US2951750A - Fuel gas mixture for metal working - Google Patents

Fuel gas mixture for metal working Download PDF

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Publication number
US2951750A
US2951750A US811274A US81127459A US2951750A US 2951750 A US2951750 A US 2951750A US 811274 A US811274 A US 811274A US 81127459 A US81127459 A US 81127459A US 2951750 A US2951750 A US 2951750A
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United States
Prior art keywords
mixture
gas mixture
fuel gas
mixtures
metal working
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US811274A
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Samuel H White
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Priority to US811274A priority Critical patent/US2951750A/en
Priority to GB10160/60A priority patent/GB898906A/en
Priority to ES0257128A priority patent/ES257128A1/en
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Publication of US2951750A publication Critical patent/US2951750A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/38Selection of media, e.g. special atmospheres for surrounding the working area
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/76Adjusting the composition of the atmosphere
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/20Carburising
    • C23C8/22Carburising of ferrous surfaces

Definitions

  • This invention is directed to a gaseous fuel designed more particularly, :but in no wise limited to use with oxygen for welding and heating metals, preheating of metals in cutting operations, case-hardening of metals, metal spraying, lead burning, working of glass, and like purposes.
  • the primary object of the present invention is the production of a gas for the designed purpose which in its definite and essentially critical proportions produces a greater flame temperature, and materially reduces the amount of time, oxygen and gas required for any particular work in comparison with previous mixtures or bare untreated gases.
  • Another object of the invention is to provide a gaseous fuel mixture that is uniformly discharged from the storage cylinder and does not leave a residue that necessitates purging of the cylinder after use.
  • the compounded mixture of the ingredients and in the range and proportions on the basis of a sixty pound mixture are as follows: a of about 50 pounds of propane or propylene, or mixtures thereof, and traces of butane, with approximately 10 pounds of propylene oxide or a mixture of about one-half propylene oxide and onehalf diethyl ether; and a maximum of about 55 pounds of propane or propylene, or mixtures thereof, and traces of butane, with approximately 5 pounds of propylene oxide or a mixture of about one-half propylene oxide and diethyl ether.
  • the diethyl ether and propylene oxide have similar boiling points and both volatize simultaneously and enter the gas stream together.
  • the foregoing proportions are substantially 83% to 92% of the gaseous fuel, namely propane and/or propylene, with or without traces of butane, and substantially 17% to 8% of the volatile chemicals, namely propylene Patented Sept. 6, 1960 oxide or a mixture thereof with diethyl ether. It has been found that the lower proportion of chemical produces a leaner mixture whereas the higher proportion provides a richer mixture and that less than 8% of the chemicals is not effective while more than 17% is no more effective or eflicient.
  • the new gas mixture is consumed uniformly so that there is no residue and the purging operation after use of the cylinders is eliminated with the use of propylene oxide or the mixture of propylene oxide and diethyl ether.
  • the tests of the new fuel show that in use, the ignition point of the gas mixture is lowered, the flame is more intense, the flame temperature is substantially 200 F. higher than that produced by previous and conventional mixtures, there is less gas and oxygen required in the flame than in previous mixtures, and due to the lower gas and oxygen pressures required for an effective flame, the highly objectionable cupped tip can be discarded and a flush type tip used for brazing, heating, hardening and soldering since this new flame will not blow off the end of the tip when used for such purposes. Due to the higher flame temperature, the heating of the metal is about 15% faster than with prior mixtures.
  • the mixture in liquid or gaseous form, may be effectively used in steel containers, pipelines, or other conventional methods of application.
  • the method of generating a gaseous fuel for use in welding and cutting of metals, heating, hardening, and for like purposes comprising the mixing of a gaseous fuel selected from the group consisting of propane, propylene and mixtures thereof with possible traces of butane, with a volatile chemical selected from the group consisting of propylene oxide and a mixture of propylene oxide with diethyl ether in the following proportions by weight, substantially 83 to 92% gaseous fuel and substantially 17 to 8% chemical, whereby the ignition point of the gas mixture is lowered and the rate of flame propagation and the temperature of combustion of the gas is increased.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Gas Burners (AREA)

