US2853453A - Textile lubricants - Google Patents

Textile lubricants Download PDF

Info

Publication number
US2853453A
US2853453A US494256A US49425655A US2853453A US 2853453 A US2853453 A US 2853453A US 494256 A US494256 A US 494256A US 49425655 A US49425655 A US 49425655A US 2853453 A US2853453 A US 2853453A
Authority
US
United States
Prior art keywords
oil
parts
soluble
water
textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US494256A
Other languages
English (en)
Inventor
Maurice Elton
Philip Alan Winsor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Research Ltd
Shell Development Co
Original Assignee
Shell Research Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Research Ltd filed Critical Shell Research Ltd
Application granted granted Critical
Publication of US2853453A publication Critical patent/US2853453A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/063—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104—Aromatic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/20—Rosin acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/288—Partial esters containing free carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/066—Arylene diamines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/10—Amides of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/10—Amides of carbonic or haloformic acids
    • C10M2215/102—Ureas; Semicarbazides; Allophanates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/14—Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/042—Sulfate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/064—Thiourea type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S260/00—Chemistry of carbon compounds
    • Y10S260/15—Antistatic agents not otherwise provided for
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents

Definitions

  • the present invention relates to lubricants for textiles and to a method of lubricating textile fibers. More particularly, it relates to emulsifiable and water emulsion textile lubricants and to the lubrication of textile fibers therewith during spinning and the like.
  • the lubricated fibers possess little or no resistance to slipping with the result that they shift and slip constantly during processing and are therefore difiicult if not impossible to process satisfactorily.
  • an improved textile lubricant whose static coefficient of friction exceeds its dynamic coeflicieut of friction, is provided by an emulsifiable concentrate comprising a major proportion of a mineral lubricating oil and minor proportions each, of an oil-soluble organic sulfonate, an oil-soluble non-ionic emulsifier and a nitrogenous emulsifier which is soluble in oil but substantially insoluble in water.
  • sulfonates from about 2% to about non-ionic emulsifier, from about0.5% to about 10% and the nitrogenous emulsifier from about 1% to about 13% by weight.
  • the amount of nitrogenous emulsifier used is governed by the amount of sulfonate present in the blend. By properly adjusting their proportions the static coefiicient of friction can be maintained greater than the dynamic coefiicient of friction. Generally, the nitrogenous emulsifier is used in amounts equal to about one-half of the amount of sulfonate used in the blend.
  • the concentrates of the invention preferably contain a minor proportion of water, for example, up to 10% and preferably about 1 to 5% by weight of the composition.
  • concentrates may be used as such or they may be used in the form of aqueous emulsions obtained on diluting them with from about 19 to 99 volumes of water.
  • aqueous emulsions containing about 2% by volume of the concentrate are used.
  • Emulsification usually occurs spontaneously on diluting with water and the aqueous emulsions have very high stability.
  • the aqueous emulsions are included within the scope of the invention.
  • the emulsifiable compositions of the invention are preferably so constituted as by the incorporation of a water-soluble inorganic base, that an emulsion containing 2 parts by volume thereof in 98 parts by volume'of distilled water has a pH value greater than 7, preferably greater than 9.
  • the mineral lubricating oil used in the compositions of the invention may be of any type. It may be a lightly refined oil, such as has been refined by distillation, solvent extraction, clay treatment or treatment with dilute acid or other chemical, or a highly refined oil, such as has been treated with fuming sulfuric acid, withor without prior solvent extraction.
  • the oils may be, highly parafiinic oils containing at least 65% by weight of material remaining unsulfonated when treated with concentrated sulfuric acid, or may contain naphthenic and aromatic constituents.
