US3067461A - Apparatus for producing twisted filament yarn - Google Patents
Apparatus for producing twisted filament yarn Download PDFInfo
- Publication number
- US3067461A US3067461A US67658A US6765860A US3067461A US 3067461 A US3067461 A US 3067461A US 67658 A US67658 A US 67658A US 6765860 A US6765860 A US 6765860A US 3067461 A US3067461 A US 3067461A
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- Prior art keywords
- filaments
- streams
- spinneret
- extrusion
- polymer
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
- D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
- D02G1/0266—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting false-twisting machines
Description
Dec. 11, 1962 e. B. HUGHEY 3,067,461
APPARATUS FOR PRODUCING TWISTED FILAMENT YARN I Filed Nov. 7, 1960 1 I. A 9 6501265 gW i/Er V By 50 131.2 72/". #144? ATTORNEY a a 3,067,461 United States Patent Office 3,067,461 APPARATUS FOR PRGDUCTNG TWISTED FILAMENT YARN George B. Hughey, Pensacola, Fla, assignor, by mesne assignments, to Monsanto Chemical Company, a corporation of Delaware Filed Nov. 7, 1960, Ser. No. 67,658 Claims. (Cl. 18-8) This invention relates to the production of filaments by the melt-spinning method. More particularly, the invention relates to an apparatus for producing melt-spun synthetic textile filaments having a twist individually imparted therein.
Many methods and devices are known for imparting some of the desirable properties of spun yarn to continuous filament yarn by modifying the texture thereof. Continuous filament yarn which has been modified in some manner to increase its bulk, stretch, or both of these properties has become known as a textured yarn. A wellknown procedure for producing textured yarn includes the steps of twisting drawn yarn, then heat-setting the twisted yarn and then detwisting the yarn. In commercial practice the steps of twisting and detwisting most often are accomplished by means of a false twist apparatus. However, by the use of a false twist apparatus the twist is not a true twist and the amount of twist imparted to a bundle of filaments is not uniform from one filament to the next. Often it is desirable to employ textured yarn in the construction of fabrics and the like, the filaments of which are twisted individually and uniformly. Heretofore, prior art procedures for imparting uniform twist to the individual filaments of a bundle of filaments to increase the bulk thereof have been fraught with difficulties and are regarded as being economically unfeasible.
It is an object of this invention to provide a new and useful apparatus for twisting individual filaments during melt-spinning thereof.
It is another object of the present invention to provide a new and useful melt-spinning apparatus adapted to impart a positive twist to the individual filaments during the melt-spinning thereof.
Other objects and many advantages of this invention will be readily appreciated as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawing in which like numbers designate like parts throughout the figures thereof.
in general, the objects of the present invention are accomplished by providing one or more melt-spinning devices adapted to shape and discharge molten or plastic organic filament-forming materials into one or more streams, to cool the streams into hardened filaments and thereafter to collect the filaments in an orderly form. Each spinning device includes a plate, such as a spinneret, having a suitable number of small orifices therein. The molten or plastic mass is extruded at a constant rate and under Uressure through these small orifices to form molten streams of polymer. The device includes a protective spinning chamber adapted to receive the shaped streams which are directed downwardly therethrough and wherein the extruded streams are cooled and solidified into filaments such as by a non-turbulent flow of gas impelled against the streams. Each spinning device contains at least one rotatably mounted twist-imparting member having a thin continuous helical rib projecting therefrom. The member is positioned near the yarn path between the spinneret and means for taking up the yarn in a uniform manner. The member is adapted to produce a rotation moment to individual filaments by a peripheral effort on the filaments. The resulting twist of the filaments extends upwardly toward the point of extrusion and slightly past the point of solidification of the filaments in the spinning chamber so as to obtain a true and permanent twist in the filaments.
