GB671380A - Improvements in and relating to fuel oils - Google Patents

Improvements in and relating to fuel oils

Info

Publication number
GB671380A
GB671380A GB8333/49A GB833349A GB671380A GB 671380 A GB671380 A GB 671380A GB 8333/49 A GB8333/49 A GB 8333/49A GB 833349 A GB833349 A GB 833349A GB 671380 A GB671380 A GB 671380A
Authority
GB
United Kingdom
Prior art keywords
oil
oils
hydrocarbon
sulphide
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8333/49A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB671380A publication Critical patent/GB671380A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/189—Carboxylic acids; metal salts thereof having at least one carboxyl group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2406—Organic compounds containing sulfur, selenium and/or tellurium mercaptans; hydrocarbon sulfides
    • C10L1/2412—Organic compounds containing sulfur, selenium and/or tellurium mercaptans; hydrocarbon sulfides sulfur bond to an aromatic radical
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Oil-soluble petroleum sulphonates are derived from non-paraffinic oils, particularly naphthenic oils, by sulphonation with sulphuric acid, oleum, chlorosulphonic acid, sulphur trioxide or mixtures thereof, removing the sludge and neutralizing the acid-treated oil with sodium hydroxide or other alkali hydroxide such as potassium, lithium, rubidium or casium hydroxide. The alkali solution formed is extracted with alcohol and the alcohol layer distilled to recover the sulphonates, which may be purified by mixing with a light hydrocarbon, such as a highly paraffinic hydrocarbon having a boiling range of 100-260 DEG F. and distilling the hydrocarbon layer; alternatively, the sulphonic acids may be separated from the acid sludge, treated with the aqueous alcohol, the alcohol solution mixed with the paraffinic hydrocarbon and the mixture then neutralized. Specifications 587,624, [Group III], and 613,424 and U.S.A. Specifications 2,236,933, 2,334,532, 2,357,866, 2,368,452, 2,395,713, 2,406,763, 2,413,199, 2,414,773 and 2,416,397 are referred to.ALSO:A non-clogging fuel oil comprises a cracked hydrocarbon fuel oil and an oil-soluble alkali metal salt of a petroleum sulphonic acid derived from a non-paraffinic petroleum stock, i.e. a naphthenic oil. The fuel oils used may have a boiling range of 340 DEG F to 700 DEG F and may be thermally or catalytically cracked hydrocarbon oils or mixtures of these oils with straight-run fuel oils. Detergents and solutizers may be added to the composition, and also foam inhibitors such as dimethyl silicone, fluoro organic compounds and salts of the alkyl esters of alkylene diphosphates. Detergents specified are the alkali, alkaline earth, heavy metal and organic nitrogen base salts of organic acids various types of which are mentioned, including salts of aromatic and hydroxyaromatic carboxylic acids and aliphatic acids, carbamates, thiocarbamates and xanthates; phenates and alcoholates may also be used. Specific detergents mentioned are barium tertiaryoctyl phenol sulphide and disulphide, barium di-tertiary-amyl phenol sulphide, calcium iso-hexadecyl phenol sulphide, magnesium tertiary-amyl phenol sulphide, cobalt tertiary-amyl phenol sulphide, barium dodecyl salicylate sulphide, the sulphide of the barium salt of the amyl ester of p-hydroxy dithiobenzoic acid and calcium octyl phenol selenide. Neutral or basic salts may be used. Solutizers mentioned are the glycol-ethers and alcohols such as the glycols, examples of which are given. The fuel oil may contain from 0.005-0.01 per cent of the petroleum sulphonate, 0-0.005 per cent of the detergent and 0-0.025 per cent of solutizer; a concentrate of these ingredients in the oil may also be made up and added to more fuel oil to obtain the above proportions. Specifications 587,624 and 613,424 and U.S.A. Specifications 2,236,933, 2,334,532, 2,357,866, 2,368,452, 2,395,713, 2,406,763, 2,413,199, 2,414,773 and 2,416,397 are referred to. The Specification as open to inspection under Sect. 91, refers also to the use of hydrocarbon fuel oils in general and to the use of naphthenates as detergents. This subject-matter does not appear in the Specification as accepted.
GB8333/49A 1948-03-29 1949-03-28 Improvements in and relating to fuel oils Expired GB671380A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US17804A US2527987A (en) 1948-03-29 1948-03-29 Fuel oil composition

Publications (1)

