GB671380A - Improvements in and relating to fuel oils - Google Patents
Improvements in and relating to fuel oilsInfo
- Publication number
- GB671380A GB671380A GB8333/49A GB833349A GB671380A GB 671380 A GB671380 A GB 671380A GB 8333/49 A GB8333/49 A GB 8333/49A GB 833349 A GB833349 A GB 833349A GB 671380 A GB671380 A GB 671380A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- oils
- hydrocarbon
- sulphide
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/189—Carboxylic acids; metal salts thereof having at least one carboxyl group bound to an aromatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2406—Organic compounds containing sulfur, selenium and/or tellurium mercaptans; hydrocarbon sulfides
- C10L1/2412—Organic compounds containing sulfur, selenium and/or tellurium mercaptans; hydrocarbon sulfides sulfur bond to an aromatic radical
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
- C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
Oil-soluble petroleum sulphonates are derived from non-paraffinic oils, particularly naphthenic oils, by sulphonation with sulphuric acid, oleum, chlorosulphonic acid, sulphur trioxide or mixtures thereof, removing the sludge and neutralizing the acid-treated oil with sodium hydroxide or other alkali hydroxide such as potassium, lithium, rubidium or casium hydroxide. The alkali solution formed is extracted with alcohol and the alcohol layer distilled to recover the sulphonates, which may be purified by mixing with a light hydrocarbon, such as a highly paraffinic hydrocarbon having a boiling range of 100-260 DEG F. and distilling the hydrocarbon layer; alternatively, the sulphonic acids may be separated from the acid sludge, treated with the aqueous alcohol, the alcohol solution mixed with the paraffinic hydrocarbon and the mixture then neutralized. Specifications 587,624, [Group III], and 613,424 and U.S.A. Specifications 2,236,933, 2,334,532, 2,357,866, 2,368,452, 2,395,713, 2,406,763, 2,413,199, 2,414,773 and 2,416,397 are referred to.ALSO:A non-clogging fuel oil comprises a cracked hydrocarbon fuel oil and an oil-soluble alkali metal salt of a petroleum sulphonic acid derived from a non-paraffinic petroleum stock, i.e. a naphthenic oil. The fuel oils used may have a boiling range of 340 DEG F to 700 DEG F and may be thermally or catalytically cracked hydrocarbon oils or mixtures of these oils with straight-run fuel oils. Detergents and solutizers may be added to the composition, and also foam inhibitors such as dimethyl silicone, fluoro organic compounds and salts of the alkyl esters of alkylene diphosphates. Detergents specified are the alkali, alkaline earth, heavy metal and organic nitrogen base salts of organic acids various types of which are mentioned, including salts of aromatic and hydroxyaromatic carboxylic acids and aliphatic acids, carbamates, thiocarbamates and xanthates; phenates and alcoholates may also be used. Specific detergents mentioned are barium tertiaryoctyl phenol sulphide and disulphide, barium di-tertiary-amyl phenol sulphide, calcium iso-hexadecyl phenol sulphide, magnesium tertiary-amyl phenol sulphide, cobalt tertiary-amyl phenol sulphide, barium dodecyl salicylate sulphide, the sulphide of the barium salt of the amyl ester of p-hydroxy dithiobenzoic acid and calcium octyl phenol selenide. Neutral or basic salts may be used. Solutizers mentioned are the glycol-ethers and alcohols such as the glycols, examples of which are given. The fuel oil may contain from 0.005-0.01 per cent of the petroleum sulphonate, 0-0.005 per cent of the detergent and 0-0.025 per cent of solutizer; a concentrate of these ingredients in the oil may also be made up and added to more fuel oil to obtain the above proportions. Specifications 587,624 and 613,424 and U.S.A. Specifications 2,236,933, 2,334,532, 2,357,866, 2,368,452, 2,395,713, 2,406,763, 2,413,199, 2,414,773 and 2,416,397 are referred to. The Specification as open to inspection under Sect. 91, refers also to the use of hydrocarbon fuel oils in general and to the use of naphthenates as detergents. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17804A US2527987A (en) | 1948-03-29 | 1948-03-29 | Fuel oil composition |
Publications (1)
Publication Number | Publication Date |