With reference now to the drawing, FIGURE 1 is a front elevational view of a melt-spinning apparatus incorporating one embodiment of the invention;
FIGURE 2 is an elevational view taken from the right hand side of FIGURE 1 with a side wall of the apparatus removed for convenience of illustration; and
FIGURE 3 is a view of part of the apparatus on a larger scale taken along line 3-3 of FIGURE 1 and looking in the direction of the indicating arrows which illustrates more fully how the said member imparts a twist to the filaments.
In the drawing reference numeral 10 generally indicates a spinneret assembly which incorporates a spinneret 11 through Whose orifices a molten or plastic filament-forming polymer is extruded into a plurality of filaments 12. The molten polymer is pumped or propelled to the spinneret under pressure through a conduit 13 from a suitable source where the polymer is heated to a molten or plastic condition. The face of the spinneret preferably is horizontally disposed so that the normal extrusion axis extends vertically downward. Upon extrusion the molten polymer assumes the form of a stream or a plurality of streams of polymer. The streams are received immediately after extrusion by and cooled within the confined and protected area provided by the elongated spinning chamber 14. The bundle of filaments 12 pass downwardly through the cooling zone within chamber 14 and thence to and through yarn converging guide 15 where the filaments are gathered together in a more compact bundle. Thereafter, the bundles of filaments are taken up in an orderly manner. As illustrated, the take-up means includes reciprocatably mounted traverse guide 16 adapted to lay the melt-spun filaments on a bobbin '17 or the like suitably driven to form a filament package 20 It will be appreciated that the speed of filament take-up on bobbin 18 will be coordinated properly with the extrusion speed of the polymer so that proper melt-spinning is accomplished. Ordinarily the collection rate is considerably higher than the extrusion rate.
The spinning chamber 14 having an open front comprises two solid vertical side walls 21 and 22 in spaced apart relationship, a top panel 23 and a bottom panel 24 provided with an opening therein through which the gathered bundle of filaments passes in operation. The back wall of the chamber 14 bridging said side walls 21 and 22 and extending from panel 23 to panel 24 is made of material pervious to gas, such as gauze fabric, felt material, or as illustrated, a fine mesh wire screen 25. The screen will impart a diffused but substantially straight line flow to the cooling gas impelled therethrough so that the cooling gas contacts laterally the vertically moving streams of polymer to cool same into solid-filaments. Often it is desirable to contact the filamentary stream with a force of air sufficient to cause the streams to assume an arcuate path during part of their travel down the spinning chamber.
In the yarn path between the spinneret and the takeup means there are positioned rotatably mounted members 26 and 27 each having a continuous helical rib 28 projecting therefrom and extending longitudinally thereof. The said members are adapted to impart a rotational movement to the filaments coming into contact therewith. Preferably, the members are circular in cross section and are mounted to be normal with respect to the extrusion axis. The sides 29 of rib 28 preferably are substantially parallel. The twist-imparting members 26 and 27 are mounted on drive shafts 30 and 31 respectively driven by electric motors 32 and 33. The motors are energized by suitable electrical connections, not shown. As indicated above, the long axes of members 26 and 27 are perpendicular with respect to the extrusion axis. Instead of employing two members, as illustrated, one or more than two such members may be employed, although the use of two members gives quite satisfactory results. The members are positioned near the bottom of the spinning chamber 14 where the filamentary streams are solid. The members cause the individual filaments to become twisted with the twist running back unimpeded toward the spinneret where the streams are still plastic. By maintaining the twist in the filaments, during the metastasis of the filaments from a molten condition to a hardened state, the resulting twist is permanent.
For best results the number of grooves between the ribs 28 approximates the number of filaments being produced and the height of the ribs is less than half the distance across the cross section of the filaments. Where two twist-imparting members are employed, the filaments for best results contact opposite sides of the peripheries of the members. Drawing attention to FIGURE 2, it is noted that the filaments 12 contact the left side of the periphery of member 26 and then the right side of the periphery of member 27.