  • highly refined oils are preferred because of their greater stability and resistance to the development of odor and col-or on exposure to light and air; they should have a flash point sufiiciently high to satisfy the requirements of any particular section of the industry. Thus, in the worstedand woolen trades, a minimum flash point of 340 F. is required.
  • oil-soluble sulfonates used in the compositions of this invention can be of various types such as neutral and/ or basic and can be derived from any suitable material and prepared by any of the well-known suitable methods.
  • Preferred materials for making oil-soluble sulfonates include mineral lubricating oil fractions, alkyl-substituted aromatic compounds and alkyl-substituted polar containing aromatic compounds.
  • Petroleum sulf-onates suitable for use in compositions of this invention are described in United States Patents 2,280,419, 2,344,988, 2,361,804, 2,375,222, 2,480,638, 2,485,861, 2,509,863, 2,501,731, 2,523,582 and 2,585,520.
  • the sulfonates can'be purified by the methods described in United States Patents 2,441,258 and 2,488,721.
  • Suitable aromatic sulfonates include those described in United States Patents 2,411,583, 2,418,894, 2,442,915, 2,483,501, 2,531,324, 2,556,108 and 2,556,848.
  • various metal sulfonates are contemplated in the practice of the invention, including alkali metal sulfonates, alkaline earth metal sulfonates (including magnesium) and other polyvalent metal sulfonates
  • the nitrogen base sulfonates obtained by treating sulfonic acids with ammonia orv an amine such as aliphatic amines or alkylolamines such as triethanolamine also can be used.
  • Specific sulfonates which are suitable for use in compositions of this' invention include: Na, K, Li, Ca, Ba, Mg, ammonia, triethanolamine petroleum sulfonate, tetra-tertiary-butylnaphthalene sulfonate, diwaxbenzenesulfonate, stearylbenzenesulfonate, diwaxnaphthalenesulfonate, diisobutylencphenolsulfonatc, tertiaryctylphenol sulfonate, ditertiary-amylphcno-l sulfonate, alkylated-dibcnzothiophene sulfonate and mixtures thereof.
  • Preferred are thes a'lts of these acids in which the cationicportion is a water, soluble base of a monovalent cation.
  • Preferred sulfonates for use in compositions of thisinvention are obtained as a by-product during the menu:
  • petroleum sulfonic acids whose salts are used in the compositions of the invention preferably have an average molecular weight of from 420 to 450, although they can be as much as 350 to as high as 600, the sodium petroleum sulfonates which are available commercially being preferred.
  • oilsoluble non-ionic emulsifier A wide variety of compounds may be used as the oilsoluble non-ionic emulsifier. These compounds are preferentially oilsoluble but may also be soluble in water to a minor extent. Suitable compounds are those containing an alcoholic hydroxyl group and the following classes of compounds have proved effective:
  • Oil-soluble monohydric alcohols e. g., the octanols, nonanols, decanols, undecanols, dodecanols and the higher aliphatic alcohols.
  • These may be synthetic alcohols, e. g., alcohols produced by the so-called Oxo process, or they may be of natural origin, e. g., fatty alcohols from sperm oil.
  • oil-soluble aromatic and cycle aliphatic alcohols such as benzyl alcohol and methylcyclohexanol may be used.
  • Oil-soluble dihydric alcohols such as the hexylene glycols, octylene glycols, decylene glycols and the higher glycols.
  • Oil-soluble alcohols containing substituents such as ether and/or ester groups are particularly effective members of this class. Particularly effective members of this class are the partial esters of polyhydric al cohols and fatty acids such as glycerol monoor di-oleate or stearate, ethylene glycol mono-oleate or stearate and the mono-esters of ethers of polyethylene glycols such as the mono-oleate or stearate of nonaethylene glycol. Compounds such as glycerol di-oleate have the valuable property of lowering the friction values of the compositions.
  • a single oil-soluble non-ionic emulsifier may be employed but it is often useful to use a mixture of two or more such compounds in order to obtain optimum scourability and spontaneity of emulsion formation.
  • a mixture of glycerol dioleate and a minor proportion of diglycol laurate, and a mixture of glycerol dioleate with minor proportions of diglycol laurate and nonaethylene glycol mono-oleate have been found particularly effective.
