US2989476A - Ferrite with constricted magnetic hysteresis loop - Google Patents

Ferrite with constricted magnetic hysteresis loop Download PDF

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Publication number
US2989476A
US2989476A US620315A US62031556A US2989476A US 2989476 A US2989476 A US 2989476A US 620315 A US620315 A US 620315A US 62031556 A US62031556 A US 62031556A US 2989476 A US2989476 A US 2989476A
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ferrite
weight
oxide
hysteresis loop
nickel
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Eckert Oskar
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Steatit Magnesia AG
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Steatit Magnesia AG
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/26Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on ferrites
    • C04B35/2608Compositions containing one or more ferrites of the group comprising manganese, zinc, nickel, copper or cobalt and one or more ferrites of the group comprising rare earth metals, alkali metals, alkaline earth metals or lead
    • C04B35/2625Compositions containing one or more ferrites of the group comprising manganese, zinc, nickel, copper or cobalt and one or more ferrites of the group comprising rare earth metals, alkali metals, alkaline earth metals or lead containing magnesium
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/26Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on ferrites
    • C04B35/265Compositions containing one or more ferrites of the group comprising manganese or zinc and one or more ferrites of the group comprising nickel, copper or cobalt

Definitions

  • Ferromagnetic metals with constricted hysteresis loops have, as is well known, at small field strength within the constriction area, constant permeability, i.e., permeability independent of the field strength equal to the initial permeability, very low hysteresis losses and, in general, small residual losses.
  • thermomagnetic treatment in this connection, is meant the passing through a thermic cycle during the simultaneous presence of a magnetic longitudinal or transverse field.
  • longitudinal or transverse field is, in this connection, to be understood as relative to the later measuring field; a longitudinal or transverse field, respectively, means that such field, during the thermomagnetic treatment, is parallel, respectively vertical, to the later measuring field.
  • T hm this type of treatment, these ferromagnetic materials display a substantial alteration of the form of the hysteresis loop, and hence a change ofthe magnetic properties.
  • the invention teaches the production of such fern'tes of thenickel-copper or nickel-magnesium ferrite-systen. which can be subjected to thermomagnetic treatment of the above type, and are distinguished from hitherto familiar ferrites by the fact that, under the same manufacturing conditions, they have constricted hysteresis loops.
  • ferrites with this characteristic in the nickel-copper or nickel-magnesium-ferritesystem must have a composition of at least 50 mol percent Fe O and a small addition of cobalt oxide.
  • the addition of cobalt oxide is suitably determined between. 0.1 and 5% by weight, calculated on the total basic batch of the nickel-copper or nickel-magnesium-ferrite, expressed in metallic oxides. The invention has shown that it is par-.
  • the above ferrites may be prepared in the usual way, either by joint or partial precipitation, from correspondingmetal salt solutions, or, as is customary in ceramic arts, they may be prepared for further processing by wet milling and mixing of the respective metal oxides.
  • the powdered mixtures thus obtained may after drying be given the desired form either immediately by dry pressing, extruding, or similar methods, or it may be desirable, before ceramic forming, to proceed with a calcining firing of the entire composition or only a part thereof, prefer-ably between 750 C. and 1100 C. for the Ni-Cu ferrite or 750 C. and 1250" C. for the Ni-Mg ferrite.
  • the resultant parts are sintered, depending on the composition, in a suitable way between 1180 C. and 1350 C. for the Ni-Cu ferrite or 1250 C. and 1400 C. for the Ni-Mg ferrite system.
  • the cooling takes place slowly, particularly in the temperature range between 700 C. and room temperature.
  • the cooling speed is dependent upon the volume of the fired body. As a criterion, it may be stated that for a ring of about 46 mm. outside diameter, 34 mm. inside diameter, and 10 mm. height, the cooling time from 700 C.
  • (a) for the NiO-CuO-Fe O system In a steel ball mill are ground together 387.5 g. Fe O g. NiO, 37.5 g. C010, 3.25 g. C00. After 6 hours of grinding, the slip is poured through a 4900 mesh screen (4900 meshes per square cm.) into a porcelain dish, and dried. The powder thus obtained, is pressed, according to ceramic pressing techniques, into rings having dimensions of 59 mm. outside diameter, 35.8 mm. inside diameter, and 12 mm. height, the amount of pressure applied being about 0.5 to -l t./cm.'-. The resulting ferrite pieces, are sintered in a kiln at 1320 C.
