US2787596A - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
- Publication number
- US2787596A US2787596A US371169A US37116953A US2787596A US 2787596 A US2787596 A US 2787596A US 371169 A US371169 A US 371169A US 37116953 A US37116953 A US 37116953A US 2787596 A US2787596 A US 2787596A
- Authority
- US
- United States
- Prior art keywords
- sulphate
- alkali metal
- range
- cleaning composition
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 21
- 238000004140 cleaning Methods 0.000 title claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 15
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 15
- 229910052783 alkali metal Inorganic materials 0.000 claims description 11
- -1 DI ETHYLENE GLYCOL ALKYL ETHERS Chemical class 0.000 claims description 10
- 238000009835 boiling Methods 0.000 claims description 10
- 239000002480 mineral oil Substances 0.000 claims description 10
- 235000010446 mineral oil Nutrition 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910001868 water Inorganic materials 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 9
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 8
- 239000001166 ammonium sulphate Substances 0.000 claims description 8
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 8
- 239000003079 shale oil Substances 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000001117 sulphuric acid Substances 0.000 claims description 4
- 235000011149 sulphuric acid Nutrition 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 3
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- VUQOIZPFYIVUKD-UHFFFAOYSA-N 4,4-dimethylcyclohexan-1-ol Chemical compound CC1(C)CCC(O)CC1 VUQOIZPFYIVUKD-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000006386 neutralization reaction Methods 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 description 11
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 10
- 239000012459 cleaning agent Substances 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- RAZWADXTNBRANC-UHFFFAOYSA-N 1,2-dimethylcyclohexan-1-ol Chemical compound CC1CCCCC1(C)O RAZWADXTNBRANC-UHFFFAOYSA-N 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 238000004821 distillation Methods 0.000 description 7
- 239000003350 kerosene Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000005108 dry cleaning Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical group CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
Definitions
- cleaning agents comprising an alkali metal alkyl sulphate, obtained by the sulphation of a distillation fraction of shale oil, together with water, a mineral oil and a high molecular weight alcohol, preferably cyclohexan-ol or a monoor dimethyl derivative thereof.
- the cleaning agent comprises an alkali metal alkyl sulphate, obtained by the sulphation of a distillation fraction of shale oil, together with water, a mineral oil and a diethylene glycol alkyl ether.
- an alkali metal alkyl sulphate which has been obtained by sulphation of a shale oil distillation fraction boiling within the range 180 to 330 C. More particularly it is preferred that the distillation fraction boils over the range 200 to 300 C.
- sodium alkyl sulphates are employed and a preferred material is obtained in the manner described in British Patent No. 657,598.
- the alkali metal alkyl sulphate is a sulphate obtained by reacting with sulphuric acid a distillation fraction of shale oil, said fraction boiling within the range 180 to 330 C. and thereafter neutralising the alkyl hydrogen sulphate so obtained by means of an alkali metal base, with or without simultaneous hydrolysis .of dialkyl sulphates.
- the sulphuric acid used is preferably of 90-98% strength, and the necessary quantity of acid is run into the oil over a period of 12 hours, with stirring, so as to prevent the temperature rising above 20 C. In general, it is preferred to work between limits of 2.8 volumes of acid per 100 volumes of feed, and 18 volumes of acid per 100 volumes of feed.
- the preferred high molecular weight alcohol is dimethyl-cyclohexanol.
- the preferred diethylene glycol alkyl ether is diethylene glycol butyl ether, for example, the material known as Butyl-Cellosolve.
- the nature of the mineral oil constituent of the composition may be varied according to the primary purpose for which the composition is intended, but in general petroleum fractions are preferred. Suitable fractions are kerosene cuts, kerosene aromatic extracts and white spirit fractions, these fractions being particularly suitable when the primary purposes of the compositions are respectively laundry cleaning agents, paint cleaners and dry cleaning aids.
