US3078248A - Process of extruding fibers from a molten polyamide containing a phosphorous compound - Google Patents
Process of extruding fibers from a molten polyamide containing a phosphorous compound Download PDFInfo
- Publication number
- US3078248A US3078248A US820590A US82059059A US3078248A US 3078248 A US3078248 A US 3078248A US 820590 A US820590 A US 820590A US 82059059 A US82059059 A US 82059059A US 3078248 A US3078248 A US 3078248A
- Authority
- US
- United States
- Prior art keywords
- polymer
- sodium
- spinning
- weight
- grams
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
Definitions
- This invention relates to a process for the melt spinning of a filamentary structure from a synthetic nitrogencontaining polymer. More particularly, it is concerned with an improved process for the formation of a filament, yarn, ribbon or the like by melt spinning a synthetic linear fiber-forming polyamide.
- Another object is to reduce the number of drips when melt spinning a nitrogenous polymer containing Cl-lgroups adjacent to the nitrogen atom of the amide group in the main polymer chain.
- a still further object is to provide an improved meltspinning process for a synthetic linear fiber-forming polyamide, preferably polycarbonamides, having an increased concentration of amine end groups so that drips are eliminated or substantially reduced.
- the present invention provides an improvement in the process for the formation of a filamentary structure of a synthetic linear fiber-forming polymer having a structural unit of the formula wherein X is selected from the group consisting of oxygen and sulfur in at least 50% of the recurring units of the main polymer chain and having from about 55 to 160 gram equivalents of amine end groups per 10 grams of polymer, by extruding the molten polymer through an orifice into a quenching medium, the improvement comprising dissolving in the extrudate prior to extrusion at least 0.05% by weight, based on the weight of the polymer, of a phosphorus compound selected from the group consisting of a compound of the formula i R-P-O H O l! and a compound of the formula i RfiOZ metal wherein R is selected from the group consisting of alkyl, cycloalkyl, aryl and arylalkyl,
- n is a whole number corresponding to the valence of the metal
- Z is selected from the group consisting of hydrogen, alkyl, aryl, arylalkyl, and alkyl substituted ammonium cation, and
- R and Z being alkylene when joined to form a ring structure.
- filamentary structure is used to signify an article which has two dimensions which are small as compared to its third dimension.
- the term includes filaments, fibers, yarns, ribbons, thread and the like.
- the main polymer chain is meant a Wholly synthetic, or man-made, polymer which contains a preponderance of recurring units containing a hydrogen atom on the carbon alpha to the nitrogen atom of the amide (including thioamide) unit of the chain.
- Such polymers include the polycarbonamides, polythioamides, polyureas, polythioureas, polyurethanes and the like and all such polymers may be broadly defined as the polyamides since they con tain either the carbonamide unit or the thioamide unit as the linking units in the main polymer chain.
- the polymer is a polycarbonamide and contains from to of such groups containing the hydrogen atom on the alpha carbon atom.
- the expression by extruding the molten polymer through an orifice into a quenching medium is employed to mean the conventional melt-spinning process whereby the polymer is melted and forced through a hole or slot into a medium such as a liquid or gas, generally an inert gas, to cool and solidify the polymer into a long, substantially continuous structure.
- the terminology dissolving in the extrudate prior to extrusion is used to indicate that at the time of extrusion the polymer contains in a dissolved form one or more of the desired compounds.
- the compounds may, of course, be added to the polymer ingredients prior to polymerization or they may be added to the polymer itself prior to extrusion. In addition, the compounds may be formed in situ. In any event, the phosphorus compound is present in the polymer in the dissolved state during extrusion in quantities of at least 0.05% by weight based on the weight of the polymer.
- a polymer which contains a small amount of a conventional delusterant such as titanium dioxide, barium sulfate, aluminum trioxide and the like.
- a conventional delusterant such as titanium dioxide, barium sulfate, aluminum trioxide and the like.
- Such materials and the amounts employed are disclosed in United States Patent 2,205,722.
- a stainless steel autoclave is purged of air, filled with nitrogen and charged with an aqueous solution containing 75% by weight of hexamethylene diammonium adipate, 0.80 mole percent of hexamethylene diamine, 0.56 mole percent acetic acid, and 0.54% (based on the polymer weight) of sodium phenyl phosphinate in the form of an aqueous solution containing 25% by weight of the phosphinate.
