US2993804A - Surface treatment for metal coated objects - Google Patents

Surface treatment for metal coated objects Download PDF

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Publication number
US2993804A
US2993804A US799112A US79911259A US2993804A US 2993804 A US2993804 A US 2993804A US 799112 A US799112 A US 799112A US 79911259 A US79911259 A US 79911259A US 2993804 A US2993804 A US 2993804A
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metal
coating
coated
spangles
coating metal
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US799112A
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Yonezaki Shigeru
Obu Misao
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Yawata Iron and Steel Co Ltd
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Yawata Iron and Steel Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
    • C23C2/285—Thermal after-treatment, e.g. treatment in oil bath for remelting the coating

Definitions

  • the present invention relates to surface treatment for metal coated objects, and, more particularly, to a method of treating the surface of metal objects coated with another metal by the hot dip process so as to impart thereto excellent paint or lacquer adherence as well as good appearance.
  • metal objects coated with another metal are often coated with a liquid coating material, such as, paint or lacquer in order to improve appearance as well as corrosion resistance.
  • a liquid coating material such as, paint or lacquer
  • various processes of surface treatment for example, phosphatizing, galvannealing, and abrading by means of mechanical Wipers, etc., with a view to eliminating especially the so called spangle on the coated metal surface.
  • the invention comprises fusing the surface of a metal article which has been coated by another metal by the conventional hot dip process, and spraying gas thereto, and, alternatively, spraying simply either a gas flame or a hot gas thereto so as to effect fusing and gas spraying simultaneously.
  • this treatment lacquer or paint adherence to the treated metal surface increases considerably so that peeling off of coating films from the coated metal surface is prevented and a uniform smooth lacquer or paint coated metal surface free from spangles is obtained. It is believed that the above features have been brought about by the fact that the coated metal surface treated by the process of our invention has been covered with a large number of uniform microindentations into which lacquer or paint permeates thoroughly so as to increase adhesion thereof. In addition, the bonding strength between the coating metal layer and the surface of base metal to be coated is remarkably improved by this treatment.
  • the invention comprises applying gas at a perpendicular or oblique direction onto the coated metal surface in such manner that spangles on the metal surface are fused and innumerable uniform micro-indentations are produced thereon without formation of any spangle.
  • a gas flame may be applied to the surface of coated metal objects at a perpendicular or oblique direction so that fusing of metal surface and application of gas flame may be performed simultaneously.
  • hot gas heated by electric resistance or other heating means may be sprayed onto the metal surface to be treated.
  • Hot dip coated metal article having spangles thereon Heating to temp. above melting temp. of coating metal Spraying gas flame onto surface of coating metal at temp. GOO-1000 O. and press 1000-4000 mm. H20 for 2-60 see.
  • this treatment is performed at the time immediately after emergence of the coated metal out of the molten coating metal bath when spangles are being formed on the surface thereof, but this treatment may be applied to any coated metal product which has been already coated with another metal long before.
  • a period of time required for this treatment may vary according to the shape of a coated metal article and the thickness of coating metal layer, but, in general, a period of time between 2 seconds and one minute is suflicient for treating galvanized iron sheet and strip to obtain the desired effect.
  • a temperature for this treatment may vary according to the kind of a coating metal, the shape of coated metal article, and the thickness of coating metal layer, but a temperature between the melting point of coating metal and 250 C. above thereof may be preferred. A much higher temperature than that may be preferred if a short time treatment is desired.
  • the pressure of gas to be applied is preferably controlled according to the tempera- Example 1
  • the coating metal on the surface of ferrous strip cools and solidifies to form spangles on the surface thereof.
  • the surface of coated ferrous strip is treated with the flame of coke oven gas having the static pressure of 1300 mm. water column at a temperature of about 600 C.
