US2900710A - Method of making colored wire - Google Patents
Method of making colored wire Download PDFInfo
- Publication number
- US2900710A US2900710A US557628A US55762856A US2900710A US 2900710 A US2900710 A US 2900710A US 557628 A US557628 A US 557628A US 55762856 A US55762856 A US 55762856A US 2900710 A US2900710 A US 2900710A
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- US
- United States
- Prior art keywords
- rod
- wire
- lime
- solution
- making colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/84—Dyeing
Definitions
- This invention relates to a method of making colored wire and more particularly for making steel wire which is colored for identification purposes.
- wire There are many different types of wire which is used for many purposes. When improperly identified wire is used for the wrong purpose it does not function satisfactorily. For that reason it is desired to mark the wire so that it can be identified as to grade and type. This is most commonly done by attaching a tag to the wire or painting a portion thereof. In many instances the paint comes off or the painted portion is removed before the whole coil is utilized. The tag is often lost.
- Another object is to provide such a method in which the coloring is applied while a rod is being made into wire.
- a base coating is then applied 35 to the rod. This may be done by dipping a coil of rod into a water solution of hydrated lime.
- the lime concentration is generally between 4 and 10% by weight and the number of lime dips may vary. Generally from 1 to 12 dips are used.
- the rod with the lime coating thereon is dried either in air or by flash baking. When air drying the lime solution should be heated to a temperature of approximately 200.
- Other standard base coatings such as carbonates,.phosphates, borates, silicates, titanium dioxide, chromates and magnesium oxide may be used in place of the lime.
- the rod with the coating thereon is dipped into a tub containing a water solution of a water soluble dye.
- a water soluble dye functions for the desired purpose.
- Some dyes actually used include Eosine l, Calcocid Alizarine Green CGEX, Calcomine Sky Blue FF Ex. Cone, Alizarine Cyanine Green Base, Calcophen Red Y, each of which is manufactured by American Cyanamid Company and Monastral Fast Green GWD, Pontacyl Green NV Extra, Du Pont Naphthol Green B Extra conc. 125%, each of which is manufactured by E. I. du Pont Company.
- the concentration of the dye in the water may vary and depends on the type of dye and the number of times the coil is to be dipped into the solution.
- the solution may consist of one pound of dye to 50 gallons of water.
- the rod is atent 0 "2,900,710 Patented Aug. 25, 1959 dried between each dip in the coloring solution, preferably by permitting it to stand in the air.
- the coloring solution is maintained at a temperature between 160 and 200 F. but the solution can be applied at a lower temperature if desired.
- the coil is preferably flash baked for five minutes at a temperature of 450 F. to make sure that the coatings are thoroughly dried.
- the rod with the lime coating and coloring thereon is then drawn into wire in multiple passes in the usual manner.
- a dry lubricant is used and the color intensity on the drawn wire improves as lubricants With higher titre values are used.
- Titre is a term used in the wire drawing art to indicate the solidifying point of the fatty acid which is reacted with a particular base to compound the lubricant. Large drafting reductions give the color a brighter luster than smaller reductions. Multiple drafting spreads the coloring thickness more evenly but also thins it out.
- This method of applying coating is inexpensive and fits well into the usual operations of wire drawing. The coating so produced is uniform and suitable for further wire drawing or. as a lubricating film in producing cold headed or screw stock products.
- the method of making colored wire comprising providing a rod, cleaning the rod, applying a wire drawing base coating to the surface of the rod, applying a solution of a water soluble dye to the rod with the base coating thereon, drying the rod with the dye thereon, and then drawing the rod to wire of the desired diameter.
- the method of making colored wire comprising providing a rod, cleaning the rod, applying a water solution of hydrated lime to the surface of the rod, drying the rod with the lime thereon, applying a solution of a water soluble dye to the rod with the lime thereon, drying the rod with the lime and dye thereon, and then drawing the rod to wire of the desired diameter.
- the method of making colored wire comprising providing a coil of rod, removing scale and foreign material from the surface of the rod, dipping the coil into a water solution of hydrated lime, then drying the coils of rod, dipping the dried coil into a water solution of a water soluble dye, drying the coil of rod with the lime and dye thereon, and then drawing the rod to wire of the desired diameter.