Publication Number Publication Date
GB671380A true GB671380A (en) 1952-05-07

Family

ID=21784625

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8333/49A Expired GB671380A (en) 1948-03-29 1949-03-28 Improvements in and relating to fuel oils

Country Status (2)

Country Link
US (1) US2527987A (en)
GB (1) GB671380A (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2659666A (en) * 1949-11-10 1953-11-17 Standard Oil Developoment Comp Stabilizer for residual oils
US2678262A (en) * 1950-03-28 1954-05-11 Gulf Research Development Co Stable fuel oil compositions
US2723907A (en) * 1950-11-13 1955-11-15 Exxon Research Engineering Co Hydrocarbon fuel oil stabilization
US2684292A (en) * 1951-03-13 1954-07-20 Shell Dev Fuel oil composition
US2739051A (en) * 1951-03-31 1956-03-20 Exxon Research Engineering Co Production of stable fuel oil
BE511937A (en) * 1951-06-07
US2736641A (en) * 1952-02-01 1956-02-28 Union Oil Co Fuel oil additive
GB757086A (en) * 1952-07-16 1956-09-12 Socony Mobil Oil Co Fuel oil composition
BE523748A (en) * 1952-11-01
DE1111875B (en) * 1953-05-15 1961-07-27 Daimler Benz Ag Process for the preparation of liquid fuels for combustion in internal combustion engines and combustion plants
DE1111874B (en) * 1953-05-15 1961-07-27 Daimler Benz Ag Process for the preparation of liquid fuels for combustion in internal combustion engines and combustion plants
DE1092725B (en) * 1953-05-15 1960-11-10 Daimler Benz Ag Process for the preparation of liquid fuels for combustion in internal combustion engines and combustion plants
US2843467A (en) * 1954-05-10 1958-07-15 Gulf Research Development Co Fuel oils
US2852353A (en) * 1954-06-04 1958-09-16 Gulf Oil Corp Distillate fuel oils inhibited against haze formation
US2929695A (en) * 1954-09-27 1960-03-22 Standard Oil Co Boric acid-diol-alcohol additive and liquid leaded motor fuel containing same
US2860040A (en) * 1955-05-25 1958-11-11 Exxon Research Engineering Co Petroleum distillate fuels
US2952121A (en) * 1955-09-26 1960-09-13 Phillips Petroleum Co Prevention of filter plugging utilizing an improved jet engine fuel
BE556943A (en) * 1956-05-03
US3109815A (en) * 1958-07-30 1963-11-05 Standard Oil Co Radiation-stable and thermally stable oils
US3052600A (en) * 1960-06-15 1962-09-04 American Cyanamid Co Stabilized organic phosphate pesticidal compositions in fuel oil
US3120429A (en) * 1961-05-01 1964-02-04 Lubrizol Corp Lubricating compositions for two-cycle internal combustion engines
US3347633A (en) * 1962-12-31 1967-10-17 Phillips Petroleum Co Carbon black manufacture
JPS61111396A (en) * 1984-11-05 1986-05-29 Honda Motor Co Ltd Fuel composition for spark-ignition engine
US4744800A (en) * 1985-01-18 1988-05-17 Nippon Oil Co., Ltd. Gasoline compositions for automotive vehicles
US4659338A (en) * 1985-08-16 1987-04-21 The Lubrizol Corporation Fuel compositions for lessening valve seat recession
US4690687A (en) * 1985-08-16 1987-09-01 The Lubrizol Corporation Fuel products comprising a lead scavenger

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2454825A (en) * 1948-11-30 Viscosity reduction of petroleum
US2125305A (en) * 1936-02-14 1938-08-02 Sonneborn Sons Inc L Lubricating oil
US2362292A (en) * 1939-12-30 1944-11-07 Standard Oil Dev Co Lubricant
US2294145A (en) * 1940-11-30 1942-08-25 Standard Oil Dev Co Method of improving a mineral oil as to its foaming properties
US2361804A (en) * 1941-02-18 1944-10-31 Union Oil Co Lubricating composition
US2336074A (en) * 1942-05-16 1943-12-07 American Cyanamid Co Lubricating oil
US2454828A (en) * 1947-07-01 1948-11-30 Sonneborn Sons Inc L Viscosity reduction of petroleum mahogany sulfonate hydrocarbon solutions

Also Published As

Publication number Publication date
US2527987A (en) 1950-10-31

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