US2852359A - Method of manufacturing sheaper - Google Patents

Method of manufacturing sheaper Download PDF

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US2852359A
US2852359A US2852359DA US2852359A US 2852359 A US2852359 A US 2852359A US 2852359D A US2852359D A US 2852359DA US 2852359 A US2852359 A US 2852359A
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nitrocellulose
mixture
molten
temperature
propellant
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    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
    • C06B21/0033—Shaping the mixture
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B25/00—Compositions containing a nitrated organic compound
    • C06B25/34—Compositions containing a nitrated organic compound the compound being a nitrated acyclic, alicyclic or heterocyclic amine
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
    • C06B21/0033—Shaping the mixture
    • C06B21/0066—Shaping the mixture by granulation, e.g. flaking
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B25/00—Compositions containing a nitrated organic compound
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B45/00—Compositions or products which are defined by structure or arrangement of component of product

Definitions

  • This invention relates to theproduction of shapedpror pellants and concerns particularly the preparation" of of nitrocellulose, nitrated polyhydric alcohols and low-melting-point-nitrocompounds serving for manufacturing propellants and relates .also to the treatment of these mixtures for producing the pro.- p'ellants therefrom.
  • melts serving for the manufeature of propellants are produced according to the invention by introducing into a molten nitrocoinpound a mixture consisting of nitrocellulose and of .a nitrated polyhydric alcohol, having a water content of at least 18 percent and prepared at a temperature not exceeding l8 centigrade.
  • a molten nitrocoinpound a mixture consisting of nitrocellulose and of .a nitrated polyhydric alcohol, having a water content of at least 18 percent and prepared at a temperature not exceeding l8 centigrade.
  • a nitrocellulose having a nitrogen content of below 12.4' percent because a nitrocellulose with a higher nitrogen content than 12.4 percent results in melts which are very'viscous even when the viscosity of the nitrocellulose is low; such viscous melts cannot readily be shaped or d-eaerate'd; Furthermore, it is evaporation of the water during the dissolving process at a. rate which will ensure a complete solution of the nitrocellulose in the'melt.
  • molten mixtures of nitrocellulose, nitrated polyhydric alcohols and nitro compounds for the manufacture of propellants may be improved by choosing a certain favor: able ratio between the constituents of the mixtures,sparticuarly in the case of large bodies of powderas applied; for instance, in propellant charges for rockets; there the formation of cavities provoking detonations during the deflagration has to be avoided at. all events and, furthermore, the solidification of the molten mass must not take too long in spite of its large size.
  • This improvement consists in the step of observing in the molten mixture between the aromatic or aliphatic nitro compoundon the one hand, and the other mixture ingredients on the other hand, a fixed proportion' kept limits and ranging from 1:1 to 3:2.
  • the aromatic nitro compound content of the mixture e. g. trinitrotoluene
  • the molten mixture exhibits, upon cooling after shaping, especially in the case of large powder bodies, a strong tendency to formation of cavities and fissures.
  • the solidified'mass easily becomes brittle and this alone makes it practically useless.
  • Example II In a kettle provided with a heating jacket, 530 kg.& trinitrotoluene are melted at 80 centigrade. 280 kg. nitrocellulose with a nitrogen content of 12.1 percent are thoroughly mixed with 180 kg. diglycoldinitrate in an aqueous emulsion. The mixture is centrifuged and thus freed from the excess of water to a water content of 22 percent. The moist nitrocellulose enriched with diglycolnitrate is disintegrated in the usual manner and then slowly added to the molten trinitrotoluene while stirring. Finally, the kettle is hermetically closed and the water is removed by evacuating and the nitrocellulose dissolves.
  • Cooling of the propellant obtained by utilising the solubility of nitrocellulosein molten nitro compounds may be effected advantageouslyaccording to the invention by maintaining a certain temperature which will yield a finished product of gelatinised nitrocellulose containing the molten aromatic or aliphatic nitro compound in finest distribution and will allow the powder bodies formed from the molten mass to solidify without cavities and within the shortest possible time.
  • nitrocellulose containing 30 percent water and 12 percent
  • the water will evaporate and as evaporation proceeds, the nitro-- cellulose will dissolve; after evaporation of the water is-j completed, a homogeneous melt will remain behind.
  • the melting tank isprovided .with hermetically-sealed lid and connected to the addition of the moist nitrocelluv lose, enriched with dinitrodiglycol.
  • the temperature-j is increased by approximately 10 centigrade at.the end of the dissolving process; This rise in temperature will decrease of the viscosity of the melt 'as it forms and this, in turn, will facilitate the shaping of the melt.
  • the" molten mass is poured into a mold which has a constant temperature of for instance 25 centicare must be taken to maintain this temperature during the solidifying process .of the mass and to prevent any decrease during thecooling process.
  • a constant temperature for instance 25 centicare must be taken to maintain this temperature during the solidifying process .of the mass and to prevent any decrease during thecooling process.
  • unpleasant over-coolings. may easily occur which will lead to sudden crystallizing and cavity formation, whereby powder units with a de ficient homogeneity will be obtained; on the other hand, the solidification process of the viscous molten mass will take too long when too high a temperature is maintained during the cooling step.
  • the method based on the introduction of nitrocellulose and polyhydric alcohol in a molten nitro compound may be improved by the step of cooling down the molten mixture below the solidification tempera-.7 ture and by-transforming this undercooled melt into the desired shape. In this way, the solidification period is reduced to a fraction of the time otherwise required and hollow spaces or interior tensions within the propellant.
  • Example .IV I g
  • a mixture of 53 parts of trinitrotoluene, 28 parts of nitrocellulose, with anitrogen content of 12 percent, 18 parts of diglycol and lpercent of aistabilisator are melte This melt-.- havmg a melting .point of about 60'centigrade is cooled +30 centigrade which may be reached within minutes in a pipe branched from the kettle. After the melt has cooled down it still shows plastic characteristics and may be shaped into any desired form, for instance into a tubular form, in a continuous process by means of an extruder.
  • a method of manufacturing shaped propellants which comprises preparing at a temperature between 0 and 180 C. a mixture consisting of nitrocellulose and of a nitrated polyhydrlc alcohol selected from the group consisting of glycols and glycerines at a ratio of nitrocelluloseralcohol of about 3:2 and having a water content of at least 18%, and then introducing said mixture into a molten nitro compound selected from the group consisting of dinitrotoluene, trinitrotoluene, dinitrobenzene, trinitrobenzene, dinitrophenol, trinitrophenol, ditrinitrophenylglycolethernitrate, trinitrophenylglycolethernitrate, tetranitromethylaniline, mononitronaphthalene, trinitronaphthalene, dinitrooxytoluene, pentanitrodiphenylamine, trinitrophenylglycine, trinitrophenylethanolamine, dinitrodiethanolnitratoxamide, te
  • a nitrocellulose having. a nitrogen content from about 12 to below 12.4 percent is used for preparing the mixture of nitrocellulose and polyhydric alcohol.
  • nitrocellulose used for said mixture with alcohol is a nitrocellulose of a viscosity reduced by autoclave treatdown to a temperature of ture of butanol, butylacetate and toluene in the ratio of 3:4:5 and by determining its viscosity in a Cochiusviscosimeter (7 mm.) at 18 Centigrade.