- constituents of the cleaning agents of this invention are employed within the following ranges of proportions, based on the weight of the cleaning agent:
- compositions may be obtained containing the metal alkyl sulphate, water and mineral oil, in a single liquid phase, under wider ranges of relative proportions than would otherwise be the case. It has been found that by the use, as a further constituent of the compositions, of an ammoniurn or alkali metal carbonate or sulphate, the quantity of said alcohol or ether, required to form a single liquid phase product, is materially reduced.
- compositions comprising said metal alkyl sulphates, Water, a mineral oil, an alcohol or ether of high molecular weight and an ammonium or alkali metal salt, said salt being a sulphate or carbonate.
- said salt constitutes up to 15% by weight of the cleaning agent.
- Preferred alkali metal salts are sodium sulphate and sodium carbonate.
- compositions contain, as the sodium alkyl sulphate solution, a material obtained by sulphation of a shale oil distillation fraction and dimethylcyclohexanol.
- EXAMPLE 1 A composition suitable for laundry use and for the cleaning of rain-proof garments:
- EXAMPLE 4 A detergent for use on metal surfaces, as in garage use, or on road surfaces, as in the cleaning of aircraft runways:
- Paint cleaner for use in the cleaning of vehicles:
- EXAMPLE 6 This example illustrates the amounts of a high molecular weight alcohol required .to form a single phase liquid cleaning agent, according to the invention (a) when employing ammonium sulphate (together with sodium suiphate contained in the sodium alkyl sulphate solution), (b) in the absence of ammonium sulphate.
- a cleaning composition consisting essentially of the following ingredients by weight:
- alkali metal alkyl sulphate obtained by reacting a shale oil fraction boiling within the range of ISO-330 C. with sulphuric acid of 90-98% strength at a temperature under C. followed by a neutralization of the resulting alkyl hydrogen sulphate by treatment with an alkali metal base About 30-70 Percent A mineral oil boiling within the range of about 150-275 C "About A high molecular weight oxygen-containing organic solvent selected from the grouplconsisting of diethylene glycol alkyl others, cyclohexanol and monoand di-methyl cyclohexanol' About 1-10 An ammonium salt selected from the group consisting of ammonium carbonate and ammonium sulphate About 5-l5 Water Up to about 50 2.
- a cleaning composition as specified in claim 1 in which the oxygencontaining organic solvent is diethylenc glycol butyl ether.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB328396X | 1952-08-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2787596A true US2787596A (en) | 1957-04-02 |
Family
ID=10344752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US371169A Expired - Lifetime US2787596A (en) | 1952-08-12 | 1953-07-29 | Cleaning composition |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2787596A (en(2012)) |
| BE (1) | BE522094A (en(2012)) |
| CH (1) | CH328396A (en(2012)) |
| DE (1) | DE1098661B (en(2012)) |
| GB (1) | GB741478A (en(2012)) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2901433A (en) * | 1953-07-17 | 1959-08-25 | Pennsalt Chemicals Corp | Cleaning composition |
| US3186947A (en) * | 1958-06-16 | 1965-06-01 | Kelite Corp | Composition for cleaning hard surfaces |
| US3533955A (en) * | 1965-06-15 | 1970-10-13 | Lever Brothers Ltd | Two-phase liquid detergent compositions |
| WO2003006733A1 (en) * | 2001-07-10 | 2003-01-23 | The Procter & Gamble Company | Compositions and methods for removal of incidental soils from fabric articles |