Description

United States Patent C) FUEL GAS MIXTURE FOR METAL WORKING Samuel H. White, 20137 Sherwood Ave., Detroit, Mich. No Drawing. Filed May '6, 1959, Ser. No. 811,274
1 Claim. (Cl. 48-197) This invention is directed to a gaseous fuel designed more particularly, :but in no wise limited to use with oxygen for welding and heating metals, preheating of metals in cutting operations, case-hardening of metals, metal spraying, lead burning, working of glass, and like purposes.
Various mixtures have been heretofore proposed for such purposes, particularly the mixture of propane, butane and/or propane with diethyl ether and benzine, and also other similar mixtures which while effective as compared with untreated gases, are nevertheless wanting in an ideal mixture tending to the most direct and eifective results combined with economy in use, particularly in the oxygen content of the flame, the quantity of fuel gas consumed and the necessity for an intense flame temperature necessary to rapidly do the work for which it is intended.
One disadvantage of the mixtures incorporating benzine and diethyl ether resides in the fact that benzine has a higher boiling point than diethyl ether and consequently the two do not vaporize uniformly and some benzine is left in the supply cylinder after all of the diethyl ether is drawn off. This residue necessitates purging of the cylinders after each use prior to refilling the cylinder with proper mixtures.
The primary object of the present invention is the production of a gas for the designed purpose which in its definite and essentially critical proportions produces a greater flame temperature, and materially reduces the amount of time, oxygen and gas required for any particular work in comparison with previous mixtures or bare untreated gases.
Another object of the invention is to provide a gaseous fuel mixture that is uniformly discharged from the storage cylinder and does not leave a residue that necessitates purging of the cylinder after use.
The compounded mixture of the ingredients and in the range and proportions on the basis of a sixty pound mixture are as follows: a of about 50 pounds of propane or propylene, or mixtures thereof, and traces of butane, with approximately 10 pounds of propylene oxide or a mixture of about one-half propylene oxide and onehalf diethyl ether; and a maximum of about 55 pounds of propane or propylene, or mixtures thereof, and traces of butane, with approximately 5 pounds of propylene oxide or a mixture of about one-half propylene oxide and diethyl ether. The diethyl ether and propylene oxide have similar boiling points and both volatize simultaneously and enter the gas stream together.
The foregoing proportions are substantially 83% to 92% of the gaseous fuel, namely propane and/or propylene, with or without traces of butane, and substantially 17% to 8% of the volatile chemicals, namely propylene Patented Sept. 6, 1960 oxide or a mixture thereof with diethyl ether. It has been found that the lower proportion of chemical produces a leaner mixture whereas the higher proportion provides a richer mixture and that less than 8% of the chemicals is not effective while more than 17% is no more effective or eflicient.
It is understood that the proportions given are exact and definitely critical in each range, and cannot be materially varied without sacrificing the valuable and necessary characteristics of the mixture. A lesser proportion than stated has no beneficial effect and a larger proportion tends to decrease the effectiveness of the flame. This has been proven through a long series of laboratory and practical tests and uses, which tests clearly disclosed that any material variation from the critical proportions above mentioned sacrifice one or another of the valuable and highly important results.
The new gas mixture is consumed uniformly so that there is no residue and the purging operation after use of the cylinders is eliminated with the use of propylene oxide or the mixture of propylene oxide and diethyl ether.
The tests of the new fuel show that in use, the ignition point of the gas mixture is lowered, the flame is more intense, the flame temperature is substantially 200 F. higher than that produced by previous and conventional mixtures, there is less gas and oxygen required in the flame than in previous mixtures, and due to the lower gas and oxygen pressures required for an effective flame, the highly objectionable cupped tip can be discarded and a flush type tip used for brazing, heating, hardening and soldering since this new flame will not blow off the end of the tip when used for such purposes. Due to the higher flame temperature, the heating of the metal is about 15% faster than with prior mixtures.
The mixture, in liquid or gaseous form, may be effectively used in steel containers, pipelines, or other conventional methods of application.
This mixture readily lends itself to any and all uses for which a gas of this character may or can be used, bearing in mind always that the defined proportions in the particular ranges are critical and should not be changed if the desired results are to be obtained.
Although a certain specific embodiment of the invention has been described, it is obvious that many modifications thereof are possible. The invention, therefore, is not to be restricted except insofar as is necessitated by the prior art and by the spirit of the appended claim.
That which is claimed as new is:
The method of generating a gaseous fuel for use in welding and cutting of metals, heating, hardening, and for like purposes comprising the mixing of a gaseous fuel selected from the group consisting of propane, propylene and mixtures thereof with possible traces of butane, with a volatile chemical selected from the group consisting of propylene oxide and a mixture of propylene oxide with diethyl ether in the following proportions by weight, substantially 83 to 92% gaseous fuel and substantially 17 to 8% chemical, whereby the ignition point of the gas mixture is lowered and the rate of flame propagation and the temperature of combustion of the gas is increased.
Harris Aug. 17, 1926 Deley Nov. 26, 1946
US811274A 1959-05-06 1959-05-06 Fuel gas mixture for metal working Expired - Lifetime US2951750A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US811274A US2951750A (en) 1959-05-06 1959-05-06 Fuel gas mixture for metal working
GB10160/60A GB898906A (en) 1959-05-06 1960-03-22 Fuel gas mixture
ES0257128A ES257128A1 (en) 1959-05-06 1960-04-05 Fuel gas mixture for metal working