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  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

METHOD OF MANUFACT RING PROPELLANTS FranzR. Achilles, .Martin'ez, Argentina" NoDrawing. ,ApplicafionFeliruary 6, 1256 Serial Nib 563,812
Claims priority, application Germany February: 5, 1955 i 1; Claims. 01. s2. .s
This invention relates to theproduction of shapedpror pellants and concerns particularly the preparation" of of nitrocellulose, nitrated polyhydric alcohols and low-melting-point-nitrocompounds serving for manufacturing propellants and relates .also to the treatment of these mixtures for producing the pro.- p'ellants therefrom.
It is known in the art of manufacturing propellants, such as ordnance and rifle gunpowder and propellant charges for rockets, to dehydrate a mixture of nitrocellulose, nitroglycerin or one or several similar nitrated polyhydric alcohols and water on a heated calender-and thus by means of the nitrated polyhyd'ric alcohols gelatinize the nitrocellulose. The gelatinized mixtures are again calendered to form thin skins and are then cut into bands or flakes or pressed through a nozzle into tubular form. This calendering takes much time ancienergy and is very dangerous due to the mass being friction: sensitive and combustible at high temperatures. Another disadvantage is that the resulting vapors of the uitrated alcohols inconvenience the calender operators,
In the manufacture of explosives i. e. of rapidly remass into molds, e. If this method is used in the manufacture of propellants i. e, of slowly reacting explosive mixtures of chemical 6. 11;- pounds with a gas development ejecting the projectiles from a gun or rocket barrel, particularly of propellants Containing nitrocellulose and nitrated polyhydricalc'ohols, there are difliculties resulting from the fact that, when the aqueous mixtureprepared in. the usual manner and containing e. g. nitrocellulose and. diglycoldinitrate, is added to molten trinitrotoluene or to another molten nitro-compoundQonly part of the nitrocellulose gelati-nized so that no homogeneous solution is obtained. Now, on the base of thorough experiments it been discovered that the manufacture of melts containpolyhydric alcohols for the use in propellants requires for obtaining homogeneous solutions that the nitrocellulose enriched with nitrated polyhydric' alcohol. has a certain water content which must amount to at least 18 powder. "If, however; the water content of the mixture is. exceedingly high, the melting process will take too much time and this fact will render the final product instable.
Experiments have 'further shown that, when mixing the nitrated polyhydric' alcohol; a low temperature ,must be maintained which does no't exceed 18 Centigrade, in order :to prevent thc nitrocellu Patented Sept. 16, 1958 lose from gelatinizing before it is added to the melt, and to-avoid' the formation of lumps.
Based on these discoveries, melts serving for the manufeature of propellants are produced according to the invention by introducing into a molten nitrocoinpound a mixture consisting of nitrocellulose and of .a nitrated polyhydric alcohol, having a water content of at least 18 percent and prepared at a temperature not exceeding l8 centigrade. In this way, not only the calendering work being otherwise usual for dehydrating the powder mixtures when manufacturing propellants is completely avoided but also a' perfectly homogeneous solution Q3133. ble of being easily cast is obtained without any formation of lumps.
It is advantageous to use for the powder mixture a nitrocellulose having a nitrogen content of below 12.4' percent because a nitrocellulose with a higher nitrogen content than 12.4 percent results in melts which are very'viscous even when the viscosity of the nitrocellulose is low; such viscous melts cannot readily be shaped or d-eaerate'd; Furthermore, it is evaporation of the water during the dissolving process at a. rate which will ensure a complete solution of the nitrocellulose in the'melt.
Furthermore, experiments have proved that favorable results are obtained by'llsing propellants according to the invention a nitrocellulose autoclave to reduce its viscosity to such a degree that upon the determination of the viscosity in a Cochius-viscosimeter (7 mm.) at 18 centigrade, a 10 percent solution of the nitrocellulose in. a mixture of butanol, butylacetate and toluene in the ratio of 3:4:5 will have a rate of flow from 15-20 seconds.
diglycoldimtrate, nitrated methriol and similar nitrated Example I In a kettle provided with a heating jacket, 53 kg. tri? nitrotoluene of 12.1 percent and a viscosity of 20 seconds, measured in a 3 percent acetone solution according .to Coch'ius, are thoroughly mixed at 14 centigr de tained. The nitrocellulose enriched With the nitrated polyhydric alcohol is disintegrated in the usual manner important to effect the for the manufacture of or trinitrophenol, di-
d1oxyethylsulfodinitrate. Mixtureswithin rather narrow 7 "thus obtained homogeneous melt, which may be easily cast, will be shaped in the usual manner.
