US2910356A - Cast nickel alloy of high aluminum content - Google Patents
Cast nickel alloy of high aluminum content Download PDFInfo
- Publication number
- US2910356A US2910356A US616355A US61635556A US2910356A US 2910356 A US2910356 A US 2910356A US 616355 A US616355 A US 616355A US 61635556 A US61635556 A US 61635556A US 2910356 A US2910356 A US 2910356A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- alloy
- percent
- nickel
- cast
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/007—Alloys based on nickel or cobalt with a light metal (alkali metal Li, Na, K, Rb, Cs; earth alkali metal Be, Mg, Ca, Sr, Ba, Al Ga, Ge, Ti) or B, Si, Zr, Hf, Sc, Y, lanthanides, actinides, as the next major constituent
Definitions
- This invention relates to cast nickel aluminum alloys in which the aluminum is present in amounts in excess of percent by weight.
- Intermetallic compounds such as the nickel-aluminum compound NiAl
- NiAl nickel-aluminum compound
- the melting point is high compared with that of nickel and aluminum, and there are important differences over the constituent metals in modulus-.of-rupture strengths and oxidation resistance at high temperatures.
- the intermetallic Ni Al also possesses distinctive properties.
- NiAl intermetallic compositions have been prepared heretofore by the methods of powder metallurgy, casting methods resulting in extremely weak, porous and fragile bodies, due primarily to the high exothermic heat developing in the mass.
- the present invention contemplates a casting procedure for nickel-aluminum mixtures with the aluminum in excess of 10% and, particularly, in the 14-30% range in which the exothermic temperatures are controlled by the particle size of the mixed metals, by the method of heating, and by the sequence of treatment during heating.
- An outstanding object of the invention is to provide a cast nickel-aluminum composition which contains intermetallic phase alloys and Which possesses high tensile strength both at room and high temperatures. Another object is to provide a cast alloy of nickel and aluminum, containing at least 10 percent aluminum, which may be hot rolled. Still another object is to provide a cast nickelaluminum alloy containing about 14 to 30 percent aluminum which, at high temperatures, is thermal-chock resistant and hard, possesses adequate impact strength and resists oxidation.
- Additional objects are to provide a nickel-aluminum alloy with at least 14 percent aluminum which serves readily as a base for additional metal alloys, and which eliminates use of fluxes in the alloy casting process.
- Fig. 1 is a perspective view of the crucible and mold unit partly tilted toward pouring position
- Fig. 2 is a set of curves showing change of hardness, density and tensile strength for different values of aluminum content of the nickel aluminum alloy
- Fig. 3 is a set of stress-strain curves showing the ductility of the nickel-aluminum alloy for different selected percentages
- Fig. 4 is a set of curves showing the stress-time-torupture values of the nickel-aluminum alloy ascompared with Inconel;
- Fig. 5 is a set of curves indicating oxidation effects of the alloy for different temperatures and in comparison with Nichrome;
- Fig. 6 is a curve showing the variation of hardness of the nickel-aluminum alloy having 17.5 percent aluminum, with variation in the temperature of homogenization.
- the castings are prepared in a bell-jar vacuum induction furnace unit, as illustrated in Fig. 1, including the support casing 10, the base plate 11, and induction furnace 12, the 'mold 13 and the bell-jar 14.
- the furnace comprises a tubular, refractory, alumina crucible 15, having an open top end for reception of the metal charge, an enclosing tubular coil 16 of an electrical conductor 17 serving to impart inductive heating flux to the metallic crucible contents, and a cooling jacket 18, provided with coolant connections 19 and 20, surrounding the coil '16.
- the furnace is mounted pivotally on upright stanchions 21, one of which is shown in Fig. l.
- the pivot rod terminates in a pinion 22 external to stanchion 21; and a rack 23, movable in sleeve 24 by mechanism (not shown) placed in the support casing 10, serves to rotate the crucible through a limited arc of movement for discharge of the molten metal.
- the mold for the casting is attached to the upper edge of jacket 18,
- mold is secured detachably to the jacket so as to extend at right angles to the crucible axis, and, when the crucible is tipped, liquid in the crucible flows directly into the upper mold 13 where it is solidified by cooling to room temperature.
- the raw materials used in-the charge are electrolytic nickel (99.95% purity) and 28 aluminum (99.0+%
- the nickel be prepared, not as a powder or grain, but in the form of discrete fragments or particles and preferably in the form of small flat chips; and the aluminum is used in small fragments or pieces of 1-inch diameter bar stock.
- the nickel chips are placed on the bottom of the crucible and the aluminum bar pieces over the nickel.
- the nickel acts as a susceptor in the induction field and raises the aluminum temperature to the melting point.
- the reaction between the molten aluminum and solid nickel is strongly exothermic, especially, for high-aluminum alloys, as 20 to 30 percent aluminum, and the charge becomes molten in a few seconds, where the initial charge weight is in the neighborhood of 400 to 600 grams.
- the melt is stirred effectively by both the chemical reaction and the induction field. About 1 minute after the start of the reaction (for the charge mentioned) the melt is poured into the mold. This is not a limiting or critical time period as the holding time may be extended, but the time should be definite and not be extended unnecessarily because of the tendency to vaporization and danger of contamination by the crucible material.
- the mold substance is preferably copper in order to give a chill cast effect, but a ceramic mold is feasible although producing a larger grain size in the casting.
- the nickel-aluminum alloy has been described as containing 14 to 30 percent aluminum. This range is of interest since, heretofore, castings of this alloy in the specified range possessing adequate tensile strength, thermal shock and oxidation resistance and other desired properties have not been obtainable. In addition, this range includes the intermetallic phases NiAl and Ni Al, and tests on-these substances, as made by powder metallurgy methods, show these alloys to have desirable prop erties. In order to ascertain the properties of the alloy, cast as described hereinabove, a series of alloys with different aluminum percentages, was examined as to hardness, tensile strength and density, and graphs showing these properties are found in Fig. 2. These graphs show a linear decrease of density with increase of aluminum;
- NiAl plus Ni Al phases of the nickelaluminum phase system Ni Al being the intermetallic phase containing approximately from 13.3 to 16 percent aluminum and NiAl being the intermetallic phase containing approximately from 24 to 36.5 percent aluminum at room temperature.
- FIG. 3 to 6 are graphs showing other properties of the 17.5 percent aluminum alloy.
- Fig. 3 illustrates the stressstrain characteristic ofthe alloy to the rupture point, not only for the 17.5 percent aluminumgalloy but also for alloys containing 14 and 25 percent aluminum, the values corresponding to the intermetallic phasesNiAl and Ni Al, respectively.
- FIG. 4 illustrates the stressto -rupture time for the 17.5 percent aluminum alloy as compared with Inconel, a refractory alloy capable of uses parallel tothe described alloy.
- Fig. 5 shows graphs descriptive of oxidation properties of'the described 17.5 percent alloy as Compared to Nichrome, both at 1800 F. The oxidation gain ofthe 17.5 percent alloy at temperatures of 1500 F. and 2100 F. is also shown.
- Fig. 6 illustrates the efiect of homogenization treatment on the 17.5 percent aluminum. alloy for temperatures varying from 1200 F.
- the room-temperature tensile strength of the 17.5 percent aluminum alloy rolled to 10% reduction is 73,400 pounds per square inch, and with 50 percent rolling, 86,300 pounds per square inch. It is further noted that homogenization treatment of the as-cast 17.5 percentaluminum alloy at 2400 F. increases the tensile strength to 94,250 pounds per square inch, with no elongation. In addition, it is important to note that the tensile strength of the alloy is retained at elevated temperatures. For example, at 1500 F. the 17.5 percent aluminum alloy has a tensile strength of 52,900 pounds per square inch (p.s.i.), as-ca st.
- the tensile strength is increased to 55,250 p.s.i.
- Rolled 50 percent at 2400 F. the tensile strength becomes 50,000 p.s.i.
- the tensile strength becomes 52,600 p.s.i. and rolled 34 percent at 2400 F., with 5.0 percent molybdenum added, the tensile strength is 55,000 p.s.i.
- the ductility of the alloy the values of elongation in percent for the as-cast alloy at room temperature and as-cast alloy at 1500 F.
- the nickel-aluminum alloys containing from 14 to 30 percent aluminum and prepared as castings with or without subsequent hot working, not only possess desirable properties such as high strength, corrosion resistance and low specific gravity but also are formed of metals readily available as distinguished, from the expensive alloying conium, vanadium, niobium,.tantalum and iron.
- the tensile strength of 17.5 percent-aluminum alloy at room temperature is increased from 83,800 pounds per square inch to 88,600 pounds per square inch by the addition of 5.0 percent molybdenum, and to 92,600 pounds per square inch by the addition of 0.05 percent boron.
- a nickel-aluminum alloy casting having the combination of superior hot formability, strength, room-temperature and 1500" F. ductility, oxidation resistance and stress-to-rupture time, said casting being composed of an alloy consisting of the two phases Ni A1 and NiAl with about 17.5 percent aluminum, said casting being produced by forming the nickel in small discrete chips, forming the aluminum in pieces each larger than each of said nickel chips, placing the nickel chips and aluminum pieces in an induction furnace in contiguous overlying layers, introducing an inert atmosphere into said furnace at a pressure in excess of atmospheric, melting said aluminum prior to melting said nickel by applying electromagnetic flux to said nickel said nickel chips thereupon dissolving into the molten aluminum and reacting therewith to form said alloy and pouring said molten alloy into a mold external to said furnace said mold being at a temperature below that of said furnace, an inert atmosphere at a pressure in excess of atmospheric being continuously maintained in the apparatus during melting, casting and cooling.
Description
Oct. 27, 1959 E. M. GRALA ETAL CAST NICKEL ALLOY OF HIGH ALUMINUM CONTENT Original Filed July 19, 1956 5 SheetS -Sheet 1 DENSITY 7.6 looxlcn 1.2 4 1s ao III E .A I 3 o f, I t; 6.1; 12 7 60 5 t E STRENGTH m w 3 HARDNESS :3 z u z 6.4 se 40 a: o :2 a I 6.0 64 l R 20 as so 0 o I 25 so as I0 I5 20 ALUMINUM cou'rzm,
F IG. 2-
INVENTORS EDWARD M GRALA WILLIAM A MAXWELL ATTORNE Y E. M. GRALA ETAL CAST NICKEL ALLOY OF HIGH ALUMINUM CONTENT Original Filed July 19,1956
3 Sheets-Sheet 2 STRESS psi TEST MPERATURE- l TIME TO R'UPTURE, m. F l 6. 4
INVENTORS EDWARD M. GRALA WILLIAM A. MAXWELL BY 1W ATTORNEY Oct. 27, 1959 AL ETAL 2,910,356
CAST NICKEL ALLOY OF HIGH ALUMINUM CONTENT Original Filed July 19, 1956 5 Sheets-Sheet 3 WEIGHT GAIN. mg lcm TIME, m. Fl 6. 5
WATER QUENCH u 8O 59 j :11 Ill 5 X 0 8 j 2 1s *9 3 g g a D 5 AS c1$ AIR oon. E 70 I 59 I I fi/ 65 1 29 I200 I400 I600 I800 2000 2200 2400 2600 TEMPERATURE OF HOMOGENIZATION,
INVENTORS EDWARD M. GRALA WILLIAM A. MAX WEZL ATTORNEY United States Patent 2,910,356 CAST NICKEL ALLOY OF HIGH ALUMINUM CONTENT Edward M. Grala, Chicago, Ill., and William A. Maxwell,
Towson, Md., assignors to the United States of Americaas represented by the Secretary of the Navy Original application July 19, 1956, Serial No. 532,128. Divided and this application October 16, 1956, Serial No. 616,355
1 Claim. (Cl. 75--170) (Granted under Title 35, US. Code (1952), see. 266) The invention described herein may be manufactured and used by or for the Government of the United States of America for governmental purposes without the payment of any royalties thereon or therefor.
This invention relates to cast nickel aluminum alloys in which the aluminum is present in amounts in excess of percent by weight.
Intermetallic compounds, such as the nickel-aluminum compound NiAl, are known to possess properties radically different from those of their constituent elements. In the case of NiAl, for example, the melting point is high compared with that of nickel and aluminum, and there are important differences over the constituent metals in modulus-.of-rupture strengths and oxidation resistance at high temperatures. The intermetallic Ni Al also possesses distinctive properties.
NiAl intermetallic compositions have been prepared heretofore by the methods of powder metallurgy, casting methods resulting in extremely weak, porous and fragile bodies, due primarily to the high exothermic heat developing in the mass. The present invention contemplates a casting procedure for nickel-aluminum mixtures with the aluminum in excess of 10% and, particularly, in the 14-30% range in which the exothermic temperatures are controlled by the particle size of the mixed metals, by the method of heating, and by the sequence of treatment during heating.
An outstanding object of the invention is to provide a cast nickel-aluminum composition which contains intermetallic phase alloys and Which possesses high tensile strength both at room and high temperatures. Another object is to provide a cast alloy of nickel and aluminum, containing at least 10 percent aluminum, which may be hot rolled. Still another object is to provide a cast nickelaluminum alloy containing about 14 to 30 percent aluminum which, at high temperatures, is thermal-chock resistant and hard, possesses adequate impact strength and resists oxidation.
Additional objects are to provide a nickel-aluminum alloy with at least 14 percent aluminum which serves readily as a base for additional metal alloys, and which eliminates use of fluxes in the alloy casting process.
Other objects and many of the attendant advantages of this invention will be readily appreciated as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings wherein:
Fig. 1 is a perspective view of the crucible and mold unit partly tilted toward pouring position;
Fig. 2 is a set of curves showing change of hardness, density and tensile strength for different values of aluminum content of the nickel aluminum alloy;
Fig. 3 is a set of stress-strain curves showing the ductility of the nickel-aluminum alloy for different selected percentages;
Fig. 4 is a set of curves showing the stress-time-torupture values of the nickel-aluminum alloy ascompared with Inconel;
, 2,910,356 Patented Oct. 27., 1959 Fig. 5 is a set of curves indicating oxidation effects of the alloy for different temperatures and in comparison with Nichrome; and
Fig. 6 is a curve showing the variation of hardness of the nickel-aluminum alloy having 17.5 percent aluminum, with variation in the temperature of homogenization.
In the manufacture of the alloy, the castings are prepared in a bell-jar vacuum induction furnace unit, as illustrated in Fig. 1, including the support casing 10, the base plate 11, and induction furnace 12, the 'mold 13 and the bell-jar 14. The furnace comprises a tubular, refractory, alumina crucible 15, having an open top end for reception of the metal charge, an enclosing tubular coil 16 of an electrical conductor 17 serving to impart inductive heating flux to the metallic crucible contents, and a cooling jacket 18, provided with coolant connections 19 and 20, surrounding the coil '16. The furnace is mounted pivotally on upright stanchions 21, one of which is shown in Fig. l. The pivot rod terminates in a pinion 22 external to stanchion 21; and a rack 23, movable in sleeve 24 by mechanism (not shown) placed in the support casing 10, serves to rotate the crucible through a limited arc of movement for discharge of the molten metal.
For convenience, and to eliminate spillage, the mold for the casting is attached to the upper edge of jacket 18,
mid-point between the pivot points and on the side of The the crucible which is below on pouring movement. mold is secured detachably to the jacket so as to extend at right angles to the crucible axis, and, when the crucible is tipped, liquid in the crucible flows directly into the upper mold 13 where it is solidified by cooling to room temperature.
In order to prevent oxidation of the molten aluminum, air is withdrawn from the crucible space in bell-jar 14 through the vacuum opening 25 in the base 11 which communicates with the vacuum pump through casing .10. Also, to prevent the molten aluminum from vaporizing, a slight positive pressure of an inert gas, such as argon, is maintained within the bell-jar.
The raw materials used in-the charge are electrolytic nickel (99.95% purity) and 28 aluminum (99.0+%
purity). It is desirable that the nickel be prepared, not as a powder or grain, but in the form of discrete fragments or particles and preferably in the form of small flat chips; and the aluminum is used in small fragments or pieces of 1-inch diameter bar stock. In a typical treatment the nickel chips are placed on the bottom of the crucible and the aluminum bar pieces over the nickel. When the alternating furnace current is turned on, the nickel acts as a susceptor in the induction field and raises the aluminum temperature to the melting point. The reaction between the molten aluminum and solid nickel is strongly exothermic, especially, for high-aluminum alloys, as 20 to 30 percent aluminum, and the charge becomes molten in a few seconds, where the initial charge weight is in the neighborhood of 400 to 600 grams. The melt is stirred effectively by both the chemical reaction and the induction field. About 1 minute after the start of the reaction (for the charge mentioned) the melt is poured into the mold. This is not a limiting or critical time period as the holding time may be extended, but the time should be definite and not be extended unnecessarily because of the tendency to vaporization and danger of contamination by the crucible material. The mold substance is preferably copper in order to give a chill cast effect, but a ceramic mold is feasible although producing a larger grain size in the casting.
Close control over the process during the melting and reacting of the constituent metals is obtained by control of the size of the aluminum and nickel particles in the charge, the larger the pieces, generally considered, the better the control. The dissolving of the solid nickel into the molten aluminum retards the violence of the reaction and keeps the maximum temperature of the reaction down. In the case of powders, not only is the reaction much more violent, but the gases entrapped in the powder briquette during the cold pressing operation areinvolved during the reaction and produce large pores in the fused mass. Consequently, this porous mass must be ground into powder and fabricated into useful form by powder metallurgy methods.
The nickel-aluminum alloy has been described as containing 14 to 30 percent aluminum. This range is of interest since, heretofore, castings of this alloy in the specified range possessing adequate tensile strength, thermal shock and oxidation resistance and other desired properties have not been obtainable. In addition, this range includes the intermetallic phases NiAl and Ni Al, and tests on-these substances, as made by powder metallurgy methods, show these alloys to have desirable prop erties. In order to ascertain the properties of the alloy, cast as described hereinabove, a series of alloys with different aluminum percentages, was examined as to hardness, tensile strength and density, and graphs showing these properties are found in Fig. 2. These graphs show a linear decrease of density with increase of aluminum;
an increase in hardness up to about 25 percent aluminum, followed by a decrease; and a pronounced peak in tensile strength at an aluminum percentage of 17.5, in the alloy. On examination of the structure of this 17.5 percentage alloy by X-ray techniques, it is found to correspond to the NiAl plus Ni Al phases of the nickelaluminum phase system, Ni Al being the intermetallic phase containing approximately from 13.3 to 16 percent aluminum and NiAl being the intermetallic phase containing approximately from 24 to 36.5 percent aluminum at room temperature.
It is pointed out that the 17.5 percent aluminum alloy not only possesses marked tensile strength amounting to 79,600 pounds per square inch at room temperature, but *also the hardness and density are .substantiaL. In Figs.
3 to 6 are graphs showing other properties of the 17.5 percent aluminum alloy. Fig. 3 illustrates the stressstrain characteristic ofthe alloy to the rupture point, not only for the 17.5 percent aluminumgalloy but also for alloys containing 14 and 25 percent aluminum, the values corresponding to the intermetallic phasesNiAl and Ni Al, respectively. ,Fig. 4 illustrates the stressto -rupture time for the 17.5 percent aluminum alloy as compared with Inconel, a refractory alloy capable of uses parallel tothe described alloy. Fig. 5 shows graphs descriptive of oxidation properties of'the described 17.5 percent alloy as Compared to Nichrome, both at 1800 F. The oxidation gain ofthe 17.5 percent alloy at temperatures of 1500 F. and 2100 F. is also shown. Fig. 6 illustrates the efiect of homogenization treatment on the 17.5 percent aluminum. alloy for temperatures varying from 1200 F.
to 2500 F. the alloy being held at selected temperatures for a numberof hours, as 48 hours, bringing about elimination of as-cast heterogeneities, changes in composition of the Ni Al and NiAl phases and changesin the relative quantity of each phase. The phase changes are apparent from examination of photomicrographs, indicating a progressive solution of the NigAl phase in the NiAl phase which becomes complete around 2400 F. Beginning around 2200 F.,-also, a needledikemartensite structure appears in the grains on cooling, which appears to be closely related to the increase in hardness as shown inFig.6.
It is noteworthy that at 2400 F. .where all phases of the 17.5 percent-aluminum alloy havev transformed to NiAl, the alloy could be readily hot-rolled, a reduction of 15.9 percent per pass being sustainable. Much smaller values of reduction were obtainable for this alloy at 2200 F. and 2100 F. amounting to 3.9 and 2.1 percent, respectively. The only other alloy susceptible to successful hot-rolling is the 28 percent aluminum alloy, a. crackother aluminum percentages above 10 percent have defree reduction per pass of 3.3 percent being obtainable at 2600 F. In this hot-rolling procedure, about'3 seconds were required to remove the ingots, to be rolled, from the furnace to the rolls. Even though the cold rolls act as a quenching medium, the centers of the ingots are untransformed NiAl, as appears from microscopic examination of polished specimens of rolled material. The fact that the alloy was able to sustain an approximately 16 percent reduction indicates that the untransformed NiAl phase is plastic.
The room-temperature tensile strength of the 17.5 percent aluminum alloy rolled to 10% reduction is 73,400 pounds per square inch, and with 50 percent rolling, 86,300 pounds per square inch. It is further noted that homogenization treatment of the as-cast 17.5 percentaluminum alloy at 2400 F. increases the tensile strength to 94,250 pounds per square inch, with no elongation. In addition, it is important to note that the tensile strength of the alloy is retained at elevated temperatures. For example, at 1500 F. the 17.5 percent aluminum alloy has a tensile strength of 52,900 pounds per square inch (p.s.i.), as-ca st. Homogenized for 48 hours at 2000" F., the tensile strength is increased to 55,250 p.s.i. Rolled 50 percent at 2400 F. the tensile strength becomes 50,000 p.s.i. As cast, with 0.5 percent molybdenum added, the tensile strength becomes 52,600 p.s.i. and rolled 34 percent at 2400 F., with 5.0 percent molybdenum added, the tensile strength is 55,000 p.s.i. Of interest also is the ductility of the alloy, the values of elongation in percent for the as-cast alloy at room temperature and as-cast alloy at 1500 F. being, respectively, 0.6 and 2.9 percent, the homogenized alloys (48 hours at 2000 F.) for room temperature and 1500" F. being respectively, 0 and 2.5 percent, and the hot-rolled alloys (50% and 2400 F.) for room temperature and 1500 F. being, respectively, 0 and 4.4 percent.
The nickel-aluminum alloys, containing from 14 to 30 percent aluminum and prepared as castings with or without subsequent hot working,, not only possess desirable properties such as high strength, corrosion resistance and low specific gravity but also are formed of metals readily available as distinguished, from the expensive alloying conium, vanadium, niobium,.tantalum and iron. For example, the tensile strength of 17.5 percent-aluminum alloy at room temperature is increased from 83,800 pounds per square inch to 88,600 pounds per square inch by the addition of 5.0 percent molybdenum, and to 92,600 pounds per square inch by the addition of 0.05 percent boron.
Special attention has been given to the 17.5 percentaluminum alloy because. of its outstanding tensile strength and hot-rolling capability; However, alloys with sirable values, as indicated by the typical room temperature data in the following table.
Chemical Hardcomposition, ness percent; Phases present Tensile Elon- Rock- Density,
strength gation will g./ml. Ni AI 86 14 Ni Al 50, 600 6 3 62 7. 39 82. 5 17. 5 Ni Al-NiA1 83, 800 0 69 6.99 75 25 NiAl 24, 0 72 6.33 72 28 N iAl 20, 000 0 71 6. 12 70 30 NiAl 10, 300 0 5. 98
Obviously-many modifications and variations of the present invention are possible in the light of the above teachings. It is therefore to be understood that within the scope of the appended claim the invention may be practiced otherwise than as specifically described.
This application is a division of copending application No. 532,128, filed July 19, 1956.
What is claimed is:
A nickel-aluminum alloy casting having the combination of superior hot formability, strength, room-temperature and 1500" F. ductility, oxidation resistance and stress-to-rupture time, said casting being composed of an alloy consisting of the two phases Ni A1 and NiAl with about 17.5 percent aluminum, said casting being produced by forming the nickel in small discrete chips, forming the aluminum in pieces each larger than each of said nickel chips, placing the nickel chips and aluminum pieces in an induction furnace in contiguous overlying layers, introducing an inert atmosphere into said furnace at a pressure in excess of atmospheric, melting said aluminum prior to melting said nickel by applying electromagnetic flux to said nickel said nickel chips thereupon dissolving into the molten aluminum and reacting therewith to form said alloy and pouring said molten alloy into a mold external to said furnace said mold being at a temperature below that of said furnace, an inert atmosphere at a pressure in excess of atmospheric being continuously maintained in the apparatus during melting, casting and cooling.
References Cited in the file of this patent UNITED STATES PATENTS 2,755,184 Turner et al July 17, 1956 FOREIGN PATENTS 342,868 Great Britain Feb. 12, 1931 OTHER REFERENCES
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US616355A US2910356A (en) | 1956-07-19 | 1956-10-16 | Cast nickel alloy of high aluminum content |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US53212856A | 1956-07-19 | 1956-07-19 | |
US616355A US2910356A (en) | 1956-07-19 | 1956-10-16 | Cast nickel alloy of high aluminum content |
Publications (1)
Publication Number | Publication Date |
---|---|
US2910356A true US2910356A (en) | 1959-10-27 |
Family
ID=27063750
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US616355A Expired - Lifetime US2910356A (en) | 1956-07-19 | 1956-10-16 | Cast nickel alloy of high aluminum content |
Country Status (1)
Country | Link |
---|---|
US (1) | US2910356A (en) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3021211A (en) * | 1959-06-05 | 1962-02-13 | Westinghouse Electric Corp | High temperature nickel base alloys |
US3130045A (en) * | 1959-10-13 | 1964-04-21 | Owens Illinois Glass Co | Method of effecting exothermic reactions |
US3322515A (en) * | 1965-03-25 | 1967-05-30 | Metco Inc | Flame spraying exothermically reacting intermetallic compound forming composites |
US3436248A (en) * | 1965-03-25 | 1969-04-01 | Metco Inc | Flame spraying exothermically reacting intermetallic compound forming composites |
US3466166A (en) * | 1967-01-03 | 1969-09-09 | Gen Electric | Method for making a hollow metal article |
US3653976A (en) * | 1967-05-05 | 1972-04-04 | Gen Motors Corp | Thermocouple probe assembly with nickel aluminide tip |
US3925071A (en) * | 1968-05-20 | 1975-12-09 | Chrysler Corp | Heat resistant alloys |
US4379720A (en) * | 1982-03-15 | 1983-04-12 | Marko Materials, Inc. | Nickel-aluminum-boron powders prepared by a rapid solidification process |
US4610736A (en) * | 1983-03-23 | 1986-09-09 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Nickel base coating alloy |
US4642145A (en) * | 1982-03-08 | 1987-02-10 | Tsuyoshi Masumoto | Nickel alloy |
USH301H (en) | 1985-07-03 | 1987-07-07 | The United States Of America As Represented By The Department Of Energy | Oxidation resistant filler metals for direct brazing of structural ceramics |
US5116691A (en) * | 1991-03-04 | 1992-05-26 | General Electric Company | Ductility microalloyed NiAl intermetallic compounds |
US5116438A (en) * | 1991-03-04 | 1992-05-26 | General Electric Company | Ductility NiAl intermetallic compounds microalloyed with gallium |
US5215831A (en) * | 1991-03-04 | 1993-06-01 | General Electric Company | Ductility ni-al intermetallic compounds microalloyed with iron |
US5516380A (en) * | 1994-10-14 | 1996-05-14 | General Electric Company | NiAl intermetallic alloy and article with improved high temperature strength |
US5725691A (en) * | 1992-07-15 | 1998-03-10 | Lockheed Martin Energy Systems, Inc. | Nickel aluminide alloy suitable for structural applications |
US20050281704A1 (en) * | 2004-06-21 | 2005-12-22 | Siemens Westinghouse Power Corporation | Boron free joint for superalloy component |
US20100215978A1 (en) * | 2009-02-24 | 2010-08-26 | Honeywell International Inc. | Method of manufacture of a dual alloy impeller |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB342868A (en) * | 1930-01-13 | 1931-02-12 | Heraeus Vacuumschmelze Ag | Improvements relating to sulphur resisting alloys |
US2755184A (en) * | 1952-05-06 | 1956-07-17 | Thompson Prod Inc | Method of making ni3al |
-
1956
- 1956-10-16 US US616355A patent/US2910356A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB342868A (en) * | 1930-01-13 | 1931-02-12 | Heraeus Vacuumschmelze Ag | Improvements relating to sulphur resisting alloys |
US2755184A (en) * | 1952-05-06 | 1956-07-17 | Thompson Prod Inc | Method of making ni3al |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3021211A (en) * | 1959-06-05 | 1962-02-13 | Westinghouse Electric Corp | High temperature nickel base alloys |
US3130045A (en) * | 1959-10-13 | 1964-04-21 | Owens Illinois Glass Co | Method of effecting exothermic reactions |
US3322515A (en) * | 1965-03-25 | 1967-05-30 | Metco Inc | Flame spraying exothermically reacting intermetallic compound forming composites |
US3436248A (en) * | 1965-03-25 | 1969-04-01 | Metco Inc | Flame spraying exothermically reacting intermetallic compound forming composites |
US3466166A (en) * | 1967-01-03 | 1969-09-09 | Gen Electric | Method for making a hollow metal article |
US3653976A (en) * | 1967-05-05 | 1972-04-04 | Gen Motors Corp | Thermocouple probe assembly with nickel aluminide tip |
US3925071A (en) * | 1968-05-20 | 1975-12-09 | Chrysler Corp | Heat resistant alloys |
US4642145A (en) * | 1982-03-08 | 1987-02-10 | Tsuyoshi Masumoto | Nickel alloy |
US4379720A (en) * | 1982-03-15 | 1983-04-12 | Marko Materials, Inc. | Nickel-aluminum-boron powders prepared by a rapid solidification process |
US4610736A (en) * | 1983-03-23 | 1986-09-09 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Nickel base coating alloy |
USH301H (en) | 1985-07-03 | 1987-07-07 | The United States Of America As Represented By The Department Of Energy | Oxidation resistant filler metals for direct brazing of structural ceramics |
US5116691A (en) * | 1991-03-04 | 1992-05-26 | General Electric Company | Ductility microalloyed NiAl intermetallic compounds |
US5116438A (en) * | 1991-03-04 | 1992-05-26 | General Electric Company | Ductility NiAl intermetallic compounds microalloyed with gallium |
US5215831A (en) * | 1991-03-04 | 1993-06-01 | General Electric Company | Ductility ni-al intermetallic compounds microalloyed with iron |
US5725691A (en) * | 1992-07-15 | 1998-03-10 | Lockheed Martin Energy Systems, Inc. | Nickel aluminide alloy suitable for structural applications |
US5516380A (en) * | 1994-10-14 | 1996-05-14 | General Electric Company | NiAl intermetallic alloy and article with improved high temperature strength |
US20050281704A1 (en) * | 2004-06-21 | 2005-12-22 | Siemens Westinghouse Power Corporation | Boron free joint for superalloy component |
US7641985B2 (en) * | 2004-06-21 | 2010-01-05 | Siemens Energy, Inc. | Boron free joint for superalloy component |
US20100215978A1 (en) * | 2009-02-24 | 2010-08-26 | Honeywell International Inc. | Method of manufacture of a dual alloy impeller |
US8187724B2 (en) | 2009-02-24 | 2012-05-29 | Honeywell International Inc. | Method of manufacture of a dual alloy impeller |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2910356A (en) | Cast nickel alloy of high aluminum content | |
EP0693567B1 (en) | High-strength, high-ductility cast aluminum alloy and process for producing the same | |
US3524744A (en) | Nickel base alloys and process for their manufacture | |
CN109706354A (en) | A kind of material and preparation method thereof with good plasticity | |
CN115233042A (en) | Co-based Co-Fe-Ni-Al eutectic entropy alloy resistant to high-temperature oxidation and preparation method and application thereof | |
CN111719070A (en) | High-strength die-casting aluminum alloy material for mobile phone middle plate and preparation method thereof | |
CN111945042A (en) | High-strength high-toughness die-casting aluminum alloy material and preparation method thereof | |
US3529958A (en) | Method for the formation of an alloy composed of metals reactive in their elemental form with a melting container | |
Dey et al. | Micropyretic synthesis of tough NiAl alloys | |
Sandrock | The metallurgy and production of rechargeable hydrides | |
US3276865A (en) | High temperature cobalt-base alloy | |
US4908182A (en) | Rapidly solidified high strength, ductile dispersion-hardened tungsten-rich alloys | |
US2228600A (en) | Powder metallurgy | |
US3620852A (en) | Process for producing cobalt alloys | |
US3037858A (en) | Columbium base alloy | |
Chang et al. | Rapidly solidified Mg-Al-Zn-rare earth alloys | |
CN113355565A (en) | High-temperature-resistant welded aluminum alloy suitable for extrusion casting and preparation method thereof | |
US4084964A (en) | High HfC-containing alloys | |
US3676084A (en) | Refractory metal base alloy composites | |
US4534938A (en) | Method for making alloy additions to base metals having higher melting points | |
CN114752792B (en) | High-entropy alloy with excellent mechanical property and oxidation resistance at high temperature and preparation method thereof | |
CN115961221B (en) | Block amorphous alloy shaped charge liner and preparation method thereof | |
Jongenburger et al. | Recrystallization of ODS superalloys | |
US4765851A (en) | Aluminum alloy for the preparation of powders having increased high-temperature strength | |
KR950003051B1 (en) | Heat-resistant nickel forging alloy |