US2795562A - Coating composition for producing a two-colored patterned effect - Google Patents

Coating composition for producing a two-colored patterned effect Download PDF

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Publication number
US2795562A
US2795562A US337423A US33742353A US2795562A US 2795562 A US2795562 A US 2795562A US 337423 A US337423 A US 337423A US 33742353 A US33742353 A US 33742353A US 2795562 A US2795562 A US 2795562A
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Prior art keywords
colour
aqueous
weight
producing
coating
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US337423A
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Jud Arthur
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JEAN SPILLMANN
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JEAN SPILLMANN
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/4803—Polysaccharides, e.g. cellulose, or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/061—Special surface effect
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S260/00—Chemistry of carbon compounds
    • Y10S260/25—Metal catalyst

Definitions

  • the present invention relates to a method for producing and finishing in one operation two-coloured wallpaperlike coatings on any primed surface or on another suitable grounding, and to coating material for carrying out this method.
  • the new and improved method makes it possible to produce in one operation on primed or pretreated surfaces or on any other suitable grounding a wallpaper-like coating patterned in two colours with an appearance similar to paper.
  • This coating is particularly suited for walls of rooms, but also for any other articles made of wood, gypsum, masonry, pavatex, and paper which are suitably primed or grounded, or even glass and the like.
  • the method according to the invention consists in applying a coating material containing two differently coloured colour carriers which themselves are not miscible with each other to the surface to be coloured, one of said colour carriers being of aqueous and the other of non-aqueous nature, and the aqueous colour-carrier containing cellulose-containing fibre materials, such as e. g. cellulose pulp, wood pulp, lignin, straw pulp, sulphite and sulphate cellulose, together with weighting agents such as chalk, gypsum, sulphate of barium, kaolin, or other suitable clays, spars and earths.
  • the two colourcarriers of the coating material also contain body colour for obtaining the desired colour tone.
  • Acertain patterning effect is alreadyattained by the kind of implement used for painting.
  • the patterning varies, depending on the coating being applied by means of a brush, 'roller' or spray gun.
  • particular patterns may also be obtained by subsequently treating the raw materialsof the paper and papier-mach industry, deposited to the surface of the coat, by means of rubber dabs, dabbing brushes, paper or rubber pads, rollers or Consequently, in a single operation bicoloured surfaces of an extraordinary variety with respect to patterning may be produced.
  • non-aqueous colour-carriers there may be used nonaqueous, volatile binders such as alcoholic lacquer, cellulose lacquer, synthetic resin lacquer, or other suitable varnish and non-aqueous, non-volatile binders such as linseed oil, stand oil, blown oils or other drying oils, to which may be added raw materials of the paper and papier-mach industry, colours and substrates, preferably in the following proportion:
  • cellulose fibres 1 part by weight of linseed oil 1 part by weight of linseed oil stand oil 3 parts by weight of turpentine 4 parts by weight of kaolin 8 parts by weight of zinc-oxide 3 parts by weight of cellulose fibres
  • aqueous colour-carriers there are suited preferably cellulose sizing dissolved in water, casein, or other glues soluble in water, furthermore binders of mineral nature such as e. g. lime, water glass etc. to which are added raw materials of the paper and papier-mach industry, colours and substrates.
  • water-soluble cellulose sizing in combination with a synthetic resin binder is employed, for instance in the following proportion:
  • the amount of body colour required for obtaining the desired colour tones is added to the colour-carriers in order to attain a two-colour colouration of the surface coating.
  • the aqueous component is poured into the non-aqueous component and the whole stirred with a slowly turning stirrer so that both components are reduced to small non-coherent particles and a uniform distribution is obtained.
  • This material alters its structure as soon as it is applied on the surface in that the non-aqueous particles separate from the aqueous particles and coalesce to form a continuous covering film on the treated surface, whereas the aqueous particles deposit on said film in form of non-coherent islands between which islands the continuous film rests still visible.
  • the coating of the invention may be applied without difliculties on vertical walls.
  • a coating material for protiucing two-colored, pat I
  • terned surface coating comprising; an aqueous color carrier comprising abindingage'ntand a cellulosiefibremnd an immiscible, non-aqueous colorcari'ier and-cellulosic 5 stantially five parts, by weight; of non-aqueousco1orlcar rier to six parts by. weight of aqueous color carrier;
  • a material as claimed; in1claitn 3 whereinrth aque 1115 nus color, carrier comprises, by weight, one part of cel-.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Civil Engineering (AREA)
  • Textile Engineering (AREA)
  • Paper (AREA)
  • Paints Or Removers (AREA)