The method of preparing according to the invention molten mixtures of nitrocellulose, nitrated polyhydric alcohols and nitro compounds for the manufacture of propellants may be improved by choosing a certain favor: able ratio between the constituents of the mixtures,sparticuarly in the case of large bodies of powderas applied; for instance, in propellant charges for rockets; there the formation of cavities provoking detonations during the deflagration has to be avoided at. all events and, furthermore, the solidification of the molten mass must not take too long in spite of its large size. This improvement consists in the step of observing in the molten mixture between the aromatic or aliphatic nitro compoundon the one hand, and the other mixture ingredients on the other hand, a fixed proportion' kept limits and ranging from 1:1 to 3:2. Experience has shown, that obtaining a complete solution of the nitrocellulose and, as a consequence thereof 7 an entirely homogeneous propellant, which can be easily cast, is rendered very difficult, when the aromatic nitro compound content of the mixture, e. g. trinitrotoluene, is too low; on the other content exceeding 60 percent of the solution, the molten mixture exhibits, upon cooling after shaping, especially in the case of large powder bodies, a strong tendency to formation of cavities and fissures. Moreover, the solidified'mass easily becomes brittle and this alone makes it practically useless. These disadvantages are noticed not only with trinitrotoluene, but also with other aromatic nitro compounds, such as trinitroglycolether or trinitromethylaniline.
Example II In a kettle provided with a heating jacket, 530 kg.& trinitrotoluene are melted at 80 centigrade. 280 kg. nitrocellulose with a nitrogen content of 12.1 percent are thoroughly mixed with 180 kg. diglycoldinitrate in an aqueous emulsion. The mixture is centrifuged and thus freed from the excess of water to a water content of 22 percent. The moist nitrocellulose enriched with diglycolnitrate is disintegrated in the usual manner and then slowly added to the molten trinitrotoluene while stirring. Finally, the kettle is hermetically closed and the water is removed by evacuating and the nitrocellulose dissolves.
Cooling of the propellant obtained by utilising the solubility of nitrocellulosein molten nitro compounds may be effected advantageouslyaccording to the invention by maintaining a certain temperature which will yield a finished product of gelatinised nitrocellulose containing the molten aromatic or aliphatic nitro compound in finest distribution and will allow the powder bodies formed from the molten mass to solidify without cavities and within the shortest possible time.
On the other hand, for obtaining the melt it was found useful to effect the dissolving of the nitrocellulose in a vacuum tank while stirring, in order to facilitate the removal of the air. bubbles from the solution. Furthermore, with a view ofobtaining as homogeneousa solution' as possible and one of low viscosity, the temperature of the solution may be increased for a short period after the elimination of the water, and for dissolving the nitrocellulose in the molten nitro compound it is advisable to maintain a 1y 10 to centigrade above the melting point of the nitro compound. 7 p 7 Example Ill In a melting tank of stirring equipment and enclosed by a heating with hot water, I melt 100 kilograms trinitrotoluene, (melting point approximately 80 centigrade). To the melt I add, gradually in measured doses, 70 kilograms temperature which lies approximate 300 liters capacity, provided with jacket heated- ""sitrs en enriched with dinitrodiglycol 'at the ratio of 322'.-
. grade;
hand, with the nitro compound the bottomto the top and from the solidification of the molten powder mixtures, which is cut down to only a few minutes, without formation of a 4 at centigradeito form a homogeneous mass.
I a vacuum line after ture before its solidification is quite complete so'as'to;
. 4 nitrocellulose, containing 30 percent water and 12 percent By maintaining a temperature of centigrade, the water will evaporate and as evaporation proceeds, the nitro-- cellulose will dissolve; after evaporation of the water is-j completed, a homogeneous melt will remain behind.
For eliminating the air bubbles,'the melting tank isprovided .with hermetically-sealed lid and connected to the addition of the moist nitrocelluv lose, enriched with dinitrodiglycol. For complete elimination of airbubbles fromthe. mixture, the temperature-j is increased by approximately 10 centigrade at.the end of the dissolving process; This rise in temperature will decrease of the viscosity of the melt 'as it forms and this, in turn, will facilitate the shaping of the melt.
For shaping, the" molten mass is poured into a mold which has a constant temperature of for instance 25 centicare must be taken to maintain this temperature during the solidifying process .of the mass and to prevent any decrease during thecooling process. By applying too. low cooling temperatures, unpleasant over-coolings. may easily occur which will lead to sudden crystallizing and cavity formation, whereby powder units with a de ficient homogeneity will be obtained; on the other hand, the solidification process of the viscous molten mass will take too long when too high a temperature is maintained during the cooling step.
