US2905577A - Creep resistant chromium steel - Google Patents

Creep resistant chromium steel Download PDF

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Publication number
US2905577A
US2905577A US557449A US55744956A US2905577A US 2905577 A US2905577 A US 2905577A US 557449 A US557449 A US 557449A US 55744956 A US55744956 A US 55744956A US 2905577 A US2905577 A US 2905577A
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steel
percent percent
temperature
solution
chromium steel
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US557449A
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Geoffrey T Harris
Henry C Child
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Birmingham Small Arms Co Ltd
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Birmingham Small Arms Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium

Definitions

  • This invention relates to ferritic chromium steels. Such steels have been used to a large extent in recent years for creep-resistant applications such as turbine and compressor discs in gas turbines. The normal procedure has been to harden and temper the alloy and it has been shown by numerous workers that the composition of the steel is critical if optimum properties are to be obtained, it being generally accepted that if the composition of the steel is such that it is not wholly austenitic-at the hardening or solution temperature, the final structure of the steel will be a tempered martensite with areas of free ferrite and if these areas of free ferrite are extensive, they have a deleterious effect on the creep strength and transverse ductility of the material.
  • any of the strongerdeoxidisers such as aluminium, cerium, magnesium could be present if desired but these are not essential.
  • chromium steels which are essentially ferritic (for example containing at least 60% ferrite) at normal solution or hardening temperatures (for example l000-1300 C.) and so do not harden on quenching, are subsequently treated to improve or provide creep strength.
  • the treatment referred to may consist of cold or Warm working the soft ferritic steel or by a combination of solution hardening and precipitation hardening of the material or by all three mechanisms.
  • Cold or warm working may comprise heating the solution treated material to the desired temperature within a suitable range, e.g. 20700 C., and then working it by rolling, stamping, pressing or any other means to a reduction in thickness or diameter of, for example 1% to 10%.
  • Solution hardening or precipitation hardening may be effected with the use of precipitation hardening additions, such for example, as molybdenum, tungsten, niobium, tantalum, titanium or other suitable known materials.
  • Steels suitable for cold or Warm working as above described may have any composition within the specification
  • the alloys are normally solution treated at 1000-1300 I (Land air, all or wateriquenched. .They aresuhsequently aged in the temperature range 500-700 C.
  • a normally non-handenahle chromium steel contain ing .at least 60% ferrite at 1000-1300 C., at least one element selected from the group consisting of 06% molybdenum, 0-6% tungsten and 0 2% vanadium where in the elements are present in'atotal amount'of at least 1.5% for the purpose of solution treatment wherein said steel has been treated to improve creep strength by the steps comprising solution treating the steel at a temperature in the range of 1000-1300 C., quenching the steel for the purpose of e'fifecting solutiontreatment thereof and working the steel at a temperature the temperature range of 20-700 C. to reduce the thickness thereof substantially 1%10%.
  • the steel .as defined in;.claim'1 containing at least one element selected from the group consisting of 0-2% titanium, and .0-.2% niobium and tantalum wherein said elements are present in an effective amount for producing precipitation hardening and wherein the steel has been treated to improve creep strength by the step comprising aging the steel in a temperature, range of 500-700 C. after the steel has been Worked to reduce the thickness thereof;

