alkali metal salt, i.e., a water soluble chlorophyll compound.
  • the Water soluble chlorophyll compounds may be introduced into the mouth advantageously by brushing the teeth with the aid of a dentrifrice composition containing the said compounds.
  • Experimental determinations indicate, however, that Water soluble chlorophyll compounds are not released in water solutions from dentrifrice compositions which contain such chlorophyll compounds and polishing agents such as Water insoluble calcium compounds.
  • these determinations indicate that the chlorophyll compounds are not released in the aqueous media of the human mouth when such dentifrice compositions are used for brushing the teeth.
  • the present invention is based upon the surprising discovery that dentifrice compositions containing water soluble chlorophyll compounds and water insoluble calcium compounds as polishing agents can be prepared from which the chlorophyll compounds are released when the compositions are employed in the aqueous media of the human mouth.
  • the novel dentifrice compositions of the present invention comprise at least one water insoluble calcium compound, a water soluble chlorophyll compound, and a watersoluble material selected from the group consisting of alkali metal salts of orthophosphoric acid, pyrophosphoric acid, tripolyphosphoric acid, citric acid, silicic acid, gluconic acid, and ethylene diamine tetraacetic acid.
  • the pH of the compositions should be within the range of about to 11 based upon a 20% water slurry of the composition.
  • Suitable water soluble -alkali metal salt materials which may be employed in the dentifrice compositions of this invention include mono--, di-, and tri-sodium phosphate, disodium pyrophosphate, tetrasodium pyrophosphate, sodium tripolyphosphate, mono-, di-, and tri-potassium phosphate, dipotassium pyrophosphate, tetrapotassiurn pyrophosphate, potassium tripolyphosphate, sodium citrate, sodium gluconate, sodium silicate, potassium citrate, potassium gluconate, potassium silicate, etc.
  • the alkali metal salts may be emfee.
  • the sodium salts are preferably used because of their relatively low cost.
  • the water insoluble calcium compounds used as polishing agents in the dentifrice compositions of this invention may be selected from a relatively large number of materials.
  • Representative materials include, for example, calcium carbonate, calcium sulfate, anhydrous dicalcium phosphate, dicalcium phosphate dihydrate, commercial tricalcium phosphate, etc. If desired, these materials may be replaced in minor amounts by other Water insoluble materials, e.g., aluminum hydroxide, magnesium carbonate, etc.
  • the water insoluble polishing agent should be incorporated in the compositions in an appreciable amount and preferably should constitute the major proportion of the compositions, amounting to about 20% to by Weight of the finished dentifrice by weight.
  • the Water soluble chlorophyll compounds used in the dentifrice compositions herein described include those compounds known technically as sodium copper chlorophyllin, sodium magnesium chlorophyllin, sodium nickel chlorophyllin, sodium iron chlorophyllin, sodium potassium copper chlorophyllin, potassium copper chlorophyllin, potassium magnesium chlorophyllin, potassium nickel chlorophyllin, potassium iron chlorophyllin, etc.
  • the water soluble chlorophyll compounds should be present in the composition in amounts up to about 1.0% by weight of the final composition.
  • dentifrice compositions were prepared contain ing the various water insoluble calcium com ounds as polishing agents and the varying amounts of the several different water soluble alkali metal salts indicated in the table. Each one of the compositions contained 0.1% of water soluble potassium copper chlorophyllin. The values given in the table indicate the percent of the water soluble chlorophyll compound released when the compositions were mixed with water in the ratio of about one part of the dentifrice composition for four parts of Water.
  • the novel compositions of this invention may contain certain additional ingredients.
  • the dentifrice compositions ordinarily will contain a detergent or cleansing ingredient.
  • the amount of detergent and the particular detergent used may be the same as employed in conventional dentifrice preparations. Examples of suitable materials include soaps, i.e., water soluble salts of higher fatty acids, as well as synthetic detergents.
  • the amount of detergent used depends upon the particular one selectedand upon the amount of foaming action desired in the product. For example, if ordinary soaps are employed they may be used in amounts up to about of the final composition whereas such materials as synthetic detergents may be used in amounts up to about 8% of the final composition.
  • flavoring materials may be used to impart a pleasant taste to the compositions and to render the same more palatable.
  • Suitable flavoring materials include oil of Wintergreen, oil. of peppermint, oil of spearmint, oil of eucalyptus, cloves, menthol, anise, thyme, soluble saccharine, etc.
  • Example I A dentifrice composition in paste form comprises:
  • This composition has a pH of approximately 7.5.
  • Example II A dentifrice composition in paste form comprises:
  • This composition has a pH of approximately 8.0.
  • Example III A dentifrice composition in paste form comprises:
  • This composition has a pH of approximately 8.5.
  • This composition has a pH of approximately 8.8,
  • Example V A dentifrice composition in powder form comprises:
  • This composition has a pH of approximately 10.8.
  • Example VI A dentifrice composition in powder form comprises:-
  • This composition has a pH of approximately 8.5.
  • certain adjuvant materials may be incorporated in minor amounts in the novel compositions herein described.
  • a binder or thickening agent may be present.
  • the amount of binder used depends largely upon the particular material selected. If sodium alginate is used as the binder, it advantageously may be used in amounts up to about 3% of the final composition. Gum tragacanth may be used in amounts ranging from about 0.1% up to about 3%, based upon the finished product, while carboxymethyl cellulose may be used in even larger amounts, e.g., up to about 4% or even a little more.
  • such binders. as Irish moss and pectin may be used in relatively widely varied proportions.
  • ingredients such as titanium dioxide may be incorporated in the composition in amounts ranging up to about 2.0% to lighten the color of the finished composition.
  • the present invention in the broadest aspects thereof, contemplates .the formulation of the novel dentifrice compositions in any desired physical form, e.g., in an aqueous form such as a cream or paste; as a dry powder; etc.
  • a powdered dentifrice composition may be prepared readily and simply by mixingthe ingredients in the proper proportions in any desired order.
  • liquid ingredients e.g., water, ethanol and the like
  • the water soluble alkali metal salt material is added to the mixture after which the polishing agent, water soluble chlorophyll compound, and any desired adjuvant ingredients (flavoring ingredients, titanium dioxide, etc.) are introduced.
  • a detergent is employed in the composition itpreferably is introduced into the thoroughly mixed liquid ingredients prior to the introduction of the water soluble alkali metal salt.
  • a dentifrice composition comprising at least one water insoluble calcium compound, a water soluble chlorophyll compound, and a water soluble material selected from the group consisting of alkali metal salts of orthophosphoric acid, pyrophosphoric acid, tripolyphosphoric acid, citric acid, silicic acid, gluconic acid, and ethylene diamine tetraacetic acid.
  • a dentifrice composition comprising at least one water insoluble calcium compound, amounts up to about 1% of a water soluble chlorophyll compound, and a water soluble material selected from the group consisting of alkali metal salts of orthophosphoric acid, pyrophosphoric acid, tripolyphosphoric acid, citric acid, silicic acid, gluconic acid, and ethylene diamine tetraacetic acid.
  • a dentifrice composition comprising a polishing agent consisting essentially of at least one water insoluble calcium compound, small amounts up to about 1% of a water soluble chlorophyll compound, and a water soluble material selected from the group consisting of alkali metal salts of orthophosphoric acid, pyrophosphoric acid, tripolyphosphoric acid, citric acid, silicic acid, gluconic acid, and ethylene diamine tetraacetic acid.
  • a dentifrice composition in paste form comprising amounts up to about 1% of a Water soluble chlorophyll compound, about 20% to 95% of dicalcium phosphate dihydrate, a water soluble material selected from the group consisting of alkali metal salts of orthophosphoric acid, pyrophosphoric acid, tripolyphosphoric acid, citric acid, silicic acid, gluconic acid, and ethylene diamine tetraacetic acid.
  • a dentifrice composition in powder form comprising amounts up to about 1% of sodium copper chlorophyllin,
  • a polishing agent consisting essentially of dicalcium phosphate dihydrate, amounts of up to about 10% of a water soluble material selected from the group consisting of alkali metal salt of orthophosphoric acid, pyrophosphoric acid, tripolyphosphoric acid, citric acid, silicic acid, gluconic acid, and ethylene diamine tetraacetic acid.
  • a dentifrice composition comprising amounts up to about 1% of a water soluble chlorophyll compound, about 20% to 95% of a polishing agent consisting essentially of an insoluble inorganic calcium compound, and amounts up to about 10% of an alkali metal salt of ethylene diamine tetraacetic acid.
  • a dentifrice composition comprising amounts up to about 1% of a water-soluble chlorophyll compound, from about 20% to about 95% of a polishing agent consisting essentially of a water-insoluble inorganic calcium compound, and amounts up to about 10% of a water-soluble alkali metal phosphate.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Cosmetics (AREA)
US272525A 1952-02-19 1952-02-19 Chlorophyll dentifrice compositions Expired - Lifetime US3137632A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BE516996D BE516996A (fr) 1952-02-19
US272525A US3137632A (en) 1952-02-19 1952-02-19 Chlorophyll dentifrice compositions
GB28159/52A GB708232A (en) 1952-02-19 1952-11-07 Dentifrice compositions
FR1066412D FR1066412A (fr) 1952-02-19 1952-11-10 Compositions dentifrices contenant de la chlorophylle
CH316281D CH316281A (de) 1952-02-19 1952-11-14 Zahnpflegemittel
DEC6922A DE968516C (de) 1952-02-19 1953-01-08 Zahnpflegemittel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US272525A US3137632A (en) 1952-02-19 1952-02-19 Chlorophyll dentifrice compositions