When manufacturing larger-sized powder units, such 7 as the cylindric units applied as propellant charges'for rockets, asupervis ion of the coolingprocess is required, not only for temperature control; care must also be taken that the cooling of thecylindric unit will be effected from theinside to the outside; otherwise, local concentrations of the mass will lead to formation of hollow spaces inside the unit during the cooling process. Inorder to shorten as much as possible the period of sometimes requires as much as 20 to 30 hours, especially in vvthe case of manufacturing large bodies of powder having large wall thickness, and yet to avoid with seen-J rity they risk of formation of cavities and irregularities during crystallisation, whichwould have an adverse effect onthe ballistics, the method based on the introduction of nitrocellulose and polyhydric alcohol in a molten nitro compound may be improved by the step of cooling down the molten mixture below the solidification tempera-.7 ture and by-transforming this undercooled melt into the desired shape. In this way, the solidification period is reduced to a fraction of the time otherwise required and hollow spaces or interior tensions within the propellant.
I This undercooling of the molten mixture is based on v the discovery, which resulted from extensive experimentation, that the molten powder mixtures possess the property to'pass, when being cooled down below the solidificae tion point, for a time of transition into an instable state in which they exhibit a viscous nature, and'are therefore. still easily cast. The shaping of the molten mass being in a semi-plastic state maybe effected in the usual manner 1 by means of an extruder, a screw press, or similar de vices. to shape the molten powder mix The best way is allow. the formed body to solidify at room temperatur without further modification of its shape. The formed units may preferably be left standing for a short time at room temperature. v
Example .IV I g A mixture of 53 parts of trinitrotoluene, 28 parts of nitrocellulose, with anitrogen content of 12 percent, 18 parts of diglycol and lpercent of aistabilisator are melte This melt-.- havmg a melting .point of about 60'centigrade is cooled +30 centigrade which may be reached within minutes in a pipe branched from the kettle. After the melt has cooled down it still shows plastic characteristics and may be shaped into any desired form, for instance into a tubular form, in a continuous process by means of an extruder.
Having described my invention, what I claim and desire to protect by Letters Patent is:
l. A method of manufacturing shaped propellants, which comprises preparing at a temperature between 0 and 180 C. a mixture consisting of nitrocellulose and of a nitrated polyhydrlc alcohol selected from the group consisting of glycols and glycerines at a ratio of nitrocelluloseralcohol of about 3:2 and having a water content of at least 18%, and then introducing said mixture into a molten nitro compound selected from the group consisting of dinitrotoluene, trinitrotoluene, dinitrobenzene, trinitrobenzene, dinitrophenol, trinitrophenol, ditrinitrophenylglycolethernitrate, trinitrophenylglycolethernitrate, tetranitromethylaniline, mononitronaphthalene, trinitronaphthalene, dinitrooxytoluene, pentanitrodiphenylamine, trinitrophenylglycine, trinitrophenylethanolamine, dinitrodiethanolnitratoxamide, tetranitropentaerytrite, dioxyethylsulfodinitrate and having a melting point below 130 C., thereafter shaping the propellant from the obtained molten mass, and solidifying the propellant.
2. The method according to claim 1, wherein a nitrocellulose having. a nitrogen content from about 12 to below 12.4 percent is used for preparing the mixture of nitrocellulose and polyhydric alcohol.
3. The method according to claim 1, wherein the nitrocellulose used for said mixture with alcohol is a nitrocellulose of a viscosity reduced by autoclave treatdown to a temperature of ture of butanol, butylacetate and toluene in the ratio of 3:4:5 and by determining its viscosity in a Cochiusviscosimeter (7 mm.) at 18 Centigrade.
4. The method according to claim 1, wherein the evaporation of the water contained in the mixture of nitrocellulose and polyhydric alcohol having a water content of at least 18 percent, is elfected during the dissolving process at a rate which corresponds to the rate of the nitrocellulose gelatinization.
5. The method according to claim 1, wherein the proportion of the nitro compounds: the mixture of nitrocellulose and nitrated polyhydric alcohol is chosen from 1:1 to 3:2.
6. The method according to claim 1, wherein the propellant formed from the molten mixture is cooled to a temperature of about 25 C. which is maintained during the solidifying process of the mass.
7. The method according to claim 1, wherein the production of the melt is effected under partial vacuum and while stirring, so as to eliminate air bubbles.
8. The method according to claim 1, wherein the mixture of nitrocellulose and polyhydric alcohol is introduced while maintaining therein a temperature from about 10 C. to 20 C. above the melting point of the nitro compound.
9. The method according to claim 1, wherein the temperature of the solution is increased by approximately 10 centigrade after the elimination of the water for a short period sufiicient for completely eliminating air bubbles from the molten mass.
7 10. The method according to claim 1, wherein the molten mixture is cooled down below its solidification temperature and is shaped in this under-cooled state.
11. The method according to claim 1, wherein the molten mass is shaped shortly before solidification is quite completed, the shaping being terminated at room temperature.
12. The method according to claim 1, wherein the shaped and solidified powder units are allowed to stand at room temperature for a few minutes.
References Cited in the file of this patent UNITED STATES PATENTS