- the autoclave is heated until its temperature is 195 C. at 250 p.s.i. pressure.
- an aqueous slurry containing 20% TiO; is added (2.0% Ti0 based on the weight of polymer). The heating is continued until the temperature reaches 240 C.
- the polyhexamethylene adipamide flake is melted in a steam atmosphere as taught in Waltz United States Patent 2,571,975 and is spun into a 70 total denier 34 filament yarn at a rate of 1350 yards per minute. The spinning is continued for a period of 2 days and the formation of spinning drips observed and recorded. The average time of drip-free spinning for this period is 11 hours. For a comparative control not containing the phosphinate compound this time is 2 /2 hours. For polyhexamethylene adipamide of comparable molecular weight wherein the concentration of amine end groups is 40 gram equivalents per 10 grams and which does not contain the phosphinate compound this time is about 6 /2 hours.
- the example thus shows that the addition of the phosphinat'e compound reduces the frequency of spinning drips in dull polymer with increased amine end concentration to a value equal or less than the value prevailing for a polymer with low amine end group concentration.
- the yarn is cold drawn and scoured according to conventional techniques.
- the product is a white yarn with superior dyeability.
- EXAMPLE II A stainless steel autoclave is charged with 464.0 pounds of an aqueous solution containing 52.02% by weight of hexamethylene diammonium adipate, 487 grams of aminopropyl morpholine (0.85 mole percent), 1280 grams of an aqueous solution containing 25% by weight of sodium phenyl phosphinate (0.5% based on the polymer weight). The autoclave is purged of air, filled with nitrogen and heated until its temperature is 220 C. at 250 p.s.i. pressure. Then 91.0 grams of an aqueous slurry containing 20% Ti0 is added (0.02% based on the weight of polymer). The heating is continued until the temperature reaches 240 C. at 250 psi. pressure.
- the polymer polymerization cycle is continued as in Example 1 of United States Patent 2,163,636.
- the molten polymer has a relative viscosity of 35.1 and a concentration of amine ends of 114 gram equivalents per 10 grams of polymer.
- the polymer is extruded in the form of a ribbon upon a casting Wheel. After quenching, it is cut into chips suitable for remelting at the grid of a spinning assembly.
- the polyhexamethylene adipamide flake is spun into a 30 total denier 10 filament yarn at a rate of about 1206 37pm. The spinning is continued for a period of hours and the formation of spinning drips observed and recorded.
- the average time of drip-free spinning for this period is 25 hours.
- this time is 12 hours.
- For poly hexamethylene adipamide of comparable molecular weight wherein the concentration of amine end groups is 40 and which does not contain a phosphinate compound this time is about 30 hours.
- the example shows that the addition of the phosphinate compound reduces the frequency of spinning drips in brlght polymer with increased amine end concentration to about the value prevailing for a polymer with low amine end group concentration.
- the yarn is cold drawn and scoured according to conventional techniques.
- the product is a white, oxidationresistant yarn with superior dyeability.
- EXAMPLE III A polyhexamethylene adiparnide yarn is prepared following the procedure of Example I using 0.68 weight percent of sodium 2,5-dimethylphenylphosphinate. Essentially the same reduction in frequency of spinning drips is observed.
- the poly(2-methyl hexamethylcne oxamide) flake is melted in a screw melter maintained at 285 C. and spun into a 30 total denier 10 filament yarn at a speed of about 100 y.p.m.
- the average drip-free spinning time is approximately twice as long as for a comparative control of the same polymer having a concentration of amine end of 40 gram equivalents per 10 grams of polymer in which no phosphinate compound has been added.
- EXAMPLE V The salt of m-xylylene diamine and adipic acid is made by preparing an 11% by weight solution of adipic acid in methanol in a stainless steel container, and then adding an equimolar quantity of m-xylylene diamine in the form of a 67% by weight solution in methanol while stirring the solution vigorously. The stirring is reduced to a mod erate rate and continued for 30 seconds after which the container is blanketed with nitrogen and allowed to stand without agitation for 3 hours. The salt is then filtered off and dried in a vacuum oven at a temperature of 80 C. The salt, in an amount of 2000 grams, is charged into a 5 pound capacity autoclave with 2000 grams of water.
- the polymer is discharged from the autoclave and cut into flake as described in United States Patent 2,289,774.