Applications Claiming Priority (1)

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US811274A US2951750A (en) 1959-05-06 1959-05-06 Fuel gas mixture for metal working

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US2951750A true US2951750A (en) 1960-09-06

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ES (1) ES257128A1 (en)
GB (1) GB898906A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3660059A (en) * 1970-04-13 1972-05-02 Dow Chemical Co Fuel gas composition
US3989479A (en) * 1973-09-25 1976-11-02 Anne Joffre White Gaseous fuel mixture
US5236467A (en) * 1992-06-12 1993-08-17 Excellene Limited Double fortified hydrocarbon and process for making and using the same
US5380346A (en) * 1992-06-12 1995-01-10 Fritz; James E. Fortified hydrocarbon and process for making and using the same
US5632786A (en) * 1995-09-14 1997-05-27 Amoco Corporation Process and fuel for spark ignition engines
US20150034705A1 (en) * 2013-07-31 2015-02-05 Goodrich Corporation Pressure welding using propylene

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1596729A (en) * 1923-12-06 1926-08-17 Harris John Gaseous fuel
US2411759A (en) * 1944-02-04 1946-11-26 Samuel Harry White Gas mixture

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1596729A (en) * 1923-12-06 1926-08-17 Harris John Gaseous fuel
US2411759A (en) * 1944-02-04 1946-11-26 Samuel Harry White Gas mixture

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3660059A (en) * 1970-04-13 1972-05-02 Dow Chemical Co Fuel gas composition
US3989479A (en) * 1973-09-25 1976-11-02 Anne Joffre White Gaseous fuel mixture
US5236467A (en) * 1992-06-12 1993-08-17 Excellene Limited Double fortified hydrocarbon and process for making and using the same
US5380346A (en) * 1992-06-12 1995-01-10 Fritz; James E. Fortified hydrocarbon and process for making and using the same
US5632786A (en) * 1995-09-14 1997-05-27 Amoco Corporation Process and fuel for spark ignition engines
US20150034705A1 (en) * 2013-07-31 2015-02-05 Goodrich Corporation Pressure welding using propylene
US9156102B2 (en) * 2013-07-31 2015-10-13 Goodrich Corporation Pressure welding using propylene

Also Published As

Publication number Publication date
GB898906A (en) 1962-06-14
ES257128A1 (en) 1960-07-01

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