The invention is generally applicable to any substance that can be suitably melt spun. Specific polymeric materials capable of being melt spun include: nylon 66, nylon 6, nylon 4, nylon 610, nylon ll, and their filamentforming copolmers,e.g., 6/66 6/610/66, etc.; polyesters derived from terephthalic acid and ethylene glycol and from terephthalic acid and bis-1,4-(hydrxytnethyl) cyclohexane; polyethylene and polypropylene; and other substances.
The present apparatus most suitable for twisting yarn whose filaments have a non-circular cross section such as that produced where a spinneret having non-circular shaped orifices is employed during the manufacture thereof. Yarns of X- or Y-shaped cross section are examples of yarns having a non-circular cross section. The yarns may have a triangular cross section as shown in FIGURE 3 or may have a square cross section or other polygonal or multilobal shape.
There has just been described above a simple, inexpensive and effective apparatus for imparting a persistent twist in the individual filaments of melt-spun yarn as they are being produced. The resulting yarn is bulky, that is, it has greater covering power and warmth due to enhanced lateral spacing of the filaments. Among other advantages of the present invention is the fact that the device may be run at high speed and requires little operator attention. The construction and arrangement of the device make it possible to convert at moderate expense existing melt-spinning equipment into a machine of the type disclosed and claimed herein. The inherent properties of the yarn twisted in accordance with this invention are such that they impart numerous and desirable effects in woven, non-woven, and knitted fabrics made therefrom.
Obviously, many modifications and variations of the present invention are possible in the light of the above teaching. It should be understood, therefore, that the foregoing disclosure relates to only preferred embodiments of the invention and that numerous modifications may be made therein without departing from the spirit and scope of the invention as set forth in the appended claims.
What is claimed is:
1. A melt-spinning apparatus for use in the production of individually twisted filaments from a thermoplastic filament-forming polymer comprising a spinneret for extruding said polymer in a molten condition in a yarn path extending generally downward along a vertical extrusion line at a predetermined extrusion rate, means for collecting the resulting filaments in package form at a predetermined increased collection rate positioned below said spinneret, a spinning chamber adapted to receive the streams of polymer immediately upon extrusion thereor" wherein the streams are cooled into hardened filaments, at least one rotatably mounted member having a con-- tinuous helical rib projecting therefrom and extending longitudinally thereof, said member being positioned within said chamber in the yarn path at a point where the streams normally have been cooled into hardened filaments, whereby the filaments are twisted individually by a peripheral effort on the filaments exerted by said member with the twist running back toward the spinneret beyond the point where the filaments become hardened.
2. A melt-spinning apparatus for use in the production of individually twisted filaments from a thermoplastic filament-forming polymer comprising a spinneret for extruding said polymer in a molten condition in a yarn path extending generally downward along a vertical extrusion line at a predetermined extrusion rate, means for collecting the resulting laments in package form at a predetermined increased collection rate positioned below said spinneret whereby to attenuate the filaments, a spinning chamber adapted to receive the streams of polymer immediately upon extrusion thereof wherein the streams are cooled into hardened filaments, at least one rotatably mounted twist-imparting member having a continuous helical rib projecting therefrom and extending longitudinally thereof, said member being positioned within said chamber in the yarn path at a point where the streams normally have been cooled into hardened filaments, the long axis of said twist-imparting member being substantially perpendicular with respect to the extrusion axis, and means for rotating said twist-imparting member, whereby the filaments are twisted individually by a peripheral effort on the filaments exerted by the said helical rib with the twist running back toward the spinneret beyond the point where the filaments become hardened.
3. A melt-spinning apparatus for use in the production of individually twisted filaments from a thermoplastic filament-forming polymer comprising a spinneret for extruding said polymer in a molten condition in a yarn path extending generally downward along a vertical extrusion line at a predetermined extrusion rate, means for collecting the resulting filaments in package form at a predetermined increased collection rate positioned below said spinneret whereby to attenuate the filaments, a spinning chamber adapted to receive the streams of polymer immediately upon extrusion thereof wherein the streams are cooled into hardened filaments, two spaced apart rotatably mounted twist-imparting members each having a continuous helical rib projecting therefrom and extending longitudinally thereof, said members being positioned within said chamber in the yarn path where the streams have been cooled into hardened filaments, the long axes of said twist-imparting members being substantially perpendicular with respect to the extrusion axis, and means for rotating said twist-imparting members, whereby the filaments are positively twisted individually by a peripheral efiiort on the filaments exerted by the said helical ribs with the twist running back toward the spinneret beyond the point where the filaments become hardened.