  • the nitrogenous emulsifier which is used in the compositions of the invention is soluble in mineral oil but substantially insoluble in water.
  • Suitable nitrogenous emulsifiers of this type are the primary, secondary and tertiary amines containing at least one hydrophobic group attached to the nitrogen atom, for example, dodecylamine, octadecylamine, dicetylamine, N- octadecyl-N-hydroxyethylamine, N-alkyl-N-hydroxypropylpiperidines in which the alkyl radicals are derived from coconut oil and the mono-acyl or as-diacyl derivatives of aliphatic polyamines such as oleyl ethylenediamine and as-distearylethylene diamine.
  • nitrogenous emulsifiers for use in the compositions of the invention are the organic compounds free from sulfonic acid groups which contain the atomic grouping
  • the 4 iminazoles, imidazolines and pyrimidines are the organic compounds free from sulfonic acid groups which contain the atomic grouping
  • the 4 iminazoles, imidazolines and pyrimidines are the organic compounds free from sulfonic acid groups which contain the atomic grouping
  • the 4 iminazoles, imidazolines and pyrimidines are O-ethylurea, S-dodecylthiourea, 1-guanidino-palmitic acid, lhydroxyethylguanidine, 2-undecylimidazoline, 1-/3-hydroxyethyl-2-heptadecyleneimidazoline, Z-naphthenyl-imidazoline, 2-heptadecylbenziminazole, Z-undecylpyrimidine and
  • compositions of the invention are intended for use as textile fiber lubricants, the proportion of nitrogenous emulsifier present is dependent to a large extent on the content of petroleum sulfonate.
  • the nitrogenous emulsifier promotes emulsion stability and produces compositions which lower the coefiicients of inter fiber friction. If present in too high concentration relative to the quantity of sulfonate in the blend, however, the nitrogenous emulsifier will cause the dynamic coefficient of inter fiber friction to become greater than the static coefficient of friction with consequent unsatisfactory processing of the lubricated fibers.
  • the amount of nitrogenous emulsifier present should be just sufiicient to produce a composition of suitable frictional properties, i. e., with a static coefficient of friction greater than the dynamic coefficient of friction.
  • compositions of the invention In addition to the aforementioned essential ingredients, other substances having particular properties may be incorporated in minor amounts in the compositions of the invention.
  • a coupling agent or mutual solvent to aid in solubilizing the ingredients, in promoting spontaneous emulsion formation, and in stabilizing the emulsion.
  • Such substances include mon-ohydric alcohols containing less than 8 carbon atoms in the molecule, for example, isopropyl alcohol, butyl and amyl alcohols, cyclohexanol, diacetone alcohol, phenols, the glycols, such as hexylene glycol, and polyethylene lycol and glycol mono-ethers such as the ethyl or butyl ether of ethylene glycol.
  • compositions of the invention can be incorporated in minor amounts in the compositions of the invention, as for example, the alkali metal soaps of higher fatty acids and rosin acids, alkali metal salts of sulfuric acid esters of higher primary and secondary alcohols and alkali metal salts of alkyl aryl sulfouates.
  • alkali metal soaps of higher fatty acids and rosin acids alkali metal salts of sulfuric acid esters of higher primary and secondary alcohols
  • alkali metal salts of alkyl aryl sulfouates alkali metal salts of alkyl aryl sulfouates.
  • Anti oxidants are also desirable additional ingredients in the compositions of the invention, for example, 2,4-
  • anti-foaming agents such as silicones and fine dispersions of N,N-distearyl ethylene diamine or N,N- distearyl hexamethylene diamine in mineral oil may also advantageously be incorporated.
  • compositions of the invention are to be used as textile oils, it may also be desirable to incorporate small proportions of compounds which will inhibit the growth of mildew on the wetted fibers.
  • Salicylanilide is a suitable fungicide for this purpose.
  • Corrosion inhibitors may also be incorporated in the invention.
  • Compounds which are particularly suitable are the primary amines containing from 6 to 15; carbon atoms in the molecule, such as octylamine and octadecylamine and the heterocyclic nitrogen containing organic compounds such as the alkyl substituted oxazolines and the oxazoline salts of fatty acids.