Claims (1)

1. A METHOD OF MANUFACTURING SHAPED PROPELLANTS, WHICH COMPRISES PREPARING AT A TEMPERATURE BETWEEN 0* AND 180*C. A MIXTURE CONSISTING OF NITROCELLULOSE AND OF A NITRATED POLYHYDRIC ALCOHOL SELECTED FROM THE GROUP CONSISTING OF GLYCOLS AND GLYCERINES AT A RATIO OF NITROCELLULOSE ALCOHOL OF ABOUT 3:2 AND HAVING A WATER CONTENT OF AT LEAST 18%, AND THEN INTRODUCING SAID MIXTURE INTO A MOLTEN NITRO COMPOUND SELECTED FROM THE GROUP CONSISTING OF DINITROTOLUENE, TRINITROTOLUENE, DINITROBENZENE, TRINITROBENZENE, DINITROPHENOL, TRINITROPHENOL, DITRINITROPHENYLGLYCOLETHERNITRATE, TRINITROPHENYLGLYCOLETHERNITRATE, TETRANITROMETHYLANILINE, MONONITRONAPHTHALENE, TRINITRONAPHTHALENE, DINITROOXYTOLUENE, PENTANITRODIPHENYLAMINE, TRINITROPHENYLGLYCINE, TRINITROPHENYLETHANOLAMINE, DINITRODIETHANOLNITRATOXAMIDE, TETRANITROPENTAERYTRITE, DIOXYETHYLSULFFODINITRATE AND HAVING A MELTING POINT BELOW 130*C., THEREAFTER SHAPING THE PROPELLANT FROM THE OBTAINED MOLTEN MASS, AND SOLIDIFYING THE PROPELLANT.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3022206A (en) * 1958-07-21 1962-02-20 Phillips Petroleum Co Manufacture of solid propellant
US3032972A (en) * 1956-12-21 1962-05-08 Hercules Powder Co Ltd Propellants
US3116597A (en) * 1959-12-29 1964-01-07 Hercules Powder Co Ltd Rocket propellants, motors and their manufacture
US3389026A (en) * 1959-12-08 1968-06-18 Navy Usa Plasticized high explosive and solid propellant compositions
US3400025A (en) * 1966-04-19 1968-09-03 Army Usa Flexible explosive comprising rdx, hmx or petn and mixed plasticizer
US3878003A (en) * 1960-08-16 1975-04-15 Us Army Composite double base propellant with HMX oxidizer