Description

United States Patent CREEP RESISTANT CHROMIUM STEEL Geolfrey T. Harris, Sheflield, and Henry C. Child, Rotherham, England, assignors to The Birmingham Small Arms Company Limited, Birmingham, England, a British company No Drawing. Application January 5, 1956 Serial No. 557,449
3 Claims. (Cl. nus-s1 This invention relates to ferritic chromium steels. Such steels have been used to a large extent in recent years for creep-resistant applications such as turbine and compressor discs in gas turbines. The normal procedure has been to harden and temper the alloy and it has been shown by numerous workers that the composition of the steel is critical if optimum properties are to be obtained, it being generally accepted that if the composition of the steel is such that it is not wholly austenitic-at the hardening or solution temperature, the final structure of the steel will be a tempered martensite with areas of free ferrite and if these areas of free ferrite are extensive, they have a deleterious effect on the creep strength and transverse ductility of the material.
v 2,905,577 Patented Sept. 22, 1959 Percent Carbon 0.05-0.33 Manganese v i Q 0.05-2.0 Nickel 0-4 Silicon 0.05-1.0 I Cobalt 0-4 I Chromium 9-20 Trungsten 03* Molybdenum; 0-3 Niobium and tantalum 0-2 Titanium 0-2 Vanadium 0-2 Nitrogen 0.0010.2 Boron 0005 *At least 0.7% total of these elements for adequate creep strengths.
In addition up to 0.5 total of any of the strongerdeoxidisers such as aluminium, cerium, magnesium could be present if desired but these are not essential.
Example of alloys within these ranges are:
0 Mn Si Cr Mo Nb V '1! N B W Percent Percent Percent Percent Percent Percent Percent Percent Percent Percent It is an object of the present invention to obviate the close control of composition.
According to this invention chromium steels which are essentially ferritic (for example containing at least 60% ferrite) at normal solution or hardening temperatures (for example l000-1300 C.) and so do not harden on quenching, are subsequently treated to improve or provide creep strength.
The treatment referred to may consist of cold or Warm working the soft ferritic steel or by a combination of solution hardening and precipitation hardening of the material or by all three mechanisms.
Cold or warm working may comprise heating the solution treated material to the desired temperature within a suitable range, e.g. 20700 C., and then working it by rolling, stamping, pressing or any other means to a reduction in thickness or diameter of, for example 1% to 10%.
Solution hardening or precipitation hardening may be effected with the use of precipitation hardening additions, such for example, as molybdenum, tungsten, niobium, tantalum, titanium or other suitable known materials.
Further features of the invention will be apparent from the following description of detailed methods, given by way of example of carrying out the invention.
Steels suitable for cold or Warm working as above described may have any composition within the specification The above alloys tested at 30 tons/sq. in. at 500 the following figures:
C. gave For solution hardening and precipitation hardening materials the specification is as above described with the exception of:
Percent Molybdenum 0-6* Tungsten 0-6 Vanadium 0-2 Niobium and tantalum 02T Titanium 0 2? Solution hardening addition, totalling at least 1.5%.
tPrecipitation hardening addition. These steels may also be warm worked but satisfactory creep strength can be achieved without this process. Examples:
0 Mn Si Cr Mo W V Nb N B Percent Percent Percent Percent Percent Percent Percent Percent Percent Percent WEX352 0. 05 0. 8 0. 3 13 1 1 0. 2 0. 6 0. 1 0. 01 WEX409 0. 05 0. 8 0. 3 13 2 2 0. 2 0. 5 0. 1 0. 01 WEX051 0. 05 0. 8 0. 3 13 2 2 0. 2 0. 25 0. 1 0. 01
The alloys are normally solution treated at 1000-1300 I (Land air, all or wateriquenched. .They aresuhsequently aged in the temperature range 500-700 C.
The above examples, when oil quenched at 1200" C., aged for 2.0 hours M650 and testede :30 DDS t i $50.01G.gawethetolldwingfigures: Y
What we 'claim is:
l. A normally non-handenahle chromium steel contain ing .at least 60% ferrite at 1000-1300 C., at least one element selected from the group consisting of 06% molybdenum, 0-6% tungsten and 0 2% vanadium where in the elements are present in'atotal amount'of at least 1.5% for the purpose of solution treatment wherein said steel has been treated to improve creep strength by the steps comprising solution treating the steel at a temperature in the range of 1000-1300 C., quenching the steel for the purpose of e'fifecting solutiontreatment thereof and working the steel at a temperature the temperature range of 20-700 C. to reduce the thickness thereof substantially 1%10%.
'2. The steel .as defined in;.claim'1 containing at least one element selected from the group consisting of 0-2% titanium, and .0-.2% niobium and tantalum wherein said elements are present in an effective amount for producing precipitation hardening and wherein the steel has been treated to improve creep strength by the step comprising aging the steel in a temperature, range of 500-700 C. after the steel has been Worked to reduce the thickness thereof;
3. The steel as defined in claim 1 containing at least one-element selected from the "group consisting of 0 2% titaniumyand 0 2% niobium and tantalum wherein said elements are present in an effective amount ior producing precipitation hardening and wherein the steel has been treated to impress creep strength theneof .by the step comprising aging the steeliat a temperature range of 5 00-7 00 C. following quenching ofsaid steel and before working of said steel to reduce the'thickness thereof.
References Cited in the file of this patent