- the method of making colored wire comprising providing a rod, cleaning the rod, applying a wire drawing base coating of a material of the class consisting of hydrated lime, carbonates, phosphates, borates, silicates, titanium dioxide, chromates and magnesium oxide to the surface of the rod, drying the rod with the base coating thereon, applying a solution of a water soluble dye to the rod with the base coating thereon, drying the rod with the base coating and dye thereon, and then drawing the rod to wire of the desired diameter.
- a wire drawing base coating of a material of the class consisting of hydrated lime, carbonates, phosphates, borates, silicates, titanium dioxide, chromates and magnesium oxide
Description
METHOD OF MAKING COLORED WIRE Leonard T. Hurat, Cleveland, and Edward P. Presby, Garfield Heights, Ohio, assignors to United States Steel Corporation, a corporation of New Jersey No Drawing. Application January 6, 1956 Serial No. 557,628 10 4 Claims. (Cl. 29-407) This invention relates to a method of making colored wire and more particularly for making steel wire which is colored for identification purposes. There are many different types of wire which is used for many purposes. When improperly identified wire is used for the wrong purpose it does not function satisfactorily. For that reason it is desired to mark the wire so that it can be identified as to grade and type. This is most commonly done by attaching a tag to the wire or painting a portion thereof. In many instances the paint comes off or the painted portion is removed before the whole coil is utilized. The tag is often lost.
It is therefore an object of our invention to provide a method of coloring wire wherein the color adheres tightly to the wire.
Another object is to provide such a method in which the coloring is applied while a rod is being made into wire.
These and other objects will be more apparent after referring to the following specification.
In carrying out our invention scale and foreign material is removed from the rod. A base coating is then applied 35 to the rod. This may be done by dipping a coil of rod into a water solution of hydrated lime. The lime concentration is generally between 4 and 10% by weight and the number of lime dips may vary. Generally from 1 to 12 dips are used. After each dip the rod with the lime coating thereon is dried either in air or by flash baking. When air drying the lime solution should be heated to a temperature of approximately 200. Other standard base coatings such as carbonates,.phosphates, borates, silicates, titanium dioxide, chromates and magnesium oxide may be used in place of the lime. Each of the above steps are conventional in the wire drawing art. After the lime coating is dried the rod with the coating thereon is dipped into a tub containing a water solution of a water soluble dye. Any water soluble dye functions for the desired purpose. Some dyes actually used include Eosine l, Calcocid Alizarine Green CGEX, Calcomine Sky Blue FF Ex. Cone, Alizarine Cyanine Green Base, Calcophen Red Y, each of which is manufactured by American Cyanamid Company and Monastral Fast Green GWD, Pontacyl Green NV Extra, Du Pont Naphthol Green B Extra conc. 125%, each of which is manufactured by E. I. du Pont Company. The concentration of the dye in the water may vary and depends on the type of dye and the number of times the coil is to be dipped into the solution. Increasing the number of dips increases the vividness of the color on the drawn wire and also increases the coverage. Increasing the concentration of the coloring solution improves the vividness of the color. By way of example, the solution may consist of one pound of dye to 50 gallons of water. The rod is atent 0 "2,900,710 Patented Aug. 25, 1959 dried between each dip in the coloring solution, preferably by permitting it to stand in the air. To increase the speed of drying the coloring solution is maintained at a temperature between 160 and 200 F. but the solution can be applied at a lower temperature if desired. After the last dip the coil is preferably flash baked for five minutes at a temperature of 450 F. to make sure that the coatings are thoroughly dried. The rod with the lime coating and coloring thereon is then drawn into wire in multiple passes in the usual manner. A dry lubricant is used and the color intensity on the drawn wire improves as lubricants With higher titre values are used. Titre is a term used in the wire drawing art to indicate the solidifying point of the fatty acid which is reacted with a particular base to compound the lubricant. Large drafting reductions give the color a brighter luster than smaller reductions. Multiple drafting spreads the coloring thickness more evenly but also thins it out. This method of applying coating is inexpensive and fits well into the usual operations of wire drawing. The coating so produced is uniform and suitable for further wire drawing or. as a lubricating film in producing cold headed or screw stock products.
