US2913695A - Electric resistance heating elements - Google Patents

Electric resistance heating elements Download PDF

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US2913695A
US2913695A US596012A US59601256A US2913695A US 2913695 A US2913695 A US 2913695A US 596012 A US596012 A US 596012A US 59601256 A US59601256 A US 59601256A US 2913695 A US2913695 A US 2913695A
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bed
elements
resistance
electric resistance
furnace
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US596012A
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Borghult Per
Haglund John Helge
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Kanthal AB
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Kanthal AB
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    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/62—Heating elements specially adapted for furnaces
    • H05B3/64—Heating elements specially adapted for furnaces using ribbon, rod, or wire heater

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  • resistance elements which have been produced in a powder metallurgical process, mainly from silicides, especially molybdenum silicide, possibly with a residue of oxides, carbides, such as silicon carbide, and borides, in which process there may be used as the metallic constituent, in addition to molybdenum, one or more of the elements Ti, Zr, V, Nb, Ta andv Cr (titanium, zirconium, vanadium, niobium (columbium), tantalum and chromium).
  • Resistance elements made of such materials have fairly limited mechanical strength characteristics which have, in the past, placed the user before the alternative of either supporting the elements at a plurality of locations, or producing the same in lengths which are frequently too short as compared to the furnace dimensions concerned. If, in accordance with the common practice in the field of metallic resistance elements, an attempt is made to support elements of the type above referred to directly upon the refractory liner of the furnaces, this will result in that the elements stick to the liner and will be pulled apart on thermal expansions occurring since they are not freely movable.
  • Such sticking in addition to the action of the silicon dioxide film, may also be caused by the fact that the material of the elements have often a tendency to react chemically with the base material while forming reaction products having softening temperatures which are lower than the operating temperature of the elements. It should be noted in this connection that this sticking is not at all tied up with the degree of refractoriness of the liner material per se.
  • the present invention has for its object to overcome the drawback referred to and mainly resides in that the resistance element, composed substantially of silicidcs, preferably molybdenum silicide, possibly with a residue of oxides, carbides and borides, is loosely supthe element.
  • the bed material may suitably consist of one or more of the following substances, viz. silicon dioxide, silicon carbide or aluminum silicate. Particularly satisfactory results have been obtained using a bed of mullite or sillimanite. It is to be understood, however, that the invention is not restricted to the employment of a bed material of this composition, since it is possible to use any desired heatresistant material having a high electric resistance. However, the bed material must consist of substances which, even at the highest operating temperature concerned, remain chemically indifferent against the material of the resistance element so that no reaction products will form.
  • the substances which, in the broadest aspect of the invention, may be comprised in the supporting bed for the resistance elements are: carbides, borides, silicides, silicates and oxides, either singly or in combination with each other.
  • the major part of the grains of the supporting bed should be spherical in shape, or should have beaded edges and corners, at least, so as to facilitate their relative mobility.
  • the grains should be screened into defin'ite granular fractions through different screens sized, for instance, according to the Tyler standard screen scale, it being preferable that the grains of each bed should be of one single granular fraction ranging, for instance, between two adjacent mesh numbers, or should be of two adjacent granular fractions, at least, for instance one fraction having grain sizes ranging from 6 to 8 mesh, and one adjacent fraction having grain sizes ranging from 4 to 6 mesh. It is understood, of course, that the average grain size should be so selected as to afford satisfactwice the average diameter of the grains contained in the bed.
  • the grain sizes of the bed particles should range between a minimum of 0.004" and a maximum of 0.4 (0.1 to 10 mm.).
  • the elements can be used also in conjunction with furnace liners which, when directly contacted by the elements, would subject the elements to destructive actions.
  • the present invention makes it possible to use refractory liner materials of a standard quality selected exclusively taking into account its refractoriness while disregarding any tendency of the material to react chemically with the element material at elevated temperatures.