Claims (1)

1. A NORMALLY NON-HARDENABLE CHLORMIUM STEEL CONTAINING AT LEAST 60% FERRITE AT 1000*-1300*C., AT LEAST ONE ELEMENT SELECTED FROM THE GROUP CONSISTING OF 0-6% MOLYBDENUM, 0-6% TUNGSTEN AND 0-2% VANADIUM WHEREIN THE ELEMENTS ARE PRESENT IN A TOTAL AMOUNT OF AT LEAST 1.5% FOR THE PURPOSE OF SOLUTION TREATMENT WHEREIN SAID STEEL HAS BEEN TREATED TO IMPROVE CREEP STRENGTH BY THE STEPS COMPRISING SOLUTION TREATING THE STEEL AT A TEMPERATURE IN THE RANGE OF 1000*-1300*C., QUENCHING THE STEEL FOR THE PURPOSE OF EFFECTING SOLUTION TREATMENT THEREOF AND WORKING THE STEEL AT A TEMPERATURE WITHIN THE TEMPERATURE RANGE OF 20*-700*C. TO REDUCE THE THICKNESS THEREOF SUBSTANTIALLY 1%-10%.
US557449A 1956-01-05 1956-01-05 Creep resistant chromium steel Expired - Lifetime US2905577A (en)