- the flake is melt-spun to form 13 filament, 40 denier yarn in the conventional manner by extruding through a spinning pack of the type described in United States Patent 2,266,363 the temperature of the molten polymer being 250 to 270 C.
- the filaments are quenched and cold drawn in the conventional manner.
- the average drip-free spinning time is about twice that of a comparative control containing the same concentration of amine ends and no phosphinate compound.
- the resulting yarn has superior dyeability.
- EXAMPLE VI 2000 grams of caprolactam are charged in an autoclave and heated above the melting point. In the molten caprolactam are dissolved 8.0 grams of hexamethylene diamine and 5.4 grams of sodium phenylphosphinate. The polymerization of the caprolactam is conducted by raising the temperature to 270 C. and the pressure to 250 psi. and maintaining these conditions for 30 minutes. The pressure is next reduced to atmospheric and then to about 10 mm. mercury, which pressure is maintained for about 2 hours while the temperature is raised to and maintained at 270 C. The molten polymer is then discharged as a ribbon by extruding it from the autoclave through a narrow slot.
- the ribbon is quenched on a water-cooled casting wheel and cut into /2 inch flake.
- the polymer has 85 gram equivalents of amine end groups per 10 gram of polymer.
- a yarn is melt spun from the flake with low frequency of spinning drips, drawn and washed. The yarn shows superior dyeability to deep shades.
- the synthetic linear fiber-forming polymers useful in the practice of the present invention are any of those which have the structural unit in at least 50% of the recurring units of the main polymer chain.
- the polymers which may be used are those containing the following recurring units.
- copolymers may be used in the practice of this invention provided such copolymers have the high amine end groups and do not contain over 50% of other recurring structural units.
- the desired concentration of amine end groups may be obtained by adding an appropriate amount of a primary or secondary amine or polyamines.
- Suitable amines include: methyl amine, ethyl amine, propyl amine, isopropyl amine, hexamethylene diamine, piperazine, N-arnino pentyl piperazine, N,N-diaminopentyl piperazine, N-amino propyl morpholine and many others.
- the amine eifecting the increase of amine end groups may be added before or at the beginning of the polymerization or during the early stages of the polymerization.
- the most convenient time for adding the amine is to the salt solution prior to evaporation of the solvent and prior to polymerization.
- the phosphinate compound should be added prior to heating the polyamide forming reactants to elevated temperature near the melting point of the polyamide. It is essential that it be added prior to the melt-spinning operation. Conveniently, it may be added to the salt solution before the beginning of the polymerization reaction.
- Phosphorus compounds other than those of the examples which may be used for the same purpose include:
- potassium p-dodecylphenylphosphinate sodium p-dimethylaminophenylphosphinate, potassium p-dimethylaminophenylphosphinate, sodium p-(beta-carboxyethyl)phenylphosphinate, tetramethylammoniumphenylphosphinate, 3-hydroxypropylphosphinic acid phostone, 3-hydroxy-Z-methylpropylphostahinic acid phostone, sodium o-methylphenylphosphinate,
- the concentration of the phosphinate compound in the polymer should be at least 0.05% based on the weight of the polymer and preferably at least 0.2%. Amounts up to the limit of solubility in the polymer may be employed.
- the phosphinate compound makes possible melt spinning of the polymer with reduced frequency of drips and reduced requirements for wiping spinnerets.
- the phosphinate compound may be removed from the yarn, if desired, by a scouring operation.
- the term scouring is used to signify a process whereby the yarn is contacted with a solvent for the phosphinate compound so that the phosphinate compound is partially or totally extracted from the yarn. Water or water containing a small amount of soap or detergent may be employed as the solvent.
- the process of this invention is applicable to polymers containing different concentrations of a delusterant (dull, semi-dull, and bright yarn). Since the spinning of dull yarns, in the absence of a phosphinate compound, frequently causes more spinning drips than the spinning of bright yarns, the advantages of the process of this invention are most pronounced when applied to delustered polymer.
- the yarns obtained by the process of this invention are more deeply and uniformly dyeable at higher rate. They have specific utility in textile end uses where deep shades are desired, and in processes wherein high rate of dyeing is required, such as in slasher dyeing of warps.