Publications (1)

Publication Number Publication Date
US3137632A true US3137632A (en) 1964-06-16

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Family Applications (1)

Application Number Title Priority Date Filing Date
US272525A Expired - Lifetime US3137632A (en) 1952-02-19 1952-02-19 Chlorophyll dentifrice compositions

Country Status (6)

Country Link
US (1) US3137632A (fr)
BE (1) BE516996A (fr)
CH (1) CH316281A (fr)
DE (1) DE968516C (fr)
FR (1) FR1066412A (fr)
GB (1) GB708232A (fr)

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3903252A (en) * 1972-06-08 1975-09-02 Lorvic Corp Dental disclosing compositions and the method of making and using the same
DE2747092A1 (de) * 1977-10-20 1979-04-26 Wuertt Parfuemerie Farbstoffhaltige zahnpflegemittel
FR2426458A1 (fr) * 1978-05-25 1979-12-21 Colgate Palmolive Co Composition de pate dentifrice ayant une texture uniforme
US4264580A (en) * 1979-04-23 1981-04-28 Barberio Giacinto G Dental cream composition
US4301143A (en) * 1979-12-17 1981-11-17 Colgate-Palmolive Company Dental cream composition
US4323551A (en) * 1981-02-19 1982-04-06 The Procter & Gamble Company Mouthwash compositions
US4332791A (en) * 1980-04-29 1982-06-01 Blendax-Werke R. Schneider Gmbh & Co. Toothpaste active against plaque comprising a copper compound and a silica polishing agent
US4339429A (en) * 1980-04-29 1982-07-13 Blendax-Werke R. Schneider Gmbh & Co. Toothpaste active against plaque comprising a copper compound and a plastic polishing agent
EP0097476A2 (fr) * 1982-06-22 1984-01-04 The Procter & Gamble Company Compositions orales
US4515772A (en) * 1982-06-22 1985-05-07 The Procter & Gamble Company Oral compositions
US4590066A (en) * 1982-06-22 1986-05-20 The Procter & Gamble Company Oral compositions
US4661341A (en) * 1984-10-30 1987-04-28 The Procter & Gamble Company Oral compositions
US4678662A (en) * 1985-10-09 1987-07-07 Monsanto Company Pyrophosphate coating process for calcium carbonate dental abrasives
US4684518A (en) * 1982-06-22 1987-08-04 The Procter & Gamble Company Oral compositions
EP0236290A1 (fr) * 1986-03-05 1987-09-09 Monsanto Company Dentifrices contre les calculs dentaires
US4806340A (en) * 1985-09-13 1989-02-21 Colgate-Palmolive Company Anticalculus oral composition
US4885155A (en) * 1982-06-22 1989-12-05 The Procter & Gamble Company Anticalculus compositions using pyrophosphate salt
US4999184A (en) * 1982-06-22 1991-03-12 The Procter & Gamble Company Oral compositions
US5000943A (en) * 1989-05-30 1991-03-19 Nabisco Brands, Inc. Canine biscuits containing an inorganic pyrophosphate
US5000973A (en) * 1989-05-30 1991-03-19 Nabisco Brands, Inc. Nutritionally-balanced canine biscuits containing an inorganic pyrophosphate
US5011679A (en) * 1989-05-30 1991-04-30 Nabisco Brands, Inc. Raw hide having a coating containing an inorganic pyrophosphate
US5015485A (en) * 1989-05-30 1991-05-14 Nabisco Brands, Inc. Dog biscuits having a coating containing an inorganic pyrophosphate
US5094870A (en) * 1989-05-30 1992-03-10 Nabisco Brands, Inc. Canine biscuits containing an inorganic pyrophosphate