  • the rings are cooled to room temperature in the kiln during a period of approximately 24 hours.
  • the ferrite rings thus obtained are provided with 0.4 mm. copper enameled wire with windings as primary winding, and, as secondary winding, further 200 windings with 0.2 mm. copper enameled wire are applied.
  • FIG. 1a In the oscillographic photograph of this ferrite, produced in accordance with the invention, which is shown in FIG. 1a, one can distinctly recognize the loop constriction of the hysteresis loop.
  • the rings are cooled to room temperature in the kiln for a period of approximately 24 hours.
  • the ferrite rings thus obtained are provided with 0.4 mm. copper enameled wire with 100 windings as primary winding, and, as secondary winding, further 200 windings with 0.2 mm. copper enameled wire are applied.
  • the oscillogi'aphic photograph of this ferrite, produced in accordance with the invention, which is shown in FIG. 2a one can distinctly recognize the loop constriction of the hysteresis loop.
  • the ferrite toroid of the example with 100 windings as a primary winding is placed in a kiln. While heating to 600 C., and slow cooling for 12 hours to room tem perature, a longitudinal magnetic field is maintained by means of the ring winding by 1 a. direct current, corresponding to a magnetic field strength of about 15 a.- windings/cm. If the hysteresis loop of the ferrite after this thermomagnetic treatment is recorded in the same manner as described above, the result is analogous to that of metals when they are subjected to heat treatment in the longitudinal magnetic field; a complete change of the form of the hysteresis loop, as may be seen in FIGS. 1b and 2b, takes place. In analogous manner, heat treatment in the transverse magnetic field may be carried out with corresponding effect; (see the above cited book by Bozorth).
  • ferrites with distinctly rectangular hysteresis loop may be produced which are of importance to the entire fields of electronics and for magnetic amplification, for telephone and high-frequency fields;
  • ferrities of high quality and a permeability independent of field strength may be produced, which are particularly suitable for the field of telecommunication.
  • a cobalt-modified ferrite with a constricted magnetic hysteresis loop said ferrite being of the class consisting of nickel-copper-iron and nickel-magnesium-iron systems containing 0.1 to by weight of cobalt oxide, the iron oxide content of said composition being at least 50 mol percent expressed in metal oxides, said ferrite exclusive of the cobalt oxide content containing about 72.5 to 90% by weight of ferric oxide, about to 27.5% by weight of MO and the remainder consisting essentially of a metal oxide selected from the group consisting of up to by weight of CH0 and up to 22.5% by weight of MgO, said ferrite being formed by sintering at about 1180 C. to about 1400" C. and cooling the sintered ferrite from 700 C. down to room temperature over a period of at least twelve hours.
  • A 27.5% NiO, 0% CuO, 72.5% Fe O by weight
  • B 2.5% NiO, 25% CuO, 72.5% Fe O by weight
  • C 2.5% NiO, 7.5% CuO, 90% Fe O by weight
  • D l0% NiO, 0% CuO, 90% R2 0 by weight.
  • A 27.5 NiO, 0% MgO, 72.5% Fe O by weight
  • B 2.5% NiO, 22.5% MgO, F6203, by weight
  • C 2.5% NiO, 7.5% MgO, Fe o by weight
  • a process for preparing cobalt-modified ferrites selected from the class consisting of nickel-copper-iron ferrites containing at least 50 mol percent of iron oxide plus 0.1 to 5% by weight of cobalt oxide and nickelmagnesium-iron ferrites containing at least 50 mol per cent of iron oxide plus 0.1 to 5% by weight of cobalt oxide comprising intimately mixing ferric oxide, nickel oxide, cobalt oxide and an oxide selected from the group consisting of copper oxide and magnesium oxide in the proportions required to provide at least 50 mol percent of ferric oxide and 0.1 to 5% by weight of cobalt oxide the remainder being said other specified oxides, molding said powder mixture to shape, firing the molded article at about 1180 C. to about 1400 C. and thereafter slowly cooling the fired body from 700 C. down to room temperature over a period of at least about 12 hours to provide a ferrite body having a constricted hysteresis loop.
  • Bozorth Physical Reviews, Sept. 15, 1955, p. 1792.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Magnetic Ceramics (AREA)
US620315A 1955-10-29 1956-11-05 Ferrite with constricted magnetic hysteresis loop Expired - Lifetime US2989476A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE849464X 1955-10-29
DEST10528A DE1057256B (de) 1955-10-29 1955-11-10 Verfahren zur Herstellung von ferromagnetischen Ferritkoerpern mit eingeschnuerter Hystereseschleife

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DE (1) DE1057256B (de)
FR (1) FR1159944A (de)
GB (1) GB849464A (de)
NL (1) NL110779C (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3100194A (en) * 1958-01-15 1963-08-06 Philips Corp Ferromagnetic material and method of making the same
US6251299B1 (en) * 1998-12-28 2001-06-26 Tdk Corporation Magnetic material, inductance element using the same and manufacturing method thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL252610A (de) * 1959-06-17
NL272060A (de) * 1960-12-06

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE510462A (de) * 1951-04-09
US1976230A (en) * 1930-12-25 1934-10-09 Mitsubishi Electric Corp Permanent magnet and method of manufacturing same
US1997183A (en) * 1932-05-21 1935-04-09 Clarence T Rottler Sharpening tool
US2549089A (en) * 1948-12-15 1951-04-17 Rca Corp Mixed ferrite compositions, including lithium ferrite
US2568881A (en) * 1948-12-28 1951-09-25 Steatite Res Corp Ceramic parts for electrical devices having magnetic properties and method of making
US2656319A (en) * 1949-01-03 1953-10-20 Aladdin Ind Inc Magnetic core composition and method of producing the same
FR1100865A (fr) * 1954-03-05 1955-09-26 Matériaux magnétiques à base d'oxydes pour la réalisation de bandes d'enregistrement magnétique
US2723239A (en) * 1952-09-29 1955-11-08 Rca Corp Ferrospinel compositions
US2736708A (en) * 1951-06-08 1956-02-28 Henry L Crowley & Company Inc Magnetic compositions
GB748070A (en) * 1953-12-21 1956-04-18 Philips Electrical Ind Ltd Improvements in or relating to methods of manufacturing ferromagnetic cores having substantially rectangular hysteresis loops
FR1125577A (fr) * 1955-05-03 1956-11-02 Lignes Telegraph Telephon Matériaux ferromagnétiques à cycle d'hystérésis rectangulaire
US2778803A (en) * 1953-02-06 1957-01-22 Aerovox Corp Magnetically hard materials
US2860105A (en) * 1953-12-21 1958-11-11 Philips Corp Method of manufacturing ferromagnetic cores
US2886530A (en) * 1955-07-19 1959-05-12 Greger Herbert Hans Process of manufacturing ceramic ferrites

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2659698A (en) * 1949-01-03 1953-11-17 Aladdin Ind Inc Magnetic core and method for manufacturing same

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1976230A (en) * 1930-12-25 1934-10-09 Mitsubishi Electric Corp Permanent magnet and method of manufacturing same
US1997183A (en) * 1932-05-21 1935-04-09 Clarence T Rottler Sharpening tool
US2549089A (en) * 1948-12-15 1951-04-17 Rca Corp Mixed ferrite compositions, including lithium ferrite
US2568881A (en) * 1948-12-28 1951-09-25 Steatite Res Corp Ceramic parts for electrical devices having magnetic properties and method of making
US2656319A (en) * 1949-01-03 1953-10-20 Aladdin Ind Inc Magnetic core composition and method of producing the same
BE510462A (de) * 1951-04-09
US2736708A (en) * 1951-06-08 1956-02-28 Henry L Crowley & Company Inc Magnetic compositions
US2723239A (en) * 1952-09-29 1955-11-08 Rca Corp Ferrospinel compositions
US2778803A (en) * 1953-02-06 1957-01-22 Aerovox Corp Magnetically hard materials
GB748070A (en) * 1953-12-21 1956-04-18 Philips Electrical Ind Ltd Improvements in or relating to methods of manufacturing ferromagnetic cores having substantially rectangular hysteresis loops
US2860105A (en) * 1953-12-21 1958-11-11 Philips Corp Method of manufacturing ferromagnetic cores
FR1100865A (fr) * 1954-03-05 1955-09-26 Matériaux magnétiques à base d'oxydes pour la réalisation de bandes d'enregistrement magnétique
FR1125577A (fr) * 1955-05-03 1956-11-02 Lignes Telegraph Telephon Matériaux ferromagnétiques à cycle d'hystérésis rectangulaire
US2886530A (en) * 1955-07-19 1959-05-12 Greger Herbert Hans Process of manufacturing ceramic ferrites

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3100194A (en) * 1958-01-15 1963-08-06 Philips Corp Ferromagnetic material and method of making the same
US6251299B1 (en) * 1998-12-28 2001-06-26 Tdk Corporation Magnetic material, inductance element using the same and manufacturing method thereof

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FR1159944A (fr) 1958-07-03
GB849464A (en) 1960-09-28
NL110779C (de) 1965-03-15
DE1057256B (de) 1959-05-14

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