  • Paint or lacquer adherence of the above treated zinc-coated ferrous product has been found to be excellent. Comparative test has been conducted on the paint or lacquer adherence of treated, non-treated, and phosphate treated zinc-coated ferrous product, respectively. Test has shown that paint adhesion of treated zinc-coated sheet corresponds almost to that of phosphate treated one, and paint adherence has increased by about 30-50% in the treated one greater than the non-treated. In addition, the appearance of treated and painted zinccoated sheet or strip is much smoother and more beautiful than the non-treated.
  • Example 2 Galvanized iron sheet produced by theconventional hot dip process which comprises subjecting the sheet to removing grease, pickling, flux treatment, dipping in the molten zinc bath, and then to conductor roll has been in the storage for a considerable period of time, and this galvanized iron sheet is treated with the cracked ammonia gas (its static pressure: 3000 mm. water column) at a temperature of 650 C. for a period of 10 seconds.
  • the cracked ammonia gas its static pressure: 3000 mm. water column
  • paint or lacquer adhesion to the treated galvanized iron sheet has increased by 20-40%
  • the appearance of treated and painted galvanized iron sheet is much smoother and more beautiful than the non-treated and painted one.
  • Example 3 An aluminum-coated steel sheet which has been in the storage for a considerable period of time is treated it accordance with the invention with .a coke oven gas flame (its static pressure: 1300 mm. Water column) at a temperature of 800 C. for a period of 5 seconds. By this treatment, paint or lacquer adhesion to the treated aluminum-coated steel sheet has improved lay 20-30%.
  • a method of treating the surface of a metal article hot dip coated with another metal, the surface of the coating metal having spangles thereon, comprising heating said metal article to a temperature above the melting point of said coating metal and spraying a gas flame onto the surface of the coating metal at an angle thereto and over the entire surface of the coating metal at a temperature between 600 and 1000 C. at a pressure of from 1000 to 4000 mm. of water and for a period of from 2 to 60 seconds, whereby spangles on said coating metal surface are fused and innumerable micro-indentations are formed thereon and an improved appearance and paint adherence is obtained on said coating metal surface.
  • a method of treating the surface of a metal article hot dip coated with another metal, the surface of the coating metal having spangles thereon comprising spraying a gas flame at a temperature above the melting point of said coating metal onto the surface of the coating metal at an angle thereto and over the entire surface of the coating metal at a pressure of from about 1000 to 4000 mm. of water for a period of from 2 to 60 seconds, whereby the simultaneous heating and gas flame impingement cause the spangles on the coating metal surface to be fused and innumerable micro-indentations are formed in the surface and an improved appearance and paint adherence is obtained on said coating metal surface.
  • a method of treating the surface of a steel strip coated with zinc by a hot dip process comprising cooling the zinc coated steel strip after it emerges from the molten zinc bath until spangles form on the surface of the zinc coating, and immediately directing a coke oven gas flame against the thus cooled strip at a static pressure of from 1000 to 1500 mm. of water and a temperature of from 400 to 800 C. for a period of from 2 seconds to one minute, whereby the spangles on the zinc coating are fused and innumerable micro-indentations are formed in the zinc coating, and an improved appearance and paint adherence is obtained for the Zinc coating.
  • a method of treating the surface of a ferrous sheet coated with Zinc by a hot dip process, the zinc coating having spangles on the surface thereof, comprising directing a cracked ammonia gas flame against the sheet at a static pressure of from 2000 to 4000 mm. of water and at a temperature of from 500 to 750 C. for a period of from 2 seconds to one minute, whereby the spangles on the zinc coating are fused and innumerable micro-indentations are formed therein, and improved appearance and paint adherence are obtained for said zinc coating.
  • a method of treating the surface of a ferrous sheet coated with aluminum by a hot dip process, the aluminum coating having spangles on the surface thereof, comprising directing a coke oven gas flame against said sheet at a static pressure of from 1000 to 1500 mm. of Water, at a temperature of from 500 to 1000 C. and for a period of from 2 seconds to one minute, whereby the spangles on the aluminum coating are fused and innumerable micro-indentations are formed therein, and improved appearance and paint adherence are obtained for said aluminum coating.