US5114704A (en) * 1989-05-30 1992-05-19 Nabisco Brands, Inc. Raw hide having a coating containing an inorganic pyrophosphate
WO1993019728A1 (fr) * 1992-04-07 1993-10-14 Smithkline Beecham Corporation Formulation pour les dents
US5294434A (en) * 1991-04-22 1994-03-15 King Ronald M Aloe vera gel toothpaste
US5294432A (en) * 1991-08-30 1994-03-15 Church & Dwight Co., Inc. Anticalculus dentifrices
US5514366A (en) * 1993-04-07 1996-05-07 Diamond; Jeffrey H. Dental and oral preparation for smokers for solubilizing and removing tobacco tars as well as onion and garlic essential oils
US5645841A (en) * 1995-06-05 1997-07-08 Whitehill Oral Technologies, Inc. Ultramulsion based oral care rinse compositions
US5651959A (en) * 1995-06-05 1997-07-29 Whitehill Oral Technologies, Inc. Ultramulsion based oral care compositions
US5665374A (en) * 1995-06-05 1997-09-09 Whitehill Oral Technologies, Inc. Ultramulsion containing interdental delivery devices
US6086372A (en) * 1997-06-04 2000-07-11 Block Drug Company, Inc. Dental and oral preparation
US20070110681A1 (en) * 2001-12-04 2007-05-17 Whitehill Oral Technologies, Inc. Flavor-stable dental devices
US8715625B1 (en) 2010-05-10 2014-05-06 The Clorox Company Natural oral care compositions
WO2016116950A3 (fr) * 2015-01-19 2016-10-13 Chitra Vasant Savangikar Composition de chlorophylle

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE543046A (fr) * 1954-11-24
NL7407759A (fr) * 1973-06-13 1974-12-17
US4046872A (en) * 1974-04-29 1977-09-06 Colgate Palmolive Company Dental cream
US4075317A (en) * 1974-04-29 1978-02-21 Colgate-Palmolive Company Dental cream composition
US4122164A (en) * 1975-10-02 1978-10-24 Colgate-Palmolive Company Dental cream composition
DE3504178A1 (de) * 1985-02-07 1986-08-14 Blendax Werke Schneider Co Zahnpasta
EP3142627B1 (fr) * 2014-05-15 2020-03-18 The Procter and Gamble Company Compositions d'hygiène buccale présentant une fraîcheur améliorée

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB444276A (en) * 1935-04-08 1936-03-18 Paul Reinhold Grueter An improved process for the manufacture of medicinal preparations containing chlorophyll or chlorophylline
GB490384A (en) * 1936-02-15 1938-08-15 Ig Farbenindustrie Ag Tooth cleansing agents
DE665707C (de) * 1934-01-19 1938-10-01 Reinhold Grueter Dr Verfahren zur Herstellung haltbarer Zubereitungen aus Chlorophyll oder chlorophyllhaltigen Stoffen und Mononatriumphosphat
US2191199A (en) * 1937-09-17 1940-02-20 Hall Lab Inc Abrasive detergent composition
GB522646A (en) * 1937-12-20 1940-06-24 Ig Farbenindustrie Ag The manufacture of aqueous solutions having a high content of calcium
US2216816A (en) * 1938-06-13 1940-10-08 Pepsodent Co Dentifrice
GB601801A (en) * 1945-12-03 1948-05-12 Lakeland Foundation Improvements relating to oral cleansing preparations and methods of making the same
US2519665A (en) * 1948-10-06 1950-08-22 Colgate Palmolive Peet Co Dentifrice
US2647073A (en) * 1951-04-13 1953-07-28 Amm I Dent Inc Ammoniated dentifrice containing anhydrous dicalcium phosphate