Description

United States Patent COATING COMPOSITION FOR PRODUCING A TWO-COLORED PATTERNED EFFECT Arthur Jud, Oberengstringen, Zurich, Switzerland, sihgnlor of one-half to Jean Spillmann, Zurich, Switzer- No Drawing. Application February 17, 1953, Serial No. 337,423
Claims priority, application Switzerland February, 1952 4 Claims. (Cl. 260-9) The present invention relates to a method for producing and finishing in one operation two-coloured wallpaperlike coatings on any primed surface or on another suitable grounding, and to coating material for carrying out this method.
As is well known, two or more colours each of them having a different colour-carrier do not readily mingle with each other, or may be mixed only under difliculties. Nevertheless, it was hitherto hardly possible to apply such a coating material containing two or more colour-tones in one operation to the grounding to be treated in such manner as to prevent the different colours from running into one another; at any rate the coating could hardly be applied by means of a brush. In practice therefore it was impossible to produce this type of surface coatings, particularly on vertical surfaces, such as for instance room walls, with a neat, uniform and stainless appearance.
Furthermore, the production of wallpaper-like patterns or ornaments on walls or other surfaces was hitherto very cumbersome and time-consuming, since the various colour-tones and patterns had to be applied individually and thus in several operations. Moreover, it was hardly possible to achieve a paperand wallpaper-like appearance.
It is an object of the present invention to provide a method, which eliminates all the mentioned drawbacks. Due to the composition of the coating material according to the invention, the new and improved method makes it possible to produce in one operation on primed or pretreated surfaces or on any other suitable grounding a wallpaper-like coating patterned in two colours with an appearance similar to paper. This coating is particularly suited for walls of rooms, but also for any other articles made of wood, gypsum, masonry, pavatex, and paper which are suitably primed or grounded, or even glass and the like.
The method according to the invention consists in applying a coating material containing two differently coloured colour carriers which themselves are not miscible with each other to the surface to be coloured, one of said colour carriers being of aqueous and the other of non-aqueous nature, and the aqueous colour-carrier containing cellulose-containing fibre materials, such as e. g. cellulose pulp, wood pulp, lignin, straw pulp, sulphite and sulphate cellulose, together with weighting agents such as chalk, gypsum, sulphate of barium, kaolin, or other suitable clays, spars and earths. The two colourcarriers of the coating material also contain body colour for obtaining the desired colour tone.
When such a coating material is applied on the priming layer, by means of a brush, a roller, a spray gun or any other known paint applying tool, then the non-aqueous colour-carriers spreads over and uniformly covers the primed ground, while the aqueous colour-carrier refusingly separates, whereby the raw materials of the paper and papier-mach industry added to this colour-carrier 2,795,562 Patented June 11, 1957 are deposited on the surface in specks or spots like little ice 'islands. The painting has a wallpaper-like appearance,
1 1 11 implements suited for this p p after the coating has dried.