4. A melt-spinning apparatus for use in the production of individually twisted filaments from a thermoplastic filament-forming polymer comprising a spinneret for extruding said polymer in a molten condition in a yarn path extending generally downward along a vertical extrusion line at a predetermined extrusion rate, means for collecting the resulting filaments in package form at a predetermined increased collection rate positioned below said spinneret whereby to attenuate the filaments, an elongated spinning chamber positioned above said collecting means and adapted to receive the streams of polymer immediately upon extrusion thereof, wherein the streams are cooled into hardened filaments, two spaced apart rotatably mounted twist-imparting members positioned in the yarn path in the lower half of said spinning chamber, a con tinuous helical rib projecting from and extending longitudinally of each of said members, the long axes of said members being substantially perpendicular with respect to the extrusion axis, the height of the ribs being less than half the distance across the cross section of the filaments, and electrically powered means for rotating said twistimparting members, whereby the filaments are positively twisted individually by a peripheral effort on the filaments exerted by the said helical ribs with the twist running back toward the spinneret beyond the point where the filaments become hardened.
5. A melt-spinning apparatus for use in the production of individually twisted filaments from a thermoplastic filament-forming polymer comprising a spinneret for extruding said polymer in a molten condition in a yarn path extending generally downward along a Vertical exttrusion line at a predetermined extrusion rate, means for collecting the resulting filaments in pack-age form at a predetermined increased collection rate positioned below said spinneret whereby to attenuate the filaments, an elongated spinning chamber positioned above said collecting means and adapted to receive the streams of polymer immediately upon extrusion thereof, wherein the streams are cooled into hardened filaments, two spaced apart rotatably mounted shafts of circular cross section positioned in the yarn path in the lower half of said spinning chamber, a continuous helical rib projecting from and extending longitudinally of each of said shafts, the long axes of said shafts being substantially perpendicular with respect to the extrusion axis, the height of the ribs being less than half the distance across the cross section of the filaments, and electrically powered means for rotating said shafts, whereby the filaments are positively twisted individuall by a peripheral effort on the filaments exerted by the said helical ribs with the twist running back unimpeded toward the spinneret beyond the point where the filaments become hardened.
References Cited in the file of this patent UNITED STATES PATENTS 2,086,651 Ubbelohde July 13, 1937 2,150,354 Berndt Mar. 14, 1939 2,328,074 Hunter Aug. 31, 1943 2,347,036 Dumont Apr. 18, 1944 2,708,813 Bourgeaux May 24, 1955 2,874,410 Kinney Feb. 24, 1959 2,920,346 Iori Jan. 12, 1960 2,957,747 Bolwing Oct. 25, 1960 3,010,146 Warthen Nov. 28, 1961
Claims (1)