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE665707C (de) * 1934-01-19 1938-10-01 Reinhold Grueter Dr Verfahren zur Herstellung haltbarer Zubereitungen aus Chlorophyll oder chlorophyllhaltigen Stoffen und Mononatriumphosphat
GB444276A (en) * 1935-04-08 1936-03-18 Paul Reinhold Grueter An improved process for the manufacture of medicinal preparations containing chlorophyll or chlorophylline
GB490384A (en) * 1936-02-15 1938-08-15 Ig Farbenindustrie Ag Tooth cleansing agents
US2191199A (en) * 1937-09-17 1940-02-20 Hall Lab Inc Abrasive detergent composition
GB522646A (en) * 1937-12-20 1940-06-24 Ig Farbenindustrie Ag The manufacture of aqueous solutions having a high content of calcium
US2216816A (en) * 1938-06-13 1940-10-08 Pepsodent Co Dentifrice
GB601801A (en) * 1945-12-03 1948-05-12 Lakeland Foundation Improvements relating to oral cleansing preparations and methods of making the same
US2519665A (en) * 1948-10-06 1950-08-22 Colgate Palmolive Peet Co Dentifrice
US2647073A (en) * 1951-04-13 1953-07-28 Amm I Dent Inc Ammoniated dentifrice containing anhydrous dicalcium phosphate