Acertain patterning effect is alreadyattained by the kind of implement used for painting. The patterning varies, depending on the coating being applied by means of a brush, 'roller' or spray gun. Moreover, particular patterns may also be obtained by subsequently treating the raw materialsof the paper and papier-mach industry, deposited to the surface of the coat, by means of rubber dabs, dabbing brushes, paper or rubber pads, rollers or Consequently, in a single operation bicoloured surfaces of an extraordinary variety with respect to patterning may be produced.
As non-aqueous colour-carriers there may be used nonaqueous, volatile binders such as alcoholic lacquer, cellulose lacquer, synthetic resin lacquer, or other suitable varnish and non-aqueous, non-volatile binders such as linseed oil, stand oil, blown oils or other drying oils, to which may be added raw materials of the paper and papier-mach industry, colours and substrates, preferably in the following proportion:
1 part by weight of linseed oil 1 part by weight of linseed oil stand oil 3 parts by weight of turpentine 4 parts by weight of kaolin 8 parts by weight of zinc-oxide 3 parts by weight of cellulose fibres As aqueous colour-carriers there are suited preferably cellulose sizing dissolved in water, casein, or other glues soluble in water, furthermore binders of mineral nature such as e. g. lime, water glass etc. to which are added raw materials of the paper and papier-mach industry, colours and substrates. Preferably, water-soluble cellulose sizing in combination with a synthetic resin binder is employed, for instance in the following proportion:
1 part by weight of cellulose sizing (cellulose ether) 1 part by weight of cellulose fibres (wood or paper fibres) 2 parts by weight of sulphate of barium 12 parts by weight of water 3 parts by weight of synthetic resin emulsion free from oil.
The amount of body colour required for obtaining the desired colour tones is added to the colour-carriers in order to attain a two-colour colouration of the surface coating.
The two above mentioned components are mixed together in suitable proportions, preferably as follows:
5 parts by weight of the non-aqueous component plus 6 parts by weight of the aqueous component.
The aqueous component is poured into the non-aqueous component and the whole stirred with a slowly turning stirrer so that both components are reduced to small non-coherent particles and a uniform distribution is obtained. This material alters its structure as soon as it is applied on the surface in that the non-aqueous particles separate from the aqueous particles and coalesce to form a continuous covering film on the treated surface, whereas the aqueous particles deposit on said film in form of non-coherent islands between which islands the continuous film rests still visible.
After drying of the coating, a wallpaper-like nonglossy two-tone cover is obtained. It is to be noted that the coating of the invention may be applied without difliculties on vertical walls.
I claim:
1. A coating material for protiucing two-colored, pat: I
terned surface coating comprising; an aqueous color carrier comprising abindingage'ntand a cellulosiefibremnd an immiscible, non-aqueous colorcari'ier and-cellulosic 5 stantially five parts, by weight; of non-aqueousco1orlcar rier to six parts by. weight of aqueous color carrier;
3. A material "as claimedriniclaim 2 wlvereinithe nonaqueous colortandem-comprisesby weight,- substantially one part of linseedxoil, "one part ofzstand oil' ibree parts of= turpentine,= four parts kaolin, i.eightnparts'1:o'f zine o'xide, and three partsiof'cellulose -fibres 1 4. A material as claimed; in1claitn 3 whereinrth aque 1115 nus color, carrier comprises, by weight, one part of cel-.
References Cited int-he fileof this patent I UNITED STATES PATENTS 2,292,118 Guhl ;Aug. 4,1942 25 91,904 1 Zola A us -.1952 2,658,002 Schwefsky Nov. 3, 1 953 FOREIGN PATENTS, 182,163 Great Britain June 19, 1922 $628,131