| US20040266643A1 (en) * | 2003-06-27 | 2004-12-30 | The Procter & Gamble Company | Fabric article treatment composition for use in a lipophilic fluid system |
| US20050000028A1 (en) * | 2003-06-27 | 2005-01-06 | Baker Keith Homer | Method for uniform deposition of fabric care actives in a non-aqueous fabric treatment system |
| US20050000030A1 (en) * | 2003-06-27 | 2005-01-06 | Dupont Jeffrey Scott | Fabric care compositions for lipophilic fluid systems |
| US20050003981A1 (en) * | 2003-06-27 | 2005-01-06 | The Procter & Gamble Company | Fabric care composition and method for using same |
| US20050009723A1 (en) * | 2003-06-27 | 2005-01-13 | The Procter & Gamble Company | Surfactant system for use in a lipophilic fluid |
| US20050129478A1 (en) * | 2003-08-08 | 2005-06-16 | Toles Orville L. | Storage apparatus |
| WO2006084208A3 (en) * | 2005-02-04 | 2006-11-09 | Procter & Gamble | Use of water structurants to provide fabric care benefits in a non-aqueous fabric treatment system |
| US20070056119A1 (en) * | 2003-06-27 | 2007-03-15 | Gardner Robb R | Method for treating hydrophilic stains in a lipophlic fluid system |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2355591A (en) * | 1941-01-14 | 1944-08-08 | Union Oil Co | Flushing oils |
| US2531166A (en) * | 1947-11-08 | 1950-11-21 | California Research Corp | Detergent concentrate |
| GB657598A (en) * | 1946-07-19 | 1951-09-19 | Anglo Iranian Oil Co Ltd | Improvements in or relating to the production of wetting and detergent materials |
| US2708185A (en) * | 1948-09-15 | 1955-05-10 | Scottish Oils Ltd | Detergent compositions |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE633517C (de) * | 1926-03-07 | 1936-07-29 | Chem Fab Pott & Co G M B H | Emulgierungs-, Netz- und Loesungsmittel |
-
0
- BE BE522094D patent/BE522094A/xx unknown
-
1952
- 1952-08-12 GB GB20283/52A patent/GB741478A/en not_active Expired
-
1953
- 1953-07-29 US US371169A patent/US2787596A/en not_active Expired - Lifetime
- 1953-08-01 CH CH328396D patent/CH328396A/de unknown
- 1953-08-06 DE DES34701A patent/DE1098661B/de active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2355591A (en) * | 1941-01-14 | 1944-08-08 | Union Oil Co | Flushing oils |
| GB657598A (en) * | 1946-07-19 | 1951-09-19 | Anglo Iranian Oil Co Ltd | Improvements in or relating to the production of wetting and detergent materials |
| US2531166A (en) * | 1947-11-08 | 1950-11-21 | California Research Corp | Detergent concentrate |
| US2708185A (en) * | 1948-09-15 | 1955-05-10 | Scottish Oils Ltd | Detergent compositions |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2901433A (en) * | 1953-07-17 | 1959-08-25 | Pennsalt Chemicals Corp | Cleaning composition |
| US3186947A (en) * | 1958-06-16 | 1965-06-01 | Kelite Corp | Composition for cleaning hard surfaces |
| US3533955A (en) * | 1965-06-15 | 1970-10-13 | Lever Brothers Ltd | Two-phase liquid detergent compositions |
| WO2003006733A1 (en) * | 2001-07-10 | 2003-01-23 | The Procter & Gamble Company | Compositions and methods for removal of incidental soils from fabric articles |
| US20030060396A1 (en) * | 2001-07-10 | 2003-03-27 | Deak John Christopher | Compositions and methods for removal of incidental soils from fabric articles |
| US6987086B2 (en) | 2001-07-10 | 2006-01-17 | Procter & Gamble Company | Compositions and methods for removal of incidental soils from fabric articles |
| US20050009723A1 (en) * | 2003-06-27 | 2005-01-13 | The Procter & Gamble Company | Surfactant system for use in a lipophilic fluid |
| US20060213015A1 (en) * | 2003-06-27 | 2006-09-28 | Gardner Robb R | Method for treating hydrophilic stains in a lipophilic fluid system |