  • Fig. 1 is a vertical section through the bottom portion of a furnace whereas Fig. 2 is a corresponding plan view shown partly broken away;
  • Figs. 3 and 4 are perspective scrap views showing a resistance element disposed on shelves formed on the internal wall surfaces of a furnace;
  • Fig. 5 is a side elevational view
  • Fig. 6 is a top end view of a supporting tube for a horizontally extending resistance element, while Figs. 7 and 8 are cross-sections taken along the lines VII--VII and VHF-VIII, respectively, in Fig. 5;
  • Fig. 9 is a top plan view of the lower half of the refractory liner of a tube-type furnace.
  • Fig. 10 is a cross-section through the refractory liner, taken along the line X--X in Fig. 9.
  • the bottom 1 and side walls 2 to 5 of the furnace are made of a refractory material.
  • a heating resistnace element 7 consisting of 95% molybdenum silicide (Mosi the balance to 100% consisting of oxides and silicates.
  • the resistance element is formed at its ends with enlarged terminal portions 8a, 8b passed through holes made in the wall 2.
  • the high-temperature heating zone proper of the element 7 is formed by the smaller-diameter part thereof whereas its terminal portions 8a, 3b will be at a considerably reduced temperature due to their larger cross-sectional area.
  • the resistance element 7 is composed of 90% by weight of MoSi 5% by weight of chromium boride (CrB), the balance being I resistance element.
  • CrB chromium boride
  • the refractory wall 10' is disposed as a liner on the internal surface of a supporting brick wall 11 and is formed on its surface facing the furnace chamber with shelves 12, 13, etc. Disposed on these shelves are granular beds 14, 15, etc., and resting on the latter are two branches 7a, 7b, respectively, of the resistance element. These branches are interconnected by a cantilevered intervening portion 7c.
  • Fig. 3 illustrates the enlarged terminal portions 8c and 8d of the resistance element.
  • the resistance element 21 being bent into a hairpin-like configuration, rests on a supporting bed of a granular, electrically insulating material disposed in the tube 20, this material being refractory and chemically resistant to the material of the resistance element, also at the operating temperature concerned.
  • the electric resistance of the bed 31 should be sufficiently high to prevent the formation of any noticeable leakage currents.
  • the material of the bed as mentioned hereinbefore, has a refractoriness such as to allow the grains to conserve their relative mobility even at the highest temperatures concerned thereby providing for flee thermal expansion and contraction lengthwise of the resistance element relative to the supporting tube.
  • the enlarged terminal portions 25 of the resistance element 21 are passed out through, and fill out, holes made in a plug 26 of ceramic material inserted in the corresponding end of the tube 20.
  • numeral 40 designates the upper and 41 the lower half of the ceramic liner.
  • Designated by 42 is a ceramic tube which is inserted in the furnace liner and defines the furnace chamber 43.
  • Formed in the lower half 40 of the furnace liner are a plurality-six in number in the embodiment illustrated-axially extending open channel-grooves 44 each of which forms a shelf.
  • Disposed on the bottom portion of each such groove or shelf 44 is a supporting bed 45 consisting of a granular electrically insulating material which is refractory and chemically resistant to the material of the resistance element also at the operating temperature concerned, as stated hereinbefore.
  • the straight-lined portions 46 of a looped resistance element which is bent longitudinally at intervals against a cylindrical surface.
  • the uppermost two grooves or shelves 44 are formed in the parting interface between the upper and lower halves 40 and 41, respectively, of the, liner.
  • the terminal portions 47 of the resistance elementthe cross-sectional area of which is larger than that of the resistance conductor proper, 46, are introduced through holes made in the rear wall 48 of the furnace.
  • the furnace entrance opening Disposed in the front wall 49 of the furnace is the furnace entrance opening.
  • the latter may be closed, in the conventional manner, by a furnace door which is not shown in the figure.
  • the looped resistance element should be placed in the grooves 44 before the ceramic tube 42 is moved longitudinally into its operative position.
