US27981A - James matuison - Google Patents

James matuison Download PDF

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US27981A
US27981A US27981DA US27981A US 27981 A US27981 A US 27981A US 27981D A US27981D A US 27981DA US 27981 A US27981 A US 27981A
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stone
acid
james
lines
matuison
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/44Compositions for etching metallic material from a metallic material substrate of different composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S426/00Food or edible material: processes, compositions, and products
    • Y10S426/806Salt or mineral substitute

Definitions

  • etching stone is attended with many serious difficulties, which make it impossible to produce a perfect picture.
  • an etching-ground capable of resisting the acid to be used, (generally nitric acid or hydrochloric acid.)
  • the design to be produced is now worked into this ground with a fine-pointed needle, the burin or graver, parallel lines being drawn with the ruling-machine and diamond for skies, tints, &c.
  • the lines thus produced are all of the same size, without regard to any light or shade, and a plate thus prepared has therefore no effect whatever.
  • To produce such the lines have to be etched in with nitric or hydrochloric acid, iainter or deeper, according to thelight or shade of the picture.
  • the pictures taken from stones prepared according to my method bear a close resemblance to pictures taken from copper or steel plates, and at the same time a great many more impressions can be taken from the stone than from the copper or steel plate, and the printin g is attended with less difficulties.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • ing And Chemical Polishing (AREA)

Description

UNITED STATES PATENT OFFICE.
A. HOEN, OF BALTIMORE, MARYLAND.
COMPOSITION FOR ETCHlNG STONE.
Specification forming part of Letters Patent No. 27,981, dated April 24, 1860.
To all whom it may concern.-
Be it known that I, A. HOEN, of Baltimore, in the county of Baltimore and State of Maryland, have invented a new and Improved Gomposition for Etching Stone; and I do hereby declare that the following is a full, clear, and
exact description of the same.
The ordinary method of etching stone is attended with many serious difficulties, which make it impossible to produce a perfect picture. After the stone has been prepared it is covered with an etching-ground capable of resisting the acid to be used, (generally nitric acid or hydrochloric acid.) The design to be produced is now worked into this ground with a fine-pointed needle, the burin or graver, parallel lines being drawn with the ruling-machine and diamond for skies, tints, &c. The lines thus produced are all of the same size, without regard to any light or shade, and a plate thus prepared has therefore no effect whatever. To produce such the lines have to be etched in with nitric or hydrochloric acid, iainter or deeper, according to thelight or shade of the picture. For this purpose a weak solution of the acid is poured over the whole surface of the stone, and after remaining a certain time washed off with clean water and dried, and those parts which in the opinion of the artist are etched deep enough are stopped out with lithographic ink to prevent a further action of the acid. The acid is now poured over the stone again and left standing long enough to produce the second tints, when the surface is washed and dried, as above described. The second tints are now stopped up, and the same process is repeated until the several shades of the picture are produced. The most serious defect of this process is found in the fact that the artist can never know with certainty the depth of the lines, and he can only guess it by the strength of the acid, by the time it remains on the stone, and by the nature and chemical composition of the stone itself. Another difficulty is caused by the continual stopping out of the finished parts, which completely prevents the artist from seeing the progress of his picture. His memory is his only guide, and this is very apt to confuse and mislead him. Furthermore, the gradation from one tint to the other will always be more or less visible, showing by decided marks the previous covering with ink. All these diliiculties are avoided by the use of my composition for producing the picture.
I prepare the stone and cover its surface with etching-ground in the usual manner. The design is now worked into the etching-ground and the stone is ready t6 be acted on by the acid, as previously described; but, instead of using nitric or hydrochloric acid for a mordant I use some acid which forms an insoluble combination with the lime of the lithographic stone-such as citric acid-which, after being washed off with water, leaves a very small quantity of a white powder-via, citrate of lime--in the lines, which enables the artist to judge accurately of their respective strength by the contrast they form with the dark covering of the stone. Such acid, however, when used alone, will spread and run to those parts which it is not desired to touch, and in order to give to said acids a certain consistency I mix them with gum-arabic, whereby the artist is enabled to use a camels-hair brush and to put on the acid in the same manner as if he were making an india-ink drawing. Light and shade are thus produced with equal facility and in the same manner as with the engravers tool on copper plates previously etched, no stopping out being required until the picture is finished.
The use of gum-arabic in combination with nitric or hydrochloric acid has been found impracticable, as it would prevent the lines from taking the printing-ink--a fact well known to every lithographer. On the other hand, when citric or some other acid having a similar action on the stone is used the small strata of insoluble lime left in the lines prevents the gum from sticking to the surface of the stone, and is therefore no obstacle to the lines taking ink.
The pictures taken from stones prepared according to my method bear a close resemblance to pictures taken from copper or steel plates, and at the same time a great many more impressions can be taken from the stone than from the copper or steel plate, and the printin g is attended with less difficulties.
Having thus fully described my invention,
what I claim as new, and desire to secure by in the manner specified, so as to produce what Letters Patent, is I term the lithokaustik method of etching The employment, as a mordant for lithostone. graphic stones, of a composition ofgum-arabic, A. HOEN. or its equivalent, with citric acid or some other Witnesses: acid, forming a combination insoluble in wa JAMES MATHISON, ter, with the lime of the stone, substantially W. WATKINS.
US27981D James matuison Expired - Lifetime US27981A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4556577A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. Admixture of potassium chloride and maltodextrin as salt substitute and method of preparation
US4556567A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. Salt substitute containing potassium chloride coated with maltodextrin and method of preparation
US4556568A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. Salt substitute containing potassium chloride coated with a mixture including maltodextrin and potassium bitartrate and method of preparation
US4556578A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. NaCl-Free salt substitute containing potassium chloride, maltodextrin and potassium bitartrate and method of preparation
US4556566A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. Salt substitute containing potassium chloride coated with a mixture of maltodextrin and sodium chloride and method of preparation
US4560574A (en) * 1983-06-30 1985-12-24 Mallinckrodt, Inc. Salt substitute containing potassium chloride, maltodextrin and sodium chloride and method of preparation
US4775546A (en) * 1985-07-05 1988-10-04 Meiji Seika Kaisha, Ltd. Process for treating potassium chloride
US20050142318A1 (en) * 2003-12-25 2005-06-30 Lintec Corporation Pressure sensitive adhesive sheet, a multilayer structured article for photorecording media having the sheet and multilayer photorecording medium having the article

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4556577A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. Admixture of potassium chloride and maltodextrin as salt substitute and method of preparation
US4556567A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. Salt substitute containing potassium chloride coated with maltodextrin and method of preparation
US4556568A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. Salt substitute containing potassium chloride coated with a mixture including maltodextrin and potassium bitartrate and method of preparation
US4556578A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. NaCl-Free salt substitute containing potassium chloride, maltodextrin and potassium bitartrate and method of preparation
US4556566A (en) * 1983-06-30 1985-12-03 Mallinckrodt, Inc. Salt substitute containing potassium chloride coated with a mixture of maltodextrin and sodium chloride and method of preparation
US4560574A (en) * 1983-06-30 1985-12-24 Mallinckrodt, Inc. Salt substitute containing potassium chloride, maltodextrin and sodium chloride and method of preparation
US4775546A (en) * 1985-07-05 1988-10-04 Meiji Seika Kaisha, Ltd. Process for treating potassium chloride
US20050142318A1 (en) * 2003-12-25 2005-06-30 Lintec Corporation Pressure sensitive adhesive sheet, a multilayer structured article for photorecording media having the sheet and multilayer photorecording medium having the article

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