---|---|
GB671380A true GB671380A (en) | 1952-05-07 |
Family
ID=21784625
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8333/49A Expired GB671380A (en) | 1948-03-29 | 1949-03-28 | Improvements in and relating to fuel oils |
Country Status (2)
Country | Link |
---|---|
US (1) | US2527987A (en) |
GB (1) | GB671380A (en) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2659666A (en) * | 1949-11-10 | 1953-11-17 | Standard Oil Developoment Comp | Stabilizer for residual oils |
US2678262A (en) * | 1950-03-28 | 1954-05-11 | Gulf Research Development Co | Stable fuel oil compositions |
US2723907A (en) * | 1950-11-13 | 1955-11-15 | Exxon Research Engineering Co | Hydrocarbon fuel oil stabilization |
US2684292A (en) * | 1951-03-13 | 1954-07-20 | Shell Dev | Fuel oil composition |
US2739051A (en) * | 1951-03-31 | 1956-03-20 | Exxon Research Engineering Co | Production of stable fuel oil |
BE511937A (en) * | 1951-06-07 | |||
US2736641A (en) * | 1952-02-01 | 1956-02-28 | Union Oil Co | Fuel oil additive |
GB757086A (en) * | 1952-07-16 | 1956-09-12 | Socony Mobil Oil Co | Fuel oil composition |
BE523748A (en) * | 1952-11-01 | |||
DE1111875B (en) * | 1953-05-15 | 1961-07-27 | Daimler Benz Ag | Process for the preparation of liquid fuels for combustion in internal combustion engines and combustion plants |
DE1111874B (en) * | 1953-05-15 | 1961-07-27 | Daimler Benz Ag | Process for the preparation of liquid fuels for combustion in internal combustion engines and combustion plants |
DE1092725B (en) * | 1953-05-15 | 1960-11-10 | Daimler Benz Ag | Process for the preparation of liquid fuels for combustion in internal combustion engines and combustion plants |
US2843467A (en) * | 1954-05-10 | 1958-07-15 | Gulf Research Development Co | Fuel oils |
US2852353A (en) * | 1954-06-04 | 1958-09-16 | Gulf Oil Corp | Distillate fuel oils inhibited against haze formation |
US2929695A (en) * | 1954-09-27 | 1960-03-22 | Standard Oil Co | Boric acid-diol-alcohol additive and liquid leaded motor fuel containing same |
US2860040A (en) * | 1955-05-25 | 1958-11-11 | Exxon Research Engineering Co | Petroleum distillate fuels |
US2952121A (en) * | 1955-09-26 | 1960-09-13 | Phillips Petroleum Co | Prevention of filter plugging utilizing an improved jet engine fuel |
BE556943A (en) * | 1956-05-03 | |||
US3109815A (en) * | 1958-07-30 | 1963-11-05 | Standard Oil Co | Radiation-stable and thermally stable oils |
US3052600A (en) * | 1960-06-15 | 1962-09-04 | American Cyanamid Co | Stabilized organic phosphate pesticidal compositions in fuel oil |
US3120429A (en) * | 1961-05-01 | 1964-02-04 | Lubrizol Corp | Lubricating compositions for two-cycle internal combustion engines |
US3347633A (en) * | 1962-12-31 | 1967-10-17 | Phillips Petroleum Co | Carbon black manufacture |
JPS61111396A (en) * | 1984-11-05 | 1986-05-29 | Honda Motor Co Ltd | Fuel composition for spark-ignition engine |
US4744800A (en) * | 1985-01-18 | 1988-05-17 | Nippon Oil Co., Ltd. | Gasoline compositions for automotive vehicles |
US4659338A (en) * | 1985-08-16 | 1987-04-21 | The Lubrizol Corporation | Fuel compositions for lessening valve seat recession |
US4690687A (en) * | 1985-08-16 | 1987-09-01 | The Lubrizol Corporation | Fuel products comprising a lead scavenger |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2454825A (en) * | 1948-11-30 | Viscosity reduction of petroleum | ||
US2125305A (en) * | 1936-02-14 | 1938-08-02 | Sonneborn Sons Inc L | Lubricating oil |
US2362292A (en) * | 1939-12-30 | 1944-11-07 | Standard Oil Dev Co | Lubricant |
US2294145A (en) * | 1940-11-30 | 1942-08-25 | Standard Oil Dev Co | Method of improving a mineral oil as to its foaming properties |
US2361804A (en) * | 1941-02-18 | 1944-10-31 | Union Oil Co | Lubricating composition |
US2336074A (en) * | 1942-05-16 | 1943-12-07 | American Cyanamid Co | Lubricating oil |
US2454828A (en) * | 1947-07-01 | 1948-11-30 | Sonneborn Sons Inc L | Viscosity reduction of petroleum mahogany sulfonate hydrocarbon solutions |
-
1948
- 1948-03-29 US US17804A patent/US2527987A/en not_active Expired - Lifetime
-
1949
- 1949-03-28 GB GB8333/49A patent/GB671380A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
US2527987A (en) | 1950-10-31 |
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