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Cited By (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3044872A (en) * 1959-11-02 1962-07-17 North American Aviation Inc Steel alloy composition
US3141800A (en) * 1962-01-03 1964-07-21 United States Steel Corp Dimensionally stable stainless steel press plates and method of forming same
US3183080A (en) * 1961-11-21 1965-05-11 Universal Cyclops Steel Corp Stainless steels and products thereof
US3201231A (en) * 1961-11-21 1965-08-17 Universal Cyclops Steel Corp Stainless steels
US3216868A (en) * 1961-03-06 1965-11-09 Lasalle Steel Co Elevated temperature working and heat treatment of stainless steel
US3250611A (en) * 1963-04-10 1966-05-10 Allegheny Ludlum Steel Corrosion-resisting steel and method of processing
US3309238A (en) * 1962-05-16 1967-03-14 Suedwestfalen Ag Stahlwerke Deep drawing of stainless steels, and steel therefor
US3617258A (en) * 1966-10-21 1971-11-02 Toyo Kogyo Co Heat resistant alloy steel
US3660174A (en) * 1968-05-31 1972-05-02 Uddeholms Ab Method in the manufacture of stainless, hardenable chromium-steel strip and sheet
US3719476A (en) * 1969-08-29 1973-03-06 Armco Steel Corp Precipitation-hardenable stainless steel
US3753788A (en) * 1971-10-15 1973-08-21 Republic Steel Corp Non-ribbing ferritic steel and process
US3807991A (en) * 1971-10-29 1974-04-30 Airco Inc Ferritic stainless steel alloy
US3890143A (en) * 1972-04-14 1975-06-17 Nyby Bruk Ab Welded constructions of stainless steels
US3928088A (en) * 1973-11-09 1975-12-23 Carpenter Technology Corp Ferritic stainless steel
US3929471A (en) * 1971-12-22 1975-12-30 Hitachi Ltd High speed steel having high wear-resistance
US3933479A (en) * 1974-10-10 1976-01-20 United States Steel Corporation Vanadium stabilized martensitic stainless steel
US4070208A (en) * 1977-01-03 1978-01-24 Nippon Steel Corporation Method for the manufacture of a ridging-free ferritic stainless steel sheet
US4222771A (en) * 1973-02-28 1980-09-16 Mitsubishi Jukogyo Kabushiki Kaisha High chromium steel of mixed structure containing ferrite for high temperature use
US4261739A (en) * 1979-08-06 1981-04-14 Armco Inc. Ferritic steel alloy with improved high temperature properties
US4286986A (en) * 1979-08-01 1981-09-01 Allegheny Ludlum Steel Corporation Ferritic stainless steel and processing therefor
US4540424A (en) * 1983-02-26 1985-09-10 Kubota, Ltd. Heat-resisting alloy for rolls for glass forming
EP0199046A1 (en) * 1985-04-06 1986-10-29 Nippon Steel Corporation High-strength heat-resisting ferritic steel pipe and tube
US4622067A (en) * 1985-02-07 1986-11-11 The United States Of America As Represented By The United States Department Of Energy Low activation ferritic alloys
GB2179674A (en) * 1985-07-25 1987-03-11 Nippon Kokan Kk 9% Chromium heat-resistant steel
US4857120A (en) * 1984-06-21 1989-08-15 Kabushiki Kaisha Toshiba Heat-resisting steel turbine part
US4917738A (en) * 1985-07-09 1990-04-17 Mitsubishi Jukogyo Kabushiki Kaisha Steam turbine rotor for high temperature
US4929288A (en) * 1988-01-04 1990-05-29 Borges Robert J Corrosion and abrasion resistant alloy
US5236521A (en) * 1990-06-06 1993-08-17 Nkk Corporation Abrasion resistant steel
US5292384A (en) * 1992-07-17 1994-03-08 Martin Marietta Energy Systems, Inc. Cr-W-V bainitic/ferritic steel with improved strength and toughness and method of making
US5310431A (en) * 1992-10-07 1994-05-10 Robert F. Buck Creep resistant, precipitation-dispersion-strengthened, martensitic stainless steel and method thereof
US5403410A (en) * 1990-06-06 1995-04-04 Nkk Corporation Abrasion-resistant steel
DE19505074A1 (en) * 1994-02-15 1995-09-14 Mitsubishi Materials Corp Iron@-chromium@ alloy used for diesel engine nozzles
US5824265A (en) * 1996-04-24 1998-10-20 J & L Fiber Services, Inc. Stainless steel alloy for pulp refiner plate
EP0887431A1 (en) * 1997-06-25 1998-12-30 Mitsubishi Heavy Industries, Ltd. Heat-resisting steel
DE10025808A1 (en) * 2000-05-24 2001-11-29 Alstom Power Nv Martensitic hardenable tempering steel with improved heat resistance and ductility
US6375764B1 (en) * 1998-12-24 2002-04-23 Nisshin Steel Co., Ltd. Weaving machine member made of an abrasion-resistant steel
US20040154706A1 (en) * 2003-02-07 2004-08-12 Buck Robert F. Fine-grained martensitic stainless steel and method thereof
US20040154707A1 (en) * 2003-02-07 2004-08-12 Buck Robert F. Fine-grained martensitic stainless steel and method thereof
US20080000737A1 (en) * 2005-03-17 2008-01-03 Jfe Steel Corporation, A Corporation Of Japan Stainless Steel Sheet with Excellent Heat and Corrosion Resistances for Brake Disk
EP1988182A1 (en) * 2006-02-06 2008-11-05 Babcock-Hitachi Kabushiki Kaisha Ferritic heat-resistant steel
US20140086755A1 (en) * 2011-06-07 2014-03-27 Borgwarner Inc. Turbocharger and component therefor
US10246765B2 (en) * 2014-01-17 2019-04-02 Nippon Steel & Sumitomo Metal Corporation Martensitic Cr-containing steel and oil country tubular goods

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2397997A (en) * 1944-06-21 1946-04-09 Ernest H Wyche Providing inherently aging chromium-nickel stainless steel with different tempers
US2401580A (en) * 1943-12-28 1946-06-04 Allegheny Ludlum Steel Method of increasing the high temperature strength of heat-resisting alloys
US2469887A (en) * 1945-10-02 1949-05-10 Gen Electric Forgeable high-temperature alloys
US2693413A (en) * 1951-01-31 1954-11-02 Firth Vickers Stainless Steels Ltd Alloy steels
GB722809A (en) * 1951-08-23 1955-02-02 Henry William Kirby Improvements relating to alloy steels for use at elevated temperatures
US2793113A (en) * 1952-08-22 1957-05-21 Hadfields Ltd Creep resistant steel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2401580A (en) * 1943-12-28 1946-06-04 Allegheny Ludlum Steel Method of increasing the high temperature strength of heat-resisting alloys
US2397997A (en) * 1944-06-21 1946-04-09 Ernest H Wyche Providing inherently aging chromium-nickel stainless steel with different tempers
US2469887A (en) * 1945-10-02 1949-05-10 Gen Electric Forgeable high-temperature alloys
US2693413A (en) * 1951-01-31 1954-11-02 Firth Vickers Stainless Steels Ltd Alloy steels
GB722809A (en) * 1951-08-23 1955-02-02 Henry William Kirby Improvements relating to alloy steels for use at elevated temperatures
US2793113A (en) * 1952-08-22 1957-05-21 Hadfields Ltd Creep resistant steel