- n is a whole number corresponding to the valence of the metal
- Z is selected from the group consisting of hydrogen, alkyl, aryl, arylalkyl, and alkyl substituted ammonium,
- R and Z being alkylene when joined to form a ring structure.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Polyamides (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL252702D NL252702A (xx) | 1959-06-16 | ||
US820590A US3078248A (en) | 1959-06-16 | 1959-06-16 | Process of extruding fibers from a molten polyamide containing a phosphorous compound |
DE19601469128 DE1469128A1 (de) | 1959-06-16 | 1960-06-15 | Verfahren zur Herstellung von Faeden,Fasern oder Baendern |
FR830059A FR1260346A (fr) | 1959-06-16 | 1960-06-15 | Perfectionnements apportés à la fabrication d'articles tels que des filaments, à partir de polymères synthétiques contenant de l'azote |
GB21189/60A GB898889A (en) | 1959-06-16 | 1960-06-16 | Preparation of filamentary structures from synthetic nitrogen-containing polymers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US820590A US3078248A (en) | 1959-06-16 | 1959-06-16 | Process of extruding fibers from a molten polyamide containing a phosphorous compound |
Publications (1)
Publication Number | Publication Date |
---|---|
US3078248A true US3078248A (en) | 1963-02-19 |
Family
ID=25231233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US820590A Expired - Lifetime US3078248A (en) | 1959-06-16 | 1959-06-16 | Process of extruding fibers from a molten polyamide containing a phosphorous compound |
Country Status (4)
Country | Link |
---|---|
US (1) | US3078248A (xx) |
DE (1) | DE1469128A1 (xx) |
GB (1) | GB898889A (xx) |
NL (1) | NL252702A (xx) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3230193A (en) * | 1961-05-16 | 1966-01-18 | Du Pont | Polyurethanes stabilized by phosphines |
US3254059A (en) * | 1962-02-12 | 1966-05-31 | Monsanto Co | Treatment of chips of polycarbonamide containing organic derivative of hypophosphorous acid |
US3280131A (en) * | 1964-02-10 | 1966-10-18 | Millmaster Onyx Corp | Quaternary ammonium salts of organophosphorus acids |
US3296215A (en) * | 1963-12-30 | 1967-01-03 | Monsanto Co | Synthetic linear polycarbonamides having an improved receptivity for acid dyes |
US3322716A (en) * | 1963-08-19 | 1967-05-30 | American Cyanamid Co | Flame retardant compositions consisting essentially of a thermoplastic material and a phosphinic acid |
US3330893A (en) * | 1959-12-09 | 1967-07-11 | Celanese Corp | Method for increasing the dyeability of filamentary material |
US3340339A (en) * | 1963-06-07 | 1967-09-05 | Du Pont | Method of incorporating a phosphinate and particulate material in a polyamide to make low friction filament |
US3511815A (en) * | 1968-05-08 | 1970-05-12 | Ahmet Nuri Sayin | Deep dyeing polycarbonamide filament |
US3627868A (en) * | 1968-05-24 | 1971-12-14 | Takaji Funahashi | Method of producing nibs for writing instruments |
US3666717A (en) * | 1969-04-15 | 1972-05-30 | Ici Ltd | Polyamides stabilized with a phosphine |
US3692867A (en) * | 1971-03-10 | 1972-09-19 | Allied Chem | Filament comprising a polymer blend of polyester and polyanide containing an organic phosphorus compound |
US3846532A (en) * | 1969-01-29 | 1974-11-05 | Bayer Ag | Continuous spinning and stretching process of the production of polyamide-6 filaments |
US3933963A (en) * | 1974-12-13 | 1976-01-20 | E. I. Du Pont De Nemours And Company | Spinning process |
US4017255A (en) * | 1969-12-01 | 1977-04-12 | Imperial Chemical Industries | Dyed textile materials |
US4077940A (en) * | 1976-09-14 | 1978-03-07 | Chevron Research Company | Thermal stabilization of polypyrrolidone against reversion to monomer |
EP0764729A1 (en) * | 1994-05-26 | 1997-03-26 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyhexamethyleneadipamide fiber and process for producing the fiber |
US20070203270A1 (en) * | 2003-03-05 | 2007-08-30 | Clariant Gmbh | Flame retardant dispersion |