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1783372A (en) * 1928-05-03 1930-12-02 Du Pont Detonator and process of making
US1867283A (en) * 1930-02-27 1932-07-12 Stettbacher Alfred Plastic explosive mixture of high shattering power
US2247392A (en) * 1934-01-25 1941-07-01 Du Pont Process of making smokeless powder
US2384730A (en) * 1943-08-07 1945-09-11 Du Pont Method of preparing cast explosive charges

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1783372A (en) * 1928-05-03 1930-12-02 Du Pont Detonator and process of making
US1867283A (en) * 1930-02-27 1932-07-12 Stettbacher Alfred Plastic explosive mixture of high shattering power
US2247392A (en) * 1934-01-25 1941-07-01 Du Pont Process of making smokeless powder
US2384730A (en) * 1943-08-07 1945-09-11 Du Pont Method of preparing cast explosive charges

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3032972A (en) * 1956-12-21 1962-05-08 Hercules Powder Co Ltd Propellants
US3022206A (en) * 1958-07-21 1962-02-20 Phillips Petroleum Co Manufacture of solid propellant
US3389026A (en) * 1959-12-08 1968-06-18 Navy Usa Plasticized high explosive and solid propellant compositions
US3116597A (en) * 1959-12-29 1964-01-07 Hercules Powder Co Ltd Rocket propellants, motors and their manufacture
US3878003A (en) * 1960-08-16 1975-04-15 Us Army Composite double base propellant with HMX oxidizer
US3400025A (en) * 1966-04-19 1968-09-03 Army Usa Flexible explosive comprising rdx, hmx or petn and mixed plasticizer

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