While one embodiment of our invention has been shown and described it will be apparent that other adaptations and modifications may be made without departing from the scope of the following claims.
We claim:
1. The method of making colored wire comprising providing a rod, cleaning the rod, applying a wire drawing base coating to the surface of the rod, applying a solution of a water soluble dye to the rod with the base coating thereon, drying the rod with the dye thereon, and then drawing the rod to wire of the desired diameter.
2. The method of making colored wire comprising providing a rod, cleaning the rod, applying a water solution of hydrated lime to the surface of the rod, drying the rod with the lime thereon, applying a solution of a water soluble dye to the rod with the lime thereon, drying the rod with the lime and dye thereon, and then drawing the rod to wire of the desired diameter.
3. The method of making colored wire comprising providing a coil of rod, removing scale and foreign material from the surface of the rod, dipping the coil into a water solution of hydrated lime, then drying the coils of rod, dipping the dried coil into a water solution of a water soluble dye, drying the coil of rod with the lime and dye thereon, and then drawing the rod to wire of the desired diameter.
4. The method of making colored wire comprising providing a rod, cleaning the rod, applying a wire drawing base coating of a material of the class consisting of hydrated lime, carbonates, phosphates, borates, silicates, titanium dioxide, chromates and magnesium oxide to the surface of the rod, drying the rod with the base coating thereon, applying a solution of a water soluble dye to the rod with the base coating thereon, drying the rod with the base coating and dye thereon, and then drawing the rod to wire of the desired diameter.
References Cited in the file of this patent UNITED STATES PATENTS 1,712,348 Howe May 7, 1929 1,932,454 Franks Oct. 31, 1933 2,546,447 Ham's Mar. 27, 1951
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US557628A US2900710A (en) | 1956-01-06 | 1956-01-06 | Method of making colored wire |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US557628A US2900710A (en) | 1956-01-06 | 1956-01-06 | Method of making colored wire |
Publications (1)
Publication Number | Publication Date |
---|---|
US2900710A true US2900710A (en) | 1959-08-25 |
Family
ID=24226234
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US557628A Expired - Lifetime US2900710A (en) | 1956-01-06 | 1956-01-06 | Method of making colored wire |
Country Status (1)
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US (1) | US2900710A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3188791A (en) * | 1963-04-22 | 1965-06-15 | United States Steel Corp | Locked coil cable and method of making same |
US3895971A (en) * | 1973-05-18 | 1975-07-22 | Kaiser Aluminium Chem Corp | Method of lubricating an aluminum workpiece |
US20040265485A1 (en) * | 2003-06-24 | 2004-12-30 | Yazaki Corporation | Method and apparatus for coloring electric wire |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1712348A (en) * | 1926-12-10 | 1929-05-07 | American Steel & Wire Co | Method of manufacturing wire |
US1932454A (en) * | 1929-11-30 | 1933-10-31 | Electro Metallurg Co | Metal drawing |
US2546447A (en) * | 1945-05-15 | 1951-03-27 | American Steel & Wire Co | Art of drawing fine steel wire |
-
1956
- 1956-01-06 US US557628A patent/US2900710A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1712348A (en) * | 1926-12-10 | 1929-05-07 | American Steel & Wire Co | Method of manufacturing wire |
US1932454A (en) * | 1929-11-30 | 1933-10-31 | Electro Metallurg Co | Metal drawing |
US2546447A (en) * | 1945-05-15 | 1951-03-27 | American Steel & Wire Co | Art of drawing fine steel wire |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3188791A (en) * | 1963-04-22 | 1965-06-15 | United States Steel Corp | Locked coil cable and method of making same |
US3895971A (en) * | 1973-05-18 | 1975-07-22 | Kaiser Aluminium Chem Corp | Method of lubricating an aluminum workpiece |
US20040265485A1 (en) * | 2003-06-24 | 2004-12-30 | Yazaki Corporation | Method and apparatus for coloring electric wire |
US7968142B2 (en) * | 2003-06-24 | 2011-06-28 | Yazaki Corporation | Method and apparatus for coloring electric wire |
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