WO2008039671A2 (en) * | 2006-09-19 | 2008-04-03 | Invista Technologies S.A.R.L. | Polyamide composition with improved heat stability and whiteness |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111073037B (zh) * | 2019-12-10 | 2022-04-12 | 江汉大学 | 一种高热稳定性膨胀型阻燃剂及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2510777A (en) * | 1946-12-30 | 1950-06-06 | Du Pont | Polyamide treated with a hypophosphorous acid compound |
-
0
- NL NL252702D patent/NL252702A/xx unknown
-
1959
- 1959-06-16 US US820590A patent/US3078248A/en not_active Expired - Lifetime
-
1960
- 1960-06-15 DE DE19601469128 patent/DE1469128A1/de active Pending
- 1960-06-16 GB GB21189/60A patent/GB898889A/en not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2510777A (en) * | 1946-12-30 | 1950-06-06 | Du Pont | Polyamide treated with a hypophosphorous acid compound |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3330893A (en) * | 1959-12-09 | 1967-07-11 | Celanese Corp | Method for increasing the dyeability of filamentary material |
US3230193A (en) * | 1961-05-16 | 1966-01-18 | Du Pont | Polyurethanes stabilized by phosphines |
US3254059A (en) * | 1962-02-12 | 1966-05-31 | Monsanto Co | Treatment of chips of polycarbonamide containing organic derivative of hypophosphorous acid |
US3340339A (en) * | 1963-06-07 | 1967-09-05 | Du Pont | Method of incorporating a phosphinate and particulate material in a polyamide to make low friction filament |
US3322716A (en) * | 1963-08-19 | 1967-05-30 | American Cyanamid Co | Flame retardant compositions consisting essentially of a thermoplastic material and a phosphinic acid |
US3296215A (en) * | 1963-12-30 | 1967-01-03 | Monsanto Co | Synthetic linear polycarbonamides having an improved receptivity for acid dyes |
US3280131A (en) * | 1964-02-10 | 1966-10-18 | Millmaster Onyx Corp | Quaternary ammonium salts of organophosphorus acids |
US3511815A (en) * | 1968-05-08 | 1970-05-12 | Ahmet Nuri Sayin | Deep dyeing polycarbonamide filament |
US3627868A (en) * | 1968-05-24 | 1971-12-14 | Takaji Funahashi | Method of producing nibs for writing instruments |
US3846532A (en) * | 1969-01-29 | 1974-11-05 | Bayer Ag | Continuous spinning and stretching process of the production of polyamide-6 filaments |
US3666717A (en) * | 1969-04-15 | 1972-05-30 | Ici Ltd | Polyamides stabilized with a phosphine |
US4017255A (en) * | 1969-12-01 | 1977-04-12 | Imperial Chemical Industries | Dyed textile materials |
US3692867A (en) * | 1971-03-10 | 1972-09-19 | Allied Chem | Filament comprising a polymer blend of polyester and polyanide containing an organic phosphorus compound |
US3933963A (en) * | 1974-12-13 | 1976-01-20 | E. I. Du Pont De Nemours And Company | Spinning process |
US4077940A (en) * | 1976-09-14 | 1978-03-07 | Chevron Research Company | Thermal stabilization of polypyrrolidone against reversion to monomer |
EP0764729A1 (en) * | 1994-05-26 | 1997-03-26 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyhexamethyleneadipamide fiber and process for producing the fiber |
EP0764729A4 (en) * | 1994-05-26 | 1998-10-21 | Asahi Chemical Ind | POLYHEXAMETHYLENEADIPAMIDE FIBER AND PROCESS FOR PRODUCING THE SAME |
US5929148A (en) * | 1994-05-26 | 1999-07-27 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyhexamethylene adipamide fibers and process for producing the same |
US6288153B1 (en) | 1994-05-26 | 2001-09-11 | Asahi Kasei Kabushiki Kaisha | Polyhexamethyleneadipamide fiber and composition |
US20070203270A1 (en) * | 2003-03-05 | 2007-08-30 | Clariant Gmbh | Flame retardant dispersion |
US7273901B2 (en) * | 2003-03-05 | 2007-09-25 | Clariant Produkte (Deutschland) Gmbh | Flame retardant dispersion |
WO2008039671A2 (en) * | 2006-09-19 | 2008-04-03 | Invista Technologies S.A.R.L. | Polyamide composition with improved heat stability and whiteness |
WO2008039671A3 (en) * | 2006-09-19 | 2008-09-04 | Invista Tech Sarl | Polyamide composition with improved heat stability and whiteness |
Also Published As
Publication number | Publication date |
---|---|
GB898889A (en) | 1962-06-14 |
DE1469128A1 (de) | 1969-03-20 |
NL252702A (xx) |
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