Claims (1)

1. A COATING MATERIAL FOR PRODUCING TWO-COLORED, PATTERNED SURFACE COATING COMPRISING: AN AQUEOUS COLOR CARRIER COMPRISING A BINDING AGENT AND A CELLULOSIC FIBRE AND AN IMMISCIBLE, NON-AQUEOUS COLOR CARRIER AND CELLULOSIC FIBRES THEREIN.
US337423A 1952-02-16 1953-02-17 Coating composition for producing a two-colored patterned effect Expired - Lifetime US2795562A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH745916X 1952-02-16

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US2795562A true US2795562A (en) 1957-06-11

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US337423A Expired - Lifetime US2795562A (en) 1952-02-16 1953-02-17 Coating composition for producing a two-colored patterned effect

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US (1) US2795562A (en)
BE (1) BE517645A (en)
CH (2) CH302549A (en)
DE (1) DE1100212B (en)
FR (1) FR1070770A (en)
GB (1) GB745916A (en)
LU (1) LU32011A1 (en)
NL (1) NL91141C (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2964417A (en) * 1959-09-14 1960-12-13 Airkem Inc Multicolor coating compositions
US2990386A (en) * 1956-12-31 1961-06-27 Bee Chemical Co Liquid coating composition comprising a suspension of a liquid coating component in nitromethane
US3038869A (en) * 1959-08-28 1962-06-12 Goodyear Tire & Rubber Multi-color coating composition
US3058931A (en) * 1958-04-21 1962-10-16 Sherwin Williams Co Multicolor coating composition and method for preparation thereof
US3058932A (en) * 1958-04-21 1962-10-16 Sherwin Williams Co Multicolor coating composition and method for preparation thereof
US3069279A (en) * 1959-12-07 1962-12-18 Internat Paints Canada Ltd Coating composition
US3301760A (en) * 1962-06-11 1967-01-31 Max Factor & Co Process and compositions for mending fingernails
US3370024A (en) * 1966-02-16 1968-02-20 Zolatone Process Inc Multicolor coating composition and method of making and packaging same
US4009136A (en) * 1974-06-05 1977-02-22 Rohm And Haas Company Multicolor coating compositions

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8832964B2 (en) * 2010-06-02 2014-09-16 Robert J. Foxen System and method for recovering turpentine during wood material processing

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB182163A (en) * 1921-03-18 1922-06-19 Abel Boularan A decorative liquid preparation, and a process, for producing fancy or patterned effects on paper, parchment, wood, metal, and the like
US2292118A (en) * 1940-07-24 1942-08-04 Westinghouse Electric & Mfg Co Molded article
GB628131A (en) * 1945-11-16 1949-08-23 Karl Lonne Moller Nielsen Improved method of producing a multi-coloured wall decoration
US2591904A (en) * 1947-10-29 1952-04-08 John C Zola Coating compositions and preparation thereof
US2658002A (en) * 1950-08-02 1953-11-03 United Lacquer Mfg Corp Method of forming multicolor coating composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE420740C (en) * 1924-01-31 1925-10-30 Otto Heinrich Process for the production of roughened surfaces by means of a spraying process
CH203433A (en) * 1937-08-27 1939-03-15 Wildermann Rudolf Method for producing bright colors.

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB182163A (en) * 1921-03-18 1922-06-19 Abel Boularan A decorative liquid preparation, and a process, for producing fancy or patterned effects on paper, parchment, wood, metal, and the like
US2292118A (en) * 1940-07-24 1942-08-04 Westinghouse Electric & Mfg Co Molded article
GB628131A (en) * 1945-11-16 1949-08-23 Karl Lonne Moller Nielsen Improved method of producing a multi-coloured wall decoration
US2591904A (en) * 1947-10-29 1952-04-08 John C Zola Coating compositions and preparation thereof
US2658002A (en) * 1950-08-02 1953-11-03 United Lacquer Mfg Corp Method of forming multicolor coating composition

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2990386A (en) * 1956-12-31 1961-06-27 Bee Chemical Co Liquid coating composition comprising a suspension of a liquid coating component in nitromethane
US3058931A (en) * 1958-04-21 1962-10-16 Sherwin Williams Co Multicolor coating composition and method for preparation thereof
US3058932A (en) * 1958-04-21 1962-10-16 Sherwin Williams Co Multicolor coating composition and method for preparation thereof
US3038869A (en) * 1959-08-28 1962-06-12 Goodyear Tire & Rubber Multi-color coating composition
US2964417A (en) * 1959-09-14 1960-12-13 Airkem Inc Multicolor coating compositions
US3069279A (en) * 1959-12-07 1962-12-18 Internat Paints Canada Ltd Coating composition
US3301760A (en) * 1962-06-11 1967-01-31 Max Factor & Co Process and compositions for mending fingernails
US3370024A (en) * 1966-02-16 1968-02-20 Zolatone Process Inc Multicolor coating composition and method of making and packaging same
US4009136A (en) * 1974-06-05 1977-02-22 Rohm And Haas Company Multicolor coating compositions

Also Published As

Publication number Publication date
FR1070770A (en) 1954-08-12
DE1100212B (en) 1961-02-23
NL91141C (en)
LU32011A1 (en)
CH302549A (en) 1954-10-31
BE517645A (en)
GB745916A (en) 1956-03-07
CH313214A (en) 1956-03-31

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