  • the resistance loop can conveniently be removed for replacement or repair after first withdrawing the tube 42 from the furnace.
  • Electrical heating apparatus comprising an electrical resistance heating element, and a bed of freely flowable refractory material grains having an electrical conductivity lower than that of the resistance element and chemically resistant to the material of said resistance element, said element resting uncovered upon the upper surface of said bed in contact with said refractory material grains, and said bed being operative to support said element throughout substantially the full length thereof, and to simultaneously accommodate movement thereof due to temperature-change induced expansion and contraction.
  • heating element consists essentially of heat resistant and oxidation proof silicides.
  • heating element consists essentially of molybdenum disilicide
  • the bed material consists essentially of one or more of the materials in the group consisting of heat-resistant carbides, borides, silicates, silicides and/ or oxides.
  • the bed material comprises one or more of the following substances: silicon dioxide, sillimanite and mullite.
  • the heating element consists essentially of heat resistant and oxidation proof silicides
  • the bed material consists essentially of one or more of the materials in the group consisting of heat-resistant carbides, borides, silicates, silicides and/or oxides, said bed material including one or more of the following substances: silicon dioxide, sillimanite and mullite.
  • heating element consists essentially of molybdenum disilicide
  • bed material consists essentially of sillimanite and mullite.
  • the heating element is adapted for operating at temperatures above 1000 C.
  • the bed material consists essentially of one or more of the materials in the group consisting of carbides, borides, silicates, silicides and/or oxides and having a sintering temperature higher than the operating temperature of the resistance element.

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Description

Nov. 17, 1959 P. BORGHULT ETAL ELECTRIC RESISTANCE HEATING ELEMENTS 5 Sheets-Sheet 1 Filed July 5;. use
Fig. 1
8: gOHN HELGE HAGLUND INVENTORS PER BORGHULT ATTO R NEYS Nov. 17, 1959 P. BORGHULT EI'AL 2,913,691?
ELECTRIC RESISTANCE HEATING ELEMENTS Filed July 5, 1956 5 Sheets-Sheet 2 INVENTORS PER BORGHULT 8x J'OHN HELGE HAGLUND ATTOBN E YS P. BORGHULT ETAL' 2,913,695 ELECTRIC RESISTANCE HEATING ELEMENTS Nov. 17, 1959 1 5 Sheets-Sheet 3 Filed July 5, 1956 Fig. 4
1 INVENTORS PER BORGHULT JOHN HELGE HAGLUND ATTORNEYS P. BORGHULT ETAL ELECTRIC RESISTANCE HEATING ELEMENTS Nov. 17,1959 I 5 Sheets-SheetA Filed July 5, 1956 INVENTORS PER BORGHULT ATTORNEYS I Nov. 17,1959 P. BORGHULT ET L 2,913,695
ELECTRIC RESISTANCE HEATING ELEMENTS Filed July 5, 1956 5 Sheets-Sheet 5 {50 7/ VZ LQ w X f 2 J v j q 5'45 uth ;"'1 i INVENTORS PER BORGHULT 8 JOHN HELGE HAGLUND rrpmvzvs United States Patent ELECTRIC RESISTANCE I-HEATlNG ELEMENTS Per Borghult, Enskede, and John Helge Haglund, Hallstahammar, Sweden, assignors to Aktiebolaget Kanthal, Hallstahammar, Sweden Application July 5, 1956, Serial No. 596,012 Claims priority, application Sweden July 11, 1955 13 Claims. (Cl. 338-317) The present invention relates to mounting arrangements for electric resistance heating elements for electric resistance furnaces operating at temperatures above 1000' C., preferably however, up to at least 1400 C.