1. A MELT-SPINNING APPARATUS FOR USE IN THE PRODUCTION OF INDIVIDUALLY TWISTED FILAMENTS FROM A THERMOPLASTIC FILAMENT-FORMING POLYMER COMPRISING A SPINNERET FOR EXTRUDING SAID POLYMER IN A MOLTEN CONDITION IN A YARN PATH EXTENDING GENERALLY DOWNWARD ALONG A VERTICAL EXTRUSION LINE AT A PREDETERMINED EXTRUSION RATE, MEANS FOR COLLECTING THE RESULTING FILAMENTS IN PACKAGE FORM AT A PREDETERMINED INCREASED COLLECTION RATE POSITIONED BELOW SAID SPINNERET, A SPINNING CHAMBER ADAPTED TO RECEIVE THE STREAMS OF POLYMER IMMEDIATELY UPON EXTRUSION THEREOF WHEREIN THE STREAMS ARE COOLED INTO HARDENED FILAMENTS, AT LEAST ONE ROTATABLY MOUNTED MEMBER HAVING A CONTINUOUS HELICAL RIB PROJECTING THEREFROM AND EXTENDING LONGITUDINALLY THEREOF, SAID MEMBER BEING POSITIONED WITHIN SAID CHAMBER IN THE YARN PATH AT A POINT WHERE THE
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3124628D US3124628A (en) | 1960-11-07 | Method for producing twisted | |
US67658A US3067461A (en) | 1960-11-07 | 1960-11-07 | Apparatus for producing twisted filament yarn |
GB37394/61A GB923160A (en) | 1960-11-07 | 1961-10-18 | Method and apparatus for producing twisted filament yarn |
DE19611435388 DE1435388A1 (en) | 1960-11-07 | 1961-10-25 | Method and device for the production of twisted threads |
FR877745A FR1305781A (en) | 1960-11-07 | 1961-11-02 | Method and apparatus for producing a twisted filament yarn |
CH1269561A CH382912A (en) | 1960-11-07 | 1961-11-02 | Method of producing a twisted filament yarn and apparatus for its implementation |
DK441261AA DK103249C (en) | 1960-11-07 | 1961-11-06 | Method and apparatus for making melt-spun, continuous filaments with permanent twist. |
BE610052A BE610052A (en) | 1960-11-07 | 1961-11-07 | A method and apparatus for producing a twisted filament yarn. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US67658A US3067461A (en) | 1960-11-07 | 1960-11-07 | Apparatus for producing twisted filament yarn |
Publications (1)
Publication Number | Publication Date |
---|---|
US3067461A true US3067461A (en) | 1962-12-11 |
Family
ID=22077499
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US3124628D Expired - Lifetime US3124628A (en) | 1960-11-07 | Method for producing twisted | |
US67658A Expired - Lifetime US3067461A (en) | 1960-11-07 | 1960-11-07 | Apparatus for producing twisted filament yarn |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US3124628D Expired - Lifetime US3124628A (en) | 1960-11-07 | Method for producing twisted |
Country Status (6)
Country | Link |
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US (2) | US3067461A (en) |
BE (1) | BE610052A (en) |
CH (1) | CH382912A (en) |
DE (1) | DE1435388A1 (en) |
DK (1) | DK103249C (en) |
GB (1) | GB923160A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3287888A (en) * | 1963-11-12 | 1966-11-29 | Monsanto Co | Apparatus for the treatment of synthetic filaments |
US3367100A (en) * | 1965-06-23 | 1968-02-06 | Monsanto Co | Multifilament yarn having individually twisted filaments |
US4607483A (en) * | 1985-04-01 | 1986-08-26 | Warner-Lambert Company | Method and apparatus for twisting and advancing strand material |
CN108570721A (en) * | 2018-06-25 | 2018-09-25 | 张家港市金星纺织有限公司 | A kind of preparation facilities of polypropylene fibre |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB984922A (en) * | 1963-02-02 | 1965-03-03 | British Nylon Spinners Ltd | Improvements in or relating to drawing and crimping synthetic polymer filaments |
US3457338A (en) * | 1964-09-21 | 1969-07-22 | Dow Chemical Co | Process for crimping polypropylene filaments |
US3526689A (en) * | 1968-04-03 | 1970-09-01 | Union Carbide Corp | Fused multifilament round spandex yarn |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2086651A (en) * | 1934-11-02 | 1937-07-13 | Ubbelohde Leo | Method and apparatus for making artificial silk and the like |
US2150354A (en) * | 1935-03-27 | 1939-03-14 | Berndt Karl | Method and apparatus for simultaneously spinning and twisting artificial threads |