Description

nited States The present invention relates to surface treatment for metal coated objects, and, more particularly, to a method of treating the surface of metal objects coated with another metal by the hot dip process so as to impart thereto excellent paint or lacquer adherence as well as good appearance.
In general, metal objects coated with another metal are often coated with a liquid coating material, such as, paint or lacquer in order to improve appearance as well as corrosion resistance. However, it is frequent that the liquid coating material is unable to adhere firmly to the surface of metal objects coated with another metal when it is directly applied to the metal surface without any surface treatment. With the above object in view, there have been proposed various processes of surface treatment, for example, phosphatizing, galvannealing, and abrading by means of mechanical Wipers, etc., with a view to eliminating especially the so called spangle on the coated metal surface.
Briefly, the invention comprises fusing the surface of a metal article which has been coated by another metal by the conventional hot dip process, and spraying gas thereto, and, alternatively, spraying simply either a gas flame or a hot gas thereto so as to effect fusing and gas spraying simultaneously. By this treatment, lacquer or paint adherence to the treated metal surface increases considerably so that peeling off of coating films from the coated metal surface is prevented and a uniform smooth lacquer or paint coated metal surface free from spangles is obtained. It is believed that the above features have been brought about by the fact that the coated metal surface treated by the process of our invention has been covered with a large number of uniform microindentations into which lacquer or paint permeates thoroughly so as to increase adhesion thereof. In addition, the bonding strength between the coating metal layer and the surface of base metal to be coated is remarkably improved by this treatment.
The invention comprises applying gas at a perpendicular or oblique direction onto the coated metal surface in such manner that spangles on the metal surface are fused and innumerable uniform micro-indentations are produced thereon without formation of any spangle. Accordingly, as an appropriate process of treatment embodying our invention to meet the above requirement, a gas flame may be applied to the surface of coated metal objects at a perpendicular or oblique direction so that fusing of metal surface and application of gas flame may be performed simultaneously. It is to be understood that hot gas heated by electric resistance or other heating means may be sprayed onto the metal surface to be treated. A simplified flow diagram of the process is as follows:
Hot dip coated metal article having spangles thereon Heating to temp. above melting temp. of coating metal Spraying gas flame onto surface of coating metal at temp. GOO-1000 O. and press 1000-4000 mm. H20 for 2-60 see.
atent 2,093,804 Patented J uly' 25, 1 961' In reference to the time when the treatment of the invention should be carried out, it is preferable that this treatment is performed at the time immediately after emergence of the coated metal out of the molten coating metal bath when spangles are being formed on the surface thereof, but this treatment may be applied to any coated metal product which has been already coated with another metal long before. A period of time required for this treatment may vary according to the shape of a coated metal article and the thickness of coating metal layer, but, in general, a period of time between 2 seconds and one minute is suflicient for treating galvanized iron sheet and strip to obtain the desired effect.
If the heating time is too prolonged, an alloy layer between coating metal and base metal will develop, which results in disadvantage.
A temperature for this treatment may vary according to the kind of a coating metal, the shape of coated metal article, and the thickness of coating metal layer, but a temperature between the melting point of coating metal and 250 C. above thereof may be preferred. A much higher temperature than that may be preferred if a short time treatment is desired. The pressure of gas to be applied is preferably controlled according to the tempera- Example 1 On removing the coated ferrous strip from themolten coating metal bath 'by the Sendzimir process, the coating metal on the surface of ferrous strip cools and solidifies to form spangles on the surface thereof. Immediately thereafter, the surface of coated ferrous strip is treated with the flame of coke oven gas having the static pressure of 1300 mm. water column at a temperature of about 600 C. for a period of 5 seconds, which results in a zinccoated ferrous strip free from spangles having a large number of very fine micro-indentations all over the surface thereof. Paint or lacquer adherence of the above treated zinc-coated ferrous product has been found to be excellent. Comparative test has been conducted on the paint or lacquer adherence of treated, non-treated, and phosphate treated zinc-coated ferrous product, respectively. Test has shown that paint adhesion of treated zinc-coated sheet corresponds almost to that of phosphate treated one, and paint adherence has increased by about 30-50% in the treated one greater than the non-treated. In addition, the appearance of treated and painted zinccoated sheet or strip is much smoother and more beautiful than the non-treated.