It has already been proposed to use, for operating temperature of this order of magnitude, resistance elements which have been produced in a powder metallurgical process, mainly from silicides, especially molybdenum silicide, possibly with a residue of oxides, carbides, such as silicon carbide, and borides, in which process there may be used as the metallic constituent, in addition to molybdenum, one or more of the elements Ti, Zr, V, Nb, Ta andv Cr (titanium, zirconium, vanadium, niobium (columbium), tantalum and chromium). When heating such resistance elements to elevated temperatures, due to the action of the oxygen contained in the air, there will form on the same a superficial layer of silicon dioxide which is slightly plastic and sticky at elevated temperatures so as to sinter together into a gastight film which prevents further oxidation of the interior of the element.
Resistance elements made of such materials have fairly limited mechanical strength characteristics which have, in the past, placed the user before the alternative of either supporting the elements at a plurality of locations, or producing the same in lengths which are frequently too short as compared to the furnace dimensions concerned. If, in accordance with the common practice in the field of metallic resistance elements, an attempt is made to support elements of the type above referred to directly upon the refractory liner of the furnaces, this will result in that the elements stick to the liner and will be pulled apart on thermal expansions occurring since they are not freely movable. Such sticking, in addition to the action of the silicon dioxide film, may also be caused by the fact that the material of the elements have often a tendency to react chemically with the base material while forming reaction products having softening temperatures which are lower than the operating temperature of the elements. It should be noted in this connection that this sticking is not at all tied up with the degree of refractoriness of the liner material per se.
In order to avoid the drawback referred to, attempts have been made to mount the elements in cantileverfashion so that there would be no direct contact between the elements and the refractory material within the heating zones of the elements. However, this necessitates that high demands must be placed on the mechanical strength characteristics of the elements which may lead to dimensions which are impractical from an electrical point of view.
The present invention has for its object to overcome the drawback referred to and mainly resides in that the resistance element, composed substantially of silicidcs, preferably molybdenum silicide, possibly with a residue of oxides, carbides and borides, is loosely supthe element.
2,913,695 Patented Nov. 17, 1959 ported on a bed which is only in partial contact with the element and which consists of relatively movable grains of a refractory and electrically insulating material which is chemically resistant to the material of the resistance element, also at the operating temperatures concerned. This arrangement provides for a positive and satisfactory support for the elements, and the supporting bed acts to prevent the same from sticking to the furnace liner or refractory walls. The grains of the bed should be of a refractoriness suflicient to maintain the free mobility between the single grains up to a temperature of at least 1000" C., and in any case up to the operating temperature concerned. It is preferable that the grain quality should ensure the free mobility relative to each other up to a temperature of at least 1400 C. Owing to the fact that the material of the bed is chemically resistant to the material of the elements, the latter will be protected against chemical attacking at the points at which they contact the bed. Owing to the fact that the electrical resistance of the bed material is sufiiciently high, no leakage currents in the bed will be capable of causing injury to the elements at their contact points with the bed. Due to the remaining requirements which are placed on the material of the bed as regards refractoriness and resistance to chemical attack, no difliculty will be encountered, as a rule, in satisfying also the demand for a high electrical resistance.
In operation some of the grains in the portion of the bed immediately adjacent the element will stick to the silicon dioxide film of the latter. When subsequently the length of the element changes due to temperature variations, the grains thus stuck to the element Will move together with the element and will thus slide over the readily movable grains of the bed which do not stick to In this way the element will be relieved of any destructive mechanical strains.
In accordance with the invention, the bed material may suitably consist of one or more of the following substances, viz. silicon dioxide, silicon carbide or aluminum silicate. Particularly satisfactory results have been obtained using a bed of mullite or sillimanite. It is to be understood, however, that the invention is not restricted to the employment of a bed material of this composition, since it is possible to use any desired heatresistant material having a high electric resistance. However, the bed material must consist of substances which, even at the highest operating temperature concerned, remain chemically indifferent against the material of the resistance element so that no reaction products will form. The substances which, in the broadest aspect of the invention, may be comprised in the supporting bed for the resistance elements are: carbides, borides, silicides, silicates and oxides, either singly or in combination with each other.
The major part of the grains of the supporting bed should be spherical in shape, or should have beaded edges and corners, at least, so as to facilitate their relative mobility. The grains should be screened into defin'ite granular fractions through different screens sized, for instance, according to the Tyler standard screen scale, it being preferable that the grains of each bed should be of one single granular fraction ranging, for instance, between two adjacent mesh numbers, or should be of two adjacent granular fractions, at least, for instance one fraction having grain sizes ranging from 6 to 8 mesh, and one adjacent fraction having grain sizes ranging from 4 to 6 mesh. It is understood, of course, that the average grain size should be so selected as to afford satisfactwice the average diameter of the grains contained in the bed. As a general statement, the grain sizes of the bed particles should range between a minimum of 0.004" and a maximum of 0.4 (0.1 to 10 mm.).
It has been found that if the resistance elements are supported in accordance with the teachings of the present invention, the elements can be used also in conjunction with furnace liners which, when directly contacted by the elements, would subject the elements to destructive actions. Thus the present invention makes it possible to use refractory liner materials of a standard quality selected exclusively taking into account its refractoriness while disregarding any tendency of the material to react chemically with the element material at elevated temperatures.
Practical embodiments of the invention as applied to the manner of mounting resistance elements in furnaces, are illustrated in the accompanying drawings in which:
Fig. 1 is a vertical section through the bottom portion of a furnace whereas Fig. 2 is a corresponding plan view shown partly broken away;
Figs. 3 and 4 are perspective scrap views showing a resistance element disposed on shelves formed on the internal wall surfaces of a furnace;
Fig. 5 is a side elevational view; and
Fig. 6 is a top end view of a supporting tube for a horizontally extending resistance element, while Figs. 7 and 8 are cross-sections taken along the lines VII--VII and VHF-VIII, respectively, in Fig. 5;
Fig. 9 is a top plan view of the lower half of the refractory liner of a tube-type furnace; and
Fig. 10 is a cross-section through the refractory liner, taken along the line X--X in Fig. 9.
In the embodiment illustrated in Figs. 1 and 2, the bottom 1 and side walls 2 to 5 of the furnace are made of a refractory material. Disposed on the bottom 1 is a bed 6 of a granular material consisting of aluminum silicate of the approximative composition 65% A1 and 35% SiO Supported half-way immersed into the bed 6 is a heating resistnace element 7 consisting of 95% molybdenum silicide (Mosi the balance to 100% consisting of oxides and silicates. The resistance element is formed at its ends with enlarged terminal portions 8a, 8b passed through holes made in the wall 2. The high-temperature heating zone proper of the element 7 is formed by the smaller-diameter part thereof whereas its terminal portions 8a, 3b will be at a considerably reduced temperature due to their larger cross-sectional area.
It would be possible, instead of using aluminum oxide and silicon dioxide in the form of aluminum silicate as referred to above, to use pure granular silicon carbide of grain sizes ranging between 0.08 and 0.2 inch (2 to mm.). It is suitable to use the so-called light green silicon carbide since this is the purest form technically available. As an alternative, a still further bed material may be employed, viz. powder metallurgically produced 0.16"
(4 mm.) pellets containing 15% by weight of very finely divided MoSi and 82% by weight of silicon carbide.
As a further example of carrying-the invention into effect the case may be mentioned, in which the resistance element 7 is composed of 90% by weight of MoSi 5% by weight of chromium boride (CrB), the balance being I resistance element. Such a selection of material forfthe bed, therefore, would not be compatible with the condition stipulated that the bed material must be chemically resistant to the material of the resistance element.
In the embodiment illustrated in Figs. 3 and 4, the refractory wall 10' is disposed as a liner on the internal surface of a supporting brick wall 11 and is formed on its surface facing the furnace chamber with shelves 12, 13, etc. Disposed on these shelves are granular beds 14, 15, etc., and resting on the latter are two branches 7a, 7b, respectively, of the resistance element. These branches are interconnected by a cantilevered intervening portion 7c. Fig. 3 illustrates the enlarged terminal portions 8c and 8d of the resistance element.
In the embodiment illustrated in Figs. 5 to 8 which is adapted for mounting horizontally extending resistance elements, the resistance element 21, being bent into a hairpin-like configuration, rests on a supporting bed of a granular, electrically insulating material disposed in the tube 20, this material being refractory and chemically resistant to the material of the resistance element, also at the operating temperature concerned. The electric resistance of the bed 31 should be sufficiently high to prevent the formation of any noticeable leakage currents. The material of the bed, as mentioned hereinbefore, has a refractoriness such as to allow the grains to conserve their relative mobility even at the highest temperatures concerned thereby providing for flee thermal expansion and contraction lengthwise of the resistance element relative to the supporting tube.
The enlarged terminal portions 25 of the resistance element 21 are passed out through, and fill out, holes made in a plug 26 of ceramic material inserted in the corresponding end of the tube 20.
In Figs. 9 and 10 numeral 40 designates the upper and 41 the lower half of the ceramic liner. Designated by 42 is a ceramic tube which is inserted in the furnace liner and defines the furnace chamber 43. Formed in the lower half 40 of the furnace liner are a plurality-six in number in the embodiment illustrated-axially extending open channel-grooves 44 each of which forms a shelf. Disposed on the bottom portion of each such groove or shelf 44 is a supporting bed 45 consisting of a granular electrically insulating material which is refractory and chemically resistant to the material of the resistance element also at the operating temperature concerned, as stated hereinbefore. Rested on the respective supporting beds 45 are the straight-lined portions 46 of a looped resistance element which is bent longitudinally at intervals against a cylindrical surface. The uppermost two grooves or shelves 44 are formed in the parting interface between the upper and lower halves 40 and 41, respectively, of the, liner. The terminal portions 47 of the resistance elementthe cross-sectional area of which is larger than that of the resistance conductor proper, 46, are introduced through holes made in the rear wall 48 of the furnace.
Disposed in the front wall 49 of the furnace is the furnace entrance opening. The latter may be closed, in the conventional manner, by a furnace door which is not shown in the figure. The looped resistance element should be placed in the grooves 44 before the ceramic tube 42 is moved longitudinally into its operative position. The resistance loop can conveniently be removed for replacement or repair after first withdrawing the tube 42 from the furnace.
What is claimed is:
1. Electrical heating apparatus comprising an electrical resistance heating element, and a bed of freely flowable refractory material grains having an electrical conductivity lower than that of the resistance element and chemically resistant to the material of said resistance element, said element resting uncovered upon the upper surface of said bed in contact with said refractory material grains, and said bed being operative to support said element throughout substantially the full length thereof, and to simultaneously accommodate movement thereof due to temperature-change induced expansion and contraction.
2. Apparatus as defined in claim 1 wherein the heating element consists essentially of heat resistant and oxidation proof silicides.
3. Apparatus as defined in claim 1 wherein the heating element consists essentially of molybdenum disilicide,
4. Apparatus as defined in claim 1 wherein the bed material consists essentially of one or more of the materials in the group consisting of heat-resistant carbides, borides, silicates, silicides and/ or oxides.
5. Apparatus as defined in claim 1 wherein the bed material comprises one or more of the following substances: silicon dioxide, sillimanite and mullite.
6. Apparatus as defined in claim 1 wherein the heating element consists essentially of heat resistant and oxidation proof silicides, and the bed material consists essentially of one or more of the materials in the group consisting of heat-resistant carbides, borides, silicates, silicides and/or oxides, said bed material including one or more of the following substances: silicon dioxide, sillimanite and mullite.
7. Apparatus as defined in claim 1 wherein the heating element consists essentially of molybdenum disilicide, and the bed material consists essentially of sillimanite and mullite.
8. Apparatus as defined in claim 1 wherein the heating element is adapted for operating at temperatures above 1000 C., and the bed material consists essentially of one or more of the materials in the group consisting of carbides, borides, silicates, silicides and/or oxides and having a sintering temperature higher than the operating temperature of the resistance element.
9. Apparatus as defined in claim 1 wherein the grain size of the grains of the bed is comprised between 0.004 and 0.4 inch (0.1 to mm.).
10. Apparatus as defined in claim 1 wherein the bed is of a depth at least equal to twice the average size of the grains of the bed.
11. Apparatus as defined in claim 1 wherein the References Cited in the file of this patent UNITED STATES PATENTS 357,572 Burton Feb. 15, 1887 941,339 Tone Nov. 23, 1909 1,019,568 Weintroub Mar. 5, 1912 1,025,144 Kuhn May 7, 1912 1,044,295 Tone Nov. 12, 1912 1,158,972 Boeck Nov. 2, 1915 1,597,900 Keene Aug. 31, 1926 1,645,867 Loughian Oct. 18, 1927 1,802,892 Hansen Apr. 28, 1931 1,878,619 Bechtel Sept. 20, 1932 1,894,685 Hediger Jan. 17, 1933 1,901,499 Fahrenwald Mar. 14, 1933 1,906,853 Hediger May 2, 1933 1,914,939 Boyer et al June 20, 1933 1,925,129 Boyles Sept. 5, 1933 2,001,297 Boyles May 14, 1935 2,235,091 Vineberg Mar. 18, 1941 2,280,367 Barton Apr. 25, 1942 2,622,304 Coffer Dec. 23, 1952 2,678,958 Hintenberger May 18, 1954 2,744,946 Lewicki May 8, 1956 FOREIGN PATENTS 648,331 France Aug. 3, 1928
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Cited By (6)

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US3321727A (en) * 1964-12-09 1967-05-23 Kanthal Ab Heat-resistant and oxidationproof materials
US3457390A (en) * 1967-04-05 1969-07-22 Sanders Nuclear Corp High temperature resistance heater
US3522574A (en) * 1968-01-11 1970-08-04 Kanthal Corp High temperature electric resistance device
US3571477A (en) * 1968-06-21 1971-03-16 Bert Phillips Protection of oxidizable electric furnace elements at high temperatures
US4159415A (en) * 1977-01-21 1979-06-26 Klein Tools, Inc. Electric slot furnace
US4243874A (en) * 1977-07-02 1981-01-06 Karl Fischer Radiant heating unit

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US1914939A (en) * 1930-12-09 1933-06-20 Globar Corp Nonmetallic resistor and method of making the same
US1925129A (en) * 1932-06-27 1933-09-05 Carroll H Boyles Process of equalizing resistance of enlarged ends of electric heating elements
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US2235091A (en) * 1936-09-12 1941-03-18 Samuel S Vineberg Heating unit for electrical cooking devices
US2280367A (en) * 1940-03-19 1942-04-21 William W Barton Electric heater
US2622304A (en) * 1950-10-02 1952-12-23 Climax Molybdenum Co Refractory
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US1019568A (en) * 1912-03-05 Gen Electric Method of making resistance material.
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US1025144A (en) * 1911-09-11 1912-05-07 American Electrical Heater Co Electric foot-warmer.
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FR648331A (en) * 1927-06-15 1928-12-07 Improvements to electric ovens
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3321727A (en) * 1964-12-09 1967-05-23 Kanthal Ab Heat-resistant and oxidationproof materials
US3457390A (en) * 1967-04-05 1969-07-22 Sanders Nuclear Corp High temperature resistance heater
US3522574A (en) * 1968-01-11 1970-08-04 Kanthal Corp High temperature electric resistance device
US3571477A (en) * 1968-06-21 1971-03-16 Bert Phillips Protection of oxidizable electric furnace elements at high temperatures
US4159415A (en) * 1977-01-21 1979-06-26 Klein Tools, Inc. Electric slot furnace
US4243874A (en) * 1977-07-02 1981-01-06 Karl Fischer Radiant heating unit

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