Cited By (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3044872A (en) * 1959-11-02 1962-07-17 North American Aviation Inc Steel alloy composition
US3216868A (en) * 1961-03-06 1965-11-09 Lasalle Steel Co Elevated temperature working and heat treatment of stainless steel
US3183080A (en) * 1961-11-21 1965-05-11 Universal Cyclops Steel Corp Stainless steels and products thereof
US3201231A (en) * 1961-11-21 1965-08-17 Universal Cyclops Steel Corp Stainless steels
US3141800A (en) * 1962-01-03 1964-07-21 United States Steel Corp Dimensionally stable stainless steel press plates and method of forming same
US3309238A (en) * 1962-05-16 1967-03-14 Suedwestfalen Ag Stahlwerke Deep drawing of stainless steels, and steel therefor
US3250611A (en) * 1963-04-10 1966-05-10 Allegheny Ludlum Steel Corrosion-resisting steel and method of processing
US3617258A (en) * 1966-10-21 1971-11-02 Toyo Kogyo Co Heat resistant alloy steel
US3660174A (en) * 1968-05-31 1972-05-02 Uddeholms Ab Method in the manufacture of stainless, hardenable chromium-steel strip and sheet
US3719476A (en) * 1969-08-29 1973-03-06 Armco Steel Corp Precipitation-hardenable stainless steel
US3753788A (en) * 1971-10-15 1973-08-21 Republic Steel Corp Non-ribbing ferritic steel and process
US3807991A (en) * 1971-10-29 1974-04-30 Airco Inc Ferritic stainless steel alloy
US3929471A (en) * 1971-12-22 1975-12-30 Hitachi Ltd High speed steel having high wear-resistance
US3890143A (en) * 1972-04-14 1975-06-17 Nyby Bruk Ab Welded constructions of stainless steels
US4222771A (en) * 1973-02-28 1980-09-16 Mitsubishi Jukogyo Kabushiki Kaisha High chromium steel of mixed structure containing ferrite for high temperature use
US3928088A (en) * 1973-11-09 1975-12-23 Carpenter Technology Corp Ferritic stainless steel
US3933479A (en) * 1974-10-10 1976-01-20 United States Steel Corporation Vanadium stabilized martensitic stainless steel
US4070208A (en) * 1977-01-03 1978-01-24 Nippon Steel Corporation Method for the manufacture of a ridging-free ferritic stainless steel sheet
US4286986A (en) * 1979-08-01 1981-09-01 Allegheny Ludlum Steel Corporation Ferritic stainless steel and processing therefor
US4261739A (en) * 1979-08-06 1981-04-14 Armco Inc. Ferritic steel alloy with improved high temperature properties
US4540424A (en) * 1983-02-26 1985-09-10 Kubota, Ltd. Heat-resisting alloy for rolls for glass forming
US4857120A (en) * 1984-06-21 1989-08-15 Kabushiki Kaisha Toshiba Heat-resisting steel turbine part
US4622067A (en) * 1985-02-07 1986-11-11 The United States Of America As Represented By The United States Department Of Energy Low activation ferritic alloys
EP0199046A1 (en) * 1985-04-06 1986-10-29 Nippon Steel Corporation High-strength heat-resisting ferritic steel pipe and tube
US4917738A (en) * 1985-07-09 1990-04-17 Mitsubishi Jukogyo Kabushiki Kaisha Steam turbine rotor for high temperature
GB2179674B (en) * 1985-07-25 1989-08-23 Nippon Kokan Kk 9% chromium heat-resistant steel excellent in toughness and having high cracking resistance and high creep strength in welded joint
GB2179674A (en) * 1985-07-25 1987-03-11 Nippon Kokan Kk 9% Chromium heat-resistant steel
US5116571A (en) * 1985-07-25 1992-05-26 Nippon Kokan Kabushiki Kaisha Chromoum heat-resistant steel excellent in toughness and having high cracking resistance and high creep strength in welded joint
US4929288A (en) * 1988-01-04 1990-05-29 Borges Robert J Corrosion and abrasion resistant alloy
US5236521A (en) * 1990-06-06 1993-08-17 Nkk Corporation Abrasion resistant steel
US5403410A (en) * 1990-06-06 1995-04-04 Nkk Corporation Abrasion-resistant steel
US5292384A (en) * 1992-07-17 1994-03-08 Martin Marietta Energy Systems, Inc. Cr-W-V bainitic/ferritic steel with improved strength and toughness and method of making
US5310431A (en) * 1992-10-07 1994-05-10 Robert F. Buck Creep resistant, precipitation-dispersion-strengthened, martensitic stainless steel and method thereof
DE19505074A1 (en) * 1994-02-15 1995-09-14 Mitsubishi Materials Corp Iron@-chromium@ alloy used for diesel engine nozzles
US5824265A (en) * 1996-04-24 1998-10-20 J & L Fiber Services, Inc. Stainless steel alloy for pulp refiner plate
EP0887431A1 (en) * 1997-06-25 1998-12-30 Mitsubishi Heavy Industries, Ltd. Heat-resisting steel
US5972287A (en) * 1997-06-25 1999-10-26 Mitsubishi Heavy Industries, Ltd. Heat-resisting steel
US6375764B1 (en) * 1998-12-24 2002-04-23 Nisshin Steel Co., Ltd. Weaving machine member made of an abrasion-resistant steel
US20020108680A1 (en) * 1998-12-24 2002-08-15 Nisshin Steel Co., Ltd. Abrasion resistant steel
DE10025808A1 (en) * 2000-05-24 2001-11-29 Alstom Power Nv Martensitic hardenable tempering steel with improved heat resistance and ductility
US6464804B2 (en) 2000-05-24 2002-10-15 Alstom (Switzerland) Ltd Martensitic-hardenable heat-treated steel with improved resistance to heat and ductility
US6899773B2 (en) 2003-02-07 2005-05-31 Advanced Steel Technology, Llc Fine-grained martensitic stainless steel and method thereof
US20040154707A1 (en) * 2003-02-07 2004-08-12 Buck Robert F. Fine-grained martensitic stainless steel and method thereof
US6890393B2 (en) 2003-02-07 2005-05-10 Advanced Steel Technology, Llc Fine-grained martensitic stainless steel and method thereof
US20040154706A1 (en) * 2003-02-07 2004-08-12 Buck Robert F. Fine-grained martensitic stainless steel and method thereof
US20080000737A1 (en) * 2005-03-17 2008-01-03 Jfe Steel Corporation, A Corporation Of Japan Stainless Steel Sheet with Excellent Heat and Corrosion Resistances for Brake Disk
US8852361B2 (en) * 2005-03-17 2014-10-07 Jfe Steel Corporation Stainless steel sheet with excellent heat and corrosion resistances for brake disk
EP1988182A1 (en) * 2006-02-06 2008-11-05 Babcock-Hitachi Kabushiki Kaisha Ferritic heat-resistant steel
US20090007991A1 (en) * 2006-02-06 2009-01-08 Toshio Fujita Ferritic Heat-Resistant Steel
US20110017355A1 (en) * 2006-02-06 2011-01-27 Toshio Fujita Ferritic heat-resistant steel
EP1988182A4 (en) * 2006-02-06 2013-10-16 Babcock Hitachi Kk Ferritic heat-resistant steel
US20140086755A1 (en) * 2011-06-07 2014-03-27 Borgwarner Inc. Turbocharger and component therefor
US10246765B2 (en) * 2014-01-17 2019-04-02 Nippon Steel & Sumitomo Metal Corporation Martensitic Cr-containing steel and oil country tubular goods

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