Example 2 Galvanized iron sheet produced by theconventional hot dip process which comprises subjecting the sheet to removing grease, pickling, flux treatment, dipping in the molten zinc bath, and then to conductor roll has been in the storage for a considerable period of time, and this galvanized iron sheet is treated with the cracked ammonia gas (its static pressure: 3000 mm. water column) at a temperature of 650 C. for a period of 10 seconds. By this treatment, paint or lacquer adhesion to the treated galvanized iron sheet has increased by 20-40% In addition, the appearance of treated and painted galvanized iron sheet is much smoother and more beautiful than the non-treated and painted one.
Example 3 An aluminum-coated steel sheet which has been in the storage for a considerable period of time is treated it accordance with the invention with .a coke oven gas flame (its static pressure: 1300 mm. Water column) at a temperature of 800 C. for a period of 5 seconds. By this treatment, paint or lacquer adhesion to the treated aluminum-coated steel sheet has improved lay 20-30%.
It is to be understood that the above examples are given for purposes of illustration only, and are not to be considered as limiting the invention to any of the specific conditions or materials given therein.
We claim:
l. A method of treating the surface of a metal article hot dip coated with another metal, the surface of the coating metal having spangles thereon, comprising heating said metal article to a temperature above the melting point of said coating metal and spraying a gas flame onto the surface of the coating metal at an angle thereto and over the entire surface of the coating metal at a temperature between 600 and 1000 C. at a pressure of from 1000 to 4000 mm. of water and for a period of from 2 to 60 seconds, whereby spangles on said coating metal surface are fused and innumerable micro-indentations are formed thereon and an improved appearance and paint adherence is obtained on said coating metal surface.
2. A method of treating the surface of a metal article hot dip coated with another metal, the surface of the coating metal having spangles thereon, comprising spraying a gas flame at a temperature above the melting point of said coating metal onto the surface of the coating metal at an angle thereto and over the entire surface of the coating metal at a pressure of from about 1000 to 4000 mm. of water for a period of from 2 to 60 seconds, whereby the simultaneous heating and gas flame impingement cause the spangles on the coating metal surface to be fused and innumerable micro-indentations are formed in the surface and an improved appearance and paint adherence is obtained on said coating metal surface.
3. A method of treating the surface of a steel strip coated with zinc by a hot dip process, comprising cooling the zinc coated steel strip after it emerges from the molten zinc bath until spangles form on the surface of the zinc coating, and immediately directing a coke oven gas flame against the thus cooled strip at a static pressure of from 1000 to 1500 mm. of water and a temperature of from 400 to 800 C. for a period of from 2 seconds to one minute, whereby the spangles on the zinc coating are fused and innumerable micro-indentations are formed in the zinc coating, and an improved appearance and paint adherence is obtained for the Zinc coating.
4. A method of treating the surface of a ferrous sheet coated with Zinc by a hot dip process, the zinc coating having spangles on the surface thereof, comprising directing a cracked ammonia gas flame against the sheet at a static pressure of from 2000 to 4000 mm. of water and at a temperature of from 500 to 750 C. for a period of from 2 seconds to one minute, whereby the spangles on the zinc coating are fused and innumerable micro-indentations are formed therein, and improved appearance and paint adherence are obtained for said zinc coating.
5. A method of treating the surface of a ferrous sheet coated with aluminum by a hot dip process, the aluminum coating having spangles on the surface thereof, comprising directing a coke oven gas flame against said sheet at a static pressure of from 1000 to 1500 mm. of Water, at a temperature of from 500 to 1000 C. and for a period of from 2 seconds to one minute, whereby the spangles on the aluminum coating are fused and innumerable micro-indentations are formed therein, and improved appearance and paint adherence are obtained for said aluminum coating.
References Cited in the file of this patent UNITED STATES PATENTS 794,704 Fellows et a1 July 11, 1905 811,854 Lee Feb. 6, 1906 1,673,624 Howe June 12, 1928 1,732,504 Davis Oct. 22, 1929 1,936,487 Schueler Nov. 21, 1933 2,034,348 Lytle Mar. 17, 1936 2,332,978 Ahern Oct. 26, 1943' 2,708,171 Inglefield -4- May 10, 1955 2,930,106 Wrotnowski Mar. 29, 1960 FOREIGN PATENTS 352,911 Great Britain Jan. 9, 1930