  • Example I A blend was prepared from 63 parts of spindle oil, 4.9 parts of 1-fi-hydroxyethyl-2-heptadecylene imidazoline, 4.9 parts of glycerol dioleate, 1.2 parts of diglycol laurate, 9.8 parts of oil-soluble sodium petroleum sulfonates (molecular weight 420-450), 6.5 parts of colophony rosin, 3.3 parts of oleic acid, 1.2 parts of potassium hydroxide, 2.6 parts of isopropyl alcohol and 2.6 parts of water.
  • Example 11 This blend was prepared from 54.6 parts of spindle oil, 4.8 parts of 1-fi-hydroxyethyl-2-heptadecylene imidazoline, 4.8 parts of glycerol dioleate, 0.6 part of diglycol laurate, 13.0 parts of oil-soluble sodium petroleum sulfonates (molecular weight 420-450), 8.7 parts of colophony rosin, 4.4 parts of oleic acid, 2.1 parts of potassium hydroxide, 3.5 parts of isopropyl alcohol and 3.5 parts of water.
  • This blend readily emulsified with water to give a clear oil-in-water emulsion, which was unchanged after 2 weeks storage.
  • a 2% vol./vol. emulsion in distilled water had a pH of 10.9.
  • the static coefficient of friction was 0.185 and the dynamic coefficient of friction was 0.175, when measured by the Roder method referred to above.
  • Example III This blend was prepared from 57.7 parts of spindle oil, 4.6 parts of 1- 3-hydroxyethyl-2-heptadecylene imidazoline, 4.6 parts of glycerol di-oleate, 1.1 parts of diglycol laurate, 5.4 parts of glycol monooleate, 10.0 parts of oilsoluble sodium naphthasulfonates (molecular weight 420-450), 6.5 parts of colophony rosin, 3.3 parts of oleic acid, 1.6 parts of potassium hydroxide, 2.6 parts of isopropyl alcohol and 2.6 parts of water.
  • This blend was a satisfactory knitting medium for sized nylon fibers when used as a 2% vol./vol. aqueous emul- SlOIl.
  • compositions of the invention may be applied to textile fibers by any of the well-known methods, for example, by spraying running textile yarns or by running textile yarns through baths or over wicks or other similar devices from which they pick up the composition in emulsion form as described above.
  • the textile yarns may be dipped in baths containing the composition.
  • An anti-static emulsifiable textile lubricant concentrate composition comprising a major amount of mineral lubricating oiland containing from about 2% to about 20% by weight of an oil-soluble sodium petroleum sulfonate, from about 0.5% to about 10% by weight of an oil-soluble partial ester of a polyhydric alcohol with a fatty acid, from about 1% to about 13% of l-fl-hydroxyethyI-Z-heptadecylene-imidazoline and from about 1% to about 10% of water.
  • An anti-static emulsifiable textile lubricant concentrate composition comprising a major amount of mineral lubricating oil and containing from about 2% to about 20%by weight of an oil-soluble sodium petroleum sulfonate, from about 0.5% to about 10% by weight of an oil-soluble partial ester of a polyhydric alcohol with a fatty acid, from about 1% to about 13%v of 2- naphthenylimidazoline and from about 1% to about 10% of water.
  • An anti-static emulsifiable textile lubricant c centrate composition comprising a major amount of mineral lubricating oil and containing from about 2% to about 20% by weight of an oil-soluble sodium petroleum sulfo-nate, from about 0.5 to about 10% by weight of glycerol dioleate, from about 1% to about 10% iby weight of water and from about 1% to about 13% of l-,B- hydroxyethyl-Z-heptadecyleneimidazoline.
  • An anti-static emulsifiable textile lubricant concentrate composition comprising about 4.8 parts of 1-[3- hydroxyethyl-Z-heptadecyleneimidazoline, about 4.8 parts of glycerol dioleate, about 0.6 parts of diglycol laurate, about 13 parts of oil-soluble sodium petroleum sulfonate, about 8.7 parts of colophony rosin, about 4.4 parts of oleic acid, about 2.1 parts of potassium hydroxide, about 3.5 parts of isopropyl alcohol, about 3.5 parts of water and about 54.6 parts of spindle oil.
  • composition of claim 4 diluted with from 19 to 99 volumes of water.
  • An anti-static emulsifiable textileizibricant concentrate composition comprising a major amount of mineral lubricating oil and containing from about 2% to about 20% by weight o-f an oil-soluble alkali metal petroleum sulfonate, from about 0.5 to about 10% by weight of an oil-soluble partial ester of a polyhydric alcohol with a higher fatty acid, from about 1% to about 13% of an oil-soluble hydrocarbon-substituted.imidazoline and from about 1% to about 10% of water.
  • composition of claim 6 diluted with from 19 to 99 volumes of water.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Lubricants (AREA)
US494256A 1954-03-29 1955-03-14 Textile lubricants Expired - Lifetime US2853453A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9079/54A GB753749A (en) 1954-03-29 1954-03-29 Improvements in or relating to textile oils