Cited By (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3903252A (en) * 1972-06-08 1975-09-02 Lorvic Corp Dental disclosing compositions and the method of making and using the same
DE2747092A1 (de) * 1977-10-20 1979-04-26 Wuertt Parfuemerie Farbstoffhaltige zahnpflegemittel
US4223003A (en) * 1977-10-20 1980-09-16 Wurttembergische Parfumerie-Fabrik Gmbh Paste and powder dentifrices
FR2426458A1 (fr) * 1978-05-25 1979-12-21 Colgate Palmolive Co Composition de pate dentifrice ayant une texture uniforme
US4264580A (en) * 1979-04-23 1981-04-28 Barberio Giacinto G Dental cream composition
US4301143A (en) * 1979-12-17 1981-11-17 Colgate-Palmolive Company Dental cream composition
US4332791A (en) * 1980-04-29 1982-06-01 Blendax-Werke R. Schneider Gmbh & Co. Toothpaste active against plaque comprising a copper compound and a silica polishing agent
US4339429A (en) * 1980-04-29 1982-07-13 Blendax-Werke R. Schneider Gmbh & Co. Toothpaste active against plaque comprising a copper compound and a plastic polishing agent
US4323551A (en) * 1981-02-19 1982-04-06 The Procter & Gamble Company Mouthwash compositions
EP0297211A3 (en) * 1982-06-22 1989-01-11 The Procter & Gamble Company Oral compositions
EP0097476A2 (fr) * 1982-06-22 1984-01-04 The Procter & Gamble Company Compositions orales
EP0097476A3 (en) * 1982-06-22 1985-05-29 The Procter & Gamble Company Oral compositions
US4590066A (en) * 1982-06-22 1986-05-20 The Procter & Gamble Company Oral compositions
US4515772A (en) * 1982-06-22 1985-05-07 The Procter & Gamble Company Oral compositions
US4999184A (en) * 1982-06-22 1991-03-12 The Procter & Gamble Company Oral compositions
US4684518A (en) * 1982-06-22 1987-08-04 The Procter & Gamble Company Oral compositions
EP0395117A2 (fr) * 1982-06-22 1990-10-31 The Procter & Gamble Company Traitement oral et fabrication d'une composition orale
EP0297211A2 (fr) * 1982-06-22 1989-01-04 The Procter & Gamble Company Compositions orales
EP0297212A2 (fr) * 1982-06-22 1989-01-04 The Procter & Gamble Company Compositions orales
EP0297213A2 (fr) * 1982-06-22 1989-01-04 The Procter & Gamble Company Traitement oral et utilisation d'une composition orale
EP0297213A3 (en) * 1982-06-22 1989-01-11 The Procter & Gamble Company Oral treatment and manufacture of an oral composition
EP0297212A3 (en) * 1982-06-22 1989-01-11 The Procter & Gamble Company Oral compositions
EP0395117A3 (fr) * 1982-06-22 1993-07-28 The Procter & Gamble Company Traitement oral et fabrication d'une composition orale
EP0345821A1 (fr) * 1982-06-22 1989-12-13 The Procter & Gamble Company Compositions buccales
US4885155A (en) * 1982-06-22 1989-12-05 The Procter & Gamble Company Anticalculus compositions using pyrophosphate salt
US4661341A (en) * 1984-10-30 1987-04-28 The Procter & Gamble Company Oral compositions
US4806340A (en) * 1985-09-13 1989-02-21 Colgate-Palmolive Company Anticalculus oral composition
US4678662A (en) * 1985-10-09 1987-07-07 Monsanto Company Pyrophosphate coating process for calcium carbonate dental abrasives
EP0236290A1 (fr) * 1986-03-05 1987-09-09 Monsanto Company Dentifrices contre les calculs dentaires
US5000943A (en) * 1989-05-30 1991-03-19 Nabisco Brands, Inc. Canine biscuits containing an inorganic pyrophosphate
US5011679A (en) * 1989-05-30 1991-04-30 Nabisco Brands, Inc. Raw hide having a coating containing an inorganic pyrophosphate
US5015485A (en) * 1989-05-30 1991-05-14 Nabisco Brands, Inc. Dog biscuits having a coating containing an inorganic pyrophosphate
US5094870A (en) * 1989-05-30 1992-03-10 Nabisco Brands, Inc. Canine biscuits containing an inorganic pyrophosphate
US5114704A (en) * 1989-05-30 1992-05-19 Nabisco Brands, Inc. Raw hide having a coating containing an inorganic pyrophosphate
US5000973A (en) * 1989-05-30 1991-03-19 Nabisco Brands, Inc. Nutritionally-balanced canine biscuits containing an inorganic pyrophosphate
US5294434A (en) * 1991-04-22 1994-03-15 King Ronald M Aloe vera gel toothpaste
US5294432A (en) * 1991-08-30 1994-03-15 Church & Dwight Co., Inc. Anticalculus dentifrices
WO1993019728A1 (fr) * 1992-04-07 1993-10-14 Smithkline Beecham Corporation Formulation pour les dents
US5514366A (en) * 1993-04-07 1996-05-07 Diamond; Jeffrey H. Dental and oral preparation for smokers for solubilizing and removing tobacco tars as well as onion and garlic essential oils
US5662888A (en) * 1993-04-07 1997-09-02 Jeffrey Mitchell Laboratories Toothpaste for smokers for solubilizing and removing tobacco tars
US5645841A (en) * 1995-06-05 1997-07-08 Whitehill Oral Technologies, Inc. Ultramulsion based oral care rinse compositions
US5651959A (en) * 1995-06-05 1997-07-29 Whitehill Oral Technologies, Inc. Ultramulsion based oral care compositions
US5665374A (en) * 1995-06-05 1997-09-09 Whitehill Oral Technologies, Inc. Ultramulsion containing interdental delivery devices
US6086372A (en) * 1997-06-04 2000-07-11 Block Drug Company, Inc. Dental and oral preparation
US20070110681A1 (en) * 2001-12-04 2007-05-17 Whitehill Oral Technologies, Inc. Flavor-stable dental devices
US8715625B1 (en) 2010-05-10 2014-05-06 The Clorox Company Natural oral care compositions
WO2016116950A3 (fr) * 2015-01-19 2016-10-13 Chitra Vasant Savangikar Composition de chlorophylle

Also Published As

Publication number Publication date
CH316281A (de) 1956-09-30
BE516996A (fr)
FR1066412A (fr) 1954-06-04
DE968516C (de) 1958-02-27
GB708232A (en) 1954-04-28

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