| US20050000027A1 (en) * | 2003-06-27 | 2005-01-06 | Baker Keith Homer | Delivery system for uniform deposition of fabric care actives in a non-aqueous fabric treatment system |
| US20050003981A1 (en) * | 2003-06-27 | 2005-01-06 | The Procter & Gamble Company | Fabric care composition and method for using same |
| US20050000028A1 (en) * | 2003-06-27 | 2005-01-06 | Baker Keith Homer | Method for uniform deposition of fabric care actives in a non-aqueous fabric treatment system |
| US8148315B2 (en) | 2003-06-27 | 2012-04-03 | The Procter & Gamble Company | Method for uniform deposition of fabric care actives in a non-aqueous fabric treatment system |
| US20040266643A1 (en) * | 2003-06-27 | 2004-12-30 | The Procter & Gamble Company | Fabric article treatment composition for use in a lipophilic fluid system |
| US20050000030A1 (en) * | 2003-06-27 | 2005-01-06 | Dupont Jeffrey Scott | Fabric care compositions for lipophilic fluid systems |
| US7462589B2 (en) | 2003-06-27 | 2008-12-09 | The Procter & Gamble Company | Delivery system for uniform deposition of fabric care actives in a non-aqueous fabric treatment system |
| US20070056119A1 (en) * | 2003-06-27 | 2007-03-15 | Gardner Robb R | Method for treating hydrophilic stains in a lipophlic fluid system |
| US7202202B2 (en) | 2003-06-27 | 2007-04-10 | The Procter & Gamble Company | Consumable detergent composition for use in a lipophilic fluid |
| US7318843B2 (en) | 2003-06-27 | 2008-01-15 | The Procter & Gamble Company | Fabric care composition and method for using same |
| US20050129478A1 (en) * | 2003-08-08 | 2005-06-16 | Toles Orville L. | Storage apparatus |
| WO2006084208A3 (en) * | 2005-02-04 | 2006-11-09 | Procter & Gamble | Use of water structurants to provide fabric care benefits in a non-aqueous fabric treatment system |
Also Published As
| Publication number | Publication date |
|---|---|
| GB741478A (en) | 1955-12-07 |
| CH328396A (de) | 1958-03-15 |
| DE1098661B (de) | 1961-02-02 |
| BE522094A (en(2012)) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2787596A (en) | Cleaning composition | |
| US3027325A (en) | Oil-soluble calcium carbonate dispersions and method of preparation | |
| US3929680A (en) | Liquid detergent composition | |
| US4606840A (en) | Aqueous composition for the dispersion of hydrophobic substances, particularly applicable to the cleaning of objects soiled by paint or the like | |
| GB645129A (en) | Detergents | |
| US4235758A (en) | Clear liquid detergent composition containing MgABS and alkyl polyether sulphates | |
| GB671380A (en) | Improvements in and relating to fuel oils | |
| US2901433A (en) | Cleaning composition | |
| JPS59135292A (ja) | 液体洗剤組成物 | |
| US20150166912A1 (en) | Process for preparing a branched ester and use thereof | |
| EP0011715B1 (de) | Flüssiges, kältestabiles Zwei-Komponenten-Waschmittel und Waschverfahren | |
| US4752411A (en) | Liquid composition for cleaning hard surfaces | |
| FI63058B (fi) | Flytande buffrad detergentkomposition samt foerfarande foer des framstaellning | |
| EP0148517B1 (en) | Use of olefin sulphonate compositions in enhanced oil recovery processes | |
| GB770310A (en) | Compositions which contain surface-active components | |
| US2036469A (en) | Petroleum sulphonic acids and sul | |
| US1919125A (en) | Metal cutting oil | |
| EP0129987A1 (en) | Cleaning compositions | |
| US2787594A (en) | Spinning oil composition | |
| US2846359A (en) | Preventing loss of color on aging by treating with alcohol and alkali | |
| US3686099A (en) | Detergent | |
| US2396718A (en) | Emulsification of vegetable and animal oils | |
| US2607741A (en) | Offiol | |
| US2089154A (en) | Sulphonated mixed ketones | |
| US2161857A (en) | Branched chain octyl sulphates |