US2328074A (en) * | 1940-07-16 | 1943-08-31 | Du Pont | Manufacture of textile yarn |
US2347036A (en) * | 1939-07-08 | 1944-04-18 | Dumont Eugen | Process for the production of filaments from molten thermoplastic materials |
US2708813A (en) * | 1948-06-01 | 1955-05-24 | Saint Gobain | Method of and apparatus for producing glass fibers |
US2874410A (en) * | 1954-06-30 | 1959-02-24 | Du Pont | Apparatus for uniformly drawing a plurality of filaments |
US2920346A (en) * | 1957-08-09 | 1960-01-12 | Jori Luciano | Thread stretching device for wet spinning more particularly of viscose rayon |
US2957747A (en) * | 1958-07-22 | 1960-10-25 | Du Pont | Process for producing crimpable polyamide filaments |
US3010145A (en) * | 1956-03-08 | 1961-11-28 | Rolfsen Ole | Method and apparatus for producing ball-like nodules of fine-grained ores and minerals |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2509845A (en) * | 1942-12-09 | 1950-05-30 | Owens Corning Fiberglass Corp | Apparatus for forming ribbons of glass and other thermoplastic materials |
-
0
- US US3124628D patent/US3124628A/en not_active Expired - Lifetime
-
1960
- 1960-11-07 US US67658A patent/US3067461A/en not_active Expired - Lifetime
-
1961
- 1961-10-18 GB GB37394/61A patent/GB923160A/en not_active Expired
- 1961-10-25 DE DE19611435388 patent/DE1435388A1/en active Pending
- 1961-11-02 CH CH1269561A patent/CH382912A/en unknown
- 1961-11-06 DK DK441261AA patent/DK103249C/en active
- 1961-11-07 BE BE610052A patent/BE610052A/en unknown
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2086651A (en) * | 1934-11-02 | 1937-07-13 | Ubbelohde Leo | Method and apparatus for making artificial silk and the like |
US2150354A (en) * | 1935-03-27 | 1939-03-14 | Berndt Karl | Method and apparatus for simultaneously spinning and twisting artificial threads |
US2347036A (en) * | 1939-07-08 | 1944-04-18 | Dumont Eugen | Process for the production of filaments from molten thermoplastic materials |
US2328074A (en) * | 1940-07-16 | 1943-08-31 | Du Pont | Manufacture of textile yarn |
US2708813A (en) * | 1948-06-01 | 1955-05-24 | Saint Gobain | Method of and apparatus for producing glass fibers |
US2874410A (en) * | 1954-06-30 | 1959-02-24 | Du Pont | Apparatus for uniformly drawing a plurality of filaments |
US3010145A (en) * | 1956-03-08 | 1961-11-28 | Rolfsen Ole | Method and apparatus for producing ball-like nodules of fine-grained ores and minerals |
US2920346A (en) * | 1957-08-09 | 1960-01-12 | Jori Luciano | Thread stretching device for wet spinning more particularly of viscose rayon |
US2957747A (en) * | 1958-07-22 | 1960-10-25 | Du Pont | Process for producing crimpable polyamide filaments |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3287888A (en) * | 1963-11-12 | 1966-11-29 | Monsanto Co | Apparatus for the treatment of synthetic filaments |
US3367100A (en) * | 1965-06-23 | 1968-02-06 | Monsanto Co | Multifilament yarn having individually twisted filaments |
US4607483A (en) * | 1985-04-01 | 1986-08-26 | Warner-Lambert Company | Method and apparatus for twisting and advancing strand material |
CN108570721A (en) * | 2018-06-25 | 2018-09-25 | 张家港市金星纺织有限公司 | A kind of preparation facilities of polypropylene fibre |
Also Published As
Publication number | Publication date |
---|---|
US3124628A (en) | 1964-03-10 |
DK103249C (en) | 1965-12-06 |
DE1435388A1 (en) | 1968-11-07 |
CH382912A (en) | 1964-10-15 |
BE610052A (en) | 1962-05-07 |
GB923160A (en) | 1963-04-10 |
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