Claims (1)

1. A METHOD OF TREATING THE SURFACE OF A METAL ARTICLE HOT DIP COATED WITH ANOTHER METAL, THE SURFACE OF THE COATING METAL HAVING SPANGLES THEREON, COMPRISING HEATING SAID METAL ARTICLE TO A TEMPERATURE ABOVE THE MELTING POINT OF SAID COATING METAL AT AN ANGLE THERETO AND THE SURFACE OF THE COATING METAL AT AN ANGLE THERETO AND OVER THE ENTIRE SURFACE OF THE COATING METAL AT A TEMPERATURE BETWEEN 600* AND 1000* C. AT A PRESSURE OF FROM 1000 TO 4000 MM. OF WATER AND FOR A PERIOD OF FROM 2 TO 60 SECONDS, WHEREBY SPANGLES ON SAID COATING METAL SURFACE ARE FUSED AND IMUMERABLE MICRO-INDENTATIONS ARE FORMED THEREON AND AN IMPROVED APPEARANCE AND PAINT ADHERENCE IS OBTAINED ON SAID COATING METAL SURFACE.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3165844A (en) * 1962-06-19 1965-01-19 Landers Frary & Clark Steam iron
US3260577A (en) * 1961-12-20 1966-07-12 Nat Steel Corp Coated product and its manufacture

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US794704A (en) * 1904-09-29 1905-07-11 Olin S Fellows Means for removing superfluous metallic coating from sheet metal.
US811854A (en) * 1903-08-18 1906-02-06 John Lee Process of tinning or coating metal sheets with tin or other metallic coatings.
US1673624A (en) * 1925-01-02 1928-06-12 Gen Electric Treatment of metals
US1732504A (en) * 1925-02-12 1929-10-22 Charles A Davis Method and apparatus for coating
GB352911A (en) * 1929-01-10 1931-07-16 Georges Boutefeu A process for plating with tin and other materials
US1936487A (en) * 1932-03-07 1933-11-21 Julian L Schueler Art of continuous galvanizing
US2034348A (en) * 1930-09-03 1936-03-17 Lytle Clark Kenneth Nonspangled galvanized sheet
US2332978A (en) * 1939-11-08 1943-10-26 Frank J Ahern Apparatus for hot dip coating of metals
US2708171A (en) * 1952-07-08 1955-05-10 United States Steel Corp Method of controlling coating thickness in continuous galvanizing
US2930106A (en) * 1957-03-14 1960-03-29 American Felt Co Gaskets

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US811854A (en) * 1903-08-18 1906-02-06 John Lee Process of tinning or coating metal sheets with tin or other metallic coatings.
US794704A (en) * 1904-09-29 1905-07-11 Olin S Fellows Means for removing superfluous metallic coating from sheet metal.
US1673624A (en) * 1925-01-02 1928-06-12 Gen Electric Treatment of metals
US1732504A (en) * 1925-02-12 1929-10-22 Charles A Davis Method and apparatus for coating
GB352911A (en) * 1929-01-10 1931-07-16 Georges Boutefeu A process for plating with tin and other materials
US2034348A (en) * 1930-09-03 1936-03-17 Lytle Clark Kenneth Nonspangled galvanized sheet
US1936487A (en) * 1932-03-07 1933-11-21 Julian L Schueler Art of continuous galvanizing
US2332978A (en) * 1939-11-08 1943-10-26 Frank J Ahern Apparatus for hot dip coating of metals
US2708171A (en) * 1952-07-08 1955-05-10 United States Steel Corp Method of controlling coating thickness in continuous galvanizing
US2930106A (en) * 1957-03-14 1960-03-29 American Felt Co Gaskets

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3260577A (en) * 1961-12-20 1966-07-12 Nat Steel Corp Coated product and its manufacture
US3165844A (en) * 1962-06-19 1965-01-19 Landers Frary & Clark Steam iron

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