Publications (1)

Publication Number Publication Date
US2853453A true US2853453A (en) 1958-09-23

Family

ID=9864957

Family Applications (1)

Application Number Title Priority Date Filing Date
US494256A Expired - Lifetime US2853453A (en) 1954-03-29 1955-03-14 Textile lubricants

Country Status (6)

Country Link
US (1) US2853453A (en:Method)
BE (1) BE536867A (en:Method)
DE (1) DE1129255B (en:Method)
FR (1) FR1127014A (en:Method)
GB (1) GB753749A (en:Method)
NL (2) NL103782C (en:Method)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3056705A (en) * 1958-06-19 1962-10-02 Owens Corning Fiberglass Corp Surface treated glass and similar fibers
US3485913A (en) * 1965-10-20 1969-12-23 Toho Beslon Co New method of manufacturing acrylic fibers and the related products
US3522175A (en) * 1965-02-13 1970-07-28 Kao Corp Lubricant composition for synthetic fibers
US3850819A (en) * 1972-08-25 1974-11-26 Ici America Inc Low fuming spin finish for nylon weaving yarns
US4014800A (en) * 1973-05-26 1977-03-29 Hoechst Aktiengesellschaft Fiber-lubricating compositions
US4186126A (en) * 1978-04-11 1980-01-29 Messick John J Sulfonate antioxidants for synthetic and natural rubber

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE591186A (en:Method) * 1959-05-25 1900-01-01
US4082679A (en) * 1977-03-10 1978-04-04 Witco Chemical Corporation Light stabilized textile mineral oil
GB2285630A (en) * 1994-01-12 1995-07-19 Diversey Corp Aqueous lubricant compositions for conveyor tracks

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2025434A (en) * 1933-07-01 1935-12-24 American Enka Corp Lubricating natural and artificial fibers
US2036470A (en) * 1931-10-24 1936-04-07 Standard Oil Co California Emulsifiable oil product and process of making the same
US2122593A (en) * 1935-03-05 1938-07-05 Henry A Stafford Treatment of textile fibers
US2730464A (en) * 1951-05-17 1956-01-10 Shell Dev Antistatic treatment of textile yarns

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE445755A (en:Method) * 1941-06-07
US2684311A (en) * 1950-02-18 1954-07-20 Celanese Corp Process for lubricating regenerated cellulose yarns

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2036470A (en) * 1931-10-24 1936-04-07 Standard Oil Co California Emulsifiable oil product and process of making the same
US2025434A (en) * 1933-07-01 1935-12-24 American Enka Corp Lubricating natural and artificial fibers
US2122593A (en) * 1935-03-05 1938-07-05 Henry A Stafford Treatment of textile fibers
US2730464A (en) * 1951-05-17 1956-01-10 Shell Dev Antistatic treatment of textile yarns

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3056705A (en) * 1958-06-19 1962-10-02 Owens Corning Fiberglass Corp Surface treated glass and similar fibers
US3522175A (en) * 1965-02-13 1970-07-28 Kao Corp Lubricant composition for synthetic fibers
US3485913A (en) * 1965-10-20 1969-12-23 Toho Beslon Co New method of manufacturing acrylic fibers and the related products
US3850819A (en) * 1972-08-25 1974-11-26 Ici America Inc Low fuming spin finish for nylon weaving yarns
US4014800A (en) * 1973-05-26 1977-03-29 Hoechst Aktiengesellschaft Fiber-lubricating compositions
US4186126A (en) * 1978-04-11 1980-01-29 Messick John J Sulfonate antioxidants for synthetic and natural rubber

Also Published As

Publication number Publication date
GB753749A (en) 1956-08-01
NL103782C (en:Method) 1962-09-17
DE1129255B (de) 1962-05-10
BE536867A (en:Method) 1955-09-28
FR1127014A (fr) 1956-12-06
NL195998A (en:Method) 1900-01-01

Similar Documents

Publication Publication Date Title
US2345199A (en) Emulsifiable lubricant
US3926816A (en) Textile fiber lubricants
US2245649A (en) Lubricant and method of making same
US2853453A (en) Textile lubricants
EP0178177B1 (en) Soluble-oil cutting fluid
US3813337A (en) Metal working lubricant composition
US3781202A (en) Spin finish for polyamide yarn processed at high temperature
US3642623A (en) Oil base well drilling fluid composition and method
US3639235A (en) Antistatic carding lubricant
US3723314A (en) Lubricant for metalworking
US2730464A (en) Antistatic treatment of textile yarns
US2079803A (en) Soluble oil
US2810694A (en) Textile oil
US2431010A (en) Soluble cutting oil
US2466647A (en) Lubricating oil composition
US4014800A (en) Fiber-lubricating compositions
CA1061321A (en) Metal-working lubricants
US3522175A (en) Lubricant composition for synthetic fibers
US3234143A (en) Water-in-oil emulsion and method for the preparation thereof
US2002885A (en) Textile fiber spraying oils
US2406408A (en) Treatment of textile materials
US2676152A (en) Concentrated aqueous soap solution of low viscosity
US2626240A (en) Noncorrosive soluble oil containing active sulfur
US2811489A (en) Non-staining metal working lubricant
US2422075A (en